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221.
The performance of the self-exciting threshold autoregressive moving average model in forecasting river flow data is investigated. Multi-step forecasts of two daily time series are generated through three different nonlinear predictors. The model adequacy to capture the main features of the data under study and its forecasting performance are analysed and discussed. 相似文献
222.
Janaina L. Oliveira Alessandra Eugênio Júlio C. Rodrigues de Azevedo Jorge Nozaki 《洁净——土壤、空气、水》2006,34(4):383-388
The sediment of Lagoa dos Patos‐MS, Brazil, was investigated to verify the influence of metal sulfides and oxyhydroxides of Mn and Fe on the heavy metal availability. The spectrophotometric method of methylene blue was used, with 8 interlinked tubes containing the samples with SnCl2, where N2 was introduced to release the H2S extracted with 6.0 mol L–1 HCl, and trapped in 0.05 M NaOH solution. The influence of SO42–, Mn(IV) and Fe(III) oxyhydroxides was investigated with samples constituted by a mixture of MnO2; Na2SO4; FeCl3, and sediments. The presence of SnCl2 was very important to avoid the interferences of iron and manganese oxyhydroxides. The method of standard addition was applied and the efficiency was (100.8 ± 9.4)%. The ratio among the quantities of metals potentially available and the acid volatile sulfide (AVS) indicate that the system presents small metals availability to the benthic community, by the existence of sulfide capable to immobilize the metal as insoluble sulfide. 相似文献
223.
Intercomparison of Boron Isotope and Concentration Measurements. Part II: Evaluation of Results 总被引:3,自引:1,他引:3
Roberto Gonfiantini Sonia Tonarini Manfred Grning Alessandra Adorni‐Braccesi Assad S. Al‐Ammar Marcus Astner Sebastien Bchler Ramon M. Barnes Randy L. Bassett Alain Cocherie Annette Deyhle Andrea Dini Giorgio Ferrara Jrme Gaillardet Judith Grimm Catherine Guerrot Urs Krhenbühl Graham Layne Damien Lemarchand Anette Meixner D. Jack Northington Maddalena Pennisi Eva Reitznerov Ilia Rodushkin Naoji Sugiura Regina Surberg Sabine Tonn Michael Wiedenbeck Samuel Wunderli Yingkai Xiao Thomas Zack 《Geostandards and Geoanalytical Research》2003,27(1):41-57
The Istituto di Geoscienze e Georisorse (IGG), on behalf and with the support of the International Atomic Energy Agency (IAEA), prepared eight geological materials (three natural waters and five rocks and minerals), intended for a blind interlaboratory comparison of measurements of boron isotopic composition and concentration. The materials were distributed to twenty seven laboratories - virtually all those performing geochemical boron isotope analyses in the world -which agreed to participate in the intercomparison exercise. Only fifteen laboratories, however, ultimately submitted the isotopic and/or concentration results they obtained on the intercomparison materials. The results demonstrate that interlaboratory reproducibility is not well reflected by the precision values reported by the individual laboratories and this observation holds true for both boron concentration and isotopic composition. The reasons for the discrepancies include fractionations due to the chemical matrix of materials, relative shift of the zero position on the δ11 B scale and a lack of well characterized materials for calibrating absolute boron content measurements. The intercomparison materials are now available at the IAEA (solid materials) and IGG (waters) for future distribution. 相似文献
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Sara Picone Francesca Alvisi Enrico Dinelli Caterina Morigi Alessandra Negri Mariangela Ravaioli Carmela Vaccaro 《第四纪科学杂志》2008,23(5):489-501
Sedimentological, geochemical and micropalaeontological data from sediment cores in the northwestern Adriatic Sea were obtained to reconstruct the stratigraphic framework and palaeogeographic setting during the last post‐glacial sea‐level rise (14000–6000 yr BP). Four lithostratigraphic units were identified: (a) distal plain deposits (>14000 yr BP), submerged during the first phases of marine ingression; (b) coastal lagoon system; (c) barrier‐lagoon system, which is dated back to between 10019 ± 61 and 10228 ± 174 cal. yr BP from 14C dating on peat and shell remains; (d) marine prodelta deposits (<5500 yr BP). Geochemical data allow the identification of three distinct sediment sources: River Po, River Adige and Eastern Alpine rivers characterised by decreasing Ni/Mg ratios (50–70, 8–15 and 5–10, respectively) and Ba/Al ratios of 45–55, 55–65 and 35–45, respectively. The three sources display different relative abundances in time. During the Lateglacial, the Po is the main sediment source for the southern cores, whereas the Eastern Alps and the River Adige are the main sediment sources for the northern cores. This suggests a northern position of the Po River bed compared to previous studies. Coastal drowning led to a homogenization of the provenance signal within the sediments. Only after the marine transgression does a River Po signal appear in the northern cores. At the same time, in the southern cores the signal of Eastern Alpine rivers becomes stronger. Transgressive barrier‐lagoon and recent sediments do not display a predominant signal for provenance indicators. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
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Anna Breda Donatella Mellere Francesco Massari Alessandra Asioli 《Sedimentary Geology》2009,219(1-4):58-76
Overfilled incised valleys develop when the rate of sediment supply outpaces the rate of accommodation. An overfilled incised valley presents simple or compound valley-fill architecture, depending on the depth of the valley incision, compared with the height reached by the following sea-level rise.The Ventimiglia incised valley, exposed on the Ligurian coast, north-western Mediterranean margin, presents a spectacular example of compound incised-valley fill, developed in perennial “overfill” conditions. The valley was subaerially incised during the Messinian Salinity Crisis and rapidly flooded by the sea at the beginning of Pliocene, then filled by eleven coarse-grained Gilbert-type deltas during Early–Middle Pliocene time.The basal Messinian unconformity is locally paved with subaerial scree breccias and bioclastic shallow-marine sandstones, and blanketed by bathyal marls. These deposits record the lowstand, transgressive and early-highstand systems tracts of the first valley-fill sequence. The subsequent progradation of Gilbert-type deltas occurred in four stages, or depositional sequences, separated by transgressive marine-marl intervals. Within each depositional sequence, the deltaic bodies display offlapping architecture, recording falling shoreline trajectory, downward shifts in facies, and overall forced regression. The water depth and accommodation in the inundated coastal valley was gradually decreasing with time. The reduced accommodation allowed the youngest deltas to prograde out to the shelf edge, triggering mass collapses and subsequent filling into the newly created slump scars. Some of the deltas probably acted as “canyon-perched deltas” and supplied sediment to the deep-water slope and floor of the Ligurian Basin.The vertical stacking of Gilbert-type deltas is usually attributed, in tectonically active basins, to fault-related subsidence pulses. In Ventimiglia, the accommodation was created by high-frequency eustatic sea-level rises that, probably accompanied by climate controlled reductions in sediment supply, temporarily outpaced uplift, leading to the development of multiple cycles of infill. 相似文献
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229.
Assuming that similar organic components as in comet 81P/Wild 2 are present in incoming meteoroids, we try to anticipate the
observable signatures they would produce for meteor detection techniques. In this analysis we consider the elemental and organic
components in cometary aggregate interplanetary dust particles and laboratory analyses of inter- and circumstellar carbon
dust analogues. On the basis of our analysis we submit that (semi) quantitative measurements of H, N and C produced during
meteor ablation will open an entire new aspect to using meteoroids as tracers of these volatile element abundances in active
comets and their contributions to the mesospheric metal layers. 相似文献
230.