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991.
Mark J. Nilges Yuanming Pan Rudolf I. Mashkovtsev 《Physics and Chemistry of Minerals》2009,36(2):61-73
The X- and W-band single-crystal electron paramagnetic resonance spectra of an electron-irradiated natural quartz permit quantitative
analysis of a 29Si hyperfine structure (A ~12.6 MHz) and an 27Al hyperfine structure (A ≤ 0.8 MHz) for a previously reported hole-like center. The 29Si hyperfine structure arises from interaction with two equivalent Si atoms and is characterized by the direction of the unique
A axis close to a Si–O bond direction. The 27Al hyperfine structure, confirmed by pulsed electron nuclear double resonance and electron spin echo envelope modulation spectra,
is characterized by the unique A axis approximately along a twofold symmetry axis. These 29Si and 27Al hyperfine data, together with published theoretical results on peroxy radicals in SiO2 as well as our own density functional theory (DFT) calculations on model peroxy centers, suggest this hole-like center to
have the unpaired spin on a pair of oxygen atoms linked to two symmetrically equivalent Si atoms and a substitutional Al3+ ion across the c-axis channel, a first peroxy radical in quartz. The nuclear quadrupole matrix P also suggests that the Al3+ ion corresponds closely to the diamagnetic precursor to the [AlO4]0 center.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
992.
We examined the anthropogenic and natural causes of flood risks in six representative cities in the Gangwon Province of Korea.
Flood damage per capita is mostly explained by cumulative upper 5% summer precipitation amount and the year. The increasing
flood damage is also associated with deforestation in upstream areas and intensive land use in lowlands. Human encroachment
on floodplains made these urban communities more vulnerable to floods. Without changes in the current flood management systems
of these cities, their vulnerability to flood risks will remain and may even increase under changing climate conditions. 相似文献
993.
The extreme diversity of uranium deposits 总被引:10,自引:0,他引:10
Michel Cuney 《Mineralium Deposita》2009,44(1):3-9
Most available classifications of uranium deposits are based on the characteristics of the host rocks or on the morphology
of the ore deposits. The aim of the present paper is to propose the basis for a genetic classification of these deposits.
After a short introduction on the geochemical behavior of uranium in fluids and silicate melts and on the main uranium fractionation
mechanisms operating in uranium-rich peraluminous, metaluminous, and peralkaline melts, the most recent metallogenic models
of the main types of uranium deposits are shortly reviewed. 相似文献
994.
Ellen K. Cromley 《GeoJournal》2009,74(2):115-121
Geocoding and spatial analysis of data describing populations and health events are important methods in health social science
now carried out using GIS technology. This commentary considers Nancy Krieger’s work on health disparities in light of the
various ways individuals and organizations use geocoded population and health data: analyzing spatial patterns of health and
disease including health disparities, aggregating data spatially, assessing health status of individuals based on characteristics
of aggregates, modeling neighborhood contextual factors affecting health, designing observation and intervention studies,
and delivering health interventions and services. The extent to which her work addresses each of these purposes is considered.
The strengths and limitations of the research including choice of spatial analytic units and techniques as reported in the
published work are discussed. Krieger’s work, with her colleagues, has used standard methods of spatial analysis to raise
the profile of GIS and spatial analysis in the public health community. 相似文献
995.
A palygorskite unit was discovered in a road cut of undifferentiated Tertiary limestone between the villages of El Pariso
and San Roman (18°49.309N, 88°37.861W) in the southeastern Yucatán Peninsula, Mexico. This is the southern most locality of
a clay-rich sedimentary unit reported in the literature for the Tertiary carbonates of the Yucatán Peninsula. This occurrence
indicates a much wider range of palygorskite-rich clay deposition than previously recognized. The lithology is 99% clay and
1% sand to silt size diagenetic quartz grains. The clay consists of approximately 85% palygorskite, 15% montmorillonite and
trace amounts of titanium oxides. EDS analyses on palygorskite are largely consistent with sedimentary palygorskites from
other coastal marine settings, however palygorskite has a low total Fe content (average = 0.40 wt% expressed as Fe2O3) compared to many other sedimentary palygorskites. Montmorillonite chemical compositions are typical and compared to the
palygorskite have substantially higher Fe2O3 concentrations (average = 3.90 wt%). The low percentage of coarse grains in the lithology combined with a high proportion
of palygorskite and lack of detrimental trace minerals suggest the deposit is of industrial grade; however, it has limited
reserves (6,000 m3). The unit could be potentially used in a wide array of environmental applications which are needed in the region including
liners for landfills and constructed wetlands. The unit is in a geographic location which would serve the expanding economy
of the region. This resource has the potential to have great impact on the quality of the local environment and the economy
of a region under great environmental threat. 相似文献
996.
Rainfall, throughfall, stemflow and spring were studied in a secondary forest during a wet season from April to August in
2006. Some of the chemicals in throughfall, stemflow and spring were increased in contrast with incident rainfall. Specifically,
Cl−, HCO3
−, Na+ and Ca2+ were leached negatively in throughfall, but K+ and Mg2+ were leached positively. In stemflow, Cl− and Na+ were leached negatively, the others were leached positively and their concentrations were higher than those in throughfall.
Total carbon, organic carbon and inorganic carbon in throughfall and stemflow were increased as rainfall went through the
secondary forest. The concentration of free CO2 in rainfall was lower than both, throughfall and stemflow; the relationship between total acidity and free CO2 was linear. pH of throughfall and stemflow , such as maximum, minimum and mean, were lower than that of rainfall and the
extent of pH in spring was changed minimally. We came to a conclusion that rainfall via the secondary forest can lead to further
erosion, accelerate the biogeochemical cycle in epikarst zone, enhance the effective state of alkali elements in the soil,
supply vegetation with more nutrients and advance vegetation’s growth and succession, which are reasonably sufficient to form
a stable karst ecosystem. 相似文献
997.
J. Escuder Viruete A. Pérez-Estaún D. Weis 《International Journal of Earth Sciences》2009,98(2):407-425
The nature of the oceanic crust produced through rifting and oceanic spreading between North and South America during the
Late Jurassic is a key element for the Caribbean plate tectonic model reconstruction. Located in the Cordillera Central of
Hispaniola, the Loma La Monja volcano-plutonic assemblage (LMA) is composed of gabbros, dolerites, basalts, and oceanic sediments,
as well as metamorphic equivalents, which represent a dismembered fragment of this proto-Caribbean oceanic crust. Petrologic
and geochemical data show that the LMA have a relatively broad diversity in composition, which represent the crystallization
products of a typical low-pressure tholeiitic fractionation of mid-ocean ridge basalts (MORB)-type parental magmas, ranging
from N- to E-MORB. Three geochemical groups have been distinguished in the volcanic sequence: LREE-flat to slightly LREE-enriched
basalts of groups II and III occur interlayered in the lower stratigraphic levels; and LREE-depleted basalts of group I in
the upper levels. Mantle melt modeling suggests that group III magmas are consistent by mixing within a mantle melt column
of low-degree (<1%) melts of a deep garnet lherzolite source and high-degree (>15%) melts of a shallow spinel source, and
groups II and I magmas are explained with moderate to high (14–18%) and very high (>20%) fractional melting degrees of a shallower
spinel mantle source, respectively. Thus, upward in the volcanic sequence of the LMA, the magmas represent progressively more
extensive melting of shallower sources, in a plume-influenced spreading ridge of the proto-Caribbean oceanic crust. Nb/Y versus
Zr/Y systematics combined with recent plate tectonic model reconstructions reveal that Caribbean Colombian oceanic plateau
fragments in Hispaniola formed through melting of heterogeneous mantle source regions related with distinct plumes during
at least from Aptian–Albian (>96 Ma) to Late Campanian. 相似文献
998.
Blasting is often a necessary part of mining and construction operations, and is the most cost-effective way to break rock,
but blasting generates both noise and ground vibration. In urban areas, noise and vibration have an environmental impact,
and cause structural damage to nearby structures. Various wave-screening methods have been used for many years to reduce blast-induced
ground vibration. However, these methods have not been quantitatively studied for their reduction effect of ground vibration.
The present study focused on the quantitative assessment of the effectiveness in vibration reduction of line-drilling as a
screening method using a numerical method. Two numerical methods were used to analyze the reduction effect toward ground vibration,
namely, the “distinct element method” and the “non-linear hydrocode.” The distinct element method, by particle flow code in
two dimensions (PFC 2D), was used for two-dimensional parametric analyses, and some cases of two-dimensional analyses were
analyzed three-dimensionally using AUTODYN 3D, the program of the non-linear hydrocode. To analyze the screening effectiveness
of line-drilling, parametric analyses were carried out under various conditions, with the spacing, diameter of drill holes,
distance between the blasthole and line-drilling, and the number of rows of drill holes, including their arrangement, used
as parameters. The screening effectiveness was assessed via a comparison of the vibration amplitude between cases both with
and without screening. Also, the frequency distribution of ground motion of the two cases was investigated through fast Fourier
transform (FFT), with the differences also examined. From our study, it was concluded that line-drilling as a screening method
of blast-induced waves was considerably effective under certain design conditions. The design details for field application
have also been proposed. 相似文献
999.
Niels Jöns Wolfgang Bach Timothy Schroeder 《Contributions to Mineralogy and Petrology》2009,157(5):625-639
We examined small-scale shear zones in drillcore samples of abyssal peridotites from the Mid-Atlantic Ridge. These shear zones
are associated with veins consisting of chlorite + actinolite/tremolite assemblages, with accessory phases zircon and apatite,
and they are interpreted as altered plagiogranite melt impregnations, which originate from hydrous partial melting of gabbroic
intrusion in an oceanic detachment fault. Ti-in-zircon thermometry yields temperatures around 820°C for the crystallization
of the evolved melt. Reaction path modeling indicates that the alteration assemblage includes serpentine of the adjacent altered
peridotites. Based on the model results, we propose that formation of chlorite occurred at higher temperatures than serpentinization,
thus leading to strain localization around former plagiogranites during alteration. The detachment fault represents a major
pathway for fluids through the oceanic crust, as evidenced by extremely low δ18O of altered plagiogranite veins (+3.0–4.2‰) and adjacent serpentinites (+ 2.6–3.7‰). The uniform oxygen isotope data indicate
that fluid flow in the detachment fault system affected veins and adjacent host serpentinites likewise.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
1000.
Jen-Chen Fan Che-Hsin Liu Chih-Hsiang Yang Hsiao-Yu Huang 《Environmental Geology》2009,57(7):1509-1519
In this study, soil samples collected from the sides of two streams with high debris flow potential at Shenmu and Fengchiou
village in Nantou County, Taiwan, were used for seepage tank tests in the laboratory. While the tests were being conducted,
observations were made to investigate the relationships among displacement of the slope, quality of the seepage water and
occurrence of mass movement. The results showed that according to the change rate, displacement could be divided into two
stages, namely, the initial failure displacement stage and primary failure displacement stage. While the displacement of the
slope was in primary failure displacement stages, the probability of slope failure became much higher. Before general slope
failure, electrical conductivity (EC) and sulfate ion (SO4
2−) concentration of the seepage water increased significantly. The time when EC of the seepage water started to increase rapidly
was much earlier than that when displacement of the slope started to increase significantly. Therefore, from the hazard mitigation
view, there will be a longer time for response if EC of the seepage water was monitored. 相似文献