Occurrence and fate of polycyclic aromatic hydrocarbons in the coastal surface microlayer

Polycyclic aromatic hydrocarbons (PAHs) were measured in the coastal sea surface microlayer (SML), the sub-surface waters (SSW) and the overlying atmosphere in order to investigate the influence of the SML on contaminant enrichment and air-sea exchange. Samples were collected at two contrasting locations of the NW Mediterranean, one urban influenced (off Barcelona, Spain) and another comparatively clean (off Banyuls-sur-Mer, France). Statistical data analysis confirmed the accumulation of PAHs in the SML with respect to the SSW (20.3+/-9.1 vs. 13.1+/-10.0 ng L(-1) in the dissolved phase; 709+/-207 vs. 158+/-111 ng g(-1) in the particulate phase). This accumulation was higher at the contaminated location (Barcelona station) compared with the more pristine one, with PAH enrichments 1.5 and 4.5 times higher for the dissolved and particulate phases, respectively, indicating that the enrichment of PAHs in the SML is dominated by particle transport processes.     

The impact of hydrological changes on travertine deposits related to thermal springs in the Pamukkale area (SW Turkey)

Pamukkale thermal waters (35 °C), exhibiting calcium-bicarbonate-sulfate composition and high carbon dioxide concentration, are of a predominantly meteoric origin. The meteoric fluid, circulating through faults and fractures, is heated by magmatic intrusions at great depth, and ascends from deep reservoirs to the surface. Mixing with relatively cold groundwater in the near surface zone promotes different saturation conditions with respect to calcium carbonate that later precipitates at depth and/or the surface. Dissolution-deposition processes of calcium carbonate both at surface and depth environments may help to reconstruct past climate direction in the field. During wet climate conditions a high-rate of calcium carbonate accumulation would be expected to occur at the surface because thermal fluid would be under-saturated with respect to calcium carbonate at depth because of a relatively higher mixing ratio with cold groundwater. During dry climate conditions the thermal fluid would be super-saturated at depth because of the highly acidic environment. Hydrometeorological studies reveal that the annual precipitation at the Pamukkale hydrothermal field tends to decrease with time. This climatic change in the area was also detected from geological records. While humid climate conditions prevailed during the late Quaternary, the area has recently been affected by arid/semi-arid climate conditions, followed by some episodic transitions. This study has shown how the system has possibly reacted to different climate conditions since antiquity.     

Integrative taxonomic description of Plakina kanaky,a new polychromatic sponge species from New Caledonia (Porifera: Homoscleromorpha)

Four similar sponges of different colors, all unknown to science, were collected in submarine caves of New Caledonia. We aimed at determining whether the four chromotypes represented different species or phenotypic variations of a unique new species. We used an integrative taxonomic approach combining morphologic, molecular and metabolomic analyses. The main traits that define these specimens are a skeleton made of monolophose, trilophose and tetralophose calthrops only, high chemical diversity and a high abundance and diversity of prokaryotic symbionts. The symbiotic community includes two unique prokaryote morphotypes, which are described for the first time in Homoscleromorpha, and appeared to be vertically transmitted. Although several features slightly differ among chromotypes, the most parsimonious conclusion was to propose a single new species Plakina kanaky sp. nov. Our phylogenetic analysis indicated the paraphyly of the Plakina genus, with P. kanaky sp. nov. belonging to a clade that includes Plakina jani and Plakina trilopha. The present work demonstrates that integrative taxonomy should be used in order to revise the entire Plakinidae family and especially the non‐monophyletic genus Plakina.     

The age as a diagnostic of the dynamics of marine ecosystem models

The constituent-oriented age theory (CAT) worked out by Delhez et al. (1999) is a flexible tool that can be applied to diagnose complex models. It is shown here how this can be used to quantify the pace at which an ecosystem model works. At the cost of the introduction of one additional evolution equation for each compartment of the ecosystem model, the mean age of the biological material forming these compartments can be computed. The information obtained in this way complements the information provided by the concentration data; while the latter measures the standing stocks, the former provides an integrated assessment of the interaction rates and matter fluxes. The benefits of the method are demonstrated with a simple Lotka–Volterra system and a one-dimensional vertical model of the nitrogen cycle in the Ligurian Sea. The theory can be used to study the biological compartments individually or the ecosystem as a whole. In particular, the age is a valuable tool to quantify the overall cycling rate of nitrogen in the food web.Responsible Editor: Phil Dyke     

Observations of the Ushant tidal front in September 2007

The Ushant tidal front is the dominant feature of the summer season hydrological structure of the Iroise Sea. It separates tidally mixed coastal waters from thermally stratified open Celtic Sea waters. This article reports on observations made in September 2007 during two short cruises that took place aboard R/V “Côtes de la Manche”, and gives a general account of the physical structure of the front along one cross-frontal transect. The data set comprises data from a 4 month ADCP mooring, short CTD/fluorescence/nutrients transects, Lagrangian drifter trajectories, and HF radar surface current measurements. One finding is that the surface and bottom fronts, being affected by different dynamical influences, are not necessarily coincident in the vertical. This entails that the opposite density gradients located above and below the thermocline depth do not necessarily compensate, and can each be associated with a significant surface geostrophic expression. A second finding is that mixing effects bear a very strong influence on the thermal structure of the warm-water intrusions associated with frontal cyclonic eddies of the kind described by Pingree [1978. Cyclonic eddies and cross-frontal mixing. Journal of the Marine Biological Association of the United Kingdom 58 (4), 955–963].     

Light curves of the eclipsing systems of RS CVn-type

This work presents the light curves for rotating spotted stars generated by a computational code developed by us. This code is based in a model of the system and its analytical solution. The work also present an analysis of the photometric curve variations with the changes in the model's parameters.As a first result we have simulated a temporal evolution of the light curve when the photospheric spot varies its size and position and we reproduced some observational light curves of the II Peg star.Work supported by Dirección de Investigación, Universidad de La Serena, Chile.     

Assessment of a new solution for tracking pebbles in rivers based on active RFID

Low‐frequency passive integrated transponders (PIT tags), are commonly used for monitoring pebble mobility in gravel‐bed rivers. Although early studies reported high recovery rates for PIT tags used in small streams, recovery rates in larger systems remain low, substantially limiting the possibilities for their use in such rivers. These low recovery rates are potentially due to missed detections caused by tag signal collision, burial in the sediment layer deeper than the maximum detection range and insufficient (but still exhausting) field effort to cover the concerned areas. A potential solution for addressing these problems is to use active ultra‐high frequency (a‐UHF) transponders as these have a greater detection range and anti‐collision protocols. In order to assess the potential of such transponders for pebble tracking in rivers, we used 433.92 MHz COIN‐ID and COIN‐HC models (ELA Innovation Company, Montpellier, France). We completed several tests to (i) characterize transponder detection ranges in the water and in saturated sediment and (ii) develop field protocols for locating tags by combining global positioning systems (GPS) sites and transponder received signal strength indication (RSSI) levels. The results showed that (i) the maximum detection ranges are about 2.4 m in the water column and more than 2.6 m in a column of saturated gravelly‐sandy sediment, (ii) RSSI spatial interpolation can be used to determine transponder position with good accuracy (< 1 m), (iii) the desired minimal level of accuracy can be adjusted depending on in‐field effort and signal impulse interval, (iv) the RSSI maximal value observed cannot yet be used to determine transponder burial depth because of the multipath propagation of radio frequencies and the semi‐directional emission of the tag signal. Copyright © 2017 John Wiley & Sons, Ltd.     

In Situ Determination of Au and Cu in Natural Pyrite by Near‐Infrared Femtosecond Laser Ablation‐Inductively Coupled Plasma‐Quadrupole Mass Spectrometry: No Evidence for Matrix Effects

Gold and copper concentrations were determined in natural pyrite by near‐infrared femtosecond LA‐ICP‐QMS, using both sulfide reference materials (pyrrhotite Po‐726 and in‐house natural chalcopyrite Cpy‐RM) and NIST SRM 610 as external calibrators. Firstly, using NIST SRM 610 as the external calibrator, we calculated the Au concentration in Po‐726 and the Cu concentration in Cpy‐RM. The calculated concentration averages for Au and Cu were similar to the values published for Po‐726 and Cpy‐RM, respectively. Secondly, we calculated Au and Cu concentrations taking NIST SRM 610 as an unknown sample and using Po‐726 and Cpy‐RM as external calibrators. Again, the average values obtained closely reflected the preferred concentrations for NIST SRM 610. Finally, we calculated Au and Cu concentrations in natural pyrite using sulfide and silicate reference materials as external calibrators. In both cases, calculated concentrations were very similar, independent of the external calibrator used. The aforementioned data, plus the fact that we obtained very small differences in relative sensitivity values (percentage differences are between 5% and 17% for ⁵⁷Fe, ⁶³Cu and ¹⁹⁷Au) on analyses of silicate and sulfide RMs, indicate that there were no matrix effects related to the differences in material composition. Thus, it is possible to determine Au and Cu in natural sulfides using NIST silicate glasses as an external calibrator.