Twenty-three unsolved problems in hydrology (UPH) – a community perspective

ABSTRACT

This paper is the outcome of a community initiative to identify major unsolved scientific problems in hydrology motivated by a need for stronger harmonisation of research efforts. The procedure involved a public consultation through online media, followed by two workshops through which a large number of potential science questions were collated, prioritised, and synthesised. In spite of the diversity of the participants (230 scientists in total), the process revealed much about community priorities and the state of our science: a preference for continuity in research questions rather than radical departures or redirections from past and current work. Questions remain focused on the process-based understanding of hydrological variability and causality at all space and time scales. Increased attention to environmental change drives a new emphasis on understanding how change propagates across interfaces within the hydrological system and across disciplinary boundaries. In particular, the expansion of the human footprint raises a new set of questions related to human interactions with nature and water cycle feedbacks in the context of complex water management problems. We hope that this reflection and synthesis of the 23 unsolved problems in hydrology will help guide research efforts for some years to come.     

Ressaut de marée et Mascaret – exemples de la Garonne et de la Seine

In this article, we present a study on the tidal bore dynamics based on the analysis of the database acquired in 2011 during two simultaneous field campaigns in the Seine and Garonne Rivers. We have shown that in the Garonne River, contrary to the common view, undular tidal bore can form for a large majority of tides, even sometimes at neap tide when the river discharge is low. We have identified, from surface elevation measurements, low-steepness, low-frequency undular tidal bores which are not visually observable. Such low-frequency tidal bores have been also identified and characterised for the first time in the Seine River. In this river, the first undulation wave height can be higher than 1 m. We have shown that the secondary wave steepness strongly increases when the Froude number exceeds the critical value F_c. The large-steepness tidal bore regime corresponds to what is commonly termed in French mascaret.     

Inter-laboratory comparison of oxygen isotope compositions from biogenic silica

Several techniques have been introduced in the last decades for the dehydration and release of O₂ from biogenic silica (opal-A) for oxygen-isotope analysis. However, only one silica standard is universally available: a quartz standard (NBS28) distributed by the IAEA, Vienna. Hence, there is a need for biogenic silica working standards. This paper compares the existing methods of oxygen-isotope analyses of opal-A and aims to characterize additional possible working standards to calibrate the δ¹⁸O values of biogenic silica. For this purpose, an inter-laboratory comparison was organized. Six potential working standard materials were analysed repeatedly against NBS28 by eight participating laboratories using their specific analytical methods. The materials cover a wide range of δ¹⁸O values (+23 to +43‰) and include diatoms (marine, lacustrine), phytoliths and synthetically-produced hydrous silica. To characterize the proposed standards, chemical analyses and imaging by scanning electron microscopy (SEM) were also performed. Despite procedural differences at each laboratory, all methods are in reasonable agreement with a standard deviation (SD) for δ¹⁸O values between 0.3‰ and 0.9‰ (1σ). Based on the results, we propose four additional biogenic silica working standards (PS1772-8: 42.8‰; BFC: 29.0‰; MSG60: 37.0‰; G95-25-CL leaves: 36.6‰) for δ¹⁸O analyses, available on request through the relevant laboratories.     

Late Tertiary–Quaternary tectonics of the Southern Apennines (Italy): New evidences from the Tyrrhenian slope

This paper summarises the results of combined structural and geomorphological investigations we carried out in two key areas, in order to obtain new data on the structure and evolution of the Tyrrhenian slope of the southern Apennines. Analysis by a stress inversion method [Angelier, J., 1994. Fault slip analysis and paleostress reconstruction. In: Continental Deformation. P.L. Hancock Ed., Pergamon Press, Oxford, 53–100] of fault slip data from Mesozoic to Quaternary formations allowed the reconstruction of states of stress at different time intervals. By integrating these data with those deriving from the stratigraphic and morphotectonic records, chronology and timing of the sequence of the deformation events was obtained.The tectonic history of the region can be related to four deformation events. Structures related to the first event, that was dominated by a strike-slip regime with a NW–SE oriented σ1 and was active since Mid–Late Miocene, do not significantly affect the present day landscape, as they were strongly displaced and overprinted by subsequent deformation events and/or deleted by erosion. The second and third events, that may be considered as the main responsible for the morphostructural signature of the region, are comparable with the stretching phases recognised offshore and considered to be responsible for the opening and widening of the Tyrrhenian basin. In particular, the second event (with an E–W oriented σ3), took place in the Late Miocene/earliest Pliocene and was first dominated by a strike-slip regime, that was also responsible for thrusting and folding. Since Late Pliocene, it was dominated by an extensional regime that created large vertical offsets along N–S to NW–SE trending faults. The third event, that was dominated by extension with a NW–SE oriented σ3, started in the Early Pleistocene and was responsible for formation of the horst-and-graben structure with NE–SW trend that characterises the Tyrrhenian margin of the southern Apennines. The fourth deformation event, which is characterised by an extensional regime with a NE–SW trending σ3, started in the late Middle Pleistocene and is currently active.     

致密砂岩衰减岩石物理图板分析:储层微裂隙预测

致密砂岩储层普遍具有孔隙度低、微裂隙发育的特点,岩石内部常含有强烈的结构非均质性.致密砂岩发育的微裂隙使储层具有良好的连通性,促成高饱和气的天然气成藏.针对川西某探区须家河组高含气饱和度致密砂岩,本文选取致密砂岩岩心样本,进行了不同围压下的超声波实验测量.考虑储层完全饱气情况下的粒间孔隙、微裂隙双重孔隙结构,采用Biot-Rayleigh双重孔隙方程,构建致密砂岩岩石物理模型,进而分析了裂隙含量对纵波频散和衰减的影响.基于地震波衰减,构建了致密砂岩多尺度岩石物理图板.采用谱比法和改进频移法估算致密砂岩样本及储层衰减,对超声和地震频带下的图板进行校正.将校正后的图板应用到研究工区,选取二维测线和三维区块,进行储层孔隙度和裂隙含量的定量预测.对比实际资料进行分析,结果显示,本文预测的孔隙度和裂隙含量与三口测井的孔隙度曲线和实际产气情况基本吻合,基于孔隙-裂隙衰减岩石物理模型有效地预测了优质储层的分布区域.

     

New chelid turtles of the lower section of the Cerro Barcino formation (Aptian-Albian?), Patagonia, Argentina

A new chelid species (Prochelidella cerrobarcinae nov. sp.) are described from the Aptian-Albian? Puesto La Paloma Member, Cerro Barcino Formation, northern of Chubut Province, Argentina. The basal section of this member, which bears the turtle remains, is composed of tuffaceous mudstones with plane parallel lamination, asymmetrical ripples and a chert intercalation suggesting sub-aqueous deposition in a relatively shallow lacustrine environment. Pr. cerrobarcinae nov. sp. is represented by post-cranial remains of several specimens that not only represents the oldest pleurodiran chelid record in the world but, together with the chelid remains of Albian Lightning Ridge, New South Wales, Australia, indicates that chelid diversification began well before the final fragmentation of southern Gondwana.     

The role of climate and vegetation in weathering and clay mineral formation in late Quaternary soils of the Swiss and Italian Alps

Interactions between climate and soil remain ambiguous, particularly when silicate weathering and clay mineral formation and transformation rates are considered in relation to global climate changes. Recent studies suggest that climate affects weathering rates much less than previously thought. Here we show that the climate in the central European Alps has a significant, but indirect, influence on the weathering of soils through vegetation. The pattern of element leaching and mineral transformations is not only due to precipitation and temperature. Element leaching was greatest in subalpine forests near the timberline; weathering is lessened at higher and lower altitudes. Vegetation, therefore, contributes significantly to weathering processes. The highest accumulation of organic matter was found in climatically cooler sites (subalpine range) where the production of organic ligands, which enhance weathering, is greatest. Patterns of smectite formation and distribution had strong similarities to that of the elemental losses of Fe and Al (R = 0.69; P < 0.01) or base cations (R = 0.58; P < 0.05). Higher precipitation rates and the production of organic chelating compounds in the soil promoted the appearance of smectites. The relationship between climate, element leaching (Fe, Al, Ca, Mg, K, Na), and smectite formation is strongly nonlinear and driven by the podzolisation process, which is more pronounced near the timberline because of the bioclimatic constellation. Climate warming will probably, in the future, lead to a decrease in SOM stocks in the subalpine to alpine range because of more favourable conditions for biodegradation that would also affect weathering processes.     

Weathering, mineralogical evolution and soil organic matter along a Holocene soil toposequence developed on carbonate-rich materials

A toposequence of Holocene soils located between 1100–2400 m asl in the Italian Alps served as the basis for the following analyses: the weathering of limestone and dolomite, the calculation of mass balances, understanding the formation of pedogenic Fe and Al, the determination of soil mineral and clay mineral reactions and transformation and the measurement of accumulation and stabilisation mechanisms of soil organic matter. Leaching of carbonates is most intense at the lower elevations, although calcite and dolomite have a higher solubility at low temperatures. The pCO₂ in the soil is higher at lower elevations and weathering is driven mainly by carbonic acids. At higher elevations, organic acids appear to determine the mineral transformations and weathering reactions to a greater extent. This suggests that two very different weathering regimes (carbonic and organic acid weathering) exist along the toposequence. The transformation of mica into vermiculite is the main process in both the clay and fine-earth fraction. Weathering of silicate minerals started even before the carbonates had been completely removed from the soils. The transformation mechanisms of silicate minerals in the A and O horizon at higher elevations was at least as intensive as that at the climatically warmer sites. The neoformation of pedogenetic clays at climatically cooler sites was slightly greater than that at the warmer sites. However, the formation rate of secondary Fe and Al phases was more pronounced at lower elevation, which means that this process seemed to be driven dominantly by carbonic acid (weathering of primary minerals). Soil organic matter (SOM) abundance in the mineral soil is nearly 15 kg/m² at all sites and, surprisingly, no climate-driven effect could be detected. In general, the preservation and stabilisation of SOM was due to poorly crystalline Al and Fe phases and vermiculite, regardless of some variations in the composition of the parent material (varying calcite/dolomite ratio).