First Record of Hoplictis(Carnivora,Mustelidae) in East Asia from the Miocene of the Ulungur River Area,Xinjiang,Northwest China

The first unequivocal remains of medium to large-sized mustelids from the middle Miocene Halamagai and Kekemaideng formations have been found in the Ulungur River area, Xinjiang, northwestern China. These new fossils are referred to the hypercarnivorous mustelid Hoplictis Ginsburg, 1961 and denote the first record of the genus in East Asia.We define Hoplictis baihu n. sp., for the mustelid from Tieersihabahe(Halamagai Fm.), which represents the smallest species of the genus. This primitive form is closer to H. florancei and H. noueli than to H. anatolicus and later, larger and more derived Hoplictis spp., from Europe and North America. A large toothless mandible from Duolebulejin(Kekemaiden Fm.) is assigned to Hoplictis cf. helbingi, and it presumably might represent the first record of H. helbingi outside Western Europe. The systematic position of Hoplicitis in relation to Ischyrictis with which it is similar is clarified. The occurrence in East Asia of two species of Hoplictis greatly expands the known distribution and diversity of the genus, and supports a Palaearctic Neogene dispersal event of carnivorans between Europe and Asia during the late Shanwangian–early Tunggurian equivalent to MN5–6 in Europe, and indication of another dispersal event from Europe to North America,through Northwest China during the late Tunggurian, equivalent to MN7–8 in Europe.     

Body size–abundance distributions of nano- and micro-phytoplankton guilds in coastal marine ecosystems

This study focuses on body size–abundance distributions of nano- and micro-phytoplankton guilds in coastal marine areas of the Southern Adriatic–Ionian region. The aim of the study was to evaluate the occurrence of common patterns of body size–abundance distributions in relation to physical, chemical and biological environmental forcing factors and to taxonomic composition of phytoplankton guilds. This paper is based on data collected during four oceanographic cruises carried out seasonally along the Southern Apulian coast (Adriatic and Ionian Seas, SE Italy) as a part of the INTERREG II Italy–Greece Program. The study was performed at 21 stations located on 7 transects perpendicular to the coastline, with 3 stations per transect at a distance of 3, 9 and 15 NM from the coastline. At each station, profiles of the major physical features of the water were determined and water samples were collected for phytoplankton and nutrient analysis. Overall, 320 nano- and micro-phytoplankton taxa were identified, 76% of which at species level, with phytoplankton cells ranging in size from 0.008 to 4697.54 ng. Body size–abundance distributions showed some common features: they were relatively invariant (average similarity 65%) with respect to taxonomic composition (average similarity 32%), right skewed (90%), leptokurtic (77%) and log normal (76%). Moreover, abiotic, biotic and spatial ecosystem components accounted for up to 75% of body size–abundance distribution variation. The results of this study suggest that body size–abundance distributions are an intrinsic property of marine phytoplankton communities, emphasising functional dependence on ecological constraints related to trophic factors and intra-guild coexistence relationships.     

Chemistry and trophic evolution of Lake Lugano in relation to nutrient budget

Chemical studies performed in the last 50 years on the northern and southern basins of Lago di Lugano are reviewed and discussed in relation to the phosphorus and nitrogen loads from the drainage area.Both basins became eutrophic in the fifties as a consequence of the dense population and industrial activity in the drainage area; the effect of these was aggravated by the meromictic condition of the layer below 100 m in the northern basin.The reduction of phosphorus loads in progress since 1976 has resulted in a significant improvement in the chemical and biological condition of the southern basin and the upper 100 m of water in the northern basin. On the other hand, the balance between dissolved oxygen and reducing substances in the northern basin is shifting toward a decrease of the net oxygen concentration, partly as a consequence of the unusually dry conditions of the last three years.A reduction in phosphorus load down to 18 and 22 t a^–1 in the northern and southern basins respectively is still necessary in order to reduce the lake phosphorus concentration to 30–35 µg O l^–1.     

Alteration patterns of chromian spinels from La Cabaña peridotite,south-central Chile

La Cabaña peridotite is part of a dismembered ophiolite complex located within the metamorphic basement of the Coastal Cordillera of south-central Chile, and is the only location in Chile were Cr-spinels have been described so far. The La Cabaña peridotite is part of the Western Series unit, which comprises meta-sedimentary rocks, metabasites, and serpentinized ultramafic rocks. This unit has been affected by greenschist-facies metamorphism with reported peak PT conditions of 7.0–9.3 kbar and 380°–420 °C. Within La Cabaña peridotite Cr-spinels are present in two localities: Lavanderos and Centinela Bajo. In Lavanderos, Cr-spinel occurs in small chromitite pods and as accessory/disseminated grains with a porous or spongy texture in serpentinite, whereas in Centinela Bajo Cr-spinel is present as accessory zoned grains in partly serpentinized dunites, and in chromitite blocks. All Cr-spinels display variable degrees of alteration to Fe²⁺-rich chromite with a variation trend of major elements from chromite to Fe²⁺-rich chromite similar to those observed in other locations, i.e., an increase in Fe₂O₃ and FeO, a decrease in Al₂O₃ and MgO. Cr₂O₃ content increases from chromite to Fe²⁺-rich chromite in chromitite pods from Lavanderos and chromitite blocks from Centinela Bajo, but decreases in ferrian chromite zones in accessory grains from Centinela Bajo. The minor element (Ti, V, Zn, Ni) content is mostly low and does not exceed 0.4 wt.%, with the exception of MnO (<0.9 wt.%), which shows a correspondence with increasing degree of alteration. Cr# (Cr/Cr?+?Al) versus Mg# (Mg/Mg?+?Fe²⁺) and Fe³⁺/Fe³⁺+Fe²⁺ versus Mg# plots are used to illustrate the Cr-spinel alteration process. Overall, the Cr-spinels from Lavanderos (chromitite pods and disseminated grains) exhibit Cr# values ranging from 0.6 to 1.0, Mg# (Mg/Mg?+?Fe²⁺) below 0.5, and (Fe³⁺/Fe³⁺+Fe²⁺) <0.4. Cr-spinels from chromitites in Centinela Bajo have Cr# and Mg# values that range from 0.65 to 1.0, and 0.7-0.3, respectively, and (Fe³⁺/Fe³⁺+Fe²⁺)?3+/Fe³⁺+Fe²⁺) ratio is less than 0.4 in chromite cores and Fe²⁺-rich chromite, and >0.5 in ferrian chromite and Cr-magnetite. Interpretation of the data obtained and Cr-spinel textures indicate that the alteration of Cr-spinel is a progressive process that involves in its initial stages the reaction of chromite with olivine under water-saturated conditions to produce clinochlore and Fe²⁺-rich chromite. During this stage the chromite can also incorporate Ni, Mn, and/or Zn from the serpentinization fluids. As alteration progresses, Fe²⁺-rich chromite loses mass resulting in the development of a spongy texture. In a later stage and under more oxidizing conditions Fe³⁺ is incorporated in chromite/Fe²⁺-rich chromite shifting its composition to an Fe³⁺-rich chromite (i.e., ferrian chromite). Depending on the fluid/rock and Cr-spinel/silicate ratios, Cr-magnetite can also form over Fe²⁺-rich chromite and/or ferrian chromite as a secondary overgrowth. The compositional changes observed in Cr-spinels from La Cabaña reflect the initial stages of alteration under serpentinization conditions. Results from this study show that the alteration of Cr-spinels is dependent on temperature. The degree and extent of alteration (formation of Fe²⁺-rich and/or ferrian chromite) are controlled by the redox nature of the fluids, the Cr-spinel/silicate and the fluid/rock ratios.     

Composition and processes of the mantle lithosphere in northeastern Brazil and Fernando de Noronha: evidence from mantle xenoliths

Spinel–peridotite facies mantle xenoliths in Cenozoic alkali basalts of the Pico Cabuji volcano (Rio Grande do Norte State, Northeast Brazil) and the adjacent South Atlantic oceanic island of Fernando de Noronha are studied for: (1) the information they provide on the composition of the lithospheric component in the erupted basalt geochemistry, and (2) to check the effects of the Fernando de Noronha plume track on the mantle lithosphere. Xenoliths from Pico Cabuji are protogranular lherzolites and porphyroclastic harzburgites recording average equilibrium temperatures of 825 ± 116 and 1248 ± 19 °C, respectively. Pressure in the porphyroclastic xenoliths ranges from 1.9 to 2.7 GPa (Ca-in-olivine geobarometer). Both groups show major element chemical variation trends in whole-rock and Ti and HREE (Er, Yb) variations in clinopyroxene consistent with fractional melting and basalt extraction. REE (rare earth element) profiles of clinopyroxenes vary from LREE (La, Ce) enriched (spoon shaped) to LREE depleted in the protogranular group, whereas they are slightly convex upward in most porphyroclastic clinopyroxenes. HFSE (Ti and Zr) negative anomalies are in general modest in the clinopyroxenes of both groups. Xenoliths from Fernando de Noronha have textural variations similar to those of Pico Cabuji. Protogranular and porphyroclastic samples have similar temperature (1035 ± 80 °C) and the pressure is 1–1.9 and 2.3 GPa, respectively. Whole-rock chemical variation trends overlap and extend further than those of Pico Cabuji. The trace element profiles of the clinopyroxenes of the porphyroclastic xenoliths are enriched in La up to 30 × PM and are smoothly fractionated from LREE to HREE, with deep, negative, Zr and Ti anomalies. The geochemical heterogeneities of the xenoliths from both localities are interpreted in terms of reactive porous percolation. The porphyroclastic xenoliths from Pico Cabuji represent the lower part of a mantle column (the head of a mantle diapir, at the transition conductive–adiabatic mantle), where OIB infiltration triggers melting, and the protogranular xenoliths the top of the mantle column, chromatographically enriched by percolation at a low melt/rock ratio. This interpretation may also apply for Fernando de Noronha, but the different geochemical signature recorded by the clinopyroxenes requires a different composition of the infiltrated melt. Nd and Sr isotopes of the Pico Cabuji porphyroclastic clinopyroxenes (¹⁴³Nd/¹⁴⁴Nd= 0.51339–0.51255, ⁸⁷Sr/⁸⁶Sr=0.70275–0.70319) and of Fernando de Noronha (¹⁴³Nd/¹⁴⁴Nd=0.51323–0.51285, ⁸⁷Sr/⁸⁶Sr=0.70323–0.70465) plot on distinct arrays originating from a similar, isotopically depleted composition and trending to low Nd–low Sr (EMI) and low Nd–high Sr (EMII), respectively. Correlation of the isotope variation with geochemical parameters indicates that the isotopic variation was induced by the metasomatic component, of EMI type at Pico Cabuji and of EMII type at Fernando de Noronha. These different components enriched a lithosphere isotopically similar to DMM (depleted MORB mantle) at both localities. At Fernando de Noronha, the isotopic signature of the metasomatic component is similar to that of the ∼ 8 Ma old lavas of the Remedios Formation, suggesting that this is the age of metasomatism. At Pico Cabuji, the mantle xenoliths do not record the high ⁸⁷Sr/⁸⁶Sr component present in the basalts. We speculate that the EMII component derives from a lithospheric reservoir, which was not thermally affected during mantle metasomatism at Pico Cabuji, but was mobilized by the hotspot thermal influence at Fernando de Noronha. This interpretation provides a plausible explanation for the presence of distinct metasomatic components at the two localities, which would be difficult to reconcile with their genetic relationship with the same plume. Received: 12 June 1999 / Accepted: 13 December 1999     

On Dry Deposition Modelling of Atmospheric Pollutants on Vegetation at the Microscale: Application to the Impact of Street Vegetation on Air Quality

A Reynolds-averaged Navier–Stokes model is used to investigate the impact of urban canopy vegetation on air quality, with particular emphasis on the comparison between the positive effect induced by deposition versus the negative effect due to a reduction of ventilation. With this aim, a series of simulations over a simplified urban geometry with different vegetation designs are carried out. The problem is tackled at two scales. From the mesoscale point of view, the relevant variable is the total deposition flux of pollutant as a function of the pollutant concentration above the canopy (e.g. the “mesoscale” deposition velocity). This is assessed within the Monin–Obukov similarity theory framework, and a modification of the classical formulation is proposed based on the numerical results. At the microscale, the distribution of concentration within the urban canopy is investigated for the different configurations. The main conclusion is that the height of the vegetation and the magnitude of the microscale deposition velocity are key parameters that determine which of the two effects (deposition or reduction of ventilation) prevails.     

Cultural heritage and geological hazards: the case of the Calomini hermitage in Tuscany (Italy)

The Calomini hermitage is located on a steep slope, below an 80- to 130-m-high hanging rock wall. The hermitage, a significant example of religious architecture, has been a pilgrimage place since the Middle Ages. The monastery, completed by the tenth century, is built into the rock mass for more than half of its length. The stability and safety of the complex are threatened by stability problems in the rock slope. Structural and geotechnical investigations were carried out, showing the potential for rock blocks slides, particularly under dynamic conditions, with the fall of middle size blocks. Recently, some remedial works have been carried out, and wire meshes have been hung on the rock wall. Nevertheless, a significant portion of the Calomini hermitage area may be still dangerous and exposed to severe landslide hazard. Therefore, further research and countermeasures are necessary to protect a very important item of Italian cultural and architectural heritage.     

Establishing robustness of a spatial dataset in a tolerance‐based vector model

Spatial data are usually described through a vector model in which geometries are represented by a set of coordinates embedded into an Euclidean space. The use of a finite representation, instead of the real numbers theoretically required, causes many robustness problems which are well known in the literature. Such problems are made even worse in a distributed context, where data is exchanged between different systems and several perturbations can be introduced in the data representation. In order to discuss the robustness of a spatial dataset, two implementation models have to be distinguished: the identity and the tolerance model. The robustness of a dataset in the identity model has been widely discussed in the literature and some algorithms of the Snap Rounding (SR) family can be successfully applied in such contexts. Conversely, this problem has been less explored in the tolerance model. The aim of this article is to propose an algorithm inspired by those of the SR family for establishing or restoring the robustness of a vector dataset in the tolerance model. The main ideas are to introduce an additional operation which spreads instead of snapping geometries, in order to preserve the original relation between them, and to use a tolerance region for such an operation instead of a single snapping location. Finally, some experiments on real‐world datasets are presented, confirming how the proposed algorithm can establish the robustness of a dataset.     

Distribution of macrobenthic assemblages along a marine gradient in Mediterranean eutrophic coastal lagoons

Coastal lagoons can be characterised by strong environmental changes along the outer marine‐inner brackish gradient, which are reflected in the patterns of distribution of organisms and composition of assemblages. Close to the sea the assemblages are dominated by marine animals, while in the innermost confined areas, there would be estuarine taxa and organisms typical of organically‐enriched areas. During the last decades, human impact has been severe in these habitats and has often profoundly altered the distribution of animals and plants along the gradient. In this study we have analysed the distribution of macrofauna along the outer marine‐inner brackish gradient in five Italian lagoons, affected by severe human disturbance on the Adriatic, Tyrrhenian and Sardinian coasts. We aimed to measure changes in the composition of assemblages according to the distance from the sea, consistent among lagoons and time, after the occurrence of eutrophication, repeated distrophic crisis and other human interventions. We considered existing data from campaigns done during 1994, 1995 and 1999. We arranged different datasets according to the available data, in order to measure the spatial distribution of macrofauna genera with distance from the sea and through time. Analyses showed differences among assemblages related to the gradient. Nevertheless, the species characterizing the assemblages were all typical of organically‐enriched areas, which testified to an impoverishment of diversity and functioning of all these systems.