喀麦隆西南部Mamelles条带状铁建造元素地球化学特征

Mamelles铁矿床位于喀麦隆南部刚果克拉通西北缘,距离克里比地区东南方向约20km。该矿床由大规模、高品位磁铁矿矿体组成,赋存于Nyong杂岩体的条带状铁建造(BIF)中。该矿床中的BIF与角闪岩和片麻岩相伴生。在详细的野外调查基础上,我们获取了BIF的全岩地球化学数据,并用以约束它们的物质来源和沉积环境。弱正铕(Eu)异常(δEu=2.14～3.55)表明高温热液流体对MamellesBIF的贡献是通过海底火山岩蚀变作用的方式,并有少量碎屑物质输入。正铈(Ce)异常的缺失表明,这些BIF可能沉积在缺氧的深海环境中,如火山弧或弧后盆地深水区。     

Ordovician igneous and metamorphic units in southeastern Puna: New U–Pb and Sm–Nd data and implications for the evolution of northwestern Argentina

New field, petrological, geochemical, and geochronological data (U–Pb and Sm–Nd) for Ordovician rock units in the southeastern Puna, NW Argentina, indicate two lithostratigraphic units at the eastern–northeastern border of salar Centenario: (1) a bimodal volcanosedimentary sequence affected by low- to medium-grade metamorphism, comprising metasediments associated with basic and felsic metavolcanic rocks, dated 485 ± 5 Ma, and (2) a plutonic unit composed of syenogranites to quartz-rich leucogranites with U–Pb zircon ages between 462 ± 7 and 475 ± 5 Ma. Felsic metavolcanic and plutonic rocks are peraluminous and show similar geochemical differentiation trends. They also have similar Sm–Nd isotopic compositions (T_DM model ages of 1.54–1.78 Ga; ε_Nd(T) values ranging from −3.2 to −7.5) that suggest a common origin and derivation of the original magmas from older (Meso-Paleoproterozoic?) continental crust. Mafic rocks show ε_Nd(T) ranging from +2.3 to +2.5, indicating a depleted mantle source. The data presented here, combined with those in the literature, suggest Ordovician magmatism mainly recycles preexisting crust with minor additions of juvenile mantle-derived material.     

Carbon biogeochemistry of the Betsiboka estuary (north-western Madagascar)

Madagascar’s largest estuary (Betsiboka) was sampled along the salinity gradient during the dry season to document the distribution and sources of particulate and dissolved organic carbon (POC, DOC) as well as dissolved inorganic carbon (DIC). The Betsiboka was characterized by a relatively high suspended matter load, and in line with this, low DOC/POC ratios (0.4–2.5). The partial pressure of CO₂ (pCO₂) was generally above atmospheric equilibrium (270–1530 ppm), but relatively low in comparison to other tropical and subtropical estuaries, resulting in low average CO₂ emission to the atmosphere (9.1 ± 14.2 mmol m⁻² d⁻¹). Despite the fact that C4 vegetation is reported to cover >80% of the catchment area, stable isotope data on DOC and POC suggest that C4 derived material comprises only 30% of both pools in the freshwater zone, increasing to 60–70% and 50–60%, respectively, in the oligohaline zone due to additional lateral inputs. Sediments from intertidal mangroves in the estuary showed low organic carbon concentrations (<1%) and δ¹³C values (average −19.8‰) consistent with important inputs of riverine imported C4 material. This contribution was reflected in δ¹³C signatures of bacterial phospholipid derived fatty acids (i + a15:0), suggesting the potential importance of terrestrial organic matter sources for mineralization and secondary production in coastal ecosystems.     

The ionosphere: effects,GPS modeling and the benefits for space geodetic techniques

The main goal of this paper is to provide a summary of our current knowledge of the ionosphere as it relates to space geodetic techniques, especially the most informative technology, global navigation satellite systems (GNSS), specifically the fully deployed and operational global positioning system (GPS). As such, the main relevant modeling points are discussed, and the corresponding results of ionospheric monitoring are related, which were mostly computed using GPS data and based on the direct experience of the authors. We address various phenomena such as horizontal and vertical ionospheric morphology in quiet conditions, traveling ionospheric disturbances, solar flares, ionospheric storms and scintillation. Finally, we also tackle the question of how improved knowledge of ionospheric conditions, especially in terms of an accurate understanding of the distribution of free electrons, can improve space geodetic techniques at different levels, such as higher-order ionospheric effects, precise GNSS navigation, single-antenna GNSS orientation and real-time GNSS meteorology.     

Stability and chemical equilibrium of amphibole in calc-alkaline magmas: an overview, new thermobarometric formulations and application to subduction-related volcanoes

This work focuses on a rigorous analysis of the physical–chemical, compositional and textural relationships of amphibole stability and the development of new thermobarometric formulations for amphibole-bearing calc-alkaline products of subduction-related systems. Literature experimental results (550–1,120°C, <1,200 MPa, −1 ≤ ΔNNO ≤ +5), H₂O–CO₂ solubility models, a multitude of amphibole-bearing calc-alkaline products (whole-rocks and glasses, representing 38 volcanoes worldwide), crustal and high-P (1–3 GPa) mantle amphibole compositions have been used. Calcic amphiboles of basalt-rhyolite volcanic products display tschermakitic pargasite (37%), magnesiohastingsite (32%) and magnesiohornblende (31%) compositions with aluminium number (i.e. Al# = ^[6]Al/Al_T) ≤ 0.21. A few volcanic amphiboles (~1%) show high Al# (>0.21) and are inferred to represent xenocrysts of crustal or mantle materials. Most experimental results on calc-alkaline suites have been found to be unsuitable for using in thermobarometric calibrations due to the high Al# (>0.21) of amphiboles and high Al₂O₃/SiO₂ ratios of the coexisting melts. The pre-eruptive crystallization of consistent amphiboles is confined to relatively narrow physical–chemical ranges, next to their dehydration curves. The widespread occurrence of amphiboles with dehydration (breakdown) rims made of anhydrous phases and/or glass, related to sub-volcanic processes such as magma mixing and/or slow ascent during extrusion, confirms that crystal destabilization occurs with relatively low T–P shifts. At the stability curves, the variance of the system decreases so that amphibole composition and physical–chemical conditions are strictly linked to each other. This allowed us to retrieve some empirical thermobarometric formulations which work independently with different compositional components (i.e. Si^*, Al_T, Mg^*, ^[6]Al^*) of a single phase (amphibole), and are therefore easily applicable to all types of calc-alkaline volcanic products (including hybrid andesites). The Si^*-sensitive thermometer and the fO₂–Mg^* equation account for accuracies of ±22°C (σ_est) and 0.4 log units (maximum error), respectively. The uncertainties of the Al_T-sensitive barometer increase with pressure and decrease with temperature. Near the P–T stability curve, the error is <11% whereas for crystal-rich (porphyritic index i.e. PI > 35%) and lower-T magmas, the uncertainty increases up to 24%, consistent with depth uncertainties of 0.4 km, at 90 MPa (~3.4 km), and 7.9 km, at 800 MPa (~30 km), respectively. For magnesiohornblendes, the ^[6]Al^*-sensitive hygrometer has an accuracy of 0.4 wt% (σ_est) whereas for magnesiohastingsite and tschermakitic pargasite species, H₂O_melt uncertainties can be as high as 15% relative. The thermobarometric results obtained with the application of these equations to calc-alkaline amphibole-bearing products were finally, and successfully, crosschecked on several subduction-related volcanoes, through complementary methodologies such as pre-eruptive seismicity (volcano-tectonic earthquake locations and frequency), seismic tomography, Fe–Ti oxides, amphibole–plagioclase, plagioclase–liquid equilibria thermobarometry and melt inclusion studies. A user-friendly spreadsheet (i.e. AMP-TB.xls) to calculate the physical–chemical conditions of amphibole crystallization is also provided.     

Origin of peraluminous granites and granodiorites, Iberian massif, Spain: an experimental test of granite petrogenesis

The discrimination between potential source materials involved in the genesis of Iberian granites and granodiorites, as well as the role of mantle-crust interactions, are examined using constraints imposed by melting experiments, melting-assimilation experiments and Sr-Nd isotope systematics. The Sr-Nd isotope relationships indicate the existence of different genetic trends in which juvenile mantle materials are involved by different mechanisms: (1) a source trend, traced by a particular evolution of the pre-Hercynian basement and indicating mantle participation at the time of sedimentation; (2) a set of magmatic trends traced by gabbro-tonalite-enclave-granodiorite associations, implying the incorporation of new mantle material at the time of granite generation. These relationships strongly support a pure crustal origin for the peraluminous leucogranites, derived from partial melting of crustal protoliths, and a hybrid origin for the peraluminous granodiorites. These granodiorites are the most abundant granitic rocks of the Central Iberian zone (CIZ) of the Iberian massif, implying that processes of hybridisation by assimilation and/or magma mixing played an important role in granitoid production during the Hercynian orogeny. These hypotheses have been tested by means of melting and assimilation experiments. Melting experiments in the range 800–900 °C and at pressures of 3, 6, 10 and 15 kbar indicate that: (1) several potential source materials such as Bt-Ms gneisses and metagreywackes are suitable for the production of peraluminous leucogranite melts; (2) the melt compositions are always leucogranitic, regardless of pressure; (3) pressure exerts a strong influence on the fertility of the source: experiments at 3 kbar produce more than 20 vol% of melt, compared with less than 5 vol% of melt produced at 10 and 15 kbar and at the same temperature. The melting-assimilation experiments carried out at 1000 °C and 4, 7 and 10 kbar and using a proportion of 50% gabbro and 50% gneiss give high melt proportions (more than 50 vol.%) and noritic residues. These melts have the composition of leucogranodiorites, and overlap with part of the compositional range of peraluminous granodiorites of the Iberian massif. The generation of more mafic granodiorites may be explained by the incorporation of some residual orthopyroxene to the granodiorite magmas. The low solubility of Fe + Mg prevents the generation of granodiorite melts with more than 3 wt% of MgO + FeO at all crustal pressures. The large volumes of peraluminous, hybrid granodiorites, produced by assimilation of crustal rocks by mantle magmas, imply that an important episode of crustal growth took place during the Late-Palaeozoic Hercynian orogeny in the Iberian massif. Received: 30 June 1998 / Accepted: 27 November 1998     

Response of single benthic metrics and multi-metric methods to anthropogenic pressure gradients, in five distinct European coastal and transitional ecosystems

In recent times many benthic indices have been proposed to assess the ecological quality of marine waters worldwide. In this study we compared single metrics and multi-metric methods to assess coastal and transitional benthic status along human pressure gradients in five distinct environments across Europe: Varna bay and lake (Bulgaria), Lesina lagoon (Italy), Mondego estuary (Portugal), Basque coast (Spain) and Oslofjord (Norway). Hence, 13 single metrics (abundance, number of taxa, and several diversity and sensitivity indices) and eight of the most common indices used within the European Water Framework Directive (WFD) for benthic assessment were selected: index of size spectra (ISS), Benthic assessment tool (BAT), Norwegian quality index (NQI), Multivariate AMBI (M-AMBI), Benthic quality index (BQI), (Benthic ecosystem quality index (BEQI), Benthic index based on taxonomic sufficiency (BITS), and infaunal quality index (IQI). Within each system, sampling sites were ordered in an increasing pressure gradient according to a preliminary classification based on professional judgement. The different indices are largely consistent in their response to pressure gradient, except in some particular cases (i.e. BITS, in all cases, or ISS when a low number of individuals is present). Inconsistencies between indicator responses were most pronounced in transitional waters (i.e. IQI, BEQI), highlighting the difficulties of the generic application of indicators to all marine, estuarine and lagoonal environments. However, some of the single (i.e. ecological groups approach, diversity, richness) and multi-metric methods (i.e. BAT, M-AMBI, NQI) were able to detect such gradients both in transitional and coastal environments, being these multi-metric methods more consistent in the detection than single indices. This study highlights the importance of survey design and good reference conditions for some indicators. The agreement observed between different methodologies and their ability to detect quality trends across distinct environments constitutes a promising result for the implementation of the WFD’s monitoring plans. Moreover, these results have management implications, regarding the dangers of misclassification, uncertainty in the assessment, use of conflicting indices, and testing and validation of indices.