Modelling nitrogen and oxygen isotope fractionation during denitrification in a lacustrine redox-transition zone

The stable isotope composition (δ¹⁵N and δ¹⁸O) of nitrate was measured during Summer 1999 in the anaerobic hypolimnion of eutrophic Lake Lugano (Switzerland). Denitrification was demonstrated by a progressive nitrate depletion coupled to increasing δ¹⁵N and δ¹⁸O values for residual nitrate. Maximum δ¹⁵N and δ¹⁸O values amounted to 27.2 and 15.7‰, respectively.¹⁵N and ¹⁸O enrichment factors for denitrification (ε) were estimated using a closed-system model and a dynamic diffusion-reaction model. Using the Rayleigh equation (closed-system approach), we obtained ε values of −11.2 and −6.6‰ for nitrogen and oxygen, respectively. The average ε values derived using the diffusion-reaction model were determined to be −20.7 ± 3.8 for nitrogen and −11.0 ± 1.7 for oxygen. Both N and O isotope fractionation appeared to be lower when denitrification rates where high, possibly in association with high organic carbon availability. In addition, variations in the isotope effects may be attributed to the variable importance of sedimentary denitrification having only a small isotope effect on the water column. The combined measurement of N and O isotope ratios in nitrate revealed that coupled nitrification-denitrification in the open-water was of minor importance. This is the first study of nitrogen and oxygen isotope effects associated with microbial denitrification in a natural lake. Moreover, this study confirms the high potential of δ¹⁸O of nitrate as a valuable biogeochemical tracer in aquatic systems, complementing nitrate δ¹⁵N.     

Prediction of ground displacements and velocities from groundwater level changes at the Vallcebre landslide (Eastern Pyrenees, Spain)

In active landslides, the prediction of acceleration of movement is a crucial issue for the design and performance of warning systems. The landslide of Vallcebre in the Eastern Pyreenes, Spain, has been monitored since 1996 and data on rainfall, groundwater levels and ground displacements are measured on a regular basis. Displacements observed in borehole wire extensometers have shown an immediate response of the landslide to rainfall episodes. This rapid response is likely due to the presence of preferential drainage ways. The occurrence of nearly constant rates of displacement in coincidence with steady groundwater levels suggests the presence of viscous forces developed during the movement. An attempt to predict both landslide displacements and velocities was performed at Vallcebre by solving the momentum equation in which a viscous term (Bingham and power law) was added. Results show that, using similar rheological parameters for the entire landslide, computed displacements reproduce quite accurately the displacements observed at three selected wire extensometers. These results indicate that prediction of displacements from groundwater level changes is feasible.     

A thermo-plastic constitutive law for brittle-plastic behavior of rocks at high temperatures

Mechanical properties of rocks change under the influence of, temperature. Stress at the onset of yielding, ultimate strength, dilatancy, strain hardening and softening, and the confining pressure at brittle-ductile transition are all reduced by the increasing temperature. This study presents a framework of constitutive modeling of thermo-brittle-plastic behavior of rocks which encompasses these changes. The constitutive law is based on a thermo-plasticity theory first proposed for metals byPrager (1958). Two phenomenological mechanisms have been identified as central for the modeling: temperature dependence of the yield locus (thermal softening), and temperature dependence of the strain-hardening function (thermally enhanced ductility). Material parameters for two rocks, Carrara marble and Westerly granite, were determined on the basis of additional hypotheses. These parameters are used in numerical simulations of triaxial tests at different temperatures. The obtained stress-strain curves compare well to the experimental results. The changes with temperature in the stress at the onset of yielding are more accurately reproduced that the evolution of hardening or softening. Suggestions for possible improvements and future research directions are indicated.     

A Method to Estimate the Hydraulic Conductivity of the Ground by TRT Analysis

The knowledge of hydraulic properties of aquifers is important in many engineering applications. Careful design of ground‐coupled heat exchangers requires that the hydraulic characteristics and thermal properties of the aquifer must be well understood. Knowledge of groundwater flow rate and aquifer thermal properties is the basis for proper design of such plants. Different methods have been developed in order to estimate hydraulic conductivity by evaluating the transport of various tracers (chemical, heat etc.); thermal response testing (TRT) is a specific type of heat tracer that allows including the hydraulic properties in an effective thermal conductivity value. Starting from these considerations, an expeditious, graphical method was proposed to estimate the hydraulic conductivity of the aquifer, using TRT data and plausible assumption. Suggested method, which is not yet verified or proven to be reliable, should be encouraging further studies and development in this direction.     

Emission of nitric oxide from soils and termite nests in a Trachypogon savanna of the Orinoco basin

Nitric oxide fluxes from soils in the Trachypogon savanna of the Orinoco basin were determined during the dry season using the static chamber method. The emission from dry soils fluctuated from 0.4 to 3 ng N m^–2 s^–1 and increased up to 25 ng N m^–2 s^–1 after moderate watering or light rain-falls (1 to 5 mm). The mean emission values are up to 6 times lower than one observed earlier at the Chaguaramas site, but up to 10 times higher than one recorded at the Guri site, indicating an important spatial variability in NO fluxes of the Venezuelan savanna region. The changes observed after the addition of nitrogen to the soil, in the form of ammonium and/or nitrate, indicate a high denitrification potential in this acidic soil. Burning of the surface vegetation produced an increase by a factor of 10 in the emission rate of NO, but the effect was relatively short in time, about 5 days. It was estimated for the savanna region that burning increases the total NO soil emission during the dry season by 15% compared to the unburnt case. Soils with termite nests emit 10 times more NO than soil without nests, but the contribution from this source is less than 2% of the total savanna soil flux.     

Assessment of calanchi and rill–interrill erosion susceptibilities using terrain analysis and geostochastics: A case study in the Oltrepo Pavese,Northern Apennines,Italy

Soil erosion is one of the most important environmental problems distributed worldwide. In the last decades, numerous studies have been published on the assessment of soil erosion and the related processes and forms using empirical, conceptual and physically based models. For the prediction of the spatial distribution, more and more sophisticated stochastic modelling approaches have been proposed – especially on smaller spatial scales such as river basins. In this work, we apply a maximum entropy model (MaxEnt) to evaluate badlands (calanchi) and rill–interrill (sheet erosion) areas in the Oltrepo Pavese (Northern Apennines, Italy). The aim of the work is to assess the important environmental predictors that influence calanchi and rill–interrill erosion at the regional scale. We used 13 topographic parameters derived from a 12 m digital elevation model (TanDEM-X) and data on the lithology and land use. Additional information about the vegetation is introduced through the normalized difference vegetation index based on remotely sensed data (ASTER images). The results are presented in the form of susceptibility maps showing the spatial distribution of the occurrence probability for calanchi and rill–interrill erosion. For the validation of the MaxEnt model results, a support vector machine approach was applied. The models show reliable results and highlight several locations of the study area that are potentially prone to future soil erosion. Thus, coping and mitigation strategies may be developed to prevent or fight the soil erosion phenomenon under consideration. © 2020 John Wiley & Sons, Ltd.     

The NASA Astrophysics Data System: Free Access to the Astronomical Literature On-line and through Email

The Astrophysics Data System (ADS) provides access to the astronomical literature through the World Wide Web. It is a NASA funded project and access to all the ADS services is free to everybody world-wide. The ADS Abstract Service allows the searching of four databases with abstracts in Astronomy, Instrumentation, Physics/Geophysics, and the LANL Preprints with a total of over 2.2 million references. The system also provides access to reference and citation information, links to on-line data, electronic journal articles, and other on-line information. The ADS Article Service contains the full articles for most of the astronomical literature back to volume 1. It contains the scanned pages of all the major journals (Astrophysical Journal, Astronomical Journal, Astronomy & Astrophysics, Monthly Notices of the Royal Astronomical Society, and Solar Physics), as well as most smaller journals back to volume 1.The ADS can be accessed through any web browser without signup or login. Alternatively an email interface is available that allows our users to execute queries via email and to retrieve scanned articles via email. This might be interesting for users on slow or unreliable links, since the email system will retry sending information automatically until the transfer is complete. There are now 9 mirror sites of the ADS available in different parts of the world to improve access. The ADS is available at: http://ads.harvard.edu This revised version was published online in July 2006 with corrections to the Cover Date.     

U–Pb evidence for a polyorogenic evolution of the HP–HT units of the NW Iberian Massif

. A isotope dilution thermal ionisation mass spectrometry U-Pb geochronological study was carried out on the high-pressure and high-temperature units (HP-HT units) overlying the oceanic suture in the Allochthonous Complexes of the NW Iberian Variscan Belt. The rocks investigated are seven granulite- to eclogite-facies paragneisses and one leucosome within mafic high-pressure granulites in the Ordenes and Cabo Ortegal Complexes of NW Spain. U-Pb dating of zircon, monazite, titanite and rutile reveal the presence of a pervasive Early Ordovician metamorphic event at ca. 500-480 Ma and a later Early Devonian event at ca. 400-380 Ma. The U-Pb ages, in conjunction with petrological and structural data, indicate that the high-pressure event recorded by these rocks is Early Ordovician in age. Monazite ages in the paragneisses suggest that peak metamorphic conditions were reached at ca. 500-485 Ma. Subsequently, the rock ensemble underwent exhumation accompanied by partial melting and zircon growth at ca. 485-470 Ma. Melting of mafic granulites was coeval with this latter episode as indicated by zircon crystallisation age in the leucosomes dated at ca. 486 Ma. Based on these data and on the general features of magmatism and metamorphic evolution, it is proposed that this process took place at a convergent plate boundary within a peri-Gondwanan oceanic domain. Monazite, titanite and rutile data in some of the samples studied show evidence of a second metamorphic episode that took place between ca. 400 and 380 Ma (with a peak at ca. 390-385 Ma). This Early Devonian event, at variance with the previous one, was not pervasive, but, rather, was localised in areas of intense Variscan tectonothermal reworking. It is claimed that this later metamorphic event was recorded by the U-Pb system in areas where monazite and titanite growth was enhanced by fluid circulation in highly strained rocks (Variscan shear zones). According to previous structural studies and Ar-Ar dating of fabrics, this Early Devonian episode took place as the HP-HT units were deformed and thrusted upon the ophiolitic units in the early stages of the Variscan collision.     

Terrestrial laser scanning to estimate plot-level forest canopy fuel properties

This paper evaluates the potential of a terrestrial laser scanner (TLS) to characterize forest canopy fuel characteristics at plot level. Several canopy properties, namely canopy height, canopy cover, canopy base height and fuel strata gap were estimated. Different approaches were tested to avoid the effect of canopy shadowing on canopy height estimation caused by deployment of the TLS below the canopy. Estimation of canopy height using a grid approach provided a coefficient of determination of R² = 0.81 and an RMSE of 2.47 m. A similar RMSE was obtained using the 99th percentile of the height distribution of the highest points, representing the 1% of the data, although the coefficient of determination was lower (R² = 0.70). Canopy cover (CC) was estimated as a function of the occupied cells of a grid superimposed upon the TLS point clouds. It was found that CC estimates were dependent on the cell size selected, with 3 cm being the optimum resolution for this study. The effect of the zenith view angle on CC estimates was also analyzed. A simple method was developed to estimate canopy base height from the vegetation vertical profiles derived from an occupied/non-occupied voxels approach. Canopy base height was estimated with an RMSE of 3.09 m and an R² = 0.86. Terrestrial laser scanning also provides a unique opportunity to estimate the fuel strata gap (FSG), which has not been previously derived from remotely sensed data. The FSG was also derived from the vegetation vertical profile with an RMSE of 1.53 m and an R² = 0.87.