Do we have enough pieces of the jigsaw to integrate CO2 fluxes in the coastal ocean?

Annually integrated air-water CO₂ flux data in 44 coastal environments were compiled from literature. Data were gathered in 8 major ecosystems (inner estuaries, outer estuaries, whole estuarine systems, mangroves, salt marshes, coral reefs, upwelling systems, and open continental shelves), and up-scaled in the first attempt to integrate air-water CO₂ fluxes over the coastal ocean (26×10⁶ km²), taking into account its geographical and ecological diversity. Air-water CO₂ fluxes were then up-scaled in global ocean (362×10⁶ km²) using the present estimates for the coastal ocean and those from Takahashi et al. (2002) for the open ocean (336×10⁶ km²). If estuaries and salt marshes are not taken into consideration in the up-scaling, the coastal ocean behaves as a sink for atmospheric CO₂(−1.17 mol C m⁻² yr⁻¹) and the uptake of atmospheric CO₂ by the global ocean increases by 24% (−1.93 versus −1.56 Pg C yr⁻¹). The inclusion of the coastal ocean increases the estimates of CO₂ uptake by the global ocean by 57% for high latitude areas (−0.44 versus −0.28 Pg C yr⁻¹) and by 15% for temperate latitude areas (−2.36 versus −2.06 Pg C yr⁻¹) At subtropical and tropical latitudes, the contribution from the coastal ocean increases the CO₂ emission to the atmosphere from the global oceam by 13% (0.87 versus 0.77 Pg C yr⁻¹). If estuaries and salt marshes are taken into consideration in the upscaling, the coastal ocean behaves as a source for atmospheric CO₂ (0.38 mol C m⁻² yr⁻¹) and the uptake of atmospheric CO₂ from the global ocean decreases by 12% (−1.44 versus −1.56 Pg C yr⁻¹) At high and subtropical and tropical latitudes, the coastal ocean behaves as a source for atmospheric CO₂ but at temperate latitudes, it still behaves as a moderate CO₂ sink. A rigorous up-scaling of air-water CO₂ fluxes in the coastal ocean is hampered by the poorly constrained estimate of the surface area of inner estuaries. The present estimates clearly indicate the significance of this biogeochemically, highly active region of the biosphere in the global CO₂ cycle.     

Cultural heritage and geological hazards: the case of the Calomini hermitage in Tuscany (Italy)

The Calomini hermitage is located on a steep slope, below an 80- to 130-m-high hanging rock wall. The hermitage, a significant example of religious architecture, has been a pilgrimage place since the Middle Ages. The monastery, completed by the tenth century, is built into the rock mass for more than half of its length. The stability and safety of the complex are threatened by stability problems in the rock slope. Structural and geotechnical investigations were carried out, showing the potential for rock blocks slides, particularly under dynamic conditions, with the fall of middle size blocks. Recently, some remedial works have been carried out, and wire meshes have been hung on the rock wall. Nevertheless, a significant portion of the Calomini hermitage area may be still dangerous and exposed to severe landslide hazard. Therefore, further research and countermeasures are necessary to protect a very important item of Italian cultural and architectural heritage.     

A physical analogue model to analyse interactions between tensile stresses and dissolution in carbonate slopes

A physical analogue model was developed to analyse the relationship between tensional states in rock masses, seepage and karst processes. Use was made of an experimental apparatus consisting of two hydraulic circuits realized by drilling two holes into each of two blocks of sampled limestone from the central Apennines (Italy). A static load (208.85 kg) was applied to one of the blocks in order to elicit tensile stresses within it. Physical and chemical monitoring data showed that the main process involved was temperature-dependent CaCO₃ dissolution. This process was more marked in the loaded block circuit, as Ca⁺⁺ concentration in circulated water reached 54 mg/L, whereas only 28 mg/L was reached in the unloaded one. The interaction between load and dissolution caused the observed opening of microcracks, as confirmed by further increase of water loss and by dilution in the loaded block circuit, resulting in a decrease of Ca⁺⁺ concentration. These findings were confirmed by recording additional water losses after increasing the load up to 445.05 kg. A finite difference numerical model showed that tensile stresses (max 20 kPa) within the loaded block were clustered at the intersection of the main joints with the flowpaths, thus representing points of preferential and accelerated dissolution.This study is part of a research project on analogical and numerical modelling for geological risk mitigation being conducted at CERI, Research Centre for Geological Risks of the University of Rome “La Sapienza” (Valmontone, Roma, Italy; http://www.ceri@uniroma1.it).     

Organic carbon metabolism and carbonate dynamics in a Mediterranean seagrass (Posidonia oceanica), meadow

We measured monthly dissolved oxygen (DO) changes in situ benthic incubations from March 2001 to October 2002 in aPosidonia oceanica meadow and unvegetated sediments of Magalluf Bay (Mallorca Island, Spain) to determine gross primary production (GPP), community respiration (R), and net community production (NCP). From June 2001 to October 2002, we also measured fluxes of dissolved inorganic carbon (DIC) and total alkalinity (TAlk). The yearly integrated metabolic rates based on DO changes show that theP. oceanica communities are net autotrophic while the metabolic rates in the unvegetated benthic communities are nearly balanced. Higher calcium carbonate (CaCO₃) cycling, both in terms of production and dissolution, was observed inP. oceanica communities than in unvegetated benthic communities. In theP. oceanica meadow, the annual release of CO₂ from net CaCO₃ production corresponds to almost half of the CO₂ uptake by NCP based on DIC incubations. In unvegetated benthic communities, the annual uptake of CO₂ from net CaCO₃ dissolution almost fully compensates the CO₂ release by NCP based on DIC incubations. CaCO₃ dynamics is potentially a major factor in CO₂ benthic fluxes in seagrass and carbonate-rich temperate coastal ecosystems.     

Structure of the lithosphere beneath the Eastern Alps (southern sector of the TRANSALP transect)

The interpretation of the seismic Vibroseis and explosive TRANSALP profiles has examined the upper crustal structures according to the near-surface geological evidences and reconstructions which were extrapolated to depth. Only the southern sector of the TRANSALP transect has been discussed in details, but its relationship with the whole explored chain has been considered as well. The seismic images indicate that pre-collision and deep collision structures of the Alps are not easily recognizable. Conversely, good records of the Neo-Alpine to present architecture were provided by the seismic sections.Two general interpretation models (“Crocodile” and “Extrusion”) have been sketched by the TRANSALP Working Group [2002]. Both illustrate the continental collision producing strong mechanical interaction of the facing European and African margins, as documented by giant lithosphere wedging processes. Arguments consistent with the “Extrusion” model and with the indentation of Adriatic (Southalpine) lithosphere underneath the Tauern Window (TW) are:

– According to the previous DSS reconstructions, the Bouguer anomalies and the Receiver Functions seismological data, the European Moho descends regularly attaining a zone south of the Periadriatic Lineament (PL). The Moho boundary and its geometry appear to be rather convincing from images of the seismic profile;

– the Tauern Window intense uplift and exhumation is coherent with the strong compression regime, which acted at depth, thus originating the upward and lateral displacement of the mobile and ductile Penninic masses according to the “Extrusion” model;

– the indentation of the Penninic mobile masses within the colder and more rigid Adriatic crust cannot be easily sustained. Wedging of the Adriatic stiffened lower crust, under high stresses and into the weaker Penninic domain, can be a more suitable hypothesis. Furthermore, the intrusion of the European Penninic crustal wedge underneath the Dolomites upper crust is not supported by any significant uplifting of the Dolomites. The total average uplift of the Dolomites during the Neogene appears to be 6−7 times smaller than that recognized in the TW. Markedly the northward dip of the PL, reaching a depth of approximately 20 km, is proposed in our interpretation;

– finally, the Adriatic upper crustal evolution points to the late post-collision change in the tectonic grow-up of the Eastern Alps orogenic chain. The tectonic accretion of the northern frontal zone of the Eastern and Central Alps was interrupted from the Late Miocene (Serravallian–Tortonian) onward, as documented by the Molasse basin evolution. On the contrary, the structural nucleation along the S-vergent tectonic belt of the eastern Southern Alps (Montello–Friuli thrust belt) severely continued during the Messinian and the Plio–Pleistocene. This structural evolution can be considered to be consistent with the deep under-thrusting and wedge indentation of the Adriatic lithosphere underneath the southern side of the Eastern Alps thrust-and-fold belt.

Similarly, the significance of the magmatic activity for the construction of the Southern Alps crust and for its mechanical and geological differentiation, which qualified the evolution of the thrust-and-fold belt, is highlighted, starting with the Permian–Triassic magmatism and progressing with the Paleogene occurrences along the Periadriatic Lineament and in the Venetian Magmatic Province (Lessini–Euganei Hills).     

Multivariate models for landslide hazard evaluation

As part of a long-term project aimed at a better understanding of the geological and geomorphological factors that control slope instability phenomena in Southern Italy, multivariate models for assessing landslide incidence hazard were developed and tested in two Calabrian sample areas characterized by different geological-geomorphological conditions. Discriminant analysis, based on a large set of mappable geological and geomorphical variables, is able to discriminate rather successfully between stable and unstable areas or slope units. Multiple regression analysis has also proved to be a useful tool in predicting actual and potential landslide hazard. Consequently, geomathematical models may provide a feasible approach to environmental hazard assessment, particularly when applied within the framework of a wider multidisciplinary project for land evaluation and planning.     

Recent advances in the chemistry and properties of atmospheric nucleants: a review

Summary A survey is carried out of recent progress in the investigation of weather-active atmospheric nucleants. Emphasis is placed on the work date during the last decade, and some resulting implications are discussed.     

Impacts of Realistic Urban Heating. Part II: Air Quality and City Breathability

Urban morphology and inter-building shadowing result in a non-uniform distribution of surface heating in urban areas, which can significantly modify the urban flow and thermal field. In Part I, we found that in an idealized three-dimensional urban array, the spatial distribution of the thermal field is correlated with the orientation of surface heating with respect to the wind direction (i.e. leeward or windward heating), while the dispersion field changes more strongly with the vertical temperature gradient in the street canyon. Here, we evaluate these results more closely and translate them into metrics of “city breathability,” with large-eddy simulations coupled with an urban energy-balance model employed for this purpose. First, we quantify breathability by, (i) calculating the pollutant concentration at the pedestrian level (horizontal plane at \(z\approx 1.5\)–2 m) and averaged over the canopy, and (ii) examining the air exchange rate at the horizontal and vertical ventilating faces of the canyon, such that the in-canopy pollutant advection is distinguished from the vertical removal of pollution. Next, we quantify the change in breathability metrics as a function of previously defined buoyancy parameters, horizontal and vertical Richardson numbers (\(Ri_\text {h}\) and \(Ri_\text {v}\), respectively), which characterize realistic surface heating. We find that, unlike the analysis of airflow and thermal fields, consideration of the realistic heating distribution is not crucial in the analysis of city breathability, as the pollutant concentration is mainly correlated with the vertical temperature gradient (\(Ri_\text {v}\)) as opposed to the horizontal (\(Ri_\text {h}\)) or bulk (\(Ri_\text {b}\)) thermal forcing. Additionally, we observe that, due to the formation of the primary vortex, the air exchange rate at the roof level (the horizontal ventilating faces of the building canyon) is dominated by the mean flow. Lastly, since \(Ri_\text {h}\) and \(Ri_\text {v}\) depend on the meteorological factors (ambient air temperature, wind speed, and wind direction) as well as urban design parameters (such as surface albedo), we propose a methodology for mapping overall outdoor ventilation and city breathability using this characterization method. This methodology helps identify the effects of design on urban microclimate, and ultimately informs urban designers and architects of the impact of their design on air quality, human health, and comfort.     

Mineralogy,geochemistry and petrogenesis of the Khopoli mafic intrusion,Deccan Traps,India

The Khopoli intrusion, exposed at the base of the Thakurvadi Formation of the Deccan Traps in the Western Ghats, India, is composed of olivine gabbro with 50–55 % modal olivine, 20–25 % plagioclase, 10–15 % clinopyroxene, 5–10 % low-Ca pyroxene, and <5 % Fe-Ti oxides. It represents a cumulate rock from which trapped interstitial liquid was almost completely expelled. The Khopoli olivine gabbros have high MgO (23.5–26.9 wt.%), Ni (733–883 ppm) and Cr (1,432–1,048 ppm), and low concentrations of incompatible elements including the rare earth elements (REE). The compositions of the most primitive cumulus olivine and clinopyroxene indicate that the parental magma of the Khopoli intrusion was an evolved basaltic melt (Mg# 49–58). Calculated parental melt compositions in equilibrium with clinopyroxene are moderately enriched in the light REE and show many similarities with Deccan tholeiitic basalts of the Bushe, Khandala and Thakurvadi Formations. Nd-Sr isotopic compositions of Khopoli olivine gabbros (εNd_t?=??9.0 to ?12.7; ⁸⁷Sr/⁸⁶Sr?=?0.7088–0.7285) indicate crustal contamination. AFC modelling suggests that the Khopoli olivine gabbros were derived from a Thakurvadi or Khandala-like basaltic melt with variable degrees of crustal contamination. Unlike the commonly alkalic, pre- and post-volcanic intrusions known in the Deccan Traps, the Khopoli intrusion provides a window to the shallow subvolcanic architecture and magmatic processes associated with the main tholeiitic flood basalt sequence. Measured true density values of the Khopoli olivine gabbros are as high as 3.06 g/cm³, and such high-level olivine-rich intrusions in flood basalt provinces can also explain geophysical observations such as high gravity anomalies and high seismic velocity crustal horizons.