Assessment of the acid drainage neutralization capacity and the toxic metals lixiviation of tailing from Guanajuato mining district,Mexico

In Mexico, many environmental problems are generated by large mining activities taking place in several mining districts. These mining activities produce great quantities of residues; large majorities of these have high sulfur content, which could generate acid drainage due to their interaction with the oxygen in the environment. The study area was located in the Mining District of Guanajuato, Mexico with abandoned tailings generated mainly by the gold and silver production. Two areas, called as Monte de San Nicolás (SN) and Peregrina (P) were selected for this study. The results study shows that there was no risk of production of acid drainage, since these tailings contained high amount of carbonates, which neutralized the generation of acidity and consequently decreased the possibility of leaching of some elements. However, not all elements leach in acid pH, as arsenic bound to oxyhydroxides, which is in a basic environment and its increased release by increasing the pH.     

Fate and transport of pollutants through a municipal solid waste landfill leachate in Sri Lanka

This study focuses on the characterization of leachate generated from Gohagoda dumpsite in Kandy, Sri Lanka, assessment of its spatial and temporal variations, and identification of subsurface canals and perched water bodies in the wetland system affected by the leachate flow. Leachate samples were collected monthly throughout dry and rainy seasons from different points of the leachate drainage channel over a period of 1 year and they were tested for quality parameters: pH, temperature, electrical conductivity, total dissolved soils, alkalinity, hardness, total solids, volatile solids, total suspended solids, volatile suspended solids, biochemical oxygen demand (BOD₅), chemical oxygen demand, nitrate-nitrogen, nitrite-nitrogen, phosphates, ammonium-nitrogen, chloride, dissolved organic carbon, total organic carbon and heavy metals. Sequential soil extraction procedures were performed for the characterization of leachate-affected local soil. A geophysical survey using direct current resistivity technique was conducted at locations downstream of the dumpsite. Leachate characteristics indicated that the leachate is in the methanogenic phase and the results strongly suggest that the leachate may be polluting the river where the leachate is discharged directly. Leachate exceeds the allowable limits of Sri Lankan wastewater discharge standards for many of the parameters. Significant difference (P < 0.05) was observed for most of organic and inorganic parameters among all sampling locations. Many parameters showed a negative correlation with pH. The affected soils showed high heavy metal concentrations. Resistivity study confirmed a confined leachate flow at the near surface with few subsurface canals. However, no separate subsurface plume movement was observed. The results of this research can effectively be used for the establishment of an efficient and effective treatment method for the Gohagoda landfill leachate.     

Melt/biotite B/B isotopic fractionation and the boron local environment in the structure of volcanic glasses

This paper is focused on the role of boron coordination in determining the ¹¹B/¹⁰B isotopic fractionation between melt/glass and biotite at magmatic temperatures. For this purpose, three evolved volcanic rocks from Roccastrada, Mt. Amiata, and Mt. Cimini belonging to the Neogene-Quaternary magmatism of central Italy were studied. In these samples, the measured boron biotite-glass partition coefficient ranges between 0.004 and 0.011, indicating that boron behaves as an incompatible element during biotite crystallization. The ¹¹B magic-angle spinning nuclear magnetic resonance (NMR) spectra reveal the presence of trigonal BO_3/2 units, tetrahedral BO_4/2⁻ sites, and three-coordinated BO_2/2O⁻ species containing one nonbridging oxygen. The relative contributions of these different boron sites were estimated by spectral deconvolution, and it was observed that the fraction of trigonally coordinated boron decreases with increasing K₂O concentration in the glass. The ¹¹B/¹⁰B isotopic fractionation between biotite and melt/glass was observed to be large even at magmatic temperatures and was found to be 1.0066 (Roccastrada sample), 1.00535 (Mt. Amiata sample), and 1.00279 (Mt. Cimini sample). Fractionation is mostly related to the relative amount of trigonal and tetrahedral boron sites in the glass network rather than to other processes, including the speciation of hydrous species in the glass structure. The measured α values are significantly higher than the calculated ones obtained using the reduced partition function ratios (RPFRs) for B(OH)₃ and B(OH)₄⁻ as reported by Kakihana et al. (1977) and the abundance of trigonal and tetrahedral boron obtained by ¹¹B NMR spectra. Furthermore, a nonlinear relationship is observed between the percentage of BO₄ in the glass structure and the measured 1000lnα, suggesting that the approximation of monomeric B(OH)₃ and B(OH)₄⁻ species contributions through ideal mixing in calculating the RPFRs in polyanions (Oi et al., 1989) probably does not apply to silicate glasses.The large B isotopic fractionation measured between glass and biotite and its dependence on the boron coordination in the glass are a limitation to the use of δ¹¹B in the mineral to characterize magmas. Nonetheless, the high incompatible behavior of boron in the most common magmatic minerals rules out that fractional crystallization significantly modified the B isotopic composition of the melt.     

δ 11B as tracer of slab dehydration and mantle evolution in Western Anatolia Cenozoic Magmatism

Boron isotope data are presented for Cenozoic Western Anatolia rocks, which define two main associations: (i) calc-alkaline, shoshonitic and ultra-potassic rocks (Early to Middle Miocene); and (ii) Late Miocene–Quaternary intraplate alkali basalts. Boron data, together with Sr–Nd isotope and other trace elements, are consistent with a progressive dehydration of the slab, producing fluid phases gradually depleted in B (and ¹¹B). These fluids were added to the supraslab mantle, triggering a partial melting that gave rise to orogenic magmatism. The stretching and tearing of the slab caused by the faster convergence of Greece over Africa with respect to Anatolia facilitated an interaction of the upwelling subslab asthenosphere with residual slab-fluids during the Late Miocene followed by production of typical intraplate magmas during the Pleistocene–Holocene, whose relatively high δ¹¹B (approximately −2‰) is considered representative of the local asthenosphere not affected by subduction contamination.     

Eocene age of eclogite metamorphism in Pakistan Himalaya: implications for India-Eurasia collision

A geochronological investigation of two rocks with an eclogitic assemblage (omphacite-garnet-quartz-rutile) from the High Himalaya using the Sm/Nd, Rb/Sr, U/Pb and Ar/Ar methods is presented here. The first three methods outline a cooling history from the time of peak metamorphism at 49±6 Ma recorded by Sm/Nd in garnet-clinopyroxene to the closure of Rb/Sr in phengite at 43±1 Ma and U/Pb in rutile at 39–40 Ma. The Sm/Nd isotopic system was fully equilibrated during eclogitization and has not been disturbed since; its mineral ages may date the peak metamorphic conditions (650±50°C at 13–18 kbar: Pognante and Spencer, 1991). The Ar/Ar data reveal the presence of substantial amounts of excess ⁴⁰Ar in hornblende, and yield a statistically acceptable but geologically meaningless phengite plateau age of 81.4±0.2 Ma, inconsistent with Sm/Nd, Rb/Sr and U/Pb. This questions the use of such a chronometer for the dating of high-pressure assemblages. The results imply a Late Palaeocene or Early Eocene subduction of the northern Indian plate margin in NW Himalaya. The fact that eclogites are restricted to NW Himalaya may be the result of a peculiar p-T-t path associated with a high convergence rate during the first indentation, in contrast to the later and slow subduction in Central and Eastern Himalaya.     

Palaeomagnetic and geochronological results from the Cambro-Ordovician Granite Harbour Intrusives inland of Terra Nova Bay (Victoria Land, Antarctica)

Palaeomagnetic investigations and Rb–Sr dating were carried out on samples from two plutons from the Granite Harbour Intrusives of the Transantarctic Mountains inland of Terra Nova Bay. The Rb–Sr whole rock–biotite ages from Teall Nunatak (475±4, 483±4 Ma), a quartz-diorite pluton cropping out to the south of Priestley Glacier, are older than that from the Mount Keinath monzogranite (450±4 Ma), which is located to the north of the glacier. These results are consistent with the literature data, which suggest that during the last phases of the Ross Orogeny the cooling rate of the basement was significantly lower to the north than to the south of Priestley Glacier. The Teall Nunatak quartz-diorite is characterized by a stable magnetization, whose blocking-temperature spectrum ranges from 530 to 570 °C. At one site, the stable magnetization is screened by a large secondary component of opposite polarity, removed by thermal demagnetization below 300 °C. The characteristic directions after thermal demagnetization yielded a southern pole located at lat. 11°S, long. 21°E. The magnetization of Mount Keinath monzogranite consists of several components with overlapping stability spectra. A characteristic direction was isolated at one site only, obtained by demagnetizing the specimens in the temperature range from 380 to 460 °C.
  Comparison with the other East Antarctica poles shows that those from Victoria Land are very well grouped and give a reliable early Ordovician palaeopole (lat. 5°S, long. 23°E, with K =196 and A ₉₅=3.7°), whereas the poles from Wilkes, Enderby and Dronning Maud Land are dispersed. We tentatively advance the hypothesis that the dispersion reflects different magnetization ages due to the slow cooling of these regions during the last stages of the Ross Orogeny.     

Sulfur Determination in Geological Samples Based on Coupled Analytical Techniques: Electric Furnace-IC and TGA-EGA

A study has been undertaken to determine sulfur in geological samples by coupled analytical techniques. Two measurement methods have been developed: one using an electric furnace coupled to an ion chromatograph (electric furnace-IC) and another using infrared (IR) and quadrupole mass spectrometry (QMS) for evolved gas analysis (EGA) coupled with a thermogravimetric analyser (TGA). In the electric furnace-IC method, measurement was performed without any sample pre-treatment. The measurement conditions were optimised by varying sample quantity, type of catalyst (WO₃, Cu, W and V₂O₅) and sample/catalyst ratio, and the detection limit was 10 μg g⁻¹. Sulfur ores decompose at different temperatures. However, TGA-EGA allowed identification of the different forms of sulfur in the sample, even when they were found in very low concentrations, because the sulfur was continuously analysed. The developed chromatographic method allowed simultaneous analysis of several sample components, such as S, Cl and F, with a low detection limit. The method was much faster and more specific than the methods described in the literature. The results of the sulfur determination had low scatter, possibly because the samples underwent little handling during analysis: the operator only weighed and placed the sample in the furnace, the rest of the measurement process was fully automated. The results obtained by both the developed methods have been validated by using reference materials and comparison with combustion-IR spectroscopy, a standard method for determining total sulfur in a sample.     

A multi-physics ensemble of present-day climate regional simulations over the Iberian Peninsula

This work assesses the influence of the model physics in present-day regional climate simulations. It is based on a multi-phyiscs ensemble of 30-year long MM5 hindcasted simulations performed over a complex and climatically heterogeneous domain as the Iberian Peninsula. The ensemble consists of eight members that results from combining different parametrization schemes for modeling the Planetary Boundary Layer, the cumulus and the microphysics processes. The analysis is made at the seasonal time scale and focuses on mean values and interannual variability of temperature and precipitation. The objectives are (1) to evaluate and characterize differences among the simulations attributable to changes in the physical options of the regional model, and (2) to identify the most suitable parametrization schemes and understand the underlying mechanisms causing that some schemes perform better than others. The results confirm the paramount importance of the model physics, showing that the spread among the various simulations is of comparable magnitude to the spread obtained in similar multi-model ensembles. This suggests that most of the spread obtained in multi-model ensembles could be attributable to the different physical configurations employed in the various models. Second, we obtain that no single ensemble member outperforms the others in every situation. Nevertheless, some particular schemes display a better performance. On the one hand, the non-local MRF PBL scheme reduces the cold bias of the simulations throughout the year compared to the local Eta model. The reason is that the former simulates deeper mixing layers. On the other hand, the Grell parametrization scheme for cumulus produces smaller amount of precipitation in the summer season compared to the more complex Kain-Fritsch scheme by reducing the overestimation in the simulated frequency of the convective precipitation events. Consequently, the interannual variability of precipitation (temperature) diminishes (increases), which implies a better agreement with the observations in both cases. Although these features improve in general the accuracy of the simulations, controversial nuances are also highlighted.