Two-dimensional modelling of some CFC replacement compounds

The Cambridge 2-D Eulerian model has been used to study the potential atmospheric distributions and lifetimes of a number of CFC replacement compounds and their degradation products. The study has focused on HFC 134a and HCFCs 123, 141b and 142b and the major products formed by their atmospheric degradation. The loss of these compounds and their products by hydroxyl radical attack, photolysis and in-cloud hydrolysis have been investigated. The study has shown that HCFCs 141b and 142b have sufficiently long lifetimes to enter the stratosphere in significant quantities, where degradation leads to an increase in the total stratospheric chlorine concentration. The study has also highlighted areas where further experimental work would be valuable, in particular characterisation of the product channels for the degradation reactions and determination of the removal rates of the products in the aqueous phase.     

Organic matter in the Soultz HDR granitic thermal exchanger (France): natural tracer of fluid circulations between the basement and its sedimentary cover

Organic matter has been observed in cores of the Soultz-sous-Forêts granite (Alsace, France) at depths between 2158 and 2160 m, in a highly fractured and altered zone. The granite is overlain by a 1400-m-thick sedimentary cover containing petroleum (Pechelbronn oil field). The Soultz area is devoted to Hot Dry Rock geothermics thanks to a high geothermal gradient (up to 100 °C/km). During drilling operations, an artesian source produced oil in a fractured zone of the sedimentary cover (Buntsandstein). Its gas-chromatography and mass-spectrometry (GC-MS) analysis revealed the presence of normal alkanes (n-alkanes, i.e. linear hydrocarbons) centered on C₁₇, branched alkanes with a major C₁₉ peak, and few unsaturated hydrocarbons. The aromatic fraction is present in small amounts. In the Soultz granite, where it is altered, organic matter is exclusively associated with tosudite (interstratified clay mineral) which crystallized in plagioclase sites during a hydrothermal alteration episode. Organic matter has been later displaced and concentrated along veinlets in which illite and carbonates have crystallized during another hydrothermal alteration stage. The soluble organic matter analyzed by GC-MS is composed of aliphatic acids, n-alkanes with a bimodal C₁₈ and C₂₄-C₂₅ centered distribution, alkylbenzenes and aromatic acids. Organic compounds in the granite would either originate from a single source (immature sediments) or from two sources (immature sediments and migration of the Pechelbronn oil). No real evidence was found to prove which hypothesis is the best one. The presence of organic matter in the granite shows the importance of fluid flows between the sedimentary cover and the granitic basement through major fractures. In addition, the impregnation of plagioclase pseudomorphs with organic matter is made possible due to their high interconnection degree and to the intergranular microfracturation of the granite. The succession of several hydrothermal events with different physico-chemical characteris- tics may also be inferred from the occurrence of organic matter found in association with neoformed clay minerals in the granite.     

THE IMPACT OF NOAA SATELLITE SOUNDING DATA ON THE SYSTEMATIC FORECAST ERROR OF B-MODEL

This paper is to examine the impact of satellite data on the systematic error of operational B-model in China.Em-phasis is put on the study of the impact of satellite sounding data on forecasts of the sea level pressure field and 500 hPaheight.The major findings are as follows.(1)The B-model usually underforecasts the strength of features in the sea level pressure(SLP)field,i.e.pressuresare too low near high pressure systems and too high near low pressure systems.(2)The nature of the systematic errors found in the 500 hPa height forecasts is not as clear cut as that of the SLPforecasts,but most often the same type of pattern is seen,i.e.,the heights in troughs are not low enough and those inridges are not high enough.(3)The use of satellite data in the B-model analysis/forecast system is found to have an impact upon the model'sforecast of SLP and 500 hPa height.Systematic errors in the vicinity of surface lows/500 hPa troughs over the oceansare usually found to be significantly reduced.A less conclusive mix of positive and negative impacts was found for allother types of features.     

Stochastic perturbation analysis of groundwater flow. Spatially variable soils,semi-infinite domains and large fluctuations

As is well known, a complete stochastic solution of the stochastic differential equation governing saturated groundwater flow leads to an infinite hierarchy of equations in terms of higher-order moments. Perturbation techniques are commonly used to close this hierarchy, using power-series expansions. These methods are applied by truncating the series after a finite number of terms, and products of random gradients of conductivity and head potential are neglected. Uncertainty regarding the number or terms required to yield a sufficiently accurate result is a significant drawback with the application of power series-based perturbation methods for such problems. Low-order series truncation may be incapable of representing fundamental characteristics of flow and can lead to physically unreasonable and inaccurate solutions of the stochastic flow equation. To support this argument, one-dimensional, steady-state, saturated groundwater flow is examined, for the case of a spatially distributed hydraulic conductivity field. An ordinary power-series perturbation method is used to approximate the mean head, using second-order statistics to characterize the conductivity field. Then an interactive perturbation approach is introduced, which yields improved results compared to low-order, power-series perturbation methods for situations where strong interactions exist between terms in such approximations. The interactive perturbation concept is further developed using Feynman-type diagrams and graph theory, which reduce the original stochastic flow problem to a closed set of equations for the mean and the covariance functions. Both theoretical and practical advantages of diagrammatic solutions are discussed; these include the study of bounded domains and large fluctuations.     

Mean wind-direction shear through a forest canopy

The equations of motion applying to the wind field in a forest canopy are simplified to a balance between the shearing stress gradient and either the form-drag of the leaves in the upper dense canopy, or the overall horizontal pressure gradient in the more open space beneath. The equations imply that, in descending through the forest, the stress and wind vectors turn through an angle which depends on the forest characteristics and on the stability and the speed of the airflow above the forest. The turning is roughly confirmed by an overall average measured on a very flat site near Thetford, Norfolk, covered by an extensive uniform pine forest.     

The theory of geomagnetic induction

The theoretical basis of electromagnetic induction methods in geophysics is considered with special reference to the interplay of physical ideas and mathematical arguments. The design of mathematical problems to elucidate observed physical phenomena, and methods of solving them, are discussed. Earth models suitable for various types of investigation are considered. The importance of getting the correct physical interpretation of the solution of a mathematical problem is stressed.     

Sédimentation récifale rythmique dans le Jurassique superieur du Grand-Saleve (Haute-Savoie,France)

Résumé L'étude statistique des composants minéraux et organiques, selon les méthodes de l'auteur, a été effectuée sur plus de 600 coupes minces régulièrement distribuées dans une série récifale de 225 m d'épaisseur. Elle a révélé des soulèvements et des subsidences encadrant des récifs et se traduisant par une succession de microfaciès clastiques dont les assemblages faunistiques sont très bien délimités au point de vue bathymétrique. Une comparaison avec les formations récifales actuelles est tentée sur la base des faunes périrécifales.     

Tektonik und zyklische Sedimentation in der helvetischen Zone der Schweizer Alpen

Zusammenfassung In der helvetischen Kreide scheint es also im ganzen so zu sein, daß die einfachen Rhythmen (Feinschichtung und Kalk-Mergel-Schichtwechsel) klimatisch, d. h. exogen, die Zyklen und Großzyklen tektonisch, d. h. endogen, begründet sind (3).     

In-flight performance analysis of the CHAMP BlackJack GPS Receiver

JPL's BlackJack receiver currently represents the most widely used geodetic grade GPS receiver for space applications. Using data from the CHAMP science mission, the in-flight performance of the BlackJack receiver has been assessed and the impact of various software updates performed during the 2.5 years since launch is described. Key aspects of the study comprise the channel allocation, anomalous data points, and the noise level of the code and carrier data. In addition, it has been demonstrated that the code measurements collected onboard the CHAMP satellite are notably affected by multipath errors in the aft-looking hemisphere, which can be attributed to cross-talk between the occultation antenna string and the primary precise orbit determination antenna. For carrier smoothed 10 s normal points, the code noise itself varies between a minimum of 5 cm at high elevations and 0.5 m (C/A) to 1.0 m (P₁, P₂) at 10° elevation. Carrier-phase data exhibit representative errors of 0.2 to 2.5 mm. The results of the CHAMP GPS data analysis contribute to a better understanding and possible improvement of the BlackJack receiver and support the design of optimal data editing and weighting strategies in precise orbit determination applications.