Experimental Study of Brittle Behavior of Clay Shale in Rapid Triaxial Compression

The brittle failure behavior of an over-consolidated clay shale (Opalinus Clay) in undrained rapid triaxial compression was studied. The confining stress levels were chosen to simulate the range of confining stresses relevant for underground excavations at the Mont Terri Underground Research Laboratory, and to investigate the transition from axial splitting failure to macroscopic shear failure. Micro-crack initiation was observed throughout the confining stress range utilized in this study at a differential stress of 2.1 MPa on average, which indicates that friction was not mobilized at this stage of brittle failure. The rupture stress was dependent on confinement indicating friction mobilization during the brittle failure process. With increasing confinement net volumetric strain decreased suggesting that dilation was suppressed, which is possibly related to a change in the failure mode. At confining stress levels ≤0.5 MPa specimen rupture was associated with axial splitting. With increasing confinement, transition to a macroscopic shearing mode was observed. Multi-stage triaxial tests consistently showed lower strengths than single-stage tests, demonstrating cumulative damage in the specimens. Both the Mohr–Coulomb and Hoek–Brown failure criteria could not satisfactorily fit the data over the entire confining stress range. A bi-linear or S-shaped failure criterion was found to satisfactorily fit the test data over the entire confinement range studied.     

Field-seismic investigation of the August 1975 Oroville, California, earthquake sequence

Several thousand aftershocks of the August 1, 1975 Oroville, California, earthquake (M_L = 5.7) were recorded by an 8-station field-seismic network. Focal coordinates of 104 of these events were fitted by least-squares to a plane striking N07°W and dipping 59°W; the strike (but not the dip) of this plane is in good agreement with that (N09°W) obtained from a fault-plane solution for a large foreshock 8 sec before the main shock, and it agrees fairly well with the trend (N15°W) of structural lineaments in the vicinity of Lake Oroville. The surface trace of the plane of foci passes through the Oroville Dam, as well as through surface cracking 12 km south of the dam. The main shock occurred 7 years after the filling of Lake Oroville, but only a month after the most rapid filling since 1968. The rate of aftershock occurrence during the first month decayed approximately as1/t. Event duration was measured for more than 2,000 aftershocks during August and September; average log-duration, taken over samples of 100 events, decreased gradually during this period. Close-in spectra obtained from strong-motion recordings of several of the larger aftershocks have corner frequencies that are quite high compared to other western U.S. earthquakes of similar magnitude. The Oroville earthquakes had several features in common with another Sierra Nevada earthquake sequence, near Truckee, California, in September, 1966.     

Estuaries of the South Atlantic coast of North America: Their geographical signatures

Estuaries of the southeastern Atlantic coastal plain are dominated by shallow meso-tidal bar-built systems interspersed with shallow sounds and both low flow coastal plain and high flow piedmont riverine systems. Three general geographical areas can be discriminated: the sounds of North Carolina; the alternating series of riverine and ocean dominated bar-built systems of South Carolina, Georgia, and northeast Florida, and the subtropical bar-built estuaries of the Florida southeast coast. The regional climate ranges from temperate to subtropical with sea level rise and hurricanes having a major impact on the region's estuaries because of its low and relatively flat geomorphology. Primary production is highest in the central region. Seagrasses are common in the northern and southern most systems, while intertidal salt marshes composed ofSpartina alterniflora reach their greatest extent and productivity in South Carolina and Georgia. Nuisance blooms (cyanobacteria, dinoflagellates, and cryptomonads) occur more frequently in the northern and extreme southern parts of the region. Fishery catches are highest in the North Carolina and Florida areas. Human population growth with its associated urbanization reaches a maximum in Florida and it is thought that the long-term sustainability of the Florida coast for human habitation will be lost within the next 25 years. Tidal flushing appears to play an important role in mitigating anthropogenic inputs in systems of moderate to high tidal range, i.e., the South Carolina and Georgia coasts. The most pressing environmental problems for the estuaries of the southeastern Atlantic coast seem to be nutrient loading and poor land use in North Carolina and high human population density and growth in Florida. The future utilization of these estuarine systems and their services will depend on the development of improved management strategies based on improved data quality.     

Microchondrule-bearing clast in the Piancaldoli LL3 meteorite: a new kind of type 3 chondrite and its relevance to the history of chondrules

In the Piancaldoli LL3 chondrite, we found a mm-sized clast containing ~100 chondrules 0.2–64 μm in apparent diameter (much smaller than any previously reported) that are all of the same textural type (radial pyroxene; FS_1–17). This clast, like other type 3 chondrites, has a fine-grained Ferich opaque silicate matrix, sharply defined chondrules, abundant low-Ca clinopyroxene and minor troilite and Si- and Cr-bearing metallic Fe,Ni. However, the very high modal matrix abundance (63 ± 8 vol. %), unique characteristics of the chondrules, and absence of microscopically-observable olivine indicate that the clast is a new kind of type 3 chondrite. Most chondrules have FeO-rich edges, and chondrule size is inversely correlated with chondrule-core FeO concentration (the first reported correlation of chondrule size and composition). Chondrules acquired Fe by diffusion from Fe-rich matrix material during mild metamorphism, possibly before final consolidation of the rock. Microchondrules (those chondrules ? 100 μm in diameter) are also abundant in another new kind of type 3 chondrite clast in the Rio Negro L chondrite regolith breccia. In other type 3 chondrite groups, microchondrule abundance appears to be anticorrelated with mean chondrule size, viz. 0.02–0.04 vol. % in H and CO chondrites and ?0.006 vol. % in L, LL, and CV chondrites.Microchondrules probably formed by the same process that formed normal-sized droplet chondrules: melting of pre-existing dustballs. Because most compound chondrules in the clast and other type 3 chondrites formed by collisions between chondrules of the same textural type, we suggest that dust grains were mineralogically sorted in the nebula before aggregating into dustballs. The sizes of compound chondrules and chondrule craters, which resulted from collisions of similarly-sized chondrules while they were plastic, indicate that size-sorting (of dustballs) occurred before chondrule formation, probably by aerodynamic processes in the nebula. We predict that other kinds of type 3 chondrites exist which contain chondrule abundances, size-ranges and proportions of textural types different from known chondrite groups.     

Interstadial proboscidean from south-central Alaska: Implications for biogeography, geology, and archeology

In 1980 a large proboscidean femur, probably Mammuthus sp., was found in situ in a bluff exposure at the mouth of the Tyone River in the northwestern part of the Copper River Basin, Alaska. The regional setting, stratigraphy, radiocarbon chronology, flora, and implications of the fossil locality, which represents the first documented occurrence of Pleistocene terrestrial mammalian fauna in southern Alaska, are described. Radiocarbon dates and stratigraphic relations at the site indicate that the sediments containing the fossil accumulated during the transition from interstadial to glacial conditions during terminal middle Wisconsin time. During this interval the immediate vicinity was unforested and large areas of south-central Alaska may have been available for faunal and possibly human habitation. This documented find, dated at 29,450 ± 610 ¹⁴C yr B.P., extends the known range for Pleistocene mammals and possibly steppe-tundra conditions south-ward at least 150 km, and suggests that mountain passes through the Alaska Range to the north were ice free during the last part of the middle Wisconsin interstadial.     

Aspects of the mineralogy and hydrometallurgy of chrysocolla,with special reference to the Cuajone,Peru, ores

Chrysocolla in the Cuajone ores appears to be microcrystalline and to exhibit a fibrous structure.Sulphuric acid leaching of the chrysocolla is facilitated by a microcracked surface structure. A marked surface structural change is evidenced as hydrogen ions replace the copper. The end result is a noncontinuous surface layer of silica from which the copper has been essentially completely removed.The results of this study provide confirmatory evidence for the structure and hydrometallurgy of chrysocolla.     

A complete dynamical ozone budget measured in the tropical marine boundary layer during PASE

The Pacific Atmospheric Sulfur Experiment (PASE) was a field mission that took place aboard the NCAR C-130 airborne laboratory over the equatorial Pacific Ocean near Christmas Island (Kirimati, Republic of Kiribati) during August?CSeptember, 2007. Eddy covariance measurements of the ozone fluxes at various altitudes above the ocean surface, along with simultaneous mapping of the horizontal gradients provided a unique opportunity to observe all of the dynamical components of the ozone budget in this remote marine environment. The results of six daytime and two sunrise flights indicate that vertical transport into the marine boundary layer from above and horizontal advection by the tradewinds are both important source terms, while photochemical destruction consisting of 82% photolysis (leading to OH production), 11% reaction with HO₂, and 7% reaction with OH provides the main sink. The overall photochemical lifetime of ozone in the marine boundary layer was found to be 6.5 days. Ocean uptake of ozone was observed to be fairly slow (mean deposition velocity of 0.024?±?0.014 cm s^?1) accounting for a diurnally averaged loss rate that was ??30% as large as the net photochemical destruction. From the measurement of deposition velocity an ozone reactivity of ??50 s^?1 in seawater is inferred. Due to the unprecedented measurement accuracy of the dynamical budget terms, unobserved photochemistry was able to be deduced, leading to the conclusion that 3.9?±?3.0 ppt (parts per trillion by volume) of NO is present on average in the daytime tropical marine boundary layer, broadly consistent with several previous studies in similar environments. It is estimated, however, that each ppt of BrO hypothetically present would counter each ppt of NO above the requisite 3.9 ppt needed for budget closure. The long-term budget of ozone is further analyzed in the buffer layer, between the boundary layer and free troposphere, and used to derive an entrainment velocity across the trade wind inversion of 0.51 ± 0.38 cm s^?1.     

Commingling and mixing of S-type peraluminous, ultrapotassic and basaltic magmas in the Cayconi volcanic field, Cordillera de Carabaya, SE Peru

The Cayconi district of the Cordillera de Carabaya, SE Peru, exposes a remnant of an upper Oligocene–Lower Miocene (22.2–24.4 Ma) volcanic field, comprising a diverse assemblage of S-type silicic and calc-alkaline basaltic to andesitic flows, members of the Picotani Group of the Central Andean Inner Arc. Basaltic flows containing olivine, plagioclase, clinopyroxene, ilmenite and glass, and glassy rhyolitic agglutinates with phenocrystic quartz, cordierite, plagioclase, sanidine, ilmenite and apatite, respectively exhibit mineralogical and geochemical features characteristic of medium-K mafic and Lachlan S-type silicic lavas. Cordierite-bearing dacitic agglomerates and lavas, however, are characterized by dispersed, melanocratic micro-enclaves and phenocrysts set in a fine-grained quartzo-feldspathic matrix. They contain a bimodal mica population, comprising phlogopite and biotite, as well as complexly zoned, sieve-textured plagioclase grains, sector-zoned cordierite, sanidine, quartz, irregular patches of replaced olivine, clinopyroxene and orthopyroxene and accessory phases including zircon, monazite, ilmenite and chromite. The coexistence of minerals not in mutual equilibrium and the growth/dissolution textures exhibited by plagioclase are features indicative of magmatic commingling and mixing. Trachytic-textured andesite flows interlayered with olivine+plagioclase–glomerophyric, calc-alkaline basalts have a phenocrystic assemblage of resorbed orthopyroxene and plagioclase and exhibit melanocratic groundmass patches of microphenocrystic phlogopite, Ca-rich sanidine, ilmenite and aluminous spinel. The mineralogical and mineral chemical relationships in both the dacites and the trachytic-textured andesites imply subvolcanic mixing between distinct ultrapotassic mafic melts, not represented by exposed rock types, and both the S-type silicic and calc-alkaline mafic magmas. Such mixing relationships are commonly observed in the Oligo-Miocene rocks of the Cordillera de Carabaya, suggesting that the S-type rocks in this area and, by extension, elsewhere derive their unusually high K₂O, Ba, Sr, Cr and Ni concentrations from commingling and mixing with diverse, mantle-derived potassic mafic magmas.     

Ediacaran terrane accretion within the Arabian–Nubian Shield

The Ad Dawadimi Terrane is an Ediacaran basin of the Arabian Nubian Shield (ANS), Saudi Arabia. This basin terrane is situated in the far eastern part of the ANS and represents the youngest accretion event of the exposed ANS. Therefore, the timing of events within the basin is key to understanding both the closure of the Mozambique Ocean and the amalgamation of Gondwana along the northern East African Orogen. Here we present U/Pb detrital zircon data for the Abt Formation, the principle basin sediments of the Ad Dawadimi Terrane, along with ⁴⁰Ar/³⁹Ar ages on muscovite and whole rock Sm/Nd data. These data indicate that deep-water deposition in the Abt Basin did not end until after ca. 620 Ma and that deformation and greenschist-facies metamorphism of the Abt Formation occurred at 620 ± 3 (2σ) Ma along an active margin. This is the youngest terrane amalgamation event reported so far in the Arabian–Nubian Shield, but we suggest even younger sutures lie further east beneath the Phanerozoic cover of eastern Saudi Arabia. Our results suggest that the Ediacaran basins of the eastern ANS were not part of the Huqf basin in Oman, which was instead part of a passive margin of Neoproterozoic India, separated from the active margin of Africa by the Mozambique Ocean that probably did not close until the late Ediacaran or early Cambrian.