Sedimentological and provenance response to Cambrian closure of the Clymene ocean: The upper Alto Paraguai Group,Paraguay belt,Brazil

Final Gondwana amalgamation was marked by the closure of the Neoproterozoic Clymene ocean between the Amazonia craton and central Gondwana. The events which occurred in the last stage of this closure were recorded in the upper Alto Paraguai Group in the foreland of the Paraguay orogen. Outcrop-based facies analysis of the siliciclastic rocks of upper Alto Paraguai Group, composed of the Sepotuba and Diamantino Formations, was carried out in the Diamantino region, within the eastern part of the Barra dos Bugres basin, Mato Grosso state, central-western Brazil. The Sepotuba Formation is composed of sandy shales with planar to wave lamination interbedded with fine-grained sandstone with climbing ripple cross-lamination, planar lamination, swaley cross-stratification and tangential to sigmoidal cross-bedding with mud drapes, related to marine offshore deposits. The lower Diamantino Formation is composed of a monotonous, laterally continuous for hundreds of metres, interbedded siltstone and fine-grained sandstone succession with regular parallel lamination, climbing ripple cross-lamination and ripple-bedding interpreted as distal turbidites. The upper part of this formation consists of fine to medium-grained sandstones with sigmoidal cross-bedding, planar lamination, climbing ripple cross-lamination, symmetrical to asymmetrical and linguoid ripple marks arranged in lobate sand bodies. These facies are interbedded with thick siltstone in coarsening upward large-scale cycles related to a delta system. The Sepotuba Formation characterises the last transgressive deposits of the Paraguay basin representing the final stage of a marine incursion of the Clymene ocean. The progression of orogenesis in the hinterland resulted in the confinement of the Sepotuba sea as a foredeep sub-basin against the edge of the Amazon craton. Turbidites were generated during the deepening of the basin. The successive filling of the basin was associated with progradation of deltaic lobes from the southeast, in a wide lake or a restricted sea that formed after 541 ± 7 Ma. Southeastern to east dominant Neoproterozoic source regions were confirmed by zircon grains that yielded ages around 600 to 540 Ma, that are interpreted to be from granites in the Paraguay orogen. This overall regressive succession recorded in the Alto Paraguai Group represents the filling up of a foredeep basin after the final amalgamation of western Gondwana in the earliest Phanerozoic.     

Formal definition of a user-adaptive and length-optimal routing graph for complex indoor environments

Car routing solutions are omnipresent and solutions for pedestrians also exist.Furthermore,public or commercial buildings are getting bigger and the complexity of their internal structure has increased.Consequently,the need for indoor routing solutions has emerged.Some prototypes are available,but they still lack semantically-enriched modelling (e.g.,access constraints,labels,etc.) and are not suitable for providing user-adaptive length-optimal routing in complex buildings.Previous approaches consider simple rooms,concave rooms,and corridors,but important characteristics such as distinct areas in huge rooms and solid obstacles inside rooms are not considered at all,although such details can increase navigation accuracy.By formally defining a weighted indoor routing graph,it is possible to create a detailed and user-adaptive model for route computation.The defined graph also contains semantic information such as room labels,door accessibility constraints,etc.Furthermore,one-way paths inside buildings are considered,as well as three-dimensional building parts,e.g.,elevators or stairways.A hierarchical structure is also possible with the presented graph model.     

Phase transitions and path dependence in urban evolution

There is a long history of recognising and interpreting discontinuous change—phase transitions—in urban systems. In this paper, we use the aggregate retail model as an archetype to explore some new ideas. For example, we argue that the dependence of paths of development on initial conditions has been understudied, and we offer a new graphical analysis that demonstrates explicitly their influence on discrete change. We introduce an order parameter, and we plot this on a ‘results grid’ to facilitate the discovery of possible phase transitions. We illustrate the use of these new developments with an application to London. We show how retail developers can change the ‘initial conditions’ at a point in time and possibly bring about phase transitions by their actions. This also shows that it should be possible to account for the history of urban development as a sequence of initial conditions, illustrating path dependence. Secondly, the model could be deployed in relation to a new shopping zone, and the tools developed here used to calculate the minimum size of a new development in order for it to compete. We explore the ‘minimum size’ idea in relation to a new shopping zone in London.     

Scenarios with MIT integrated global systems model: significant global warming regardless of different approaches

A wide variety of scenarios for future development have played significant roles in climate policy discussions. This paper presents projections of greenhouse gas (GHG) concentrations, sea level rise due to thermal expansion and glacial melt, oceanic acidity, and global mean temperature increases computed with the MIT Integrated Global Systems Model (IGSM) using scenarios for twenty-first century emissions developed by three different groups: intergovernmental (represented by the Intergovernmental Panel on Climate Change), government (represented by the U.S. government Climate Change Science Program) and industry (represented by Royal Dutch Shell plc). In all these scenarios the climate system undergoes substantial changes. By 2100, the CO₂ concentration ranges from 470 to 1020 ppm compared to a 2000 level of 365 ppm, the CO₂-equivalent concentration of all greenhouse gases ranges from 550 to 1780 ppm in comparison to a 2000 level of 415 ppm, oceanic acidity changes from a current pH of around 8 to a range from 7.63 to 7.91, in comparison to a pH change from a preindustrial level by 0.1 unit. The global mean temperature increases by 1.8 to 7.0°C relative to 2000. Such increases will require considerable adaptation of many human systems and will leave some aspects of the earth??s environment irreversibly changed. Thus, the remarkable aspect of these different approaches to scenario development is not the differences in detail and philosophy but rather the similar picture they paint of a world at risk from climate change even if there is substantial effort to reduce emissions.     

Defense community perspectives on uncertainty and confidence judgments

In 2007, the CNA Military Advisory Board (MAB), an expert panel composed of 11 retired admirals and generals from the United States, identified climate change as a “threat multiplier” for instability in some of the most volatile regions of the world. (CNA MAB National security and the threat of climate change 2007)The Department of Defense reached a similar conclusion in last year’s Quadrennial Defense Review–a legislatively mandated analysis of the Defense Department’s strategy and priorities. This document frames the long-term course for policy decision-making at the highest levels. The reports demonstrate that climate change and energy are now mainstream elements of national security planning, and can be assessed within the frameworks used to evaluate other threats, risks, and responses. However, the exact magnitude of the threat posed by climate change is difficult to calibrate in part because the language used by scientists to predict uncertainty and the confidence levels of judgments is not sufficiently clear. The defense community has a vast amount of experience exploring and dealing with uncertainty. Scientists trying to better describe the effects of climate change may be able to draw lessons from the defense community’s approach to uncertainty including how to better communicate findings to wide audiences including policy-makers.     

Stable carbon isotopic compositions of intact polar lipids reveal complex carbon flow patterns among hydrocarbon degrading microbial communities at the Chapopote asphalt volcano

Seepage of asphalt forms the basis of a cold seep system at 3000 m water depth at the Chapopote Knoll in the southern Gulf of Mexico. Anaerobic microbial communities are stimulated in the oil-impregnated sediments as evidenced by the presence of intact polar membrane lipids (IPLs) derived from archaea and Bacteria at depths up to 7 m below the seafloor. Detailed investigation of stable carbon isotope composition (δ¹³C) of alkyl and acyl moieties derived from a range of IPL precursors with distinct polar head groups resolved the complexity of carbon metabolisms and utilization of diverse carbon sources by uncultured microbial communities. In surface sediments most of the polar lipid-derived fatty acids with phosphatidylethanolamine (PE), phosphatidylglycerol (PG) and diphosphatidylglycerol (DPG) head groups could be tentatively assigned to autotrophic sulfate-reducing bacteria, with a relatively small proportion involved in the anaerobic oxidation of methane. Derivatives of phosphatidyl-(N)-methylethanolamine (PME) were abundant and could be predominantly assigned to heterotrophic oil-degrading bacteria. Archaeal IPLs with phosphate-based hydroxyarchaeols and diglycosidic glyceroldibiphytanylglyceroltetraethers (GDGTs) were assigned to methanotrophic archaea of the ANME-2 and ANME-1 cluster, respectively, whereas δ¹³C values of phosphate-based archaeols and mixed phosphate-based and diglycosidic GDGTs point to methanogenic archaea. At a 7 m deep sulfate-methane transition zone that is linked to the upward movement of gas-laden petroleum, a distinct increase in abundance of archaeal IPLs such as phosphate-based hydroxyarchaeols and diglycosidic archaeol and GDGTs is observed; their δ¹³C values are consistent with their origin from both methanotrophic and methanogenic archaea. This study reveals previously hidden, highly complex patterns in the carbon-flow of versatile microbial communities involved in the degradation of heavy oil including hydrocarbon gases that would not have been evident from classical compound-specific isotope analyses of either bulk IPL or apolar lipid derivatives.     

High-precision osmium isotopes in enstatite and Rumuruti chondrites

Isotopic heterogeneity within the solar nebula has been a long-standing issue. Studies on primitive chondrites and chondrite components for Ba, Sm, Nd, Mo, Ru, Hf, Ti, and Os yielded conflicting results, with some studies suggesting large-scale heterogeneity. Low-grade enstatite and Rumuruti chondrites represent the most extreme ends of the chondrite meteorites in terms of oxidation state, and might thus also present extremes if there is significant isotopic heterogeneity across the region of chondrite formation. Osmium is an ideal tracer because of its multiple isotopes generated by a combination of p-, r-, and s-process and, as a refractory element; it records the earliest stages of condensation.Some grade 3-4 enstatite and Rumuruti chondrites show similar deficits of s-process components as revealed by high-precision Os isotope studies in some low-grade carbonaceous and ordinary chondrites. Enstatite chondrites of grades 5-6 have Os isotopic composition identical within error to terrestrial and solar composition. This supports the view of digestion-resistant presolar grains, most likely SiC, as the major carrier of these anomalies. Destruction of presolar grains during parent body processing, which all high-grade enstatite chondrites, but also some low-grade chondrites seemingly underwent, makes the isotopically anomalous Os accessible for analysis. The magnitude of the anomalies is consistent with the presence of a few ppm of presolar SiC with a highly unusual isotopic composition, produced in a different stellar environment like asymptotic giant branch stars (AGB) and injected into the solar nebula. The presence of similar Os isotopic anomalies throughout all major chondrite groups implies that carriers of Os isotopic anomalies were homogeneously distributed in the solar nebula, at least across the formation region of chondrites.     

Time series analysis of daily rainfall and streamflow in a volcanic dike-intruded aquifer system, O��ahu, Hawai��i, USA

A conceptual model of groundwater occurrence was developed for a dike-intruded aquifer system in M??kaha valley, O??ahu, Hawai??i, USA, and used to explain the impacts of water resource development on groundwater levels and streamflow. Time-series analyses were applied to two subsets of daily rainfall, total flow, and baseflow??from the third (1946?C1968) and fourth (1968?C1991) periods of development??to evaluate changes in streamflow response. Autocorrelation, cross-correlation, squared coherency and phase functions were used to estimate the decorrelation lag time, and the correlation length, linearity with frequency, and frequency response delay between rainfall and streamflow. The decorrelation lag time for total flow and baseflow declined by 16?C20?days (d). The correlation length between rainfall and streamflow declined 4?C7?d for total flow and 10?C13?d for baseflow. The squared coherency function indicates an overall decline in linearity between rainfall and total flow across most frequencies. The changes in hydrologic response following increased water-resource development is consistent with a model of groundwater depletion resulting in less groundwater discharge and more induced groundwater recharge. Changes in streamflow response are inconsistent with observed changes in rainfall and imply that streamflow decline is more likely to be the result of groundwater pumping.     

Indirect Effects of Salinity and Temperature on Kuwait’s Shrimp Stocks

Discharge of the Shatt Al-Arab is believed to be a dominating component of the northern Arabian Gulf’s ecology and largely responsible for productivity of Kuwait’s fisheries. With major construction of dams on the Tigris and Euphrates Rivers in Turkey, river discharge has been substantially reduced, and flooding essentially eliminated. We attempted to relate river flow and shrimp landings indirectly by correlating 19 years of salinity and temperature data from Kuwait’s waters with corresponding annual shrimp landings. For green tiger prawns (Penaeus semisulcatus), the combination of October salinities and January temperatures provided the best correlation (r = 0.67) with landings in the following shrimping season. For the combined landings of jinga and kiddi shrimps (Metapenaeus affinis and Parapenaeopsis stylifera, respectively), December salinity during season and May temperature prior to season resulted in the best correlation (r = 0.87). Landings of these two species also correlated well with spring and summer temperatures. Under normal conditions, late winter or early spring temperatures prior to fishing season influence recruitment of the green tiger prawn, whereas December salinities during harvest season influence the abundance of jinga–kiddi shrimps. With further reductions in the Shatt Al-Arab discharge and the elimination of flood events, Kuwait’s shrimp landings will most likely decrease over time.     

Lunar atmospheric H2 detections by the LAMP UV spectrograph on the Lunar Reconnaissance Orbiter

We report on the detection of H₂ as seen in our analysis of twilight observations of the lunar atmosphere observed by the LAMP instrument aboard NASA’s Lunar Reconnaissance Orbiter. Using a large amount of data collected on the lunar atmosphere between September 2009 and March 2013, we have detected and identified, the presence of H₂ in the native lunar atmosphere, for the first time. We derive a surface density for H₂ of 1.2 ± 0.4 × 10³ cm⁻³ at 120 K. This is about 10 times smaller than originally predicted, and several times smaller than previous upper limits from the Apollo era data.