Geochemistry and geochronology of chemical weathering,Butler Hill Granite,Missouri

Major element, Rb, Sr and Sr isotope abundances were examined in an ancient (Cambrian) weathering zone in the Butler Hill Granite, Missouri. Most of the major elements behaved predictably and systematically as a result of weathering intensity. MgO and the alkalis (Na₂O and K₂O) show highly erratic variations in both fresh and weathered rocks, suggesting considerable initial heterogeneity in the composition of biotite and feldspar. Rb predictably follows the behaviour of K during weathering (showing erratic variations similar to K), whereas Sr follows Ca (decreasing steadily as a result of weathering intensity). A method is postulated to date ancient weathering episodes using Rb-Sr data from a sequence of fresh to highly weathered samples. Data from the Butler Hill Granite (1185 m.y.) lend support to the proposed dating technique but show that more detailed sampling of the most intensely weathered regions is needed to produce more accurate results in future studies.     

Rubidium,strontium and the isotopic composition of strontium in ultramafic nodule minerals and host basalts

The concentrations of rubidium and strontium and the isotopic composition of strontium have been determined in minerals separated from ultramaflc nodules occurring in late Tertiary and Quaternary basalts of wide geographic distribution. Clinopyroxene, orthopyroxene and olivine from each of three Iherzolite nodules show a relatively wide range of ⁸⁷Sr/⁸⁶Sr disequilibrium and none of the minerals is in isotopic equilibrium with its host basalt. In two cases there is a correlation between ⁸⁷Sr/⁸⁶Sr and ⁸⁷Rb/⁸⁶Sr ratios of the nodule minerals, indicating apparent isochron relationships which may represent relict mantle events. Clinopyroxene and olivine from each of two wehrlite nodules are not in isotopic equilibrium, although the magnitude of the disequilibrium is smaller than that observed in the Iherzolite nodules. None of these ultramafic nodules can be a crystal cumulate from its host basalt, and it is doubtful that any type of genetic relationship exists. The strontium isotopic disequilibrium between nodule minerals seems to be a primary feature inherited from past mantle histories.     

Climate change influences on pollinator,forest, and farm interactions across a climate gradient

Improved cookstoves have been identified in Mexico as a key opportunity to advance sustainable local development priorities in disadvantaged regions while mitigating climate change. This paper reviews the Patsari Cookstove Project initiated in 2003 by an NGO, Interdisciplinary Group on Appropriate Rural Technology (GIRA). The project applied an interdisciplinary and participative user-centered approach to disseminate improved cookstoves in rural Mexico, with a special focus on indigenous and poor rural communities. To date, GIRA and the Patsari Network have disseminated thousands of stoves using a “training to trainers” model. Benefits from the project include tangible improvements in users’ health, as well as savings in time and money expended on fuelwood procurement and use. The project has also documented substantive environmental benefits from significant mitigation of greenhouse gas (GHG) emissions associated with traditional open fires. To sustain scaling up efforts over the long-term, two networks have been created: The Patsari Network, which includes several organizations promoting Patsari stoves for household users, and the Tsiri Network, which supports local food security and the empowerment of indigenous women through the promotion of institutional cookstoves. Through appropriately designed and implemented local interventions, the project demonstrates that the goals of advancing sustainable local development in rural areas and climate change mitigation may not be contradictory, and may in fact reinforce one another.     

Burial,Maturation, and Petroleum Generation History of the Arkoma Basin and Ouachita Foldbelt,Oklahoma and Arkansas

Removed overburden, burial, maturation, and petroleum generation analysis indicates that maturity in the Arkoma Basin and the Ouachita Foldbelt is explained effectively using simple burial models that account for the significant surface erosion that has occurred and assuming geothermal gradients similar to present-day gradients have been approximately constant through geologic time. Regional models, based on analysis at 115 well locations, indicate that from 5,000 to 15,000 ft (1.5–4.5 km) of section, differing with location from north to south and west to east, has been removed from the Arkoma Basin region, and as much as 25,000–40,000 ft (7.5–12 km) have been removed from areas of the Ouachita Foldbelt. Based on burial and thermal history reconstruction, increasing maturation from west to east across the basin is primarily the result of increasing overburden and subsequent surface erosion from west to east. The models predict most publicly available vitrinite reflectance data within a factor of 1.5 at two standard deviations. Comparison of model and measured reflectance-depth trends in six wells indicates that hydrothermal fluid movement should not have modified reflectance by more than approximately 20% in the center of the basin. Analysis indicates that most of the basin is overmature for oil production from intervals below the Spiro Sandstone, except to the north and northwest. Although thermal maturities are high, methane is stable throughout the basin. Except for the basal Arbuckle Group, all formations were thermally immature for oil generation prior to burial by the Mississippian and Morrowan in the Ouachita Foldbelt of Oklahoma and by the Atokan and Desmoinesian over most of the basin and study area. In the deeper part of the present basin, all strata entered and passed through the oil window during or within 10 My after Atokan time. Because no additional major quantities of hydrocarbons were generated after Atokan time, the hydrocarbons must have been emplaced and trapped during this brief time interval.     

Active regions losing their moorings by subsurface reconnection

Eleven microwave spike events observed with the 2.6–3.8 GHz spectrometer of Beijing Astronomical Observatory (BAO) are analysed. The polarization degrees of spikes are variable, some spikes have frequency drift with the drift rate of several GHz s^–1. In particular, the time delay (8 ms) between the two polarization modes of spike is detected, which is different from previous results. According to the leading spot rule, we conclude that the o-modes arrive first. Moreover, the reversal of polarization sense versus frequency is also found. A change of the emission mode may be the cause of the polarization reversal.     

Simultaneous X-ray and IR variability in the quasar 3C 273

From a combination of high-quality X-ray observations from the NASA Rossi X-ray Timing Explorer ( RXTE ) and IR observations from the UK Infrared Telescope (UKIRT) we show that the medium-energy X-ray (3–20 keV) and near-IR fluxes in the quasar 3C 273 are highly correlated. It is widely believed that the X-ray emission in quasars like 3C 273 arises from Compton scattering of low-energy seed photons, and our observations provide the first reliable detection of correlated variations in 3C 273 between the X-ray band and any lower energy band. For a realistic electron distribution we demonstrate that it is probable that each decade of the seed-photon distribution from the mm to IR wavebands contributes roughly equally to the medium-energy X-ray flux. However, the expected mm variations are too small to be detected above the noise, probably explaining the lack of success of previous searches for a correlation between X-ray and mm variations. In addition, we show that the IR leads the X-rays by  0.75±0.25 d  . These observations rule out the 'External Compton' emission process for the production of the X-rays.     

Budapest's built environment in transition

The construction of major new buildings has been noticed in Budapest since the mid 1980s. New hotels, office blocks, housing projects and most recently shopping centres have become a prominent feature of the landscape in several districts of the city. The paper first outlines a conceptualisation of the `Transition' in terms of eastern Europe as a whole identifying internationalisation, Europeanisation and national government policies as key strands in a specific case of a process of change interpreted as the interaction of antecedent conditions and current processes. It then addresses the question of conceptualising the built environment in terms of the `Transition' and three `schools of thought' in geography stressing the urban morphogenesis approach. It thus poses the question of how radical a change has `occurred on the ground' since 1989–1990. Consequently the paper examines the transition in the built environment of Budapest under three principal headings: (a) the antecedent conditions of the built environment of Budapest by spatial structure, (b) the relationship between new buildings and current processes, (c) comparing models of the spatial structure of Budapest as a socialist city and as a post-socialist-(industrial) city or post-industrial (capitalist) city. It concludes that although the processes shaping the city's built environment have changed quite radically since 1990 the physical fabric of the city and its antecedent usage have strongly influenced the spatial impact of the current processes. Budapest is a post-socialist industrial city with capitalist forms fitted into it. The city is passing from socialist to capitalist processes in a way that suggests that morphological analysis has clear potential in theorising the relationship between the global and the local. This revised version was published online in July 2006 with corrections to the Cover Date.     

Regional‐scale sedimentation process models from airborne gamma ray remote sensing and digital elevation data

Airborne gamma ray survey data were used to provide information on potassium, thorium and uranium concentrations in surface soil and rock in arid central Australia. Spatial patterns in these radioelements allow tracing of paths of sediment at catchment scale. Survey elevation data are combined with contour data to produce digital elevation models for terrain analysis, tracing of sediment flow paths and modelling of extreme floods. Gamma ray data show consistent variation with slope, a limited range of drainage areas, and erosion/deposition models derived from the conservation of mass equation. Supply‐limited sediment transport models give a reasonable reproduction of observed radioelement distribution but some elements of the distribution pattern reflect the area inundated by 500–1000 year floods rather than the effects of simple downslope movement. Partial area sediment supply models are derived by downstream accumulation of erosion and deposition rates calculated using the conservation of mass equation with transport laws based on slope alone and stream power. Comparison with observed radioelement patterns suggests that both transport laws apply in different parts of the landscape. Regional‐scale sediment transport models will require a range of models depending on location in the landscape and event frequency. This approach may allow estimation of sediment delivery ratios. Copyright © 2001 John Wiley & Sons, Ltd.