Anharmonic effect on the equation of state (EoS) for NaCl

We find clear intrinsic anharmonicity in the NaCl-B1 phase by examining the equation of state (EoS) based on previous ultrasonic velocity data for pressures up to 0.8 GPa and temperatures up to 800 K. The experimental EoS for this phase shows that its specific heat at constant volume (C _V ) is significantly smaller than that based on a harmonic model. Also, the sign of $\left( {{{\partial C_{V} } \mathord{\left/ {\vphantom {{\partial C_{V} } {\partial P}}} \right. \kern-0pt} {\partial P}}} \right)_{T} ,$ which is normally negative in the quasi-harmonic approximation, is unexpectedly positive. The thermodynamic Grüneisen parameter (γ), which has frequently been assumed to be a single-variable function of molar volume, shows not only volume dependence but also negative temperature dependence. To understand these features of C _V and γ, we introduce a thermodynamic model including positive quartic anharmonicity. To make an anharmonic model advancing the ordinarily quasi-harmonic approximation model, we introduce two parameters: anharmonic characteristic temperature (θ _a ) and its volume derivative. In the anharmonic model, the value of C _V is calculated along an isochore using classical statistical mechanics and a harmonic quantum correction. At high temperatures, the decrease in C _V from the Dulong-Petit limit is related to the value of T/θ _a . For infinitely large θ _a , the system is approximately quasi-harmonic. The temperature dependence of γ is related to C _V by the thermodynamic identity $\left( {{{\partial C_{V} } \mathord{\left/ {\vphantom {{\partial C_{V} } {\partial \ln V}}} \right. \kern-0pt} {\partial \ln V}}} \right)_{T} = C_{V} \left( {{{\partial \gamma } \mathord{\left/ {\vphantom {{\partial \gamma } {\partial \ln T}}} \right. \kern-0pt} {\partial \ln T}}} \right)_{V} + \gamma \left( {{{\partial C_{V} } \mathord{\left/ {\vphantom {{\partial C_{V} } {\partial \ln T}}} \right. \kern-0pt} {\partial \ln T}}} \right)_{V}.$ Even though our modification of the quasi-harmonic approximation is simple, our anharmonic model succeeds in reproducing the experimental γ and C _V simultaneously for the NaCl-B1 phase.     

Study on the fate of petroleum-derived polycyclic aromatic hydrocarbons (PAHs) and the effect of chemical dispersant using an enclosed ecosystem,mesocosm

Polycyclic Aromatic Hydrocarbons (PAHs) are one of the components found in oil and are of interest because some are toxic. We studied the environmental fate of PAHs and the effects of chemical dispersants using experimental 500 l mesocosm tanks that mimic natural ecosystems. The tanks were filled with seawater spiked with the water-soluble fraction of heavy residual oil. Water samples and settling particles in the tanks were collected periodically and 38 PAH compounds were analyzed by gas chromatography-mass spectrometry (GC-MS). Low molecular weight (LMW) PAHs with less than three benzene rings disappeared rapidly, mostly within 2 days. On the other hand, high molecular weight (HMW) PAHs with more than four benzene rings remained in the water column for a longer time, up to 9 days. Also, significant portions (10-94%) of HMW PAHs settled to the bottom and were caught in the sediment trap. The addition of chemical dispersant accelerated dissolution and biodegradation of PAHs, especially HMW PAHs. The dispersant amplified the amounts of PAHs found in the water column. The amplification was the greater for the more hydrophobic PAHs, with an enrichment factor of up to six times. The increased PAHs resulting from dispersant use overwhelmed the normal degradation and, as a result, higher concentrations of PAHs were observed in water column throughout the experimental period. We conclude that the addition of the dispersant could increase the concentration of water column PAHs and thus increase the exposure and potential toxicity for organisms in the natural environment. By making more hydrocarbon material available to the water column, the application of dispersant reduced the settling of PAHs. For the tank with dispersant, only 6% of chrysene initially introduced was detected in the sediment trap whereas 70% was found in the trap in the tank without dispersant.     

Geographical distribution of helium isotope ratios in northeastern Japan

In order to study the precise geographical distribution of helium isotope ratios in northeastern Japan and compare it with geophysical data, we collected 43 gas and water samples from hot and mineral springs in the region where the ratio had never been reported, and measured the ³He/⁴He and ⁴He/²⁰Ne ratios of these samples. It was found that the ³He/⁴He ratios show clear contrasts between the forearc and the back-arc regions in the Tohoku district in northeastern Japan. In the forearc region, the ratios are smaller than 1 R_A (1 R_A = 1.4 × 10⁻⁶; R_A means the ³He/⁴He ratio of the atmosphere). On the other hand, those along the volcanic front and in the back-arc region are apparently higher. Moreover, we found a variation in the ³He/⁴He ratios along the volcanic front. In Miyagi Prefecture (38–39°N), the ratios range from 2 to 5 R_A. On the other hand, the ratios are less than 1 R_A in and around the southern border between Iwate and Akita Prefectures (39–39.5°N). Comparing the distribution of helium isotope ratios to results of recent geophysical studies, we found that the features in geographical distribution of helium isotope ratios are similar to those of seismic low-velocity zone distributions and high Qp⁻¹ distributions in the uppermost mantle. These observations strongly suggest that the helium isotope ratios reflect the distribution of melts in the uppermost mantle and are a useful tool for investigating the origin, behavior, and distribution of deep fluids and melts.     

Using sulfur isotopes to determine the sources of vermillion in ancient burial mounds in Japan

This study represents an attempt to determine the sources of vermillion found in ancient Japanese burial mounds of the 1st–6th centuries A.D., by comparing their ratios of sulfur isotopes with those of cinnabar ore samples collected in Japan and China. Cinnabar ore samples were taken from three mines in central Japan (Niu in Mie, Yamato in Nara, and Sui in Tokushima prefectures), and from Wanshan in China, where mining activity has been recorded back to the 6th century A.D. and earlier. When the ratios of a ³⁴S and ³²S were compared with the Canyon Diablo meteorite standard, a high δ³⁴S value of +22.6 ± 3.6‰ was found for the Wanshan mine, as opposed to low values ranging from −7.3 ± 1.9 to −2.1 ± 1.6‰ for the Japanese mines. The ratios of sulfur isotopes in vermillion collected from ancient Japanese burial mounds also divided into two groups. High ratios (+11.1 to +22.8‰) were found in 1st‐ and 2nd‐ century burials in the western regions of northern Kyushu and San'in, suggesting that local, powerful chiefs obtained vermillion through relations with China. Lower ratios (−8.4 to −2.0‰) were found in burials of the 2nd through 6th centuries in central Japan, where the ancient Yamato dynasty emerged as the first unified polity around the end of the 2nd century A.D. We, therefore, conclude that the Yamato dynasty exploited local sources of vermillion, rather than depending solely on China. The present study demonstrates the feasibility of determining sources of vermillion using sulfur isotope ratios, and the relevance of such findings for archaeological research. © 2005 Wiley Periodicals, Inc.     

Quantitative approach for damage detection of reinforced concrete frames

The objective of this paper is to provide an analytical basis for the quantitative evaluation of damage to a reinforced concrete structure based on the vibration data obtained by using the damage detection technique. A partial reinforced concrete system of a weak beam/strong column moment frame is chosen as an example. A pushover analysis is carried out in order to numerically examine both the story shear-relative displacement characteristics and the associated damage level. In the analysis, a two dimensional nonlinear finite element analysis is employed considering several constitutive models. As a result, the degradation of the stiffness at the damaged story is characterized in association with the story relative displacement. It is also pointed out that the rotation angle of the column-base is highly correlated with the story relative displacement. Based on the analytical findings, quantitative approaches for a structural health monitoring system are suggested considering both the current sensor technologies and those available in the future. Supported by: Ministry of Education, Science, Sports and Culture, Grant-in-Aid for Scientific Research (Base Research (c) (1), Research No. 14550555)     

Cenozoic Island Arc Magmatism in Java Island (Sunda Arc, Indonesia): Clues on Relationships between Geodynamics of Volcanic Centers and Ore Mineralization

Abstract. Java island, regarded as a classic example of island arcs, is built through multi events of Cenozoic arc magmatism produced by the subduction of Indian‐Australian oceanic crusts along the southern margin of Eurasian plate. Regional crustal compositions, subducted slabs, and tectonics determined the spatial‐geochemical evolution of arc magmatism and regional metallogeny. Tertiary geodynamics of island arc was dominated by backarc‐ward migrations of volcanic centers. Only after the Miocene‐Pliocene roll‐back effects of retreating slab, slab detachment, and backarc magmatism took place in central Java. The source of arc magmas is mainly partial melting of mantle wedge, triggered by fluids released from dehydrated slabs. Increasing potassium contents of arc magmas towards the backarc‐side and younger magmas is typical for all magmas, while alkali and incompatible trace elements ratios are characteristics for different settings of volcanic centers. The oceanic nature of crust and the likely presence of hot slab subducted beneath the eastern Java determine the occurrences of adakitic magmas. Backarc magmatism has a deeper mantle source with or without contributions from subduction‐related materials. The domination of magnetite‐series magmatism determines the sulfide mineralization for the whole island. District geology, geodynamics, and magma compositions in turn control particular styles and scales of precious metals concentrations. Deep‐seated crustal faults have focused the locations of overlapping volcanic centers and metalliferous fluids into few major gold districts. Porphyry deposits are mostly concentrated within Lower Tertiary (early stage) volcanic centers in eastern Java which are not covered by younger volcanic centers, and whose sulfides are derived from partial melting of basaltic parental materials. On the other hand, high‐grade low‐sulfidation epithermal gold deposits formed in later stages of arc development and are spatially located within younger volcanic centers (Upper Miocene‐Pliocene) that overlap the older ones. Gold in low‐sulfidation epithermal system is likely to be derived from crustal materials. The overall interacting factors resulting in the petrochemical systematics that are applicable for exploration: 1) early‐stage volcanic centers with high Sr/Y and Na₂O/K₂O ratios are more prospective for porphyry mineralization, while 2) later‐stage volcanic centers with high K₂O, total alkali, and K₂O/Na₂O ratios are more prospective for low‐sulfidation epithermal mineralization.     

The nature of the CM parent asteroid regolith based on cosmic ray exposure ages

Cosmic ray exposure (CRE) ages of CM chondrites have been found to have multiple peaks (as many as four), in stark contrast to other groups of chondrites (Nishiizumi and Caffee 2012; Herzog and Caffee 2014). In this study, we sought correlations between the CRE ages and petrography of CM chondrites, and we conclude that the degree of aqueous alteration does appear to vary with the CRE ages—the CMs displaying the most aqueous alteration all have relatively short exposure ages. However, some CMs with low degrees of alteration also have short exposure ages—thus, this apparent correlation is not exclusive. We also found a definite inverse relation between the number of distinctive lithologies in a CM and its exposure age, which could indicate different responses of homogeneous and heterogeneous meteoroids to the space environment between their onset of exposure (exhumation and ejection from the parent body) and arrival at Earth. Breccias have more internal surfaces of lithologic discontinuity, possibly resulting in weaker meteoroids that disintegrate more readily than their more homogeneous counterparts. Our results suggest that CM chondrite regoliths consist of numerous genomict lithologies in a breccia with millimeter‐ to decimeter‐scale clasts, with varying degree of heating/metamorphism.     

Magnetic detection of heated soils at paleolithic sites in Japan

We present a methodological approach to detect heated soil on ancient sites, using magnetic measurements. The method is based on changes in magnetic signals of soil by heating. The following three types of soil were used for testing the method: silty soil (SS), weathered volcanic ash (WVA, = loam) and fairly fresh volcanic ash (VA) called Odori tephra. On heating above 250–600°C, the magnetic susceptibility and remanent magnetization intensity increased for the SS and WVA samples, reflecting chemical alteration of magnetic minerals (from goethites to magnetites through hematites). The VA sample showed no susceptibility change suggesting the absence of goethites within it. On heating below 250°C, only the intensities of all the samples increased. This is possibly due to acquisition of thermal remanent magnetization. The largest change of the magnetic signals was identified for the SS sample and the smallest one was seen for the VA sample. Therefore, the in situ susceptibility measurement, which is the nondestructive and indirect method, seems to be effective to detect heated soil for sites of aqueous deposits as the SS. On the other hand, for sites of aeolian deposits as the WVA (loam) and VA, the intensity measurement of collected soils seems to be the most reliable method to detect evidence of heating. The degree of the magnetic stability (coercivity) against progressive alternating-field demagnetization was also an important parameter, indicating whether the investigated soils were heated or unheated. © 1999 John Wiley & Sons, Inc.