Primary Ore Mineral Assemblage and Fluid Inclusion Study of the Batu Hijau Porphyry Cu-Au Deposit, Sumbawa, Indonesia

Abstract. The Batu Hijau porphyry Cu‐Au deposit, Sumbawa Island, Indonesia, is associated with a tonalitic intrusive complex. The temperature‐pressure condition of mineralization at the Batu Hijau deposit is discussed on the basis of fluid inclusion microthermometry. Then, the initial Cu‐Fe sulfide mineral assemblage is discussed. Bornite and chalcopyrite are major copper ore minerals associated with quartz veinlets. The quartz veinlets have been classified into ‘A’ veinlets associated with bornite, digenite, chalcocite and chalcopyrite, ‘B’ veinlets having chalcopyrite bornite along vuggy center‐line, rare ‘C’ chalcopyrite‐quartz veinlets, and late ‘D’ veinlets consisting of massive pyrite and quartz (Clode et al., 1999). Copper and gold mineralization is associated with abundant ‘A’ quartz veinlets. Abundant fluid inclusions are found in veinlet quartz consisting mainly of gas‐rich inclusions and polyphase inclusions throughout the veinlet types. The hydrothermal activity occurred in temperature‐pressure conditions of aqueous fluid immiscibility into hypersaline brine and dilute vapor. The halite dissolution (Tm[halite]) and liquid‐vapor homogenization (Th) temperatures of the polyphase inclusions in veinlet quartz range from 270 to 472d?C and from 280 to 454d?C, respectively. The estimated salinity ranges from 36 to 47 wt% (NaCl equiv.). The apparent pressures lower than 300 bars are estimated to have been along the liquid‐vapor‐halite curve for the fluid inclusions having the Th lower than the Tm that trapped the brine saturated with halite, or at slightly higher pressure relative to liquid‐vapor‐halite curve for the fluid inclusions having the Th higher than the Tm that trapped the brine unsaturated with halite. The actual temperature and pressure during the hydrothermal activity at the Batu Hijau deposit are estimated to have been around 300d?C and 50 bars. At such temperature‐pressure conditions, the principal and initial Cu‐Fe sulfide mineral assemblages are thought to be chalcopyrite + bornite solid solution (bnss) for the chalcopyrite‐bearing assemblage, and chalcocite‐digenite solid solution and bnss for the chalcopyrite‐free assemblage.     

Partial melting kinetics of plagioclase-diopside pairs

Partial melting experiments on plagioclase (An₆₀) and diopside have been carried out using pairs of large crystals to investigate textures and kinetics of melting. The experiments were done at one atmosphere pressure as a function of temperature (1,190–1,307° C) and time (1.5–192 h). Melting took place mainly at the plagioclase-diopside contact planes. Reaction zones composed of fine mixtures of calcic plagioclase and melt were developed from the surface of the plagioclase crystal inward. There exists a critical temperature, below which only a few % melting can occur over the duration of the experiments. This sluggish melting is caused by slow NaSi-CaAl diffusion in plagioclase, because the plagioclase crystal must change its composition to produce albite-rich cotectic melts. Diffusion in the solid also affects the chemical composition of the melts. During initial melting, potassium is preferentially extracted from plagioclase because K-Na diffusion in plagioclase is faster than that of NaSi-CaAl. This also causes a shift in the cotectic compositions. Above the critical temperature, on the other hand, melting is promoted by a metastable reaction in which the plagioclase composition does not change, and which produces melts with compositional gradients along the original An₆₀-diopside tie line. The critical temperature is determined by the intersection of the cotectic and the An₆₀-diopside tie line. Interdiffusion coefficients of plagioclase-diopside components in the melt are estimated from melting rates above the critical temperature by using a simplified steady-state diffusion model (e.g., 10^–8 cm²/sec at 1,300° C).Many examples of reaction zones due to partial melting have been described as spongy or fingerprint-like textures in xenoliths. Metastable melting above the critical temperature is considered to take place in natural melting where there is a high degree of melting. However, we cannot exclude the possibility of disequilibrium created by sluggish melting controlled by diffusion in the minerals. If melting occurs close to the solidus, this process can be important even for partial melting in the upper mantle.     

Limit states and failure mechanisms of viscous dampers and the implications for large earthquakes

Fluid viscous dampers are used to control story drifts and member forces in structures during earthquake events. These elements provide satisfactory performance at the design‐level or maximum considered earthquake. However, buildings using fluid viscous dampers have not been subjected to very large earthquakes with intensities greater than the design and maximum considered events. Furthermore, an extensive database of viscous damper performance during large seismic events does not exist. To address these issues, a comprehensive analytical and experimental investigation was conducted to determine the performance of damped structures subjected to large earthquakes. A critical component of this research was the development and verification of a detailed viscous damper mathematical model that incorporates limit states. The development of this model and the laboratory and simulation results conclude good correlation with the new model and the damper limit states and provide superior results compared with the typical damper model when considering near collapse evaluation of structures. Copyright © 2010 John Wiley & Sons, Ltd.     

Sulfur isotope study of Quaternary volcanic rocks from the Japanese Islands Arc

The sulfide and sulfate contents and their δ³⁴S values were determined in Quaternary volcanic rocks from the Japanese Islands Arc. The total sulfur contents are much lower (less than 40 ppm) and the δ³⁴S values are higher (+4.4 ± 2.1) than those of ocean-floor basalts (800 ± 100 ppm and +0.8 ± 0.5, respectively; Moore and Fabbi, 1971; Sakaiet al., 1982). Lateral variations of both sulfur content and δ³⁴S values were observed in the four volcanic belts in Japan. In the Northeast Japan belt, the sulfur content (30 ± 10 ppm) of the rocks in the inner zone (the Japan Sea side) is 3 to 5 times that in the outer zone (the Pacific side), although the δ³⁴S values of the two zones are almost the same (+4.3 ± 1.0). The δ³⁴S values for the two belts in West Japan are on the average 2%. higher than those of East Japan.This study suggests that the primary magmas that formed the island arc volcanic rocks are initially depleted in sulfur (<120 ppm) and enriched in ³⁴S ($\text{δ}{}^{34}\text{S: +5 ～ +7}$) compared to ocean-floor tholeiitic basalts which formed at mantle under oceanic region. This indicates that the upper-mantle is heterogeneous in sulfur content and isotope composition.     

Strong motion uncertainty determined from observed records by dense network in Japan

The variation of ground motions at specific stations from events in six narrow areas was inspected by using K-NET and KiK-net records. A source-area factor for individual observation stations was calculated by averaging ratios between observed values for horizontal peak acceleration and velocity, as well as acceleration response spectra for 5% damping, and predicted values using a ground-motion model (usually known as an attenuation relation) by Kanno et al. (Bull Seismol Soc Am, 96:879–897, 2006). Standard deviations between observed and predicted amplitudes after the correction factor are less than 0.2 on the logarithmic scale and decrease down to around 0.15 in the short-period range. Intra-event standard deviation clearly increases with decreasing distance due to differing paths around near source area. Standard deviations may increase with amplitude or decrease with magnitude; however, both amplitude and magnitude of the data are strongly correlated with distance. The standard deviation calculated in this study is obviously much smaller than that of the original ground-motion model, as epistemic uncertainties are minimized by grouping ground motions at specific stations. This result indicates that the accuracy of strong ground motion prediction could be improved if ground-motion models for specified region are determined individually. For this to be possible, it is necessary to have dense strong-motion networks in high-seismicity regions, such as K-NET and KiK-net.     

Outflow Propagation in Collapsars: Collimated Jets and Expanding Outflows

We investigate the outflow propagation in the collapsar in the context of gamma-ray bursts (GRBs) with 2D relativistic hydrodynamic simulations. We vary the specific internal energy and bulk Lorentz factor of the injected outflow from non-relativistic regime to relativistic one, fixing the power of the outflow to be 10⁵¹erg s⁻¹. We observed the collimated outflow, when the Lorentz factor of the injected outflow is roughly greater than 2. To the contrary, when the velocity of the injected outflow is slower, the expanding outflow is observed. The transition from collimated jet to expanding outflow continuously occurs by decreasing the injected velocity. Different features of the dynamics of the outflows would cause the difference between the GRBs and similar phenomena, such as, X-ray flashes.     

Relative chronology of crust formation on asteroid Vesta: Insights from the geochemistry of diogenites

The eucrites and diogenites are meteorites that probably originate from asteroid 4-Vesta. The upper part of the crust of this body is certainly composed of eucrites which are basaltic or gabbroic rocks. Diogenites are ultramafic cumulates whose relationships with eucritic lithologies are unknown. Here, we show that the orthopyroxenes of some diogenites display very deep negative Eu anomalies (Eu/Eu∗ close to 0.1 or lower). The contamination of the parental magmas of diogenites by melts derived by partial melting of the eucritic crust can satisfactorily explain the range of the Eu anomalies displayed by diogenites. Thus, these anomalies are the first firm indication that parental melts of diogenites have intruded the eucritic crust, and consequently are younger than eucrites.