Origin of a unique impact-melt rock—the L-chondrite Ramsdorf

Abstract— We have studied a unique impact-melt rock, the Ramsdorf L chondrite, using optical and scanning microscopy and electron microprobe analysis. Ramsdorf contains not only clast-poor impact melt (Begemann and Wlotzka, 1969) but also a chondritic portion (>60 g) with what appears at low magnification to be a normal, well-defined chondritic texture. However, detailed studies at high magnification show that >90 vol% of the crystals in the chondritic portion were largely melted by the impact: the chondrules lack normal microtextures and are ghosts of the original features. The only relics from the precursor chondrules are olivine crystals, which have the highest melting temperature (～1620 °C). Pyroxene-rich chondrules were so extensively melted that no phenocrysts were preserved and the melt crystallized in situ before significant mixing with exterior olivine-rich melts. Fine-grained pyroxene chondrule ghosts have sharper boundaries with the matrix than porphyritic olivine and pyroxene chondrule ghosts, probably because pyroxene-rich melts are significantly more viscous. Complex textures that formed by injection of melt along cracks and fractures in relic olivines suggest that the chondritic portion of Ramsdorf formed directly from petrologic type 3–4 material by strong shock. We infer that Ramsdorf was largely melted by shock pressures of ～75–90 GPa and that chondrule ghosts and relic olivine phenocrysts were locally preserved by rapid cooling. Quenching was not due to the addition of cold clasts into the melt but to heterogeneous shock heating that only caused internal melting of large olivines and pyroxenes. Ramsdorf appears to be one of the most heavily shocked meteorites that has retained some trace of its original texture.     

Magma transport and reservoir formation by a system of propagating cracks

A system of propagating cracks may explain magma transport and the evolution of a volcano. This paper considers only a basaltic magma. The system is controlled by two boundary conditions: the stress field, and the production rate of the magma-filled cracks in the mantle. Numerical solutions of crack propagation for various stress conditions, with a constant production rate high enough to coalesce isolated cracks, were performed, and the results applied to different tectonic conditions. For the hydrostatic stress conditions, most magma-filled cracks beneath a polygenetic volcano become trapped either in the lower crust, because there the density difference between magma and the host rocks () becomes suddenly small, compared with that in the mantle, or trapped in the upper crust, because there is near to zero. Magma traps composed of such cracks may grow into magma reservoirs if the production rate of cracks in the mantle is large. If horizontal stress with a vertical gradient is superimposed on the hydrostatic condition in the crust, that is, tensile stress which increases upward or compressional stress which increases downward, magmafilled cracks, even if the density of magma is higher than that of the crust, may ascend directly without trapping. When the crust undergoes relative tension, magma-filled cracks may become trapped. Then, the lower part of the trap may grow into a magma reservoir, while the upper part may become filled with dikes. When the production rate of cracks is small, an initial magma-filled crack can rise directly to the surface only when the stress with a gradient is superimposed as mentioned above, or when the average density in a crack decreases, owing to, for example, vesiculation of volatile components.     

Molecular-scale mechanisms of distribution and isotopic fractionation of molybdenum between seawater and ferromanganese oxides

The distribution of Mo between seawater and marine ferromanganese oxides has great impacts on concentration and isotopic composition of Mo in modern oxic seawater. To reveal the adsorption chemistry of Mo to ferromanganese oxides, we performed (i) detailed structural analyses of Mo surface complexes on δ-MnO₂, ferrihydrite, and hydrogenetic ferromanganese oxides by L₃- and K-edge XAFS, and (ii) adsorption experiments of Mo to δ-MnO₂ and ferrihydrite over a wide range of pHs, ionic strengths, and Mo concentrations. XAFS analyses revealed that Mo forms distorted octahedral (Oh) inner-sphere complexes on δ-MnO₂ whereas it forms a tetrahedral (Td) outer-sphere complex on ferrihydrite. In the hydrogenetic ferromanganese oxides, the dominant host phase of Mo was revealed to be δ-MnO₂. These structural information are consistent with the macroscopic behaviors of Mo in adsorption experiments, and Mo concentration in modern oxic seawater can be explained by the equilibrium adsorption reaction on δ-MnO₂. In addition, the large isotopic fractionation of Mo between seawater and ferromanganese oxides detected in previous studies can be explained by the structural difference between and adsorbed species on the δ-MnO₂ phase in ferromanganese oxides. In contrast, smaller fractionation of Mo isotopes on ferrihydrite is due to little change in the Mo local structures during its adsorption to ferrihydrite.The structures of Mo species adsorbed on crystalline Fe (oxyhydr)oxides, goethite, and hematite were also investigated at pH 8 and I = 0.70 M (NaNO₃). Our XAFS analyses revealed that Mo forms inner-sphere complexes on both minerals: Td edge-sharing (46%) and Oh double corner-sharing (54%) for goethite, and Td double corner-sharing (14%) and Oh edge-sharing (86%) for hematite. These structural information, combined with those for amorphous ferrihydrite and δ-MnO₂, show the excellent correlation with the magnitude of adsorptive isotopic fractionation of Mo reported in previous studies: the proportion of Oh species or their magnitude of distortion in Mo surface complexes become larger in the order of ferrihydrite < goethite < hematite < δ-MnO₂, a trend identical to the magnitude of isotopic fractionation.Based on the comparison with previous reports for Mo surface species on various oxides, the chemical factors that affect Mo surface complex structures were also discussed. The hydrolysis constant of cation in oxides, log K_OH (or the acidity of the oxide surfaces, PZC) is well correlated with the mode of attachment (inner- or outer-sphere) of Mo surface complexes. Furthermore, the symmetric change in Mo species from Td to Oh is suggested to be driven by the formation of inner-sphere complexes on specific sites of the oxide surfaces.     

Preface of “Earthquake,volcanism, and physical oceanography”

Marine Geophysical Research -     

A new occurrence of retrogressed eclogite from the Sanbagawa belt of southwest Japan and its significance

The present paper reports, for the first time, the occurrence of an omphacite‐bearing mafic schist from the Asemi‐gawa region of the Sanbagawa belt (southwest Japan). The mafic schist occurs as thin layers within pelitic schist of the albite–biotite zone. Omphacite in the mafic schist only occurs as inclusions in garnet, and albite is the major Na phase in the matrix, suggesting that the mafic schist represents highly retrogressed eclogite. Garnet grains in the sample show prograde‐type compositional zoning with no textural or compositional break, and contain mineral inclusions of omphacite, quartz, glaucophane, barroisite/hornblende, epidote and titanite. In addition to the petrographic observations, Raman spectroscopy and focused ion beam system–transmission electron microscope analyses were used for identification of omphacite in the sample. The omphacite in the sample shows a strong Raman peak at 678 cm^?1, and concomitant Raman peaks are all consistent with those of the reference omphacite Raman spectrum. The selected area electron diffraction pattern of the omphacite is compatible with the common P2/n omphacite structure. Quartz inclusions in the mafic schist preserve high residual pressure values of Δω₁ > 8.5 cm^?1, corresponding to the eclogite facies conditions. The combination of Raman geothermobarometries and garnet–clinopyroxene geothermometry gives peak pressure–temperature (P–T) conditions of 1.7–2.0 GPa and 440–540 °C for the mafic schist. The peak P–T values are comparable to those of the schistose eclogitic rocks in other Sanbagawa eclogite units of Shikoku. These findings along with previous age constraints suggest that most of the Sanbagawa schistose eclogites and associated metasedimentary rocks share similar simple P–T histories along the Late Cretaceous subduction zone.     

Using a regional numerical weather prediction model for GNSS positioning over Brazil

The global navigation satellite system (GNSS) can provide centimeter positioning accuracy at low costs. However, in order to obtain the desired high accuracy, it is necessary to use high-quality atmospheric models. We focus on the troposphere, which is an important topic of research in Brazil where the tropospheric characteristics are unique, both spatially and temporally. There are dry regions, which lie mainly in the central part of the country. However, the most interesting area for the investigation of tropospheric models is the wet region which is located in the Amazon forest. This region substantially affects the variability of humidity over other regions of Brazil. It provides a large quantity of water vapor through the humidity convergence zone, especially for the southeast region. The interconnection and large fluxes of water vapor can generate serious deficiencies in tropospheric modeling. The CPTEC/INPE (Center for Weather Forecasting and Climate Studies/Brazilian Institute for Space Research) has been providing since July 2012 a numerical weather prediction (NWP) model for South America, known as Eta. It has yield excellent results in weather prediction but has not been used in GNSS positioning. This NWP model was evaluated in precise point positioning (PPP) and network-based positioning. Concerning PPP, the best positioning results were obtained for the station SAGA, located in Amazon region. Using the NWP model, the 3D RMS are less than 10 cm for all 24 h of data, whereas the values reach approximately 60 cm for the Hopfield model. For network-based positioning, the best results were obtained mainly when the tropospheric characteristics are critical, in which case an improvement of up to 7.2 % was obtained in 3D RMS using NWP models.     

Genesis of the Mamut Porphyry Copper Deposit, Sabah, East Malaysia

Abstract: The Mamut deposit of Sabah, East Malaysia, is a porphyry type Cu‐Au deposit genetically related to a quartz monzonite (“adamellite”) porphyry stock associated with upper Miocene Mount Kinabalu plutonism. The genesis of the Mamut deposit is discussed based on petrology of the intrusives in the Mount Kinabalu area combined with ore– and alteration–petrography, fluid inclusion and sulfur isotope studies. Groundmass of the adamellite porphyry at Mamut is rich in K which suggests vapor transport of alkaline elements during the mineralizing magmatic process, while the groundmass of the post‐ore “granodiorite” porphyry at Mamut contains small amounts of normative corundum suggesting depletion in alkaline elements at the root zone of the magma column. Sub‐dendritic tremolitic amphibole rims on hornblende phenocrysts in the Mamut adamellite porphyry suggest interaction between the mineralizing magma and the exsolved fluids. Occurrences of clinopyroxene microphenocrysts and pseudomor‐phic aggregates of shredded biotite and clinopyroxene after hornblende phenocrysts in the barren intrusives imply lower water fugacity and decreasing in water fugacity, respectively. Compositional gap between the core of hornblende phenocrysts and the tremolitic amphibole rims and those in the groundmass of the Mamut adamellite porphyry suggests a decrease in pressure. Higher X_Mg (=Mg/(Mg+Fe) atomic ratio) in the tremolitic amphibole rims in the Mamut adamellite porphyry compared to those of the barren intrusions suggests high oxygen fugacity. High halogen contents of igneous hydrous minerals such as amphiboles, biotite and apatite in the Mamut adamellite porphyry suggest the existence of highly saline fluids during the intrusion and solidification of the mineralizing magma. Fluid inclusions found in quartz veinlet stockworks are characterized by abundant hypersaline polyphase inclusions associated with subordinate amounts of immiscible gaseous vapor. Both Cu and Au are dispersed in disseminated and quartz stockwork ores. Chalcopyrite and pyrrhotite as well as magnetite are the principal ore minerals in the biotitized disseminated ores. Primary assemblage of intermediate solid solution (iss) and pyrrhotite converted to the present assemblage of chalcopyrite and pyrrhotite during cooling. Subsequent to biotitization, quartz veinlet stockworks formed associated with retrograde chlorite alteration. The Cu‐Fe sul–fides associated with stockwork quartz veinlet are chalcopyrite and pyrite. Overlapping Pb and Zn and subsequent Sb mineralizations were spatially controlled by NNE‐trending fractures accompanying the phyllic and advanced argillic alteration envelope. Sulfur isotopic composition of ore sulfides are homogeneous (about +2%) throughout the mineralization stages. These are identical to those of the magmatic sulfides of Mount Kinabalu adamellitic rocks.     

Strong motion uncertainty determined from observed records by dense network in Japan

The variation of ground motions at specific stations from events in six narrow areas was inspected by using K-NET and KiK-net records. A source-area factor for individual observation stations was calculated by averaging ratios between observed values for horizontal peak acceleration and velocity, as well as acceleration response spectra for 5% damping, and predicted values using a ground-motion model (usually known as an attenuation relation) by Kanno et al. (Bull Seismol Soc Am, 96:879–897, 2006). Standard deviations between observed and predicted amplitudes after the correction factor are less than 0.2 on the logarithmic scale and decrease down to around 0.15 in the short-period range. Intra-event standard deviation clearly increases with decreasing distance due to differing paths around near source area. Standard deviations may increase with amplitude or decrease with magnitude; however, both amplitude and magnitude of the data are strongly correlated with distance. The standard deviation calculated in this study is obviously much smaller than that of the original ground-motion model, as epistemic uncertainties are minimized by grouping ground motions at specific stations. This result indicates that the accuracy of strong ground motion prediction could be improved if ground-motion models for specified region are determined individually. For this to be possible, it is necessary to have dense strong-motion networks in high-seismicity regions, such as K-NET and KiK-net.     

利用地幔内反射波探测日本列岛下660 km不连续面的深度变化（英文）

通过分析发生在日本周边深源地震的宽频带波形资料,估计了日本列岛下的660km不连续面(d660)的深度变化。许多宽频带波形记录到了在d660顶部发生反射的sScS的后续波。sScS后续波与sScS间的到时差包含了震中与台站下方的d660深度变化的信息。我们成功地检测到这两种震相并将其分离,到目前为止还没有这方面研究的报道。我们由sScS与其后续波的到时差来求每个震中与记录台站下的d660的深度变化。研究结果显示,西部日本下的d660较深(大于660km),这可能是滞留在地幔转换带中的冷的太平洋板块造成的。在日本中部,d660变深,显然这不是太平洋板块本身造成的,因为日本中部已经位于该滞留板片的东部。日本东北部下的d660变得较浅,这可能是太平洋板片形状变化或下地幔热物质上涌形成局部热异常造成的。     

Temporal variations in the current structure and volume transport of the Coastal Oyashio revealed by direct current measurement

Direct current measurements by a shipboard and bottom-mounted acoustic Doppler current profiler and concurrent hydrographic observations with a CTD were conducted off southeastern Hokkaido, Japan, between January and May 2005 to reveal temporal variations in the current structure and volume transport of the Coastal Oyashio (CO). The CO, which has a baroclinic jet structure with southwestward speeds exceeding 90 cm s^?1 and a width of 7–8 km, was associated with a surface-to-bottom density front and was formed on the offshore side of the shelf break. The volume transport of CO (T _CO) was estimated by integrating the fluxes of lower-density water that was trapped against the coast along the density front represented by the 26.2 σ _θ isopycnal line. This transport decreased monotonously from 0.79 Sv (1 Sv = 10⁶ m³ s^?1) in January to 0.21 Sv in March and subsequently to 0.12 Sv in May, possibly due to the decay of the East Sakhalin Current Water in the Okhotsk Sea. Accompanied by a decrease in T _CO, the location of the jet structure associated with the density front moved toward the coast while the maximum speed of the jet decreased and the tilt of the front became more horizontal. Consequently, more saline offshore Oyashio water flowed into the deep part of the shelf area, and the current structure altered from relatively barotropic in winter to baroclinic in spring. This study is the first to estimate the observed volume transport of the CO from direct current measurements.