Ventilation revealed by the observation of dissolved oxygen concentration south of the Kuroshio Extension during 2012–2013

From the moored buoy observation at \(33.9^{\circ }\)N, \(144.9^{\circ }\)E south of the Kuroshio Extension (KE), we obtained Eulerian time series of dissolved oxygen concentration (DO) at 200, 400, and 600 m depths from June 2012 to March 2013. We observed ventilation by meso- and submesoscale processes that transport water southward across the KE jet. First, the cyclonic mesoscale eddy in June 2012 substantially depressed DO at depths of 400 and 600 m but maintained DO at 200 m, suggesting near-surface lateral transport of high-DO water derived from the north of the KE. Second, subduction of high-DO (>230 \({\upmu }\)mol kg\(^{-1}\)) water to a depth of 600 m was observed from early February to March 2013, associated with a mesoscale/submesoscale meandering of the KE jet. In mid-March 2013, shipboard hydrographic data were collected where the water mass at the mooring site would be advected by the eastward current on the southern flank of the KE. Based on these data, the subduction event was identified as an intrusion of an anomalously thick water mass from approximately 400–900 dbar. Ventilation of the subtropical mode water at a depth of 200 m around a subsurface DO maximum layer was detected as a rapid rise in DO in January 2013. This occurred after a significant seasonal decrease in DO at a rate of \(-0.130 \pm 0.007\) \({\upmu }\)mol kg\(^{-1}\) day\(^{-1}\) from July to December 2012.     

An anthophyllite-hornblende pair from Japan

Chemical, optical and X-ray powder data on coexisting anthophyllite and hornblende in an amphibolite are presented. Some chemical features of amphibole pairs are briefly discussed.     

Horizontal electric fields in the middle latitude

Three dimensional electric fields were measured at the altitude of about 27 km in the stratosphere over the Pacific Ocean about 200–400 km away from the Sanriku coast of Honsyu Island (L = 1·4) on 16–17 October 1973, which was magnetically disturbed. The average horizontal electric field thus measured is about 10 mV/m, and the electric field vectors made clockwise semidiurnal rotations rather than diurnal. Daily variation of this electric field was compared with data at L = 2·7–3·5 published by Mozer (1973) and was found to be very similar. This suggests that these electric fields are of common origin in the plasmasphere. From their mean daily variation it is estimated that the plasmaspheric convection is decreased in the night side and is increased in the day side by 200–300 m/sec, and there is an outward flow in the first half of the afternoon and an inward flow in the plasma bulge region of about 500 m/sec.     

Diel Changes in Vertical Distribution and Feeding Conditions of the Chaetognath Parasagitta elegans (Verill) in the Subarctic Pacific in Summer

Diel changes in vertical distribution and feeding conditions of the chaetognath Parasagitta elegans (Verill) were observed in three regions of the subarctic North Pacific in the summer of 1997. Samples were collected by repeated vertical hauls with a Vertical Multiple Plankton Sampler (VMPS) for 15–45 hours by demarcating the 0–500 m water column into four sampling layers. Integrated abundance through the entire water column and the proportion of juveniles were higher in the Bering Sea than the western and eastern subarctic Pacific. Juveniles always inhabited the surface layer in the western subarctic Pacific and Bering Sea, but they inhabited the underlying layer in the eastern subarctic Pacific. Stages I–III concentrated into the upper 150 m in the western subarctic Pacific but were distributed widely from 20–300 m in the Bering Sea. Among them, Stages II and III migrated rather synchronously over a wide vertical range in the eastern subarctic Pacific. The feeding rate of P. elegans was calculated to be 0.18 prey/chaetognath/day in the western subarctic Pacific, 0.27 prey/chaetognath/day in the Bering Sea and 0.07 prey/chaetognath/day in the eastern subarctic Pacific.     

Formation of water masses and fronts due to density-induced current system

Several numerical experiments were carried out on the formation of water masses and their fronts such as observed in the Kii Channel in winter. Such water masses and fronts may caused by density-induced current system. The phenomenon is assumed to take place in the vertical two-dimensional plane not involving the effect of the earth's rotation. The linear momentum equation and the diffusion-advection equations of salinity and temperature are integrated with respect to time under a vertically hydrostatic condition. The result is that two rolls which correspond to the onshore water mass and the offshore water mass are formed with an accompanying front between them. The apparent diffusion coefficient reaches a relatively great amount inside the water masses and drops down to the eddy diffusivity level at the front. The dependence of the synoptic distributions of the temperature and salinity on several parameters is also examined. Finally another experiment is carried out involving the effect of the earth's rotation, which results in a rather different distribution pattern from that of the non-rotating model.     

The roughness height and drag law over the water surface based on the hypothesis of local equilibrium

A series of measurements of winds and wind-waves were carried out in wind-wave flumes. A data analysis based on the hypothesis of local equilibrium yielded a new empirical formula on the controversial quantity of roughness heightz ₀ over the water surface: , where the nondimensional roughness height is defined bygz ₀/u _* ² and the wave-wind parameterũ byω _p u _*/g, g being the gravitational acceleration,u _* the friction velocity of air,ω _p the peak frequency of wind-wave spectra. The obtained formula is compared with Charnock's (1955) and Toba's (1979) proposals; is constant in the former and inversely proportional toũ in the latter. As in Toba's, this formula immediately leads to a practically important conclusion that the drag coefficientC _d depends not merely on the usual variableU ₁₀ (wind velocity at 10m height over the water surface), but also on the surface state represented by wind-waves. An explicit expression is provided for the drag coefficient incorporating the wave-wind parameter; it covers the range ofC _d calculated from most of the previous drag formulas, by varying the wave-wind parameter.     

Influence of Salinity on pH and Aluminum Concentration on the Interaction of Acidic Red Soil with Seawater

Contamination of acidic red soil in the coastal areas of Okinawa Islands is a serious environmental problem. This study was conducted to examine the effects of the salinity on pH and aluminum concentration when the acidic red soil interacts with seawater. Acidic red soil from Gushikawa recreation center was fractionated into bulk soil, coarse sand and silt + clay. Different weights of each fraction were equilibrated with seawater solutions. The pH and concentrations of Al³⁺, Na⁺, K⁺, Ca²⁺ and Mg²⁺ were then analyzed in the extracts. The results showed a decreasing trend of pH with increasing soil to solution ratio while the extracted Al³⁺ revealed an increasing trend. The lowest pH values were 3.85, 4.06, 4.41, 4.66 and their corresponding highest Al³⁺ concentrations were 2.50, 1.01, 0.062 and 0.036 mmolL⁻¹ in the seawater extracts, one-tenth seawater extracts, one-hundredth seawater extracts and one-thousandth seawater solution extracts, respectively. Mostly, the concentrations of Na⁺, Ca²⁺, Mg²⁺ and especially K⁺ decreased with increasing soil weight in the high salinities but showed the opposite trend in the low salinity samples. Potassium concentration decreased by 39%, 53% and 40% in the seawater extracts, one-tenth and one-hundredth seawater extracts but increased by 200% in one-thousandth seawater extracts. The coincidence of the increase in Al³⁺ and H⁺ concentrations, and the decrease of Na⁺, K⁺, Ca²⁺ and Mg²⁺ concentrations in the solutions suggests ion exchange/adsorption, while the increased patterns, particularly at low salinity could be attributed to the dissolution of the species from the soils.     

Organic geochemistry of the Japan Sea sediments-1: Bulk organic matter and hydrocarbon analyses of Core KH-79-3, C-3 from the Oki Ridge for paleoenvironment assessments

Organic geochemical study of bulk organic matter (OM), hopanoid hydrocarbon and normal hydrocarbon (C₂₃C₃₅) was conducted for a 936-cm-long sediment core sample from the Oki Ridge of the Japan Sea (Core KH-79-3, C-3; 37°03.5 N, 134°42.6E, water depth 935 m). Stable carbon isotopic ratios were also measured for both bulk OM and individual hydrocarbons. The following results were obtained: (1) The weight ratios of total organic carbon to total nitrogen range from 6.2 to 9.4 in the core. The ¹³C values of bulk OM range from –25.1–20.7%.. The ¹³C values of OM in the sections of 140190 cm are lower (–25–24) than those in the other sections (–23–21). This result indicates that OM in the core except for the 140190 cm sections is essentially of marine origin. (2) The ¹³C value of diploptene (a hopanoid hydrocarbon) in the last glacial maximum (LGM), is –66.3 (vs. PDB), which indicates it originating in methanotrophic bacteria. This result provides evidence to support for the previous ideas (Oba et al., 1980, 1984; Masuzawa and Kitano, 1984) that the bottom waters in the Japan Sea were anoxic in LGM. (3) Long chain (C₂₃C₃₅) n-alkanes of higher-plant wax origin were found throughout the core. Their concentration is high in 140190 cm in depth, suggesting that eolian dust load was high in LGM. (4) The n-alkane/TOC ratio increases with decreasing ¹³C values of bulk OM. This result indicates that the load of terrestrial (probably eolian dust-derived) OM to the Japan Sea became higher in colder climates. (5) The CPI values of long-chain n-alkanes are different in different ¹³O stages of paleoclimate, probably reflecting variations in species of terrestrial higher plants as a result of climatological adaptations.     

Wind-wave spectra based on the hypothesis of local equilibrium

Wind-wave spectra measured in a wind-flume are analyzed according to the hypothesis of local equilibrium. The gross relation between the wave height and the frequency is reexamined to yield the basic validity of the 3/2-power law of Toba orE～? in the range of 0.4≦?≦1, where? is the wave-wind parameter defined by?=ω _p u _*/g; ω _p denotes the peak frequency of the wind-wave spectra,u _* the friction velocity andg the gravitational acceleration. Noticeable deviation is found, however, for?<0.4 or?>1. In particular, the data for large? suggest the existence of an upper limit of the wave nonlinearityE at about 5×10^?2, whereE=Eω _p ⁴ /g² withE the total power of the wind wave spectrum. Then, the spectral form is investigated in detail. As? decreases, the normalized spectrum becomes more gradual as a whole, but its forward (low frequency) part tends to show a steeper profile. In the high frequency region ( \(\tilde \omega \) >2.6), the spectrum is found to have a functional form likeu _* ² ω ^?3, which differs from the usualω-dependence asω ^?5 orω ^?4. It suggests weak dependence of the high-frequency spectra on the gravitational accelerationg and on the peak frequencyω _p ; spectral density at high frequencies may be saturated, so that its magnitude may be dominated by the frequencyω, the friction velocityu _*, the surface tension and the viscosity.