Thermoelastic properties of chromium oxide Cr<Subscript>2</Subscript>O<Subscript>3</Subscript> (eskolaite) at high pressures and temperatures

A new synchrotron X-ray diffraction study of chromium oxide Cr₂O₃ (eskolaite) with the corundum-type structure has been carried out in a Kawai-type multi-anvil apparatus to pressure of 15 GPa and temperatures of 1873 K. Fitting the Birch–Murnaghan equation of state (EoS) with the present data up to 15 GPa yielded: bulk modulus (K _0,T0), 206 ± 4 GPa; its pressure derivative K′_0,T , 4.4 ± 0.8; (?K _0,T /?T) = ?0.037 ± 0.006 GPa K^?1; a = 2.98 ± 0.14 × 10^?5 K^?1 and b = 0.47 ± 0.28 × 10^?8 K^?2, where α _0,T  = a + bT is the volumetric thermal expansion coefficient. The thermal expansion of Cr₂O₃ was additionally measured at the high-temperature powder diffraction experiment at ambient pressure and α _0,T0 was determined to be 2.95 × 10^?5 K^?1. The results indicate that coefficient of the thermal expansion calculated from the EoS appeared to be high-precision because it is consistent with the data obtained at 1 atm. However, our results contradict α ₀ value suggested by Rigby et al. (Brit Ceram Trans J 45:137–148, 1946) widely used in many physical and geological databases. Fitting the Mie–Grüneisen–Debye EoS with the present ambient and high-pressure data yielded the following parameters: K _0,T0 = 205 ± 3 GPa, K′_0,T  = 4.0, Grüneisen parameter (γ ₀) = 1.42 ± 0.80, q = 1.82 ± 0.56. The thermoelastic parameters indicate that Cr₂O₃ undergoes near isotropic compression at room and high temperatures up to 15 GPa. Cr₂O₃ is shown to be stable in this pressure range and adopts the corundum-type structure. Using obtained thermoelastic parameters, we calculated the reaction boundary of knorringite formation from enstatite and eskolaite. The Clapeyron slope (with \({\text{d}}P/{\text{d}}T = - 0.014\) GPa/K) was found to be consistent with experimental data.     

Crown foliage dynamics of mangrove <Emphasis Type="Italic">Kandelia obovata</Emphasis> in Manko Wetland,Okinawa Island,Japan

The crown foliage dynamics of Kandelia obovata (S., L.) Yong were investigated, including leaf recruitment, survival and leaf growth. Newly flushed leaves occurred successively throughout the year, with a maximum in July and a minimum in January. The highest leaf death was in August, whereas it was the lowest in January. The relative mortality rate of leaves seemed to depend on the season when new leaves flushed. The growth pattern of leaves varied among seasons. The maximum leaf area was significantly larger in winter than in autumn, but showed no significant difference between the winter and the other seasons. The half-expansion period and the intrinsic rate of increase were respectively longer and lower in winter than in the other seasons. Therefore, leaves flushed in summer grew faster in their initial stage and attained their maximum leaf area sooner than those flushed in winter. This most likely results from the difference in temperature between summer and winter. The crown leaf area was almost stable throughout the year, as if homeostatic control is likely to function. Stipule litterfall decreased significantly with increasing flower and propagule litterfalls, indicating that a high production of flowers and propagules results in low leaf recruitment. This may be because flower production and propagule growth impose a severe burden on K. obovata.     

Density measurements of liquid Fe–Si alloys at high pressure using the sink–float method

The compositional dependence on the density of liquid Fe alloys under high pressure is important for estimating the amount of light elements in the Earth’s outer core. Here, we report on the density of liquid Fe–Si at 4 GPa and 1,923 K measured using the sink–float method and our investigation on the effect of the Si content on the density of the liquid. Our experiments show that the density of liquid Fe–Si decreases from 7.43 to 2.71 g/cm³ non-linearly with increasing Si content (0–100 at%). The molar volume of liquid Fe–Si calculated from the measured density gradually decreases in the compositional range 0–50 at% Si, and increases in the range 50–100 at% Si. It should be noted that the estimated molar volume of the alloys shows a negative volume of mixing between Fe and Si. This behaviour is similar to Fe–S liquid (Nishida et al. in Phys Chem Miner 35:417–423, 2008). However, the excess molar volume of mixing for the liquid Fe–Si is smaller than that of liquid Fe–S. The light element contents in the outer core estimated previously may be an underestimation if we take into account the possible negative value of the excess mixing volume of iron–light element alloys in the outer core.     

Recent Occurrences of Dinophysis fortii (Dinophyceae) in the Okkirai Bay, Sanriku, Northern Japan, and Related Environmental Factors

Occurrence of Dinophysis fortii, a causative organism of diarrhetic shellfish poisoning, in the Okkirai Bay, Sanriku was surveyed in 1995, 1996, 1998 and 1999. In each year, its major occurrence was detected from the late May or early June and continued until the late June or early July. Seawater temperature, salinity and nutrients measurements suggested that inflows of offshore water into the bay played key role on the first major occurrence of D. fortii. With an analysis of continuous temperature data in the Otsuchi Bay which locates north of the Okkirai Bay, this influent was considered to be intermittent inflow of the offshore water by internal tidal waves which propagated from north to south. First occurrence peak of D. fortii was synchronous with phycobilin containing microalgae, synechococcoid cyanobacteria and cryptomonad, in all years. In vivo fluorescence measurement of D. fortii cells in 1995 and 96 showed that the cells in these microalgal-rich water contained more phycobilin pigment than those in the microalgal-poor water. The result may support a hypothesis that D. fortii acquires phycobilin by an uptake of these microalgae. After the first major occurrence in the bay, D. fortii sometimes occurred in rather inshore waters where showed elevated ammonium level possibly due to increased heterotrophic activity. Together with another finding that D. fortii is mixotrophic, it could be assumed that the environment being suited to heterotrophic nutrition also stimulates D. fortii growth in the bay.     

Sterols of the suspended matters in sea water

The present study deals with the content and composition of sterols of the marine-suspended matter in the surface sea water of Kagoshima-Bay. The suspended matters were separated into 3 fractions by filtration with the glass and millipore filters. The sterols in each fraction were analyzed by gas-liquid chromatography on 1.5 % SE-30. The results obtained are as follows: 1) The sterol contents ranged from 2.3 to 20.5g/liter of sea water. 2) Cholesterol was usually present as a predominant sterol in both suspended and dissolved matters. 3) A relatively large amount of other sterols such as 22-dehydro-cholesterol, campesterol, stigmasterol,-sitosterol, and fucosterol were occasionally detected.     

A Monte Carlo simulation of the intergalactic absorption and the detectability of the Lyman continuum from distant galaxies

We have made a Monte Carlo simulation of the intergalactic absorption in order to model the Lyman continuum absorption, which is required to estimate the escape fraction of the Lyman continuum from distant galaxies. To input into the simulation, we derive an empirical distribution function of the intergalactic absorbers which reproduces recent observational statistics of the Lyman α forest, Lyman limit systems (LLSs) and damped Lyman α systems (DLAs) simultaneously. In particular, we assume a common functional form of the number evolution along the redshift for all types of absorbers. The Lyman series transmissions in our simulation reproduce the observed redshift evolution of the transmissions excellently, and the Lyman continuum transmission also agrees with an observed estimation which is still quite rare in the literature. The probability distribution of the Lyman α opacity in our simulation is lognormal with a tail towards a large opacity. This tail is produced by DLAs. The probability distribution of the Lyman continuum opacity in our simulation also shows a broad tail towards a large opacity. This tail is produced by LLSs. Because of the rarity of LLSs, we have a chance to have a clean line of sight in the Lyman continuum even for   z ∼ 4  with a probability of about 20 per cent. Our simulation expects a good correlation between the Lyman continuum opacity and the Lyman α opacity, which may be useful to estimate the former from the latter for an individual line of sight.     

Arsenic species and their accumulation features in green turtles (Chelonia mydas)

Total arsenic (As) and its compounds were determined in liver, kidney, muscle, and stomach contents of green turtles (Chelonia mydas). Total As concentrations in the muscle were higher than those in the kidney and liver. Arsenobetaine (AB) was the predominant compound in all the three tissues and its levels were positively correlated with total As concentrations. This indicates that AB greatly contributes to As accumulation in green turtles. Higher concentrations of remaining As in the sample after extraction were detected in the liver, implying that lipid-soluble or protein bound As compounds accumulate in the liver of green turtles. Total As levels in tissues showed significant negative correlations with standard carapace length. The size-dependence of As accumulation in green turtles may be related to their feeding habit, shifting from carnivore to herbivore at different growth stages. Concentrations of AB and dimethylarsinic acid (DMA) were low in the stomach contents but high in the tissues, implying bioaccumulation of these arsenicals in green turtles.