Sonophotocatalysis of endocrine-disrupting chemicals

Sonolysis and photolysis often exhibit synergistic effects in the degradation of organic molecules. An assay of fish oocyte maturation provides an appropriate experimental system to investigate the hormonal activities of chemical agents. Oocyte maturation in fish is triggered by maturation-inducing hormone (MIH), which acts on receptors on the oocyte surface. A synthetic estrogen, diethylstilbestrol (DES), possesses inducing activity of fish oocyte maturation, and a widely used biocide, pentachlorophenol (PCP), exhibits a potent inhibitory effect on fish oocyte maturation. In this study, the effects of the combined treatment by sonolysis with photolysis (sonophotocatalysis) to diminish the hormonal activity of DES and the maturation preventing activity of PCP was examined. By sonophotocatalysis, hormonal activity of DES was completely lost within 30min and the inhibiting activity of PCP was lost within 120min. These results demonstrated that sonophotocatalysis is effective for diminishing the endocrine-disrupting activity of chemical agents.     

Colonization of Sulfurovum sp. on the gill surfaces of Alvinocaris longirostris, a deep-sea hydrothermal vent shrimp

Deep‐sea hydrothermal vents are unique light‐independent ecosystems that are sustained by chemosynthetic bacteria. For many of the invertebrates inhabiting in such environments, bacteria play essential roles in both energy acquisition and detoxification of potentially toxic gases such as H₂S. In this study, the bacterial flora present on the gills of Alvinocaris longirostris (Bresiliidae: Caridea), a shrimp inhabiting hydrothermal vents (1532 m depth) at the Hatoma Knoll of the Okinawa Trough, was investigated. Bacterial 16S rDNA fragments were successfully amplified from the gills and 70% of these fragments showed an identical pattern in the restriction fragment length polymorphism analysis. These fragments were assigned to the ribotype AL‐1. Phylogenetic analyses suggest that AL‐1 forms a monophyletic clade with Sulfurovum spp. (ε‐Proteobacteria). Fluorescence in situ hybridization for AL‐1 and electron microscopy showed the presence of short‐rod bacteria lining up on the cuticular layer of the surface of the gill filaments. These results suggest that bacterial association with gills also occurs in bresiliid shrimps.     

Medium-scale traveling ionospheric disturbances observed by GPS receiver network in Japan: a short review

Medium-scale traveling ionospheric disturbances (MSTID) are wave-like perturbations of the ionospheric plasma with wavelengths of several hundred kilometres and velocities of several hundred metres per second. MSTID is one of the most common ionospheric phenomena that generally induce the perturbations of ionospheric total electron content (TEC) by ∼10¹⁶ electron/m², which corresponds to ∼54 ns (16.2 cm) delay at GPS L1 signal. In the past decade, several new characteristics on MSTIDs have been revealed by the TEC observations using the dense GPS receiver network in Japan. In this paper, we provide a short review of these new observations and summarize the morphological characteristics of MSTIDs in Japan.     

Quasi-Static Strain and Stress Fields due to a Moment Tensor in Elastic–Viscoelastic Layered Half-Space

We derived explicit expressions in the time domain for 3-D quasi-static strain and stress fields, due to a point moment tensor source in an elastic surface layer overlying viscoelastic half-space under gravity. The expressions of strain in the elastic surface layer were directly obtained from the expressions of displacement in our previous paper. The conversion of strain into stress is easy, because the stress–strain relation of elastic material is linear. In the viscoelastic substratum, the expressions of strain were obtained by applying the correspondence principle of linear viscoelasticity to the associated elastic solution. The strain–stress conversion is not straightforward, as the stress–strain relation of viscoelastic material is usually given in a differential form. To convert strain into stress, we used an integral form of the stress–strain relation instead of the usual differential form. The expressions give the responses of elastic half-space at \( t = 0 \) , and the responses of an elastic plate floating on non-viscous liquid at \( t = \infty \) . The moment tensor is rationally decomposed into the three independent force systems, corresponding to isotropic expansion, shear faulting and crack opening, and so the expressions include the strain and stress fields for these force systems as special cases. As the first numerical example, we computed the temporal changes in strain and stress fields after the sudden opening of an infinitely long vertical crack cutting the elastic surface layer. Here, we observe that the stress changes caused by the sudden crack opening gradually decay with time and vanish at \( t = \infty \) everywhere. After the completion of stress relaxation, a characteristic pattern of shear strain remains in the viscoelastic substratum. Since the strain and stress fields at \( t = \infty \) can be read as the strain- and stress-rate fields caused by steady crack opening, respectively, this numerical example demonstrates the realization of a steady stress state supported by steady viscous flow in the asthenosphere, associated with steady seafloor spreading at mid-ocean ridges. For the second numerical example, we computed the temporal changes in strain and stress fields after the 2011 Tohoku-oki mega-thrust earthquake, which occurred at the North American-Pacific plate interface. In this numerical example, the stress changes caused by coseismic fault slip vanish at \( t = \infty \) in the viscoelastic substratum, but remain in the elastic surface layer. The coseismic stress changes (and also strain changes) in the elastic surface layer diffuse away from the source region with time, due to gradual stress relaxation in the viscoelastic substratum.     

Isotopic evidence for temporal variation in proportion of seasonal precipitation since the last glacial time in the inland Pacific Northwest of the USA

Large-scale atmospheric circulation patterns determine the quantity and seasonality of precipitation, the major source of water in most terrestrial ecosystems. Oxygen isotope (δ¹⁸O) dynamics of the present-day hydrologic system in the Palouse region of the northwestern U.S.A. indicate a seasonal correlation between the δ¹⁸O values of precipitation and temperature, but no seasonal trends of δ¹⁸O records in soil water and shallow groundwater. Their isotope values are close to those of winter precipitation because the Palouse receives  75% of its precipitation during winter. Palouse Loess deposits contain late Pleistocene pedogenic carbonate having ca. 2 to 3‰ higher δ¹⁸O values and up to 5‰ higher carbon isotope (δ¹³C) values than Holocene and modern carbonates. The late Pleistocene δ¹⁸O values are best explained by a decrease in isotopically light winter precipitation relative to the modern winter-dominated infiltration. The δ¹³C values are attributed to a proportional increase of atmospheric CO₂ in soil CO₂ due to a decrease in soil respiration rate and ¹³C discrimination in plants under much drier paleoclimate conditions than today. The regional climate difference was likely related to anticyclonic circulation over the Pleistocene Laurentide and Ice Sheet.     

A simple two-way coupling method of BEM and VOF model for random wave calculations

A numerical method, which combines the boundary element method (BEM) and the volume of the fluid method (VOF method), has been presented to solve wave–structure interactions; the intense wave motion at the proximity of the structure is modeled by the VOF method and the rest of the fluid region is modeled by the BEM. The combined method can considerably reduce the time-consuming VOF domain, and thus practically makes it possible to apply the VOF method for random wave calculations, in which long time computations are usually required to obtain statistically meaningful results, and therefore the use of the single-VOF model often becomes prohibitive in terms of computational time and storage memories. A VOF model CADMAS-SURF, which is based on SMAC scheme and had been constructed by a number of VOF researchers in coastal engineering in Japan, is used in the combined BEM–VOF model. The two-way coupling treatment, which enables us to deal with bidirectional wave propagations, which was originally given for the SOLA-VOF model by Yan et al. (2003a) and later improved by Kim et al. (2007), was modified for the SMAC scheme. The coupling treatments are described in detail in the paper. The validity of the combined BEM–VOF model was investigated by comparing the numerical results with the theoretical results for the propagations of Stokes 5th order waves and random waves.     

Geotechnical Characteristics of Volcanic Soils Taken from Recent Eruptions

Recent volcanic eruptions at Mt. Unzen (Japan) in 1990 and Mt. Pinatubo (Philippines) in 1991 produced voluminous amounts of ash and sediments which inundated widespread areas. In later rehabilitation and reconstruction, it is practical and economical to use these freshly deposited sediments as materials for foundations and embankments. However, the geotechnical properties of young volcanic products have not been fully investigated. Accordingly, we investigated the geotechnical characteristics of volcanic soils associated with three recent eruptions, namely, the Unzen and Izu-Oshima eruptions of 1990 and 1986, respectively, in Japan and the Pinatubo eruption of 1991 in the Philippines. We specifically investigated index properties, permeability and compaction characteristics, and strength and deformation behavior in drained conditions. Additionally, we examined the dynamic properties and liquefaction characteristics of samples taken from Mt. Pinatubo. The results showed that the geotechnical characteristics of the deposits generally varied with the sampling sites. Depending on the location, either upstream or downstream from a volcano, the preferential sizing due to alluvial deposition affects engineering properties of the deposits. For example, volcanic sediments upstream from Mt. Pinatubo have high compressibility and low cyclic strength, whereas those taken downstream show dilative tendencies and high liquefaction strength.     

Aeolian dust experiment on climate impact: An overview of Japan–China joint project ADEC

The Aeolian Dust Experiment on Climate Impact (ADEC) was initiated in April 2000 as a joint five-year Japan–China project. The goal was to understand the impact of aeolian dust on climate via radiative forcing (RF). Field experiments and numerical simulations were conducted from the source regions in northwestern China to the downwind region in Japan in order to understand wind erosion processes temporal and spatial distribution of dust during their long-range transportation chemical, physical, and optical properties of dust and the direct effect of radiative forcing due to dust. For this, three intensive observation periods (IOP) were conducted from April 2002 to April 2004.The in situ and network observation results are summarized as follows: (1) In situ observations of the wind erosion process revealed that the vertical profile of moving sand has a clear size dependency with height and saltation flux and that threshold wind velocity is dependent on soil moisture. Results also demonstrated that saltation flux is strongly dependent on the parent soil size distribution of the desert surface. (2) Both lidar observations and model simulations revealed a multiple dust layer in East Asia. A numerical simulation of a chemical transport model, CFORS, illustrated the elevated dust layer from the Taklimakan Desert and the lower dust layer from the Gobi Desert. The global-scale dust model, MASINGAR, also simulated the dust layer in the middle to upper free troposphere in East Asia, which originated from North Africa and the Middle East during a dust storm in March 2003. Raman lidar observations at Tsukuba, Japan, found the ice cloud associated with the dust layer at an altitude of 6 to 9 km. Analysis from lidar and the radio-sonde observation suggested that the Asian dust acted as ice nuclei at the ice-saturated region. These results suggest the importance of dust's climate impact via the indirect effect of radiative forcing due to the activation of dust into ice nuclei. (3) Studies on the aerosol concentration indicated that size distributions of aerosols in downwind regions have bimodal peaks. One peak was in the submicron range and the other in the supermicron range. The main soluble components of the supermicron peak were Na⁺, Ca²⁺, NO₃⁻, and Cl⁻. In the downwind region in Japan, the dust, sea salt, and a mixture of the two were found to be dominant in coarse particles in the mixed boundary layer. (4) Observation of the optical properties of dust by sky-radiometer, particle shoot absorption photometer (PSAP), and Nephelometer indicated that unpolluted dust at source region has a weaker absorption than originally believed.A sensitivity experiment of direct RF by dust indicated that single scattering albedo is the most important of the optical properties of dust and that the sensitivity of instantaneous RF in the shortwave region at the top of the atmosphere to the refractive index strongly depends on surface albedo. A global scale dust model, MASINGAR, was used for evaluation of direct RF due to dust. The results indicated the global mean RF at the top and the bottom of the atmosphere were − 0.46 and − 2.13 W m^− 2 with cloud and were almost half of the RF with cloud-free condition.     

Prolonged impact of earthquake-induced landslides on sediment yield in a mountain watershed: The Tanzawa region, Japan

To determine for how long a landslide affects sediment discharge, the sediment yields of 15 check-dam basins were compared with the time series of landslide distributions in a mountain basin in the Tanzawa region, central Japan. The distribution of sediment yield was quantitatively estimated from deposition in the sediment pools of check dams. The relationship between the landslide history and sediment discharge in the Nakagawa River basin was examined for an approximately 80-year period. Two major landslide events occurred during this period: the 1923 Kanto Earthquake and the 1972 disaster caused by heavy rainfall. The resulting trend in sediment discharge of the whole basin, estimated using reservoir sedimentation in the Miho Dam at its base, was nearly constant, with high sediment discharge (2897 m³ km^− 2 yr^− 1) in the intervening quarter-century, despite the recovery of vegetation on landslide areas in this period. Comparisons of the landslide distributions resulting from the two disasters, the sediment yields of check-dam basins, and the sediment discharge of the whole basin indicate that recent sediment discharge contains landslide debris that was originated by the Kanto Earthquake that occurred over 80 years ago. Thus, to understand high sediment discharge, it is essential to investigate not only the current basin condition and recent events, but also the landslide history of the basin for at least the previous 100 years.     

The Uptake Coefficient of I2 on Various Aqueous Surfaces

Uptake coefficient of I₂ on aqueous surfaces was measured by using an impinging flow method. Dependence of the uptake coefficient on the gas-liquid contact time and pH was investigated. The uptake coefficient was (3.7± 2.0)×10^–4 at 120 ms, 293 K and pH = 5.6. In the alkaline region, the uptake coefficient was larger by one order of magnitude than that in the neutral and acidic region. The I₂ uptake on KI solutions and synthetic sea water solutions was also measured. According to the analysis by the reactive uptake model, the uptake of I₂ was shown to be mainly determined by liquid phase reactions and the accommodation coefficient of I₂ on aqueous surfaces was estimated to be 0.01.