Effect of the formation of EDTA complexes on the diffusion of metal ions in water

The diffusion coefficients of aquo metal ions (M^z+) and their EDTA complexes (M-EDTA^(z−4)+) were compared to understand the effect of EDTA complexation on the diffusion of metal ions by the diffusion cell method for Co²⁺, Ga³⁺, Rb⁺, Sr²⁺, Ag⁺, Cd²⁺, Cs⁺, Th⁴⁺, , and trivalent lanthanides. Most studies about ionic diffusion in water have dealt with free ion (hydrated ion). In many cases, however, polyvalent ions are dissolved as complexed species in natural waters. Hence, we need to study the diffusion behavior of complexes in order to understand the diffusion phenomenon in natural aquifer and to measure speciation by diffusive gradient in thin films (DGT), which requires the diffusion coefficients of the species examined. For many ions, the diffusion coefficients of M-EDTA^(z−4)+ are smaller than those of hydrated ions, but the diffusion coefficients of M-EDTA^(z−4)+ are larger than those of hydrated ions for ions with high ionic potentials (Ga³⁺ and Th⁴⁺). As a result, the diffusion coefficients of EDTA complexes are similar among various metal ions. In other words, the diffusion of each ion loses its characteristics by the complexation with EDTA. Although the difference is subtle, it was also found that the diffusion coefficients of EDTA complexes increase as the ionic potential increases, which can be explained by the size of the EDTA complex of each metal ion.     

Spatial variability of chemical tracers in surface snow along the traverse route from the coast to 1000 km inland at east Dronning Maud Land, Antarctica

1　IntroductionAntarcticicesheetisaburialgroundforatmosphericdeposition .Sincethereiscon tinuousinteractionbetweentheicesheetandtheatmosphere,variousatmosphericsub stancesareinjectedtotheicesheetsequentiallyintimeandspace.Therefore,verticalanalysesoftheicesheetprovideuswithinformationaboutpastclimaticchange (Delmas1 992 ;LegrandandMayewski 1 997)andhorizontalanalysesoftheicesheetprovideuswithknowledgeregardinglong rangetransportofairbornematerials (Kamiyamaetal.1 989;KreutzandMayewski 1 999)…     

Mineral chemistry of MUSES‐C Regio inferred from analysis of dust particles collected from the first‐ and second‐touchdown sites on asteroid Itokawa

The mineralogy and mineral chemistry of Itokawa dust particles captured during the first and second touchdowns on the MUSES‐C Regio were characterized by synchrotron‐radiation X‐ray diffraction and field‐emission electron microprobe analysis. Olivine and low‐ and high‐Ca pyroxene, plagioclase, and merrillite compositions of the first‐touchdown particles are similar to those of the second‐touchdown particles. The two touchdown sites are separated by approximately 100 meters and therefore the similarity suggests that MUSES‐C Regio is covered with dust particles of uniform mineral chemistry of LL chondrites. Quantitative compositional properties of 48 dust particles, including both first‐ and second‐touchdown samples, indicate that dust particles of MUSES‐C Regio have experienced prolonged thermal metamorphism, but they are not fully equilibrated in terms of chemical composition. This suggests that MUSES‐C particles were heated in a single asteroid at different temperatures. During slow cooling from a peak temperature of approximately 800 °C, chemical compositions of plagioclase and K‐feldspar seem to have been modified: Ab and Or contents changed during cooling, but An did not. This compositional modification is reproduced by a numerical simulation that modeled the cooling process of a 50 km sized Itokawa parent asteroid. After cooling, some particles have been heavily impacted and heated, which resulted in heterogeneous distributions of Na and K within plagioclase crystals. Impact‐induced chemical modification of plagioclase was verified by a comparison to a shock vein in the Kilabo LL6 ordinary chondrite where Na‐K distributions of plagioclase have been disturbed.     

Space weathered rims found on the surfaces of the Itokawa dust particles

On the basis of observations using Cs‐corrected STEM, we identified three types of surface modification probably formed by space weathering on the surfaces of Itokawa particles. They are (1) redeposition rims (2–3 nm), (2) composite rims (30–60 nm), and (3) composite vesicular rims (60–80 nm). These rims are characterized by a combination of three zones. Zone I occupies the outermost part of the surface modification, which contains elements that are not included in the unchanged substrate minerals, suggesting that this zone is composed of sputter deposits and/or impact vapor deposits originating from the surrounding minerals. Redeposition rims are composed only of Zone I and directly attaches to the unchanged minerals (Zone III). Zone I of composite and composite vesicular rims often contains nanophase (Fe,Mg)S. The composite rims and the composite vesicular rims have a two‐layered structure: a combination of Zone I and Zone II, below which Zone III exists. Zone II is the partially amorphized zone. Zone II of ferromagnesian silicates contains abundant nanophase Fe. Radiation‐induced segregation and in situ reduction are the most plausible mechanisms to form nanophase Fe in Zone II. Their lattice fringes indicate that they contain metallic iron, which probably causes the reddening of the reflectance spectra of Itokawa. Zone II of the composite vesicular rims contains vesicles. The vesicles in Zone II were probably formed by segregation of solar wind He implanted in this zone. The textures strongly suggest that solar wind irradiation damage and implantation are the major causes of surface modification and space weathering on Itokawa.     

Chemical modification of sea water by submarine volcanism at Nishinoshima-Shintô Island

Sea water samples, still hot from volcanic emanations were taken in a bay of Nishinoshima-Shintô Island just after volcanic activity had ceased and were analysed for borate-B, fluoride-F and bromide-Br. The hot water is considered to be formed by the conservative mixing of volcanic emanations with sea water, and the emanations containedCl, B, F andBr in the ratio of 1∶1.84×10^?3∶0.474×10^?3∶6.47×10^?3 by weight. RatiosB/Cl andF/Cl can be used as effective measures of the contribution of volcanic emanations to sea water.     

Towed ADCP fish with Depth and Roll controllable wings and its application to the Kuroshio observation

An intelligent ADCP (Acoustic Doppler Current Profiler) fish, called DRAKE (Depth and Roll Adjustable Kite for Energy flux measurements) was developed with the controllable wings which can adjust the submerging depth of the fish and stabilize its roll motion. The Kuroshio west of Okinawa was measured in a roundtrip course on the same traverse line by the ADCP fish. The forward survey obtained the maximum submerging depth of 208 m at a fish operation speed of 2.9 ms^–1. The maximum fish speed of 5.4 ms^–1 was achieved at a submerging depth of 48 m in the return survey. The data in the overlapped area of data acquisition between depths 212 and 276 m were used to examine the accuracy of velocity measurement for the towed ADCP system. The summation of both survey data made it possible to estimate a sectional velocity structure and transport of the upper 600 m corresponding roughly to the whole section of the Kuroshio in this region.