Further characterization of carbonaceous materials in Hayabusa‐returned samples to understand their origin

Carbonaceous materials in the sample catcher of the Hayabusa spacecraft were assigned as category 3 particles. We investigated the category 3 particles with a suite of in situ microanalytical methods. Possible contaminants collected from the cleanrooms of the spacecraft assembly and extraterrestrial sample curation center (ESCuC) were also analyzed in the same manner as category 3 particles for comparison. Our data were integrated with those of the preliminary examination team for category 3 particles. Possible origins for the category 3 particles include contamination before and after the operation of the Hayabusa spacecraft.     

Heating experiments of the Tagish Lake meteorite: Investigation of the effects of short‐term heating on chondritic organics

We present in this study the effects of short‐term heating on organics in the Tagish Lake meteorite and how the difference in the heating conditions can modify the organic matter (OM) in a way that complicates the interpretation of a parent body's heating extent with common cosmothermometers. The kinetics of short‐term heating and its influence on the organic structure are not well understood, and any study of OM is further complicated by the complex alteration processes of the thermally metamorphosed carbonaceous chondrites—potential analogues of the target asteroid Ryugu of the Hayabusa2 mission—which had experienced posthydration, short‐duration local heating. In an attempt to understand the effects of short‐term heating on chondritic OM, we investigated the change in the OM contents of the experimentally heated Tagish Lake meteorite samples using Raman spectroscopy, scanning transmission X‐ray microscopy utilizing X‐ray absorption near edge structure spectroscopy, and ultraperformance liquid chromatography fluorescence detection and quadrupole time of flight hybrid mass spectrometry. Our experiment suggests that graphitization of OM did not take place despite the samples being heated to 900 °C for 96 h, as the OM maturity trend was influenced by the heating conditions, kinetics, and the nature of the OM precursor, such as the presence of abundant oxygenated moieties. Although both the intensity of the 1s?σ* exciton cannot be used to accurately interpret the peak metamorphic temperature of the experimentally heated Tagish Lake sample, the Raman graphite band widths of the heated products significantly differ from that of chondritic OM modified by long‐term internal heating.     

Failure process of masonry buildings during earthquake and associated casualty risk evaluation

Collapse of masonry structures during an earthquake is analyzed using the three-dimensional distinct element method (3D-DEM) code developed by the first author. The DEM is a numerical analysis technique, in which positions of elements are calculated by solving equations of motion step by step. Both individual and group behavior can be simulated. The structure is modeled as an assembly of distinct elements connected by virtual springs and dashpots, where elements come into contact. First, the validity of the developed 3D-DEM code is confirmed by comparing analytical results with static experimental results of masonry walls. Second, failure process of masonry buildings due to earthquake is investigated using DEM. Effects of reinforcing methods are also examined. Finally, injury to human bodies in the collapsing masonry buildings is also calculated. Assuming that occupants lie down on the floor, two types of casualty criteria are introduced and assessed.     

Stability conditions of polycyclic aromatic hydrocarbons at high pressures and temperatures

The first results of study of stability of diverse polycyclic aromatic hydrocarbons at around 7 GPa and 773–1073 K are reported. Experiments were carried out in hydraulic multi-anvil presses. The run products after quenching were analyzed using a method of matrix-assisted laser desorption-ionization (MALDI). The formation of polymers of starting matters was determined at 7 GPa and 773–883 K. The polymers are characterized by atomic masses up to 5000 Da, that are multiple by masses of starting matters. At higher temperatures (873–1073 K), the selected PAHs and their polymers become unstable. The decomposition temperature of PAHs and their polymers exclude their stability under Earth’s mantle conditions. The studies could be of great significance for the low-temperature near-surface geodynamics of small and large planetary bodies, which supposedly contain hydrocarbon compounds.     

Measurement of evaporation from the forest floor in a deciduous forest throughout the year using microlysimeter and closed‐chamber systems

Evaporation from the forest floor (E_FF) in a deciduous broadleaf forest was measured using microlysimeter and closed‐chamber systems. The microlysimeter was used at six points in the experimental basin, and measurements gave different E_FF values at different points. This could be attributed to the local photoenvironment of each sampling point, rather than to litter conditions, if the spatial variation in air temperature (Ta) or vapour pressure deficit (VPD) at the forest floor was small within this basin. A detachable microlysimeter measured condensation in the litter layer during the night, indicating that the litter layer, as well as the mulch layer, played a role in preventing evaporation from the soil layer. The closed‐chamber system made it possible to continuously measure long‐term E_FF. E_FF was closely related to VPD; even during the night, when solar radiation was zero, E_FF amounted to 14·0% of the daily E_FF. The daily E_FF was 0·20 ± 0·13 mm day^?1 during the study period, with two seasonal peaks: in late spring (0·31 mm day^?1 in April) and early fall (0·22 mm day^?1 in September). The former peak has been reported from two deciduous forests in Japan and is strongly related to the solar radiation reaching the forest floor when the trees are dormant. Copyright © 2008 John Wiley & Sons, Ltd.     

Seasonal and annual change in community structure of meso-sized copepods in Tokyo Bay, Japan

Seasonal change in the meso-sized copepod community structure in the central part of Tokyo Bay was investigated from January 2006 to December 2008. Three seasonal community groups were detected, and seasonal shifts of these communities are explained by life history characteristics of indicator species and seasonal changes in the hydrographical environment. In the winter-spring community, Acartia omorii and Centropages abdominalis dominate because of high growth rates at low temperature. A shift to the early summer community is caused by a diapause of Ce. abdominalis as resting eggs and an increase in the growth and egg-production rate of Pseudodiaptomus marinus at high temperature. A shift to the summer-fall community is caused by a diapause of A. omorii at hypoxic and high temperature conditions and an increase of Temora turbinata, Paracalanus parvus and other oceanic species by an enhancement of the estuary circulation. Then, the community returns to a winter-spring one by the recovery of A. omorii and Ce. abdominalis with low temperatures and oxygenation of bottom water and by the disappearance of oceanic warm-water species at low temperature. Seasonal community shifts occurred almost regularly, but the shift from a winter-spring community to an early summer one occurred 1 month early in 2007 when the water temperature was warmer than in other years.     

Marine artificial structures as amplifiers of Aurelia aurita s.l. blooms: a case study of a newly installed floating pier

Increase of marine artificial structures, providing more substrate for jellyfish polyps, has been argued to increase jellyfish outbreaks, although no explicit evidence exists. We report a case study demonstrating a remarkable increase of Aurelia aurita s.l. ephyrae after the installation of a floating pier (48 × 6 m) in a fishing port on the Inland Sea of Japan. Monitoring of ephyrae from January 2010, prior to the installation of the floating pier in April 2010, to July 2011, revealed that their time-weighted average density increased 3.5 fold, from 1.1 to 3.9 ephyrae m^?3, and the integrated number of ephyrae exported from the port increased 4.3 fold, from 5.7 × 10⁶ to 25 × 10⁶ ephyrae, after the installation. However, in a nearby port, a control site, the abundance of ephyrae decreased by ca. one third during the same period. Monitoring of polyps showed that they initially colonized the undersurface of the pier by August 2010, followed by a rapid population increase. They strobilated from December 2010 to May 2011. We computed the number of ephyrae released from the strobilae to be ca. 25 × 10⁶, very close to the net increase of ephyrae produced and exported from the port. This study corroborates that the installation of an artificial structure provides new a substrate for polyps, which allows them to produce more ephyrae to induce medusa blooms.     

A structure of the Kuroshio and its related upwelling on the East China Sea shelf slope

The ADCP on an advanced towed fish with controllable main and tail wings, called DRAKE measured a detailed sectional structure of the Kuroshio flowing to the NE along the East China Sea shelf slope west of Okinawa. At the observation period, a countercurrent directed to the SW formed in near-bottom water on the shelf slope. The horizontal flow perpendicular to the stream axis of the Kuroshio constructed a convergence zone around the boundary between the Kuroshio and the countercurrent. An intensive upwelling with the maximum velocity of 2.8 cm s^–1 was found to distribute on the shelf slope around the convergence zone. A dynamic cause of this intensive upwelling is discussed carefully.     

Effect of the formation of EDTA complexes on the diffusion of metal ions in water

The diffusion coefficients of aquo metal ions (M^z+) and their EDTA complexes (M-EDTA^(z−4)+) were compared to understand the effect of EDTA complexation on the diffusion of metal ions by the diffusion cell method for Co²⁺, Ga³⁺, Rb⁺, Sr²⁺, Ag⁺, Cd²⁺, Cs⁺, Th⁴⁺, , and trivalent lanthanides. Most studies about ionic diffusion in water have dealt with free ion (hydrated ion). In many cases, however, polyvalent ions are dissolved as complexed species in natural waters. Hence, we need to study the diffusion behavior of complexes in order to understand the diffusion phenomenon in natural aquifer and to measure speciation by diffusive gradient in thin films (DGT), which requires the diffusion coefficients of the species examined. For many ions, the diffusion coefficients of M-EDTA^(z−4)+ are smaller than those of hydrated ions, but the diffusion coefficients of M-EDTA^(z−4)+ are larger than those of hydrated ions for ions with high ionic potentials (Ga³⁺ and Th⁴⁺). As a result, the diffusion coefficients of EDTA complexes are similar among various metal ions. In other words, the diffusion of each ion loses its characteristics by the complexation with EDTA. Although the difference is subtle, it was also found that the diffusion coefficients of EDTA complexes increase as the ionic potential increases, which can be explained by the size of the EDTA complex of each metal ion.