Climate impacts of environmental degradation in Sudan

There exists an impressive amount of work for Sudan showing the anthropogenic degradation of natural vegetation cover. However, there are few examples of consequent climatic changes in literature. This work, thus, seeks to assess such effects of environmental forcing on various climatic patterns over the past few decades. Within the frame of the present analysis, the results are quite striking and are in concordance with scientific contentions that such land degradation could result in climatic modification. Higher temperature and less rainfall, sunshine duration and global radiation have been noticed. Evapotranspiration has responded more to the warming and drying conditions, thus showed signs of increasing rates, especially during the wet season. However, the extent of increase seems to have been suppressed by the decrease in sunshine duration and solar radiation as well as the inconsistent behaviour of wind speed. Changes in the variability of the within-year monthly observations have also occurred, thus suggesting an increase in the occurrence of extremes. The observed climatic modification in the country has exaggerated the insidious drought conditions. The present findings are hoped to contribute to our understanding of the effects of environmental problem and assist in considering policy responses. This revised version was published online in July 2006 with corrections to the Cover Date.     

Geology and Genesis of Barite Deposits of Lasbela and Khuzdar Districts, Balochistan, Pakistan

Abstract: Geology and genesis of the sediment-hosted barite deposits in the Lasbela and Khuzdar districts of Balochistan, Pakistan have been studied and described. Hot solutions generated in rifting environments during the initial stage of separation of the continental crustal block related to the Gondwanaland fragmentation subsequently reposed in Jurassic rocks, most probably played an important role on barite formation.
Paragenetic relationships indicate that the period of barite mineralization was distinctly later than that of zinc-lead sulphide mineralization in the Lasbela and Khuzdar districts. The barite deposits occur on top and in peripheral to the zinc-lead sulphides. The earliest barite mineralization took place in the clastic rock sequence of the lower Spingwar Formation as cross cutting veins. Younger mineralization as stratabound-replacement type occurred within the platform limestones of Loralai Formation, just above the Spingwar Formation. The youngest mineralization as stratiform is hosted within black shales, mudstones and argillaceous limestones of Anjira Formation at the top of Loralai Formation. In the light of the evidences gathered from field and laboratory investigations a genetic model has been deduced.     

Decoupling of As and Fe release to Bangladesh groundwater under reducing conditions. Part I: Evidence from sediment profiles

This study reexamines the notion that extensive As mobilization in anoxic groundwater of Bangladesh is intimately linked to the dissolution of Fe oxyhydroxides on the basis of analyses performed on a suite of freshly collected samples of aquifer material. Detailed sediment profiles extending to 40 to 70 m depth below the surface were obtained at six sites where local groundwater As concentrations were known to span a wide range. The sediment properties that were measured include (1) the proportion of Fe(II) in the Fe fraction leached in hot 1.2 N HCl, (2) diffuse spectral reflectance, and (3) magnetic susceptibility.In parallel with local concentrations of dissolved As ranging from <5 to 600 μg/L, Fe(II)/Fe ratios in shallow (gray) Holocene sands tended to gradually increase with depth from values of 0.3 to 0.5 to up to 0.9. In deeper (orange) aquifers of presumed Pleistocene age that were separated from shallow sands by a clay layer and contained <5 μg/L dissolved As, leachable Fe(II)/Fe ratios averaged ∼0.2. There was no consistent relation between sediment Fe(II)/Fe and dissolved Fe concentrations in groundwater in nearby wells. The reflectance measurements indicate a systematic linear relation (R² of 0.66; n = 151) between the first derivative transform of the reflectance at 520 nm and Fe(II)/Fe. The magnetic susceptibility of the shallow aquifer sands ranged from 200 to 3600 (x 10⁻⁹ m³/kg SI) and was linearly related (R² of 0.75; n = 29) to the concentrations of minerals that could be magnetically separated (0.03 to 0.79% dry weight). No systematic depth trends in magnetic susceptibility were observed within the shallow sands, although the susceptibility of deeper low-As aquifers was low (up to ∼200 × 10⁻⁹ m³/kg SI).This set of observations, complemented by incubation results described in a companion paper by van Geen et al. (this volume), suggests that the release of As is linked to the transformation of predominantly Fe (III) oxyhydroxide coatings on sand particles to Fe(II) or mixed Fe(II/III) solid phases with a flatter reflectance spectrum such as siderite, vivianite, or magnetite, without necessarily resulting in the release of Fe to groundwater. The very low As/Fe ratio of magnetically separated minerals compared to the As/Fe of bulk acid leachate (2 vs. 40 10⁻⁶, respectively) suggests that such a transformation could be accompanied by a significant redistribution of As to a mobilizable phase on the surface of aquifer particles.     

Le Silurien de la région d'Oulad Abbou (Meseta occidentale,Maroc) : une sédimentation péritidale sous contrôle tectonique

In the Oulad Abbou syncline, western coastal Meseta, the Silurian deposits exhibit siliciclastic or mixed siliciclastic/carbonate tidal facies that recorded alkaline basalt flows and syn-sedimentary deformations. These facies are staked into peritidal shallowing upward sequences reflecting the evolution from an infratidal to a supratidal environment. These sequences recorded low-amplitude and high-frequency sea-level variations. The built-up of these rhythmic sequences is related to distensive tectonic that allowed the development of isolated platform from extensive siliciclastic influx. This tectonic event is well recorded in the palaeogeographic evolution of the northern Gondwana platform during the Lower Palaeozoic time. To cite this article: A. Attou, N. Hamoumi, C. R. Geoscience 336 (2004).     

RETRACTED ARTICLE: Physiological comparative study of six wild grapevine (<Emphasis Type="Italic">Vitis sylvestris</Emphasis>) accession responses to salinity

Salinity problems for vineyards are in concerns, especially in coastal areas where several aquifers are reported to be affected by seawater intrusion and agricultural contamination. Saline irrigation affects growth, yield, and fruit quality of grapevines. Exploring germplasm base through wild ancestors of the target species is a novel adopted strategy to increase crop tolerance to irrigation with saline water. The effects of salt on growth, organic and inorganic solute accumulations, and chlorophyll florescence were studied on 3-month-old plants of six Tunisian wild grapevines with the objective to identify salt tolerance mechanisms and select tolerant genotypes. Potted plants were grown under controlled conditions and irrigated for 14 days with 0, 100, and 150 mM NaCl nutrient solution. Parameters analyzed were related to growth, water relations, mineral nutrition, and chlorophyll fluorescence. Several processes are operating either at the whole plant or at cell level. They appear to be involved in salt tolerance of wild grapevines and are more efficient in tolerant accessions. Salt adversely affects plant growth and plant nutrition. Reductions of shoot growth rate (relative growth rate, day^?1) reached 49% of control since 100 mM NaCl. They were assigned to stomatal closure and alteration of potassium nutrition and photochemistry. There were significant differences (P < 0.05) within accessions, Tebaba was the most tolerant and Houamdia the most sensitive, while the others were intermediate.     

Morphotectonic controls of groundwater flow regime and relating environmental impacts in Northwest Sinai,Egypt

The frequent appearance of some hydro-environmental hazard features, such as waterlogging and soil salinization along the susceptible zones at Northwest Sinai area (NWSA), has put serious challenges and obstacles for a correct and efficient land use planning of this region, for several decades. Although previous studies have shown that the whole region of Northern Sinai is greatly affected by the tectonic movements associated with the Syrian Arc folding system (SAS), NWSA is barren of any obvious surficial structures. The current work aims to investigate the effect of subsurface tectonic features on the hydrogeologic regime of NWSA.Hydrogeological and remote sensing data were integrated with ground geophysical gravity and magnetic measurements, using the geographic information system. Data integration asserts the role played by buried tectonic features not only in governing the landforms of the upper water-bearing quaternary formations but also in controlling their flow regime.Two major subsurface structures were identified through interpreting the geophysical measurements. A buried dome-like structure, dominating the central part of the mapped area, coincides with the radial flow pattern observed on the water table map. At the southwestern corner of the study area, an elevated groundwater level, caused by continuous groundwater accumulation at the discharge boundary, is superimposing a subsurface block-faulted depression. The waterlogging features (saturation of the soil by groundwater and inundation of local depressions due to rising of water table) dominating the discharge lowlands of NWSA support the conclusion that a buried block-faulted structure exerts a strong influence on the thickness and groundwater flow regime of the shallow quaternary aquifer.     

Hydrochemical and stable isotopic investigation of groundwater quality and its sustainability for irrigation in the Hammamet-Nabeul basin,northeastern Tunisia

The major ion hydrochemistry, sodium absorption ratio (SAR), sodium percentage, and isotopic signatures of Hammamet-Nabeul groundwaters were used to identify the processes that control the mineralization, irrigation suitability, and origin of different water bodies. This investigation highlights that groundwater mineralization is mainly influenced by water-rock interaction and pollution by the return flow of irrigation water. The comparison of groundwater quality with irrigation suitability standards proves that most parts of groundwater are unacceptable for irrigation and this long-term practice may result in a significant increase of the salinity and alkalinity in the soils. Based on isotopic signatures, the shallow aquifer groundwater samples were classified into (i) waters with depleted δ¹⁸O and δ²H contents, highlighting recharge by modern precipitation, and (ii) waters with enriched stable isotope contents, reflecting the significance of recharge by contaminated water derived from the return flow of evaporated irrigation waters. The deep-aquifer groundwater samples were also classified into (i) waters with relatively enriched isotope contents derived from modern recharge and mixed with shallow-aquifer groundwater and (ii) waters with depleted stable isotope contents reflecting a paleoclimatic origin. Tritium data permit to identify three origins of recharge, i.e., contemporaneous, post-nuclear, and pre-nuclear. Carbon-14 activities demonstrate the existence of old paleoclimatic recharge related to the Holocene and Late Pleistocene humid periods.     

Uncertainty assessment of the multilayer perceptron (MLP) neural network model with implementation of the novel hybrid MLP-FFA method for prediction of biochemical oxygen demand and dissolved oxygen: a case study of Langat River

Accurate prediction of the chemical constituents in major river systems is a necessary task for water quality management, aquatic life well-being and the overall healthcare planning of river systems. In this study, the capability of a newly proposed hybrid forecasting model based on the firefly algorithm (FFA) as a metaheuristic optimizer, integrated with the multilayer perceptron (MLP-FFA), is investigated for the prediction of monthly water quality in Langat River basin, Malaysia. The predictive ability of the MLP-FFA model is assessed against the MLP-based model. To validate the proposed MLP-FFA model, monthly water quality data over a 10-year duration (2001–2010) for two different hydrological stations (1L04 and 1L05) provided by the Irrigation and Drainage Ministry of Malaysia are used to predict the biochemical oxygen demand (BOD) and dissolved oxygen (DO). The input variables are the chemical oxygen demand (COD), total phosphate (PO₄), total solids, potassium (K), sodium (Na), chloride (Cl), electrical conductivity (EC), pH and ammonia nitrogen (NH₄-N). The proposed hybrid model is then evaluated in accordance with statistical metrics such as the correlation coefficient (r), root-mean-square error, % root-mean-square error and Willmott’s index of agreement. Analysis of the results shows that MLP-FFA outperforms the equivalent MLP model. Also, in this research, the uncertainty of a MLP neural network model is analyzed in relation to the predictive ability of the MLP model. To assess the uncertainties within the MLP model, the percentage of observed data bracketed by 95 percent predicted uncertainties (95PPU) and the band width of 95 percent confidence intervals (d-factors) are selected. The effect of input variables on BOD and DO prediction is also investigated through sensitivity analysis. The obtained values bracketed by 95PPU show about 77.7%, 72.2% of data for BOD and 72.2%, 91.6% of data for DO related to the 1L04 and 1L05 stations, respectively. The d-factors have a value of 1.648, 2.269 for BOD and 1.892, 3.480 for DO related to the 1L04 and 1L05 stations, respectively. Based on the values in both stations for the 95PPU and d-factor, it is concluded that the neural network model has an acceptably low degree of uncertainty applied for BOD and DO simulations. The findings of this study can have important implications for error assessment in artificial intelligence-based predictive models applied for water resources management and the assessment of the overall health in major river systems.     

Status of sedimentation in King Talal Dam,case study from Jordan

This paper focuses on characterizing the current status of physical and chemical characteristics of King Talal Dam (KTD) sediments. The quality of sediments was investigated based on several international sediment quality guidelines. The volume of sediment and sedimentation rate in (KTD) was also estimated. Five types of granulometric textural facies were observed for the sediments of KTD reservoir bed, with an average grain size distribution of gravel (1.38%), sand (32.38%), silt (32.35%) and clay (32.38%). The fraction of <63 micron showed that the total mean size was 8.0 micron. Other sediment parameters in KTD were 7.0% for total organic matter (TOM), 7.3 for pH, 35.9% for CaCO₃ and 100.5 meq/100 g for cation exchange capacity, with dominant mineralogical constituents of quartz, calcite, dolomite, clay minerals and minor feldspar. The total concentrations of F, Cl, NO₂, NO₃, PO₄ and SO₄ in sediment samples were lower inward for KTD. The vast majority of trace metals in sediments were generally within the standard limits recommended for soils. TOM and grain size of sediment are major factors governing the trace metal concentrations. The calculated geoaccumulation index (I _geo) and enrichment factor of metals in bottom sediments showed that the metals were in the following order: Cd > Pb > Zn > Co > Cr > Ni > Fe > Cu > Sr > Mn and Cd > Zn > Pb > Co > Cr > Ni > Cu > Sr > Mn, respectively. Based on the sonic survey of KTD reservoir, the annual sedimentation rate was about 0.4061 MCM/year, in which about 18.66% of the reservoir initial storage capacity was lost to sediments and a projected lifespan of about 198 years.     

Biostratigraphy and seismic data analysis to detect the sequence stratigraphic depositional environment of the Miocene succession: Gulf of Suez (Egypt)

This work comprises a study of the sequence stratigraphy, seismic-facies analysis, biostratigraphy and depositional environments of the northern part of the Gulf of Suez, Egypt, using a set of 24 3D seismic profiles, composite logs and sonic logs from ten wells. The syn-rift formations in the studied ten wells are described lithologically and interpreted based on investigating two seismic profiles. Biostratigraphically, the Miocene fossils are identified to correlate the five planktonic foraminiferal biozones in the examined boreholes (RB-A1, RB-B1, RB-B3, EE85-2 and RB-C1). The sequence stratigraphic analysis suggests that the Miocene succession can be subdivided into two major third order depositional sequences (S1 and S2) separated by the three major sequence boundaries (DSB1, DSB2 and DSB3).