Mineralogy and geochemistry of shallow sediments of Sonargaon, Bangladesh and implications for arsenic dynamics: Focusing on the role of organic matter

Mineralogy and geochemistry of modern shallow sediments (up to 5 m thick) within the zone of water table fluctuations were studied to determine the likely sources and processes responsible for releasing As into groundwater. Samples were collected from different geological settings with varying groundwater As concentrations during dry (December 2005) and wet (September 2006) seasons at Sonargaon, Bangladesh. Stratigraphic sequences of the studied sediments showed three distinct lithofacies, viz. clayey-silt, silty-clay, and silty-very fine sand, corresponding to fine-grained overbank associations. Total As concentrations of shallow sediments ranged from <1 to 16 mg/kg without a significant difference in the range of As concentrations between the seasons. Sequential chemical extraction analysis of As revealed that >80% of the As was fixed in insoluble and organic phases, while the amount of As in reducible and acid-soluble phases was very low (<20%) and varied inversely with total As content. Total As concentration varied with mica content (muscovite and biotite) and its related elements (Al, Mg and Fe), but not with total organic C, suggesting that biotite is the major host phase of As. Arsenic appears to be liberated from biotite and/or other As-bearing minerals via chemical weathering (i.e., hydration-decomposition), either from the near-surface sediments which are subject to seasonal cycling of the redox conditions, or from within the aquifer sediments. Once released, progressive diagenesis to form As-bearing organic matter may be responsible for controlling As distribution in the sediments and coexisting groundwater of the study area.     

An improvement in mass flux convective parameterizations and its impact on seasonal simulations using a coupled model

A new closure and a modified detrainment for the simplified Arakawa–Schubert (SAS) cumulus parameterization scheme are proposed. In the modified convective scheme which is named as King Abdulaziz University (KAU) scheme, the closure depends on both the buoyancy force and the environment mean relative humidity. A lateral entrainment rate varying with environment relative humidity is proposed and tends to suppress convection in a dry atmosphere. The detrainment rate also varies with environment relative humidity. The KAU scheme has been tested in a single column model (SCM) and implemented in a coupled global climate model (CGCM). Increased coupling between environment and clouds in the KAU scheme results in improved sensitivity of the depth and strength of convection to environmental humidity compared to the original SAS scheme. The new scheme improves precipitation simulation with better representations of moisture and temperature especially during suppressed convection periods. The KAU scheme implemented in the Seoul National University (SNU) CGCM shows improved precipitation over the tropics. The simulated precipitation pattern over the Arabian Peninsula and Northeast African region is also improved.

     

Hydrogeochemical processes and multivariate analysis for groundwater quality in the arid Maadher region of Hodna,northern Algeria

Acta Geochimica - This study focused on water quality and hydro-geochemical processes (evolution, origin) in the Maadher region, central Hodna in Algeria. In recent decades, the excessive...     

Urban heat island and its effect on the cooling and heating demands in urban and suburban areas of Hong Kong

This study investigates the urban heat island characteristics of four major areas of Hong Kong. The areas of study include a densely populated and well-developed commercial area (i.e., Tsim Sha Tsui) and three suburban areas (i.e., Cheung Chau, Lau Fau Shan and Sha Tin) with differing degrees of development. The weather station data of respective areas were acquired from the Hong Kong Observatory. The urban heat island intensity, determined as the air-temperature difference between the selected urban/suburban area and the reference rural area (i.e., Ta Kuw Ling) with thin population and lush vegetation, was used for the analysis. Results showed stronger heat island effect during winter and nighttime than during summer and daytime. An investigation of the cooling and heating degree days indicate that all areas have observed higher number of cooling degree days. However, the cooling degree days were the maximum while heating degree days were the minimum in the urban area (i.e., Tsim Sha Tsui). Clearly, the minimum heating degree days and the maximum cooling degree days in the urban area were a direct consequence of urban heat island. The 10-year (i.e., from 1995 to 2005) average shows that Cheung Chau experienced the least number of cooling degree days while Lau Fau Shan experienced the highest number of heating degree days. Seemingly, the area of Cheung Chau offers better thermal comfort conditions with the minimum number of cooling and heating degree days.     

Hydro-geochemical evaluation of groundwater with studies on water quality index and suitability for drinking in Sagardari,Jashore

Sagardari union is facing groundwater crisis because of contaminations from agriculture and urban sewage, which bring a considerable change in water quality. In view of this, hydro-chemical analyses were undertaken on 35 groundwater samples and the following hydro-geochemical parameters, pH, total dissolved solids (TDS), total hardness (TH), electrical conductivity (EC), cations and anions, were analyzed. From the analytical results, it is found that pH value was lower than WHO drinking water standard and the middle-downstream portions of the investigation region show higher EC. The piper plot indicates that the groundwater in Sagardari falls in the categories of NaClHCO₃ hydro-chemical facies. Higher TH in groundwater was detected, but still in an acceptable range. In addition, salinity and arsenic ratio are higher and moderately higher, respectively. The spatial distribution of Groundwater Quality Index (GWQI) was determined by geo-statistical modelling of Sagardari union. The study provides information and supports the administration which to make better groundwater utilization and quality control in the Sagardari union.     

Normal faulting mechanisms in the Western Desert of Egypt

Egypt is recognized as a moderate seismicity region where earthquakes are distributed within several active regions. Owing to sparse distribution of both seismicity and seismic stations, mostly moderate-size Egyptian earthquakes were recorded by regional stations. One of such cases is the moderate-size earthquakes of moment magnitudes greater than 4.0 which struck the Western Desert of Egypt in 1998 and 1999. These events are the first instrumentally recorded earthquakes occurring in the area. In the present study, the source mechanism for these earthquakes was estimated using the waveform data recorded from one of the very broadband MedNet seismograph stations and polarities from the national short-period seismographs. An iterative technique was applied to find the best-fit double-couple mechanism by a grid search over strike, dip and rake. Regional synthetic seismograms were calculated by using f–k integration in the frequency range of 0.03–0.1 Hz. A crustal structure fitted to surface wave dispersion curves was used to compute Green’s function. Focal depths were determined through the grid search method for a range of source depths. Our results show a normal faulting mechanism with minor strike-slip component. The NNW trend has been chosen as a preferred rupture plane in consistence with surface and subsurface faults and microearthquake seismicity in the epicenteral area as well.     

Association of hydrogeological factors in temporal variations of fluoride concentration in a crystalline aquifer in India

The major part of groundwater in India is found in granitic aquifers. Fluoride in groundwater from a crystalline aquifer in a semi-arid region of granitic rocks in India, known as Maheshwaram watershed, was analyzed for spatial and temporal variability during 1999–2002 to assess the effect of hydrogeological factors on fluoride concentration. Samples were collected from 32 representative wells in the area for the pre- and post-monsoon seasons and analyzed for F content. The CHESS computer program was used to calculate ionic activities of aqueous species and the mineral saturation index (SI) for calcite and fluorite. The GARDENIA computer program was used to calculate the recharge values in the study area. The influences of dissolution kinetics of fluoride minerals and recharge from rainfall on fluoride concentration were of interest and results clearly indicate that fluoride content in groundwater depends on the interaction period of groundwater with host rock. Results could also be utilized for designing remedial measures particularly with dilution method in an optimal way.     

The Effect of pH on Electro-osmotic Flow in Argillaceous Rocks

The use of electro-osmosis in geotechnical engineering has been considered since 1930. Its application has been tested in several sectors like the fight against rising damp in porous materials, the consolidation of soils as well as the remediation of the soils contaminated by oil and heavy metals, etc. The paper presents an experimental study of the electrokinetic phenomena resulting from the application of an electric field to argillaceous sandstones. The electroosmotic tests required the development of a completely new experimental device composed of a confining cell, of a system of measurement and control of the pH of the electrolyte near the electrodes, of a system of control and measurement of the voltage and current at the edges of the sample, and of a system of measurement of inlet (anodic) and outlet (cathodic) flows. Various boundary conditions are considered with and without control of pH. In addition, a micro structural modelling of the electrokinetic phenomena makes it possible to quantify the electro osmotic conductivity with a good agreement with experiments.     

Detection of trends in the 7-day sustained low-flow time series of Irish rivers

A combination of statistical hypothesis testing methods (Mann-Whitney, Mann-Kendall and Spearman’s rho) and visual exploratory analysis were used to investigate trends in Irish 7-day sustained low-flow (7SLF) series possibly driven by changes in summer rainfall patterns. River flow data from 33 gauging stations covering most major Irish rivers were analysed, after excluding catchments where low flows are influenced by significant human interventions. A statistically significant increasing trend in the 7SLF series was identified by all three tests at eight gauging stations; in contrast, a statistically significant decreasing trend was identified by all three tests at four stations. The stations with increasing trends are mainly located within the western half of the country, while there is no particular spatial clustering of the stations showing a decreasing trend. Further analysis suggests that the increasing trend in the 7SLF time series persists regardless of the starting year of analysis. However, the decreasing trend occurs only when years prior to 1970 are included in the analysis, and disappears, or is reversed, if only the data from 1970 and onwards are considered. There is strong evidence that the direction of the trends in the 7SLF series is determined mainly by trends in total summer rainfall amounts, i.e. is linked to weather.

EDITOR Z.W. Kundzewicz

ASSOCIATE EDITOR not assigned     

Elasto-plastic earthquake shear-response of one-dimensional earth dam models

A simplified analysis procedure for the non-linear hysteretic earthquake-response of earth dams is presented. The dam is modelled as a one-dimensional hysteretic shear-wedge subjected to base excitation. The hysteretic stress-strain behaviour of the dam materials is modelled by using elasto-plastic constitutive equations based on multi-surface kinematic plasticity theory. The method is based on a Galerkin formulation of the equations of motion in which the solution is expanded using eigenmodes of the linearized problem defined over the spatial domain occupied by the dam. The technique is applied to analyse the non-linear dynamic response of an earth dam subject to two very different input ground motions. The following investigations are presented: (i) comparison between the results obtained using two soil models depicting different nonlinear properties, (ii) comparison between the results of the one-mode and the multi-mode solution expansions, (iii) comparison with the results obtained through an elaborate finite element representation of the dam, and finally, (iv) comparison with the results obtained through the Makdisi-Seed¹¹ iterative procedure for earth dam analysis. The comparisons show that the proposed technique can be used to determine adequately the transient earthquake response of long earth dams. Furthermore, the efficiency and low computational cost make the technique very attractive; it can easily and systematically be extended to two- and three-dimensional calculations of earth dam response.