Platinum-group elements distribution and spinel composition in podiform chromitites and associated rocks from the upper mantle section of the Neoproterozoic Bou Azzer ophiolite, Anti-Atlas, Morocco

The distribution of platinum-group elements (PGEs), together with spinel composition, of podiform chromitites and serpentinized peridotites were examined to elucidate the nature of the upper mantle of the Neoproterozoic Bou Azzer ophiolite, Anti-Atlas, Morocco. The mantle section is dominated by harzburgite with less abundant dunite. Chromitite pods are also found as small lenses not exceeding a few meters in size. Almost all primary silicates have been altered, and chromian spinel is the only primary mineral that survived alteration. Chromian spinel of chromitites is less affected by hydrothermal alteration than that of mantle peridotites. All chromitite samples of the Bou Azzer ophiolite display a steep negative slope of PGE spidergrams, being enriched in Os, Ir and Ru, and extremely depleted in Pt and Pd. Harzburgites and dunites usually have intermediate to low PGE contents showing more or less unfractionated PGE patterns with conspicuous positive anomalies of Ru and Rh. Two types of magnetite veins in serpentinized peridotite, type I (fibrous) and type II (octahedral), have relatively low PGE contents, displaying a generally positive slope from Os to Pd in the former type, and positive slope from Os to Rh then negative from Rh to Pd in the latter type. These magnetite patterns demonstrate their early and late hydrothermal origin, respectively. Chromian spinel composition of chromitites, dunites and harzburgites reflects their highly depleted nature with little variations; the Cr# is, on average, 0.71, 0.68 and 0.71, respectively. The TiO₂ content is extremely low in chromian spinels, <0.10, of all rock types. The strong PGE fractionation of podiform chromitites and the high-Cr, low-Ti character of spinel of all rock types imply that the chromitites of the Bou Azzer ophiolite were formed either from a high-degree partial melting of primitive mantle, or from melting of already depleted mantle peridotites. This kind of melting is most easily accomplished in the supra-subduction zone environment, indicating a genetic link with supra-subduction zone magma, such as high-Mg andesite or arc tholeiite. This is a general feature in the Neoproterozoic upper mantle.     

Reliability Based Assessment of Shallow Foundations Using Mathcad

A reliability based method was used to design and analyse shallow foundations using first-order Taylor series approximation. The computer program Mathcad was used to facilitate all mathematical and computional efforts. This method is an effective tool to assist the foundation designers and analyists to investigate how reliable their designs or analyses are in relation to the ultimate bearing capacity of the foundations. The approach presented in this paper provides a reliable alternative for design and analysis of shallow foundations, rather than the conventional design methods, which employs the assumptions of a specified saftey factor. Several examples were presented for design and analysis of strip footings embedded in sandy soil, and rectangular and square footings analysis embedded in clayey soils. The program input and output of each example are also presented and discussed.     

Composition,radioactivity, and possible applications of kaolin deposits of Sinai,Egypt

This work discusses the composition, radioactivity, and possible utilization of the kaolin resources in Sinai which are hosted in thick sandstone sequences belonging to the Carboniferous (Wadi Khaboba) and Early Cretaceous (Wadi Iseila and Abansakar) ages. The characterization of kaolin was done by microscopic and SEM examination, supported by XRD and ICP-MS analyses. The studied kaolin resources consist of kaolinite, as the main constituent, associated with subsidiary dickite and halloysite, and minor contribution of smectite and illite. The most dominant non-clay mineral is quartz, besides minor gypsum, dolomite, and hematite. Ferrugination dominates, in most cases, at the upper boundaries of the kaolin lenses, suggesting possible supergene activity. The high Al₂O₃/SiO₂ ratio for the Cretaceous kaolin (0.54, in average) specifies its better grade relative to the Carboniferous kaolin (0.43, in average). The kaolin of the middle part of lens C in Wadi Iseila contains Si/Al molecular ratio of about unity, suggesting high-grade kaolin. The Carboniferous kaolin has enriched the radionuclides: U, Th, and Ra (at disequilibrium state due to leaching of eU relative to Ra) and the REE, relative to that of the Cretaceous age. The Carboniferous kaolin is characterized by a higher contribution of HREE (zircon signature), whereas LREE seems to be more influential for the Early Cretaceous kaolin (monazite signature). In spite of the very high CIA index (93 to 99), none of the analyzed kaolin deposits displays Ce abnormality. The high radioactivity of some Carboniferous kaolin can be a serious impediment for its utilization or its exportation. The kaolin of Sinai does not satisfy the international standards for paperwork industries and refractory manufacturing, but beneficiation may overcome this challenge. However, some lenses have high-grade kaolin with a low percentage of oxides of iron, magnesium, calcium, sodium, and potassium and a low radioactivity, hence nominated for the local refractory industry. The high-grade kaolin of Sinai fulfills the standards required for ceramics manufacturing in the global market. Grade 3 kaolin (< 30%, Al₂O₃) can be used in the manufacturing of white Portland cement and red glaze manufacturing on both local and global markets.     

Uncertainty assessment of the multilayer perceptron (MLP) neural network model with implementation of the novel hybrid MLP-FFA method for prediction of biochemical oxygen demand and dissolved oxygen: a case study of Langat River

Accurate prediction of the chemical constituents in major river systems is a necessary task for water quality management, aquatic life well-being and the overall healthcare planning of river systems. In this study, the capability of a newly proposed hybrid forecasting model based on the firefly algorithm (FFA) as a metaheuristic optimizer, integrated with the multilayer perceptron (MLP-FFA), is investigated for the prediction of monthly water quality in Langat River basin, Malaysia. The predictive ability of the MLP-FFA model is assessed against the MLP-based model. To validate the proposed MLP-FFA model, monthly water quality data over a 10-year duration (2001–2010) for two different hydrological stations (1L04 and 1L05) provided by the Irrigation and Drainage Ministry of Malaysia are used to predict the biochemical oxygen demand (BOD) and dissolved oxygen (DO). The input variables are the chemical oxygen demand (COD), total phosphate (PO₄), total solids, potassium (K), sodium (Na), chloride (Cl), electrical conductivity (EC), pH and ammonia nitrogen (NH₄-N). The proposed hybrid model is then evaluated in accordance with statistical metrics such as the correlation coefficient (r), root-mean-square error, % root-mean-square error and Willmott’s index of agreement. Analysis of the results shows that MLP-FFA outperforms the equivalent MLP model. Also, in this research, the uncertainty of a MLP neural network model is analyzed in relation to the predictive ability of the MLP model. To assess the uncertainties within the MLP model, the percentage of observed data bracketed by 95 percent predicted uncertainties (95PPU) and the band width of 95 percent confidence intervals (d-factors) are selected. The effect of input variables on BOD and DO prediction is also investigated through sensitivity analysis. The obtained values bracketed by 95PPU show about 77.7%, 72.2% of data for BOD and 72.2%, 91.6% of data for DO related to the 1L04 and 1L05 stations, respectively. The d-factors have a value of 1.648, 2.269 for BOD and 1.892, 3.480 for DO related to the 1L04 and 1L05 stations, respectively. Based on the values in both stations for the 95PPU and d-factor, it is concluded that the neural network model has an acceptably low degree of uncertainty applied for BOD and DO simulations. The findings of this study can have important implications for error assessment in artificial intelligence-based predictive models applied for water resources management and the assessment of the overall health in major river systems.     

Pan African layered diorite-tonalite-granodiorite from Sinai massif: an open system fractionation at a subduction zone

This paper reports on the occurrence of layered Pan African dioritetonalite-granodiorite (DTG) rocks. The layering is marked by alternation of melanocratic (M) layers (diorites and tonalites) and leucocratic (L) layers (tonalites and granodiorites). M-samples have cumulus biotite+hornblende+relict pyroxene+plagioclase+K-feldspars+magnetite+apatite, and have transitional calc-alkaline and metaluminous affinities. They were derived from subduction-related magma enriched in Rb, Ba, K and LREE and depleted in Sr and Nb. L-samples have cumulus plagioclase+hornblende. They are enriched in Sr and depleted in Rb, Ba, K, Nb and LREE. They have calc-alkaline and peraluminous affinites.
The formation of the rhythmic layers of DTG composition can be attributed to periodical replenishment of pulses of basic magma into a more evolved acidic magma chamber under open system conditions. Field relations, mineralogy and element concentration among the M- and L-layers indicate that at the subduction zone, the ascending magma was contaminated with lower crustal materials (marginal basin metasediments) which led to LILE-enrichment, Nb-depletion and transition from calc-alkaline to alkaline and from metaluminous to peraluminous affinities as well.     

Hook whistlers observed at low latitude ground station Varanasi

Employing the Haselgrove ray tracing equations and a diffusive equilibrium model of the ionosphere, the propagation characteristics of hook whistlers recorded at low-latitude ground station Varanasi (geomag. lat., 16°6′.N) are discussed. It is shown that the two traces of the hook whistlers are caused by the VLF waves radiated from the return stroke of a lightning discharge which after penetrating the ionosphere at two different entry points, propagated to the opposite hemisphere in the whistler mode and were received at 16 geomagnetic latitude. Further the crossing of ray paths for the same frequency leads to the explanation of the hook whistler. The lower and higher cut-off frequencies are explained in terms of their deviating away from the bunch of the recorded whistler waves and crossing of ray paths for the same frequency.     

Instability of a streaming jet under the influence of vacuum magnetic fields

The magnetohydrodynamic stability of a streaming liquid cylinder subject to surface tension and pervaded by a magnetic vacuum field has been elaborated for all axisymmetric and non-axisymmetric disturbances. The dispersion relation is obtained and studied analytically and numerically. the streaming has always a destabilizing effect. The axial magnetic fields inside and outside the jet have always stabilizing effects for all perturbations. The transverse magnetic field has a destabilizing effect. However, if the axial field intensity is so high and paramount over that the transverse field, the destabilizing character of the model is suppressed. The latter is satisfied if the Alfvén wave velocity is greater than the equilibrium liquid velocity.     

Lie transforms and the Hamiltonization of non-Hamiltonian systems

To develop the perturbation solution of the non-Hamiltonian system of differential equationsy=g(y, t; ), it is sufficient to obtain the perturbation solution of a Hamiltonian system represented by the HamiltonianK=Y·g(y, t; ) which is linear in the adjoint vectorY. This Hamiltonization allows the direct use of the perturbation methods already established for Hamiltonian systems. To demonstrate this fact, a Hamiltonian algorithm developed by this author and based on the Lie-Deprit transform is applied to the Hamiltonized system and is shown to be equivalent to the application of the non-Hamiltonian form of this same algorithm to the original non-Hamiltonian system.     

Optimal and sustainable extraction of groundwater in coastal aquifers

Four examples are investigated for the optimal and sustainable extraction of groundwater from a coastal aquifer under the threat of seawater intrusion. The objectives and constraints of these management scenarios include maximizing the total volume of water pumped, maximizing the profit of selling water, minimizing the operational and water treatment costs, minimizing the salt concentration of the pumped water, and controlling the drawdown limits. The physical model is based on the density-dependent advective-dispersive solute transport model. Genetic algorithm is used as the optimization tool. The models are tested on a hypothetical confined aquifer with four pumping wells located at various depths. These solutions establish the feasibility of simulating various management scenarios under complex three-dimensional flow and transport processes in coastal aquifers for the optimal and sustainable use of groundwater.