Small angle X-ray scattering mapping and kinetics study of sub-critical CO2 sorption by two Australian coals

Time- and position-resolved synchrotron small angle X-ray scattering data were acquired from samples of two Australian coal seams: Bulli seam (Bulli 4, R_o = 1.42%, Sydney Basin), which naturally contains CO₂ and Baralaba seam (R_o = 0.67%, Bowen Basin), a potential candidate for sequestering CO₂. This experimental approach has provided unique, pore-size-specific insights into the kinetics of CO₂ sorption in the micro- and small mesopores (diameter 5 to 175 Å) and the density of the sorbed CO₂ at reservoir-like conditions of temperature and hydrostatic pressure.For both samples, at pressures above 5 bar, the density of CO₂ confined in pores was found to be uniform, with no densification in near-wall regions. In the Bulli 4 sample, CO₂ first flooded the slit pores between polyaromatic sheets. In the pore-size range analysed, the confined CO₂ density was close to that of the free CO₂. The kinetics data are too noisy for reliable quantitative analysis, but qualitatively indicate faster kinetics in mineral-matter-rich regions.In the Baralaba sample, CO₂ preferentially invaded the smallest micropores and the confined CO₂ density was up to five times that of the free CO₂. Faster CO₂ sorption kinetics was found to be correlated with higher mineral matter content but, the mineral-matter-rich regions had lower-density CO₂ confined in their pores. Remarkably, the kinetics was pore-size dependent, being faster for smaller pores.These results suggest that injection into the permeable section of an interbedded coal-clastic sequence could provide a viable combination of reasonable injectivity and high sorption capacity.     

The structure of the crust in TESZ area by kriging interpolation

A precise 3D model of the crust is necessary to start any tectonic or geodynamic interpretation. It is also essential for seismic interpretations of structures lying below as well as for correct analysis of shallow structures using reflection seismics. During the last decades, a number of wide-angle refraction experiments were performed on the territory of central and eastern Europe (POLONAISE’97, CELEBRATION 2000, SUDETES 2003), resulting in many high quality 2D models. It is an interesting and complicated transition zone between Precambrian and Palaeozoic Platforms. This paper presents 3D model of the velocity distribution in the crust and upper mantle interpolated from 2D models of the structure along 33 profiles. The obtained model extends to a depth of 50 km and accurately describes the main features of the crustal structures of Poland and surrounding areas. Different interpolation techniques (Kriging, linear) are compared to assure maximum precision. The final model with estimated uncertainty is an interesting reference of the area for other studies.     

Deglacial to postglacial palaeoenvironments of the Celtic Sea: lacustrine conditions versus a continuous marine sequence

Recent work on the last glaciation of the British Isles has led to an improved understanding of the nature and timing of the retreat of the British?Irish Ice Sheet (BIIS) from its southern maximum (Isles of Scilly), northwards into the Celtic and Irish seas. However, the nature of the deglacial environments across the Celtic Sea shelf, the extent of subaerial exposure and the existence (or otherwise) of a contiguous terrestrial linkage between Britain and Ireland following ice retreat remains ambiguous. Multiproxy research, based on analysis of 12 BGS vibrocores from the Celtic Deep Basin (CDB), seeks to address these issues. CDB cores exhibit a shell‐rich upward fining sequence of Holocene marine sand above an erosional contact cut in laminated muds with infrequent lonestones. Molluscs, in situ Foraminifera and marine diatoms are absent from the basal muds, but rare damaged freshwater diatoms and foraminiferal linings occur. Dinoflagellate cysts and other non‐pollen palynomorphs evidence diverse, environmentally incompatible floras with temperate, boreal and Arctic glaciomarine taxa co‐occurring. Such multiproxy records can be interpreted as representing a retreating ice margin, with reworking of marine sediments into a lacustrine basin. Equally, the same record may be interpreted as recording similar conditions within a semi‐enclosed marine embayment dominated by meltwater export and deposition of reworked microfossils. As assemblages from these cores contrast markedly with proven glaciomarine sequences from outside the CDB, a glaciolacustrine interpretation is favoured for the laminated sequence, truncated by a Late Weichselian transgressive sequence fining upwards into fully marine conditions. Reworked rare intertidal molluscs from immediately above the regional unconformity provide a minimum date c. 13.9 cal. ka BP for commencement of widespread marine erosion. Although suggestive of glaciolacustrine conditions, the exact nature and timing of laminated sediment deposition within the CDB, and the implications this has on (pen)insularity of Ireland following deglaciation, remain elusive.     

Lithosphere thermal structure at the eastern margin of the Bohemian Massif: a case petrological and geophysical study of the Nied?wied? amphibolite massif (SW Poland)

The crustal section beneath amphibolite Nied?wied? Massif (Fore-Sudetic Block in NE Bohemian Massif), modelled on the basis of geological and seismic data, is dominated by gneisses with subordinate granites (upper and middle crust) and melagabbros (lower crust). The geotherm was calculated based on the chemical analyses of the heat-producing elements in the rocks forming the crust and the measurements of their density and heat conductivity. The results were verified by heat flow calculations based on temperature measurements from 1,600?m deep well in the Nied?wied? Massif and by temperature–depth estimates in mantle xenoliths coming from the nearby ca. 4.5?My basanite plug in Lutynia. The paleoclimate-corrected heat flow in the Nied?wied? Massif is 69.5?mW?m^?2, and the mantle heat flow is 28?mW?m^?2. The mantle beneath the Massif was located marginally relative to the areas of intense Cenozoic thermal rejuvenation connected with alkaline volcanism. This results in geotherm which is representative for lithosphere parts located at the margins of zones of continental alkaline volcanism and at its waning stages. The lithosphere–asthenosphere boundary (LAB) beneath Nied?wied? is located between 90 and 100?km depth and supposedly the rheological change at LAB is not related to the appearance of melt.     

Mixing processes in wide open channels

The work contains analyses of two cases of stream diffusion under conditions of turbulent flow in an open channel. The analysed cases were: a source of rectangular cross-section placed in the channel axis and at the wall. To describe the mixing process the known equation of the turbulent diffusion was used. Verification of the solution for the considered cases was made based on research performed on models.     

Geomorphology of medium‐high mountains under changing human impact,from managed slopes to nature restoration: a study from the Sudetes,SW Poland

In the last few hundred years, medium‐high mountain geomorphic systems of the East Sudetes, central Europe, have evolved under varying human impacts and have shown distinctive behaviours, depending on the nature and intensity of human activities. The general trend within this period has been from initial disturbance brought about by the spread of agriculture, through managed rural landscapes in the 19th and early 20th century, to gradual restoration of natural conditions observed in the last few tens of years, concurrent with considerable population decline in the mountain valleys. Accelerated soil erosion was successfully mitigated by the introduction of agricultural terraces in the 19th century, and most sediment could have been stored within the slopes. The current phase of nature restoration is understood as a return to general slope stability, weak coupling between slopes and channels, and limited sediment transfer across and out of mountainous drainage basins, which typified most of the Holocene prior to human colonization. Copyright © 2006 John Wiley & Sons, Ltd.