Textural properties vs. CEC and EGME retention of Na–X zeolite prepared from fly ash at room temperature

Zeolite Na–X (FAU type) was synthesized from F-class fly ash in simple and economical way. Several months of storage of fly ash in NaOH solution, at room temperature, without any prior treatment, results in the production of material with ca. 50% content of Na–X zeolite. The most efficient reaction takes place at (OH)⁻ activity of 0.1–0.15 mol (OH)⁻/g of ash and at S/L ratio of 33 to 67 g/dm³. Higher S/L value causes an accelerating dissolution–crystallization equilibrium attainment. Cl⁻ ion acts as the inhibitor of this reaction.     

HAND contour: a new proxy predictor of inundation extent

Tools for accurately predicting environmental risks, such as the location and spatial extent of potential inundation, are not widely available. A dependence on calibration and a lack of available flood data have prevented the widespread application of existing hydrodynamic methods for predicting the extent of inundation. We use the height above the nearest drainage (HAND) terrain model to develop a simple static approach for mapping the potential extent of inundation that does not depend on flood observations and extends beyond methods for mapping low‐lying areas. While relying on the contour concept, the method utilizes drainage‐normalized topography and flowpaths to delineate the relative vertical distances (drop) to the nearest river. The HAND‐delineated relative drop is an effective distributed predictor of flood potential, which is directly related to the river stage height. We validated the new HAND contour approach using a flood event in Southern Brazil for which high‐resolution maps were available. The results indicated that the flood hazard‐mapping method accurately predicted the inundation extent of the channel carrying the flood wave and the channels influenced by flooding. For channels positioned outside of the flood‐wave area, the method overestimated the actual flood extent. As an original static assessment of floodwaters across the landscape, the HAND contour method could be used to map flood hazards in areas with poor information and could promote the development of new methods for predicting hydrological hazards. Copyright © 2015 John Wiley & Sons, Ltd.     

Atrazine effects on meiobenthic assemblages of a modular estuarine mesocosm

Atrazine is a widely used herbicide in the US found at levels ranging from <10 ng/L to 62.5 microg/L in estuaries throughout the southeast. Effects of atrazine on estuarine meiobenthic assemblages chronically exposed to environmentally relevant concentrations are unknown. The purpose of our research was to assess effects of atrazine on meiobenthos at concentrations near the proposed USEPA SWQC (26 microg/L) using modular estuarine salt marsh mesocosms as a field surrogate. Indigenous copepod and nematode densities were assessed after 28 days of exposure in transplanted colonization chambers. Cluster analysis showed a group characterized by low copepod densities, mostly atrazine exposed chambers, and a group containing all but one control chamber. The later group included chambers with high densities of the copepods Paronychocamptus wilsoni and Enhydrosoma baruchi. Compared to controls, copepod densities was approximately 70% lower in atrazine chambers, with three of the most common copepod species (E. baruchi, Onychocamptus sp. and P. wilsoni) showing an average of 50-70% reduction in population densities (p<0.05). Although nematode density did not differ between atrazine and control chambers, the nematode-to-copepod ratio was significantly higher in atrazine (9.95+/-7.61; p=0.011) than in control chambers (0.61+/-0.35). Our findings suggest that chronic exposures over multiple generations to atrazine at concentrations near the proposed USEPA SWQC could have significant effects on the abundance and composition of estuarine meiobenthic copepod assemblages.     

The Newport line off Oregon - Studies in the North East Pacific

The Newport Hydrographic (NH) Line along 44.65°N off central Oregon was sampled seasonally during two epochs: 1961-1971 through the TENOC program and 1997-2003 through the GLOBEC Northeast Pacific Long Term Observations Program (LTOP); some observations are available for 2004 and 2005. During TENOC, the line extended 305 km offshore to 128°W, with stations 18 km apart over the continental shelf and 36 km offshore. During LTOP, the line was shorter (to 126°W) with closer station spacing over the continental shelf (9 km apart) and slope (18 km apart). LTOP cruises included biochemical sampling and underway current measurements. During both TENOC and LTOP, the seasonal cycle is very strong (accounting for >50% of the variance in surface layer properties), with rapid transitions in spring and fall. The summer regime is subject to coastal upwelling driven by southward winds, equatorward surface currents, and advection of low-salinity waters from the Columbia River. The winter regime off Newport is subject to coastal downwelling and poleward surface currents driven by northeastward winds. Comparison between TENOC and LTOP summer regimes shows the near-surface layer (0-100 m) at most locations is significantly warmer and fresher during LTOP than TENOC, and steric heights over the continental margin are significantly higher. Comparison of LTOP and TENOC winters shows that average differences at most locations were not statistically significant, but that the variance of steric height and shelf-break temperatures was significantly higher during LTOP than TENOC. Interannual variability of climate indices is also stronger during LTOP, which included a rare Subarctic invasion in 2002 as well as the strong 1997-1998 El Niño. During both TENOC and LTOP, interannual variability of steric height is closely related to the El Niño/La Niña cycle. Nutrient concentrations and nitrate-to-phosphate ratios of upwelling-source waters vary inversely with halocline temperature. Both reflect alongshore advection by coastal currents: southward currents bring cool, nitrate-rich waters in summer (especially during the Subarctic invasion), and northward currents bring relatively warm, nitrate-poor waters to the NH line in winter (especially during El Niño). Seasonal and interannual variations in the nutrient level of upwelling-source water are reflected in time series of vertically-integrated chlorophyll over the LTOP survey region (about 150 km by 300 km). Seasonal variations in chlorophyll and currents are congruent with seasonal variations in copepod biomass and diversity. We were not successful in establishing a clear connection between chlorophyll levels and interannual variations in copepod biomass or diversity, nor in explaining the large decrease in the survival rate of coho salmon between TENOC (6%) and LTOP (3%).     

Coastal upwelling in the California current system

Coastal upwelling in the California Current system has been the subject of large scale studies off California and Baja California, and of small scale studies off Oregon. Recent studies of the winds along the entire coast from 25°N to 50°N indicate that there are significant along-shore variations in the strength of coastal upwelling, which are reflected in the observed temperature distribution. Active upwelling appears to be restricted to a narrow coastal band (about 10–25 km wide) along the entire coast, but the region influenced by coastal upwelling may be much wider. Intensive observations of the upwelling zone during summer off Oregon show the presence of a southward coastal jet at the surface, a mean vertical shear, a poleward undercurrent along the bottom, and persistently sloping isopycnals over the continental shelf; most of the upwelling there occurs during relatively short periods (several days long) of upwelling-favorable winds. During the upwelling season off Oregon, the offshore Ekman transport is carried by the surface Ekman layer, and the onshore return flow occurs through a quasi-geostrophic interior. It is not known whether the structure and dynamics observed off Oregon are typical of the upwelling zone along the entire coast, though some of the same features have been observed off Baja California. Current and future research will eventually show whether the Oregon results are also applicable in the region of persistently strong upwelling-favorable winds off northern California, and in the region of complex bathymetry off central and southern California.     

Quaternary ontogeny of a pampean ‘laguna’

Our sedimentological study of Lobos Lake sediments has shown that, below modern deposits, there is a clastic and biological record of three different paleoenvironments: two aquatic (freshwater and mixohaline respectively) and one subaereal. This record documents the climatic and geomorphologic changes that affected the basin during its evolution up to its present water level, from the upper Pleistocene to the Holocene.This is the seventh in a series of papers published in this issue on Paleolimnology in Southern South America. Dr. C. A. Fernández served as guest editor for these papers.     

The role of volatile exsolution and sub-solidus fluid/rock interactions in producing high Fe/Fe ratios in siliceous igneous rocks

Highly differentiated igneous rocks can, in some cases, have ⁵⁶Fe/⁵⁴Fe ratios that are significantly higher than those of mafic- to intermediate-composition igneous rocks. Iron isotope compositions were obtained for bulk rock, magnetite, and Fe silicates from well-characterized suites of granitic and volcanic rocks that span a wide range in major- and trace-element contents. Sample suites studied include granitoids from Questa, N.M. (Latir volcanic field) and the Tuolumne Intrusive Series (Sierra Nevada batholith), and volcanic rocks from Coso, Katmai, Bishop Tuff, Grizzly Peak Tuff, Seguam Island, and Puyehue volcano. The rocks range from granodiorite to high-silica granite and basalt to high-silica rhyolite. The highest δ⁵⁶Fe values (up to +0.31‰) are generally restricted to rocks that have high Rb (>100 ppm), Th (>∼15 ppm) and SiO₂ (>70 wt.%) but low Fe (<2 wt.% total Fe as Fe₂O₃) contents. Magnetite separated from these rocks has high δ⁵⁶Fe values, whereas Fe silicates have δ⁵⁶Fe values close to zero. Although in principle crystal fractionation might explain the high δ⁵⁶Fe values, trace-element ratios in high-δ⁵⁶Fe igneous rocks indicate that crystal fractionation is an unlikely explanation. The highest δ⁵⁶Fe values occur in volcanic and plutonic rocks that contain independent evidence for fluid exsolution, including sub-chondritic Zr/Hf ratios, suggesting that loss of a low-δ⁵⁶Fe ferrous chloride fluid is the most likely explanation for the high δ⁵⁶Fe values in the bulk rocks. Based on magnetite solubility in chloride solutions and predicted Fe isotope fractionations among Fe silicates, magnetite, and ferrous chloride fluids, the increase in δ⁵⁶Fe values of bulk rocks may be explained by isotopic exchange between magnetite and , which predicts an increase in the δ⁵⁶Fe values of magnetite upon fluid exsolution. This model is consistent with the δ⁵⁶Fe values measured in this study for bulk rocks, as well as magnetite and Fe silicates. Our results suggest that fluid exsolution from siliceous hydrous magmas, which sometimes produce porphyry-style Cu, Mo, or Cu-Au mineralization, may be traced using Fe isotopes.     

Impact of human activities on the central Mediterranean offshore: Evidence from Hg distribution in box-core sediments from the Ionian Sea

Total Hg concentrations have been measured for five box-core sediments collected seawards of the Augusta industrial area (SE Sicily). In more coastal sediments, upcore increasing Hg concentrations, exceeding the Hg background concentration estimated for the Strait of Sicily, indicate Hg contamination over time due to the industrial area development. Strong correlation between total organic C (TOC) and Hg concentrations was found only for core BX2, that displays organic C to total N (C/N) ratios indicative of autochthonous organic matter. For other sediments, high Hg enrichment factors with respect to TOC indicate, in addition to Hg trapping by TOC, other factors as responsible for Hg accumulation. In the presence of some contribution of detrital organic matter, Hg is mainly adsorbed onto the mineral component of the bottom sediments probably because TOC is saturated by Hg excess. Contaminant impact affected also the open sea environment. Main drivers of Hg flux towards the offshore were dredged materials, which repeatedly discharged sediment, resulting in substantial increases in TOC contents and high C/N ratios. Consistent with the geochemistry of recent turbidites, these anomalous sedimentary inputs induced sediment redox environment modifications, constrained by Mn peaks, which affected Hg distribution.