Infrared detection of ore variability that influences the environmental risks during perlite mining and processing

In the mining of perlite deposits, controlling the generation of fine particles and the concentration of metals is of outstanding importance to meet the environmental and market requirements. Particle size and chemical purity are conventionally manipulated during the processing of the ore to achieve high product specifications. However, the current practices do not consider a proactive approach that focuses in the in-pit characterisation of the ore that would minimise the environmental impact and optimise the mining process since its early stages. This paper presents a method for the in-pit detection of the perlite ore variability that is related to the generation of fine particles and the elevated concentration of metals. Particle size and chemical purity showed to be dependent on the mineralogical variations of the ore, specifically opal and montmorillonite. Using a portable infrared spectrometer, an index that establishes the relative proportions of these minerals in the perlite ore was created. Such index provided insight into the correlation between mineralogy, fine particles and concentration of metals. Consequently, the index could be used not only for mineralogical determination but also as a predictor of the presence of the main impurities in the perlite ore. These results can be implemented in perlite mining to reduce the generation of waste and can influence the production of high-quality perlite products.     

Solar Radius at Subterahertz Frequencies and Its Relation to Solar Activity

The Sun emits radiation at several wavelengths of the electromagnetic spectrum. In the optical band, the solar radius is 695?700 km, and this defines the photosphere, which is the visible surface of the Sun. However, as the altitude increases, the electromagnetic radiation is produced at other frequencies, causing the solar radius to change as a function of wavelength. These measurements enable a better understanding of the solar atmosphere, and the radius dependence on the solar cycle is a good indicator of the changes that occur in the atmospheric structure. We measure the solar radius at the subterahertz frequencies of 0.212 and 0.405 THz, which is the altitude at which these emissions are primarily generated, and also analyze the radius variation over the 11-year solar activity cycle. For this, we used radio maps of the solar disk for the period between 1999 and 2017, reconstructed from daily scans made by the Solar Submillimeter-wave Telescope (SST), installed at El Leoncito Astronomical Complex (CASLEO) in the Argentinean Andes. Our measurements yield radii of \(966.5'' \pm2.8''\) for 0.2 THz and \(966.5'' \pm2.7''\) for 0.4 THz. This implies a height of \(5.0 \pm2.0 \times10^{6}\) m above the photosphere. Furthermore, we also observed a strong anticorrelation between the radius variation and the solar activity at both frequencies.     

Multi‐kilometre long pathway of geofluids migration: Clues concerning an ophiolite serpentinization setting possibly responsible for the inferred abiotic provenance of methane in thermal water outflows of the South‐West Carpathians (Romania)

Methane occurrences displaying signatures of a possible abiotic origin had previously been reported in the South‐West Carpathians (Romania). Such an accumulation, at Tisovi?a, was intercepted by a well drilled in an ophiolitic rocks massif, whereas in two other localities—situated tens of kilometres faraway—the concerned methane is released via thermal groundwater outflows that are apparently not associated with any ultramafic products. By using groundwater ionic compositions, corroborated with previously published isotopic (¹³C‐CH₄, ²H‐CH₄, ³He/⁴He) and molecular gas analyses, we assessed in more detail the conjectured abiotic provenance of methane, and quantitatively investigated the hypothesis of a progressive mixing between two, abiotic and thermogenic, methane end‐members. The corresponding geofluids behaviour was modelled by hypothesizing a “concealed” ophiolite serpentinization setting (largely similar to that at Tisovi?a), whose abiotic methane production was “diverted” towards remote discharges at ground surface, via a ~20‐km‐long flowpath supposedly generated by recently operating extensional tectonics.     

Coastal Phytoplankton Do Not Rest in Winter

The climatology and interannual variability of winter phytoplankton was analyzed at the Long Term Ecological Research Station MareChiara (LTER-MC, Gulf of Naples, Mediterranean Sea) using data collected from 1985 to 2006. Background winter chlorophyll values (0.2–0.5 μg chl a dm⁻³) were associated with the dominance of flagellates, dinoflagellates, and coccolithophores. Winter biomass increases (<5.47 μg chl a dm⁻³) were often recorded until 2000, generally in association with low-salinity surface waters (37.3–37.9). These blooms were most often caused by colonial diatoms such as Chaetoceros spp., Thalassiosira spp., and Leptocylindrus danicus. In recent years, we observed more modest and sporadic winter biomass increases, mainly caused by small flagellates and small non-colonial diatoms. The resulting negative chl a trend over the time series was associated with positive surface salinity and negative nutrient trends. Physical and meteorological conditions apparently exert a strict control on winter blooms, hence significant changes in winter productivity can be foreseen under different climatic scenarios.     

An atmosphere–ocean regional climate model for the Mediterranean area: assessment of a present climate simulation

We present an atmosphere–ocean regional climate model for the Mediterranean basin, called the PROTHEUS system, composed by the regional climate model RegCM3 as the atmospheric component and by a regional configuration of the MITgcm model as the oceanic component. The model is applied to an area encompassing the Mediterranean Sea and compared to a stand-alone version of its atmospheric component. An assessment of the model performances is done by using available observational datasets. Despite a persistent bias, the PROTHEUS system is able to capture the inter-annual variability of seasonal sea surface temperature (SST) and also the fine scale spatio-temporal evolution of observed SST anomalies, with spatial correlation as high as 0.7 during summer. The close inspection of a 10-day strong wind event during the summer of 2000 proves the capability of the PROTHEUS system to correctly describe the daily evolution of SST under strong air–sea interaction conditions. As a consequence of the model’s skill in reproducing observed SST and wind fields, we expect a reliable estimation of air–sea fluxes. The model skill in reproducing climatological land surface fields is in line with that of state of the art regional climate models.     

Water-soluble organic and nitrogen levels in cloud and rainwater in a background marine environment under influence of different air masses

Chemical characterization was performed on cloud and rainwater samples collected as part of the Rain In Cumulus over the Ocean Experiment (RICO). This experiment took place at a mountaintop site (East Peak) in Puerto Rico from December 2004 to March 2007 in order to determine water-soluble organic and nitrogen fractions in a marine background environment. For cloud water, similar average concentrations of 1.0 (±0.3) mg/L were found for total organic carbon (TOC) and total nitrogen (TN) and an average concentration of 0.8 (±0.2) mg/L was found for dissolved organic carbon (DOC). In rainwater, these concentrations were lower, ranging from 0.3 to 0.5 (±0.1) mg/L. Changes in the concentrations of these species were observed in periods under the influence of anthropogenic, African dust, and volcanic ash air masses. In these periods the concentrations of TOC, DOC, and TN were 2 to 4 times higher than in periods under the influence of trade winds. The insoluble organic material arriving during African dust events showed total carbon (TC) concentrations on averaging 1.5 mg/L for cloud water. The TC was composed mainly of organic carbon with polar compounds from low to high molecular weight (MW). The polar compounds with high MW were probably associated with pollution (e.g., fossil fuel combustion) from other regions. Crustal species (Al and Fe) dominated particles associated with dust episodes, confirming the soil origin. Our results suggested that a fraction (40–80%) of TOC and (<100%) of TN in Puerto Rican cloud/rainwater could be originated from long-range transport of dust, ash and/or pollution.     

Sabella spallanzanii filter-feeding on bacterial community: ecological implications and applications

The filtration process of Sabella spallanzanii Gmelin on bacterial community was studied in a coastal area of the Northern Ionian Sea (Mediterranean Sea) at three sites, S. Vito, Lido Gandoli and Lido Silvana, where some specimens of S. spallanzanii were transplanted. Analyses were performed both on water and worm samples. A total of six microbial groups were examined: culturable heterotrophic bacteria, total culturable bacteria at 37 degrees C, culturable vibrios, total and fecal coliforms and fecal streptococci. The bacterial densities were usually orders of magnitude higher in the worm homogenates than in the corresponding seawater and the highest values were observed in August. The ability of S. spallanzanii to accumulate the microbial pollution indicators suggests this species can be employed as a bioindicator for monitoring water quality. Moreover, the accumulation capability of S. spallanzanii for specific micro-organisms provides a potential role in sewage bioremediation.     

What controls selenium release during shale weathering?

This study demonstrates that only a combination of a chromous chloride reduction with dual sequential extraction schemes can clearly separate the proportions of Se present in the sulphide versus the organic pools in shales. The data reveals that even small amounts of pyrite outcompete the organic matter for the available Se and pyrite oxidation will control the release of selenium during shale weathering.     

Life Cycle,Growth and Secondary Production in a Brackish-Water Population of the Polychaete Notomastus latericeus (Capitellidae) in the Mediterranean Sea

Abstract. Three years of observations on a population of Notomastus latericeus Sars from Acquatina lagoon (Lecce, Italy) are reported. The population dynamics, life cycle, and reproduction were investigated in order to explain periodic density variations of this species. Some physical parameters of the water column were measured and sediment analyses were performed to characterize the environment. Secondary production was also estimated as part of a functional study of the benthic system in the Acquatina lagoon. The species is opportunistic; its density is apparently correlated to variation in salinity, but its presence in the lagoon is dependent on recruitment success and competition with other polychaete species.     

Hierarchical procedure for creating local typologies for riparian zone research and management based on biophysical features

Riparian systems have been included as a key component in ecosystem management because of their role in buffering the impact of land-use activities on fluvial systems. Riparian knowledge can be enhanced with a typology that reflects the multiple relationships occurring throughout the landscape. We propose a hierarchical procedure based on biophysical aspects for building local to regional typologies for guiding research and management, using the Cuitzmala River Basin as a case study. The variables involved were obtained from geospatial databases, water balances, and topographic profiles. The levels and variables are context (altitude, geoform [mountains/hills/plains], and runoff coefficient), structure (stream order, longitudinal slope, hydroperiod, and segment length), and microstructure (lateral slope, bankfull width, and length-to-width ratio). We consider humidity and functional gradient along the basin to identify groups of streams and fluvial networks. Inside each network, we described structural and microstructural features associated with riparian functions, linking them with management decisions. Therefore, the proposed hierarchical procedure can help in making riparian heterogeneity visible, focusing research and management goals, and allowing the recognition of a spatial dimension of the processes being studied.