In‐plane and out‐of‐plane behavior of confined masonry walls for various toothing and openings details and prediction of their strength and stiffness

Eight half‐scale brick masonry walls were tested to study two important aspects of confined masonry (CM) walls related to its seismic behavior under in‐plane and out‐of‐plane loads. Four solid wall specimens tested to investigate the role of type of interface between the masonry and tie‐columns, such as toothing varying from none to every course. The other four specimens with openings were tested to study the effectiveness of various strengthening options around opening to mitigate their negative influence. In the set of four walls, one wall was infilled frame while the other three were CM walls of different configurations. The experimental results were further used to determine the accuracy of various existing models in predicting the in‐plane response quantities of CM walls. Confined masonry walls maintained structural integrity even when severely damaged and performed much better than infill frames. No significant effect of toothing details was noticed although toothing at every brick course was preferred for better post‐peak response. For perforated walls, provision of vertical elements along with continuous horizontal bands around openings was more effective in improving the overall response. Several empirical and semi‐empirical equations are available to estimate the lateral strength and stiffness of CM walls, but those including the contribution of longitudinal reinforcement in tie‐columns provided better predictions. The available equations along with reduction factors proposed for infills could not provide good estimates of strength and stiffness for perforated CM walls. However, recently proposed relations correlating strength/stiffness with the degree of confinement provided reasonable predictions for all wall specimens. Copyright © 2016 John Wiley & Sons, Ltd.     

Pyroclastic flows and surges over water: an example from the 1883 Krakatau eruption

Pyroclastic deposits from the 1883 eruption of Krakatau are described from areas northeast of the volcano on the islands of Sebesi, Sebuku, and Lagoendi, and the southeast coast of Sumatra. Massive and poorly stratified units formed predominantly from pyroclastic flows and surges that traveled over the sea for distances up to 80 km. Granulometric and lithologic characteristics of the deposits indicate that they represent the complement of proximal subaerial and submarine pyroclastic flow deposits laid down on and close to the Krakatau islands. The distal deposits exhibit a decrease in sorting coefficient, median grain size, and thickness with increasing distance from Krakatau. Crystal fractionation is consistent with the distal facies being derived from the upper part of gravitationally segregated pyroclastic flows in which the relative amount of crystal enrichment and abundance of dense lithic clasts diminished upwards. The deposits are correlated to a major pyroclastic flow phase that occurred on the morning of 27 August at approximately 10 a.m. Energetic flows spread out away from the volcano at speeds in excess of 100 km/h and traveled up to 80 km from source. The flows retained temperatures high enough to burn victims on the SW coast of Sumatra. Historical accounts from ships in the Sunda Straits constrain the area affected by the flows to a minimum of 4x10³ km². At the distal edge of this area the flows were relatively dilute and turbulent, yet carried enough material to deposit several tens of centimeters of tephra. The great mobility of the Krakatau flows from the 10 a.m. activity may be the result of enhanced runout over the sea. It is proposed that the generation of steam at the flow/seawater interface may have led to a reduction in the sedimentation of particles and consequently a delay in the time before the flows ceased lateral motion and became buoyantly convective. The buoyant distal edge of these ash-and steam-laden clouds lifted off into the atmosphere, leading to cooling, condensation, and mud rain.     

Gravity wave exclusion circles in background flows modulated by the semidiurnal tide

In this short paper the exclusion circles and vertical phase locities for gravity waves launched from the ground into a time-varying wind are studied using a ray-tracing technique. It is shown that waves with initial observed phase speeds that should place them within the local temporally varying exclusion circle, are often Doppler shifted outside of the circle. This, and the finite lifetime of some critical levels, allow waves to survive the critical layer and reach higher altitudes. Also, for slower phase-speed waves, the temporally varying wind can shift the observed frequency to negative values, so that the observed phase motions will be opposite (i.e. horizontally reversed and vertically upward), even though the energy still propagates upward. This effect can also cause the phase velocity to move inside the local exclusion circle. Due to the directional filtering of wave sources by the stratospheric wind, the percentage of such reverse-propagating waves will change systematically with local time and height in our simplified but realistic model. These results are related to ground-based systems, optical and radar, which sample the wind field and gravity waves in the middle atmosphere.     

Geochemistry of silicic magmas in the Macolod Corridor, SW Luzon, Philippines: evidence of distinct, mantle-derived, crustal sources for silicic magmas

Silicic volcanic deposits (>65 wt% SiO₂), which occur as domes, lavas and pyroclastic deposits, are relatively abundant in the Macolod Corridor, SW Luzon, Philippines. At Makiling stratovolcano, silicic domes occur along the margins of the volcano and are chemically similar to the silicic lavas that comprise part of the volcano. Pyroclastic flows are associated with the Laguna de Bay Caldera and these are chemically distinct from the domes and lavas at Makiling stratovolcano. As a whole, samples from the Laguna de Bay Caldera contain lower concentrations of MgO and higher concentrations of Fe₂O_3(t) than the samples from domes and lavas. The Laguna de Bay samples are more enriched in incompatible trace elements. The silicic rocks from the domes, Makiling Volcano and Laguna de Bay Caldera all contain high alkalis and high K₂O/Na₂O ratios. Melting experiments of primitive basalts and andesites demonstrate that it is difficult to produce high K₂O/Na₂O silicic magmas by fractional crystallization or partial melting of a low K₂O/Na₂O source. However, recent melting experiments (Sisson et al., Contrib Mineral Petrol 148:635–661, 2005) demonstrate that extreme fractional crystallization or partial melting of K-rich basalts can produce these silicic magmas. Our model for the generation of the silicic magmas in the Macolod Corridor requires partial melting of mantle-derived, evolved, moderate to K-rich, crystallized calc-alkaline magmas that ponded and crystallized in the mid-crust. Major and trace element variations, along with oxygen isotopes and ages of the deposits, are consistent with this model. Electronic Supplementary Material Supplementary material is available for this article at     

The crystal chemistry of lithium and Fe3+ in synthetic orthopyroxene

Lithian ferrian enstatite with Li₂O = 1.39 wt% and Fe₂O₃ 7.54 wt% was synthesised in the (MgO–Li₂O–FeO–SiO₂–H₂O) system at P = 0.3 GPa, T = 1,000°C, fO₂ = +2 Pbca, and a = 18.2113(7), b = 8.8172(3), c = 5.2050(2) Å, V = 835.79(9) Å³. The composition of the orthopyroxene was determined combining EMP, LA-ICP-MS and single-crystal XRD analysis, yielding the unit formula ^M2(Mg_0.59Fe _0.21 ²⁺ Li_0.20) ^M1(Mg_0.74Fe _0.20 ³⁺ Fe _0.06 ²⁺ ) Si₂O₆. Structure refinements done on crystals obtained from synthesis runs with variable Mg-content show that the orthopyroxene is virtually constant in composition and hence in structure, whereas coexisting clinopyroxenes occurring both as individual grains or thin rims around the orthopyroxene crystals have variable amounts of Li, Fe³⁺ and Mg contents. Structure refinement shows that Li is ordered at the M2 site and Fe³⁺ is ordered at the M1 site of the orthopyroxene, whereas Mg (and Fe²⁺) distributes over both octahedral sites. The main geometrical variations observed for Li-rich samples are actually due to the presence of Fe³⁺, which affects significantly the geometry of the M1 site; changes in the geometry of the M2 site due to the lower coordination of Li are likely to affect both the degree and the kinetics of the non-convergent Fe²⁺-Mg ordering process in octahedral sites.     

P-T paths and problems of high-temperature polymetamorphism

Many Precambrian granulite-facies metamorphic complexes contain so-called straight gneisses, which are massive rocks with a clearly pronounced blastomylonitic texture, lineation, and gneissosity. These rocks occur exclusively in high-temperature ductile shear zones, which can develop either during the primary exhumation of rock complexes or during the overprinting by high-temperature dynamometamorphism. The main criterion for distinguishing between these two types of straight gneisses is the configuration of their P-T trajectories, which are recorded in the mineral assemblages in these rocks and their host gneisses. Ductile shear zones developed in Archean granulite gneisses simultaneously with their exhumation, and, hence, their P-T trajectories are segments of decompression and/or isobaric cooling paths. Straight gneisses in Proterozoic polymetamorphic complexes commonly compose high-temperature ductile shear zones overprinted on Archean granulite complexes, and the P-T paths of these rocks are Z-shaped. This means that, at a constant pressure in the middle part of the continental crust, the T _min of the older P-T trajectory corresponded to T _max of the younger trajectory, and often T _max–T _min > 100°C. Such ductile shear zones commonly have a strike-slip morphology and can be easily seen in aerial photographs and discerned during structural geological surveying. These zones can overprint older gneisses without any notable thermal effect on the latter. Relations of this type were identified in the granulite complexes of Limpopo in South Africa, Sharyzhalgai in the southwestern Baikal area, and Lapland in the Kola Peninsula. The results of our research propose a solution for the well-known problem of the significant discrepancies between the isotopic ages in high-temperature-high-pressure complexes and the partial or complete distortion of radiogenic isotopic systems under the effect of a newly inflowing metamorphic fluid. The application of geochronologic techniques to these situations is senseless, and only P-T trajectories provide insight into the actual age relations between the discrete tectono-metamorphic stages. It is thus expedient to conduct not only structural studies of metamorphic complexes but also their detailed petrological examination and the calculation of their P-T paths before geochronologic dating.     

Conceptual hydrodynamic model of the Pamukkale hydrothermal field, southwestern Turkey, based on hydrochemical and isotopic data

The results of study on the hydrochemical and isotope characteristics of shallow and deep waters at Pamukkale hydrothermal field Turkey are described in order to obtain a better understanding of the hydrological circulation. The field can be grouped into two groundwater sub-systems; cold water springs of Ca–HCO₃ type (10–12 °C), and CO₂-rich thermal waters of Ca–HCO₃–SO₄ type (25–58 °C). The occurrence of these water types is closely related to the morphology of the region, where intense tectonism formed horst and graben structures. Hence, two hydrogeological systems were defined: a deep geothermal system which is related to extensive and deep circulation of meteoric water in the regional flow system, and a shallow system which is related to local groundwater flow through sedimentary strata. The meteoric water falling at higher elevations percolates to the local groundwater system at a shallow level and flows to the deep geothermal system. During a deep convection cycle from a recharge to discharge area, the cold water attains heat from the asthenospheric intrusions, causing it to ascend. Variations of chemical and isotopic composition of thermal waters result from their mixing with cool groundwater in a shallow aquifer during their ascent to the surface.

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Résumé Les résultats d'une étude portant sur les caractéristiques hydrochimiques et isotopiques de puits phréatiques et profonds situés dans le champ hydrothermal de Pamukkale, sont décrits de telle manière à éclairer le fonctionnement des circulations hydrologiques. Le champ peut étre divisé en deux sous-systèmes d'eaux souterraines, l'un avec des eaux de sources froides (10–12 °C) de type Ca–HCO3, et les eaux thermales (25–58 °C) riches en CO₂ et de type Ca–HCO₃–SO4. L'occurrence de ces types d'eaux est fermement liée à la morphologie de la région, oùne tectonique intense a engendré des structures en horsts et en grabens. Dés lors deux systèmes hydrogéologiques ont été définis : un système profond, qui est lié à la circulation extensive et profonde des eaux météoritiques dans le système régional d'écoulement, et un système phréatique lié aux écoulements locaux des eaux souterraines à travers les strates sédimentaires. Les eaux météoritiques aux altitudes élevées, percolent jusqu'aux systèmes locaux phréatiques, puis coulent jusqu'aux systèmes géothermaux plus profonds. Durant le cycle de convection profond des zones de recharge jusqu'aux zones de décharge, l'eau froide atteint les zones chaudes liées aux intrusions athenosphériques, provoquant la remontée. Les variations de la composition chimique et isotopique des eaux thermales résultent dans leurs mélanges avec des eaux souterraines froides dans les aquifères phréatiques durant leur remontée jusqu'à la surface.

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Resumen Se describen los resultados del estudio de las características isotópicas e hidroquímicas de las aguas someras y profundas para obtener un mejor entendimiento de la circulación hidrológica del campo hidrotermal Pamukkale. El campo puede agruparse en dos sub-sistemas de agua subterránea: manantiales de agua fría del tipo Ca–HCO₃ (10–12°C) y aguas termales ricas en CO₂ del tipo Ca–HCO₃–SO₄(25–58°C). El ambiente de estos tipos de aguas se relaciona estrechamente con la morfología de la región donde el tectonismo intenso ha formado estructuras extensionales tipo graben y horst. Se definieron dos sistemas hidrogeológicos: un sistema geotermal profundo que se relaciona con la circulación profunda y extensa de agua meteórica en el sistema regional de flujo y un sistema somero el cual se relaciona con flujo local de agua subterránea a través de estratos sedimentarios. El agua meteórica que cae en altas elevaciones percola al sistema local de agua subterránea en un nivel somero y fluye hacia el sistema geotermal profundo. Durante un ciclo de convección del área de recarga hacia la zona de descarga, el agua fría se calienta a partir de los intrusivos astenosféricos lo que ocasiona que asciendan. Como resultado de la mezcla de las aguas recalentadas, con agua subterránea fría en un acuífero somero durante el ascenso hacia la superficie, se derivan variaciones en la composición química e isotópica de las aguas termales.

     

The age and thermal history of Cerro Rico de Potosi, Bolivia

 Cerro Rico de Potosi, Bolivia, is the world’s largest silver deposit and has been mined since the sixteenth century for silver, and for tin and zinc during the twentieth century, together with by-product copper and lead. The deposit consists primarily of veins that cut an altered igneous body that we interpret to be a dacitic volcanic dome and its underlying tuff ring and explosion breccia. The deposit is compositionally and thermally zoned, having a core of cassiterite, wolframite, bismuthinite, and arsenopyrite surrounded by a peripheral, lower-temperature mineral assemblage consisting principally of sphalerite, galena, lead sulfosalt, and silver minerals. The low-temperature assemblage also was superimposed on the high-temperature assemblage in response to cooling of the main hydrothermal system. Both the dacite dome and the ore fluids were derived from a larger magmatic/hydrothermal source at depth. The dome was repeatedly fractured by recurrent movement on the fault system that guided its initial emplacement. The dome was extruded at 13.8±0.2 Ma (2σ), based on U-Th-Pb dating of zircon. Mineralization and alteration occurred within about 0.3 my of dome emplacement, as indicated by a ⁴⁰Ar/³⁹Ar date of 13.76±0.10 Ma (1σ) for sericite from the pervasive quartz-sericite-pyrite alteration associated with the main-stage, high-temperature, mineralization. The last thermal event able to reset zircon fission tracks occurred no later than 12.5±1.1 Ma (1σ), as indicated by fission-tract dating. Minor sericite, and magmatic-steam alunite veins, were episodically formed around 11 Ma and between 8.3 and 5.7 Ma; the younger episodes occurring at the time of extensional fracturing at Cerro Rico and widespread volcanism in the adjacent Los Frailes volcanic field. None of these younger events appear to be significant thermal/mineralizing events; the exceptionally flat thermal release pattern of ³⁹Ar from sericite and the results of the fission-tract dating of zircon show that none of the younger events was hot enough, and lasted long enough, to cause significant loss of Ar or annealing of zircon fission tracks. U-Th-Pb dating of zircon cores indicates a Precambrian progenitor for some zircons, and REE analyses of dated samples of hydrothermally altered dacite show the presence of a prominent positive Eu anomaly, which constrains interpretations of the origin and evolution of the magmatic/hydrothermal system. Received: 14 October 1995/Accepted: 29 January 1996