Temporal association of arc–continent collision,progressive magma contamination in arc volcanism and formation of gold-rich massive sulphide deposits on Wetar Island (Banda arc)

Whole-rock ⁸⁷Sr/⁸⁶Sr and δ¹⁸O analyses of volcanic rocks and ³He/⁴He analyses of sulphides and sulphates from mineralized rocks on Wetar, Indonesia indicate a variable contribution of assimilated crustal material or sediment sourced from the subducted Australian craton to the south. These new data support the idea of progressive source contamination with precisely dated events showing that Wetar Island hosts the most extreme examples of crustal assimilation in the region. The increased continental contamination occurs during the Pliocene (Zanclian to Piacenzian) during distinct magmatic events between 5 and 4 Ma, and at 2.4 Ma when ⁸⁷Sr/⁸⁶Sr ratios in unaltered lavas, with whole-rock δ¹⁸O values between 5.7 and 9.6‰, increase from 0.707484 to extreme radiogenic values of 0.711656.The earlier of these magmatic events is important in the generation of the hydrothermal systems responsible for the mineralization recorded on Wetar. Samples from this yield radiogenic ³He/⁴He ratios between 0.5 and 1.4 R/R_A, similar to the data from volcanic rocks on nearby Romang. The later magmatic event coincides with the arrival of the Australian Continental Margin at the subduction zone along the Banda arc. Progressive incorporation of continental-sourced components into the source region below the Wetar Island edifice coincides with the formation of gold-rich volcanogenic massive sulphide deposits hosted within the contaminated volcanic pile.     

The degradation characteristics of microbial biomass in soil

Soil microbial biomass is a primary source of soil organic carbon (SOC) and therefore plays a fundamental role in carbon and nitrogen cycling. However, little is known about the fate and transformations of microbial biomass in soil. Here we employ HR-MAS NMR spectroscopy to monitor ¹³C and ¹⁵N labeled soil microbial biomass and leachate degradation over time. As expected, there is a rapid loss of carbohydrate structures. However, diffusion edited HR-MAS NMR data reveals that macromolecular carbohydrates are more resistant to degradation and are found in the leachate. Aromatic components survive as dissolved species in the leachate while aliphatic components persist in both the biomass and leachate. Dissolved protein and peptidoglycan accumulate in the leachate and recalcitrant amide nitrogen and lipoprotein persists in both the degraded biomass and leachate. Cross-peaks that appear in ¹H-¹⁵N HR-MAS NMR spectra after degradation suggest that specific peptides are either selectively preserved or used for the synthesis of unknown structures. The overall degradation pathways reported here are similar to that of decomposing plant material degraded under similar conditions suggesting that the difference between recalcitrant carbon from different sources is negligible after decomposition.     

Cyclic strength and deformation of crushable carbonate sand

Cyclic triaxial tests have been carried out on a skeletal carbonate sand from the west coast of Eire. Results are presented for undrained cyclic shear tests on samples with 80% of relative density consolidated under both isotropic and anisotropic conditions. Failure was defined as a 5% double amplitude cyclic strain and a 5% peak axial strain for stress-reversal and non-reversal stress conditions, respectively. Using this definition the cyclic strength for isotropically consolidated samples was affected by the confining pressure although the angular platey nature of the sand resulted in higher cyclic strengths than for a comparable silica sand. For anisotropically consolidated samples the cyclic strength increased with increasing initial static shear stress while on the other hand the cyclic strength normalised in the usual way with respect to the initial confining pressure decreased as this pressure increased.     

Analytical derivation of water retention for random monodisperse granular media

The mechanics of water retention in unsaturated granular media is of critical importance to a broad range of disciplines including soil science, geotechnical engineering, hydrology and agriculture. Fundamental to water retention is the relationship between degree of saturation and suction, referred to as the water retention curve (WRC). The majority of WRC models are empirically based and seldom incorporate physically meaningful parameters. This study presents an analytical model for the WRC that considers separate contributions from fully filled pores and partially filled pores containing liquid bridges. A recently established unique k-gamma pore volume distribution function for randomly assembled monodisperse granular materials is adopted to determine the contributions of fully filled pores. Calculation of the contribution of residual pore water retained in partially filled pores is undertaken by representing pores as individual cells shaped as platonic shapes of various sizes and determining the volume of all liquid bridges suspended between particles within the pore cells. Weighting factors for the various cell types are obtained from the pore volume distribution to determine the relative contribution of different pore cell geometries to the total residual pore water. The combined model accurately describes experimental data for monodisperse spherical glass beads for both wetting and drying, even though the underlying assumptions do not reflect exactly the complex, interconnected and highly irregular geometry of the pore space. A single parameter provides the lateral shift between the wetting and drying curves. The results of this study provide a geometric understanding of the mechanisms of water retention in granular media.     

Distribution and spatial variation of hydrothermal faunal assemblages at Lucky Strike (Mid-Atlantic Ridge) revealed by high-resolution video image analysis

Whilst the fauna inhabiting hydrothermal vent structures in the Atlantic Ocean is reasonably well known, less is understood about the spatial distributions of the fauna in relation to abiotic and biotic factors. In this study, a major active hydrothermal edifice (Eiffel Tower, at 1690 m depth) on the Lucky Strike vent field (Mid-Atlantic Ridge (MAR)) was investigated. Video transects were carried out by ROV Victor 6000 and complete image coverage was acquired. Four distinct assemblages, ranging from dense larger-sized Bathymodiolus mussel beds to smaller-sized mussel clumps and alvinocaridid shrimps, and two types of substrata were defined based on high definition photographs and video imagery. To evaluate spatial variation, faunal distribution was mapped in three dimensions. A high degree of patchiness characterizes this 11 m high sulfide structure. The differences observed in assemblage and substratum distribution were related to habitat characteristics (fluid exits, depth and structure orientation). Gradients in community structure were observed, which coincided with an increasing distance from the fluid exits. A biological zonation model for the Eiffel Tower edifice was created in which faunal composition and distribution can be visually explained by the presence/absence of fluid exits.     

Groundwater management in northern Iraq

Groundwater is vital and the sole resource in most of the studied region of northern Iraq. It has a significant role in agriculture, water supply and health, and the elimination of poverty in rural areas. Although Iraq is currently dramatically disturbed by complex political and socio-economic problems, in its northern part, i.e. the Kurdish-inhabited region, fast urbanization and economic expansion are visible everywhere. Monitoring and water management schemes are necessary to prevent aquifer over-exploitation in the region. Artificial recharge with temporary runoff water, construction of subsurface dams and several other aquifer management and regulation measures have been designed, and some implemented, in order to improve the water situation. Recommendations, presented to the local professionals and decision-makers in water management, include creation of Water Master Plans and Water User Associations, synchronization of drilling programmes, rehabilitation of the existing well fields, opening of new well fields, and the incorporation of new spring intakes in some areas with large groundwater reserves, as well as construction of numerous small-scale schemes for initial in situ water treatment where saline groundwater is present.     

Th sorption and export models in the water column: A review

Over the past few decades, the radioisotope pair of ²³⁸U / ²³⁴Th has been widely and increasingly used to describe particle dynamics and particle export fluxes in a variety of aquatic systems. The present paper is one of five review articles dedicated to ²³⁴Th. It is focused on the models associated with ²³⁴Th whereas the companion papers (same issue) are focused on present and future methodologies and techniques (Rutgers van der Loeff et al.), C / ²³⁴Th ratios (Buesseler et al.), ²³⁴Th speciation (Santschi et al.) and present and future applications of ²³⁴Th [Waples, J.T., Benitez-Nelson, C.R., Savoye, N., Rutgers van der Loeff, M., Baskaran, M., Gustafsson, Ö., this issue. An Introduction to the application and future use of ²³⁴Th in aquatic systems. Marine Chemistry, FATE special issue]. In this paper, we review current ²³⁴Th scavenging models and discuss the relative importance of the non-steady state and physical terms associated with the most commonly used model to estimate ²³⁴Th flux. Based on this discussion we recommend that for future work the use of models should be accompanied by a discussion of the effect that model and data uncertainty have on the model results. We also suggest that future field work incorporate repeat occupations of sample sites on time scales of 1–4 weeks in order to evaluate steady state versus non-steady state estimates of ²³⁴Th export, especially during high flux events (> ca. 800 dpm m^− 2 d^− 1). Finally, knowledge of the physical oceanography of the study area is essential, particularly in ocean margins and in areas of established upwelling (e.g., Equatorial Pacific). These suggestions will greatly enhance the application of ²³⁴Th as a tracer of particle dynamics and flux in more complicated regimes.     

A Correction on Coastal Heads for Groundwater Flow Models

We introduce a simple correction to coastal heads for constant‐density groundwater flow models that contain a coastal boundary, based on previous analytical solutions for interface flow. The results demonstrate that accurate discharge to the sea in confined aquifers can be obtained by direct application of Darcy's law (for constant‐density flow) if the coastal heads are corrected to ((α + 1)/α)h_s ? B/2α, in which h_s is the mean sea level above the aquifer base, B is the aquifer thickness, and α is the density factor. For unconfined aquifers, the coastal head should be assigned the value . The accuracy of using these corrections is demonstrated by consistency between constant‐density Darcy's solution and variable‐density flow numerical simulations. The errors introduced by adopting two previous approaches (i.e., no correction and using the equivalent fresh water head at the middle position of the aquifer to represent the hydraulic head at the coastal boundary) are evaluated. Sensitivity analysis shows that errors in discharge to the sea could be larger than 100% for typical coastal aquifer parameter ranges. The location of observation wells relative to the toe is a key factor controlling the estimation error, as it determines the relative aquifer length of constant‐density flow relative to variable‐density flow. The coastal head correction method introduced in this study facilitates the rapid and accurate estimation of the fresh water flux from a given hydraulic head measurement and allows for an improved representation of the coastal boundary condition in regional constant‐density groundwater flow models.