“A Salute to the Bandido”: A Political Ecology of Voice Exploration into Peru’s Freedom of Voice Surrounding Hydrocarbon Development

This paper sets out to evaluate the freedom of voice for Peruvian stakeholders affected by hydrocarbon development. This occurs through the utilization of a political ecology of voice (PEV) theoretical framework based upon the theory of voice by Albert Hirschman and political ecology. PEV can be defined as the study of economic, political, social, and geographical factors over a specific time period and their impact upon the use of voice by stakeholders. Peru’s case study was focused on its main oil-producing Loreto Region and incorporated evaluation of hydrocarbon voice mechanisms (prior consultation and environmental impact assessments) supported by interview testimony of stakeholders and state officials. PEV analysis reveals a political environment which is dangerous, inflexible, and intolerant of Peruvian stakeholders voicing over hydrocarbon development. This is due to the state’s zealous pursuit of its “selva (rainforest) hydrocarbon and development vision” which severely undermines Peruvian stakeholder’s freedom of voice.     

Mineralogy and oxygen isotope systematics of magnetite grains and a magnetite‐dolomite assemblage in hydrated fine‐grained Antarctic micrometeorites

We report the mineralogy and texture of magnetite grains, a magnetite‐dolomite assemblage, and the adjacent mineral phases in five hydrated fine‐grained Antarctic micrometeorites (H‐FgMMs). Additionally, we measured the oxygen isotopic composition of magnetite grains and a magnetite‐dolomite assemblage in these samples. Our mineralogical study shows that the secondary phases identified in H‐FgMMs have similar textures and chemical compositions to those described previously in other primitive solar system materials, such as carbonaceous chondrites. However, the oxygen isotopic compositions of magnetite in H‐FgMMs span a range of ?¹⁷O values from +1.3‰ to +4.2‰, which is intermediate between magnetites measured in carbonaceous and ordinary chondrites (CCs and OCs). The δ¹⁸O values of magnetites in one H‐FgMM have a ~27‰ mass‐dependent spread in a single 100 × 200 μm particle, indicating that there was a localized control of the fluid composition, probably due to a low water‐to‐rock mass ratio. The ?¹⁷O values of magnetite indicate that H‐FgMMs sampled a different aqueous fluid than ordinary and carbonaceous chondrites, implying that the source of H‐FgMMs is probably distinct from the asteroidal source of CCs and OCs. Additionally, we analyzed the oxygen isotopic composition of a magnetite‐dolomite assemblage in one of the H‐FgMMs (sample 03‐36‐46) to investigate the temperature at which these minerals coprecipitated. We have used the oxygen isotope fractionation between the coexisting magnetite and dolomite to infer a precipitation temperature between 160 and 280 °C for this sample. This alteration temperature is ~100–200 °C warmer than that determined from a calcite‐magnetite assemblage from the CR2 chondrite Al Rais, but similar to the estimated temperature of aqueous alteration for unequilibrated OCs, CIs, and CMs. This suggests that the sample 03‐36‐46 could come from a parent body that was large enough to attain temperatures as high as the OCs, CIs, and CMs, which implies an asteroidal origin for this particular H‐FgMM.     

随机波浪下斯托克司漂移速度是否引起水面漂移物离散的研究

漂浮于自由水面的污染物的的迁移、扩散会受到天然随机海浪的影响。之前的研究（以Herterich和Hasselmann（1982）为代表）普遍认为,随机波浪作用下的斯托克司漂移速度会引起水面污染物的离散,这个离散甚至有可能跟风和海流引起的离散同一量级。本研究就随机波浪作用下的斯托克司漂移速度是否会引起水面漂移物的离散进行理论和试验探讨。从理论推导可知,随机波浪下的质量输移速度是个定常分量,因此它不会随时间变化而引起水面漂移物的离散。随后我们在实验室水槽中进行了漂移物在随机波浪（P-M谱）作用下的漂移过程的测量。试验结果也印证了随机波浪作用下的斯托克司漂移速度不会引起水面漂移物离散的结论。     

Hydrothermal evolution of the morphology,molecular composition,and distribution of organic matter in CR (Renazzo-type) chondrites

The morphology, molecular composition, and distribution of organic matter (OM) were investigated in a suite of CR chondrites to better constrain its hydrothermal evolution. Multiple focused ion beam sections were extracted from the matrices of seven CR chondrites. Scanning transmission X-ray microscopy and transmission electron microscopy reveal OM ubiquitously distributed across the CR matrices. OM mainly occurs as either discrete submicron rounded or irregularly shaped vein-like particles. Two spectral populations of organic particles were identified by carbon K-edge X-ray absorption near edge structure (XANES): the most abundant one, similar to insoluble organic matter (IOM) residues, contains aromatic, carbonyl, and carboxylic groups. The second population is more aromatic-rich and lacks a distinctive carbonyl peak. An additional, ubiquitous organic component occurs associated with amorphous silicates and phyllosilicates. Less aromatic but aliphatic- and carboxylic-rich, this diffuse OM is interpreted as the result of the redistribution of organic compounds by aqueous fluids. The most altered CR1 GRO 95577 contains a more mature OM and highly aliphatic- and carboxylic-rich diffuse OM. This evolution, from the CR2s to the CR1, is comparable to that of terrestrial gas shale maturation involving cracking reactions, releasing bitumen-like, aliphatic-, and carboxylic-rich compounds, and aromatic residues. Our observations support the accretion of soluble OM and its later polymerization to IOM, as well as the maturation of IOM and its partial oxidation, releasing mobile compounds. The differences in GRO 95577 are clearly attributable to the hydrothermal episode(s), but the relative role of water and temperature on the evolution of OM remains elusive.     

The representation of sediment source group tracer distributions in Monte Carlo uncertainty routines for fingerprinting: An analysis of accuracy and precision using data for four contrasting catchments

Previous studies comparing sediment fingerprinting un-mixing models report large differences in their accuracy. The representation of tracer concentrations in source groups is perhaps the largest difference between published studies. However, the importance of decisions concerning the representation of tracer distributions has not been explored explicitly. Accordingly, potential sediment sources in four contrasting catchments were intensively sampled. Virtual sample mixtures were formed using between 10 and 100% of the retrieved samples to simulate sediment mobilization and delivery from subsections of each catchment. Source apportionment used models with a transformed multivariate normal distribution, normal distribution, 25th–75th percentile distribution and a distribution replicating the retrieved source samples. The accuracy and precision of model results were quantified and the reasons for differences were investigated. The 25th–75th percentile distribution produced the lowest mean inaccuracy (8.8%) and imprecision (8.5%), with the Sample Based distribution being next best (11.5%; 9.3%). The transformed multivariate (16.9%; 17.3%) and untransformed normal distributions (16.3%; 20.8%) performed poorly. When only a small proportion of the source samples formed the virtual mixtures, accuracy decreased with the 25th–75th percentile and Sample Based distributions so that when <20% of source samples were used, the actual mixture composition infrequently fell outside of the range of uncertainty shown in un-mixing model outputs. Poor performance was due to combined random Monte Carlo numbers generated for all tracers not being viable for the retrieved source samples. Trialling the use of a 25th–75th percentile distribution alongside alternatives may result in significant improvements in both accuracy and precision of fingerprinting estimates, evaluated using virtual mixtures. Caution should be exercised when using a normal type distribution, without exploration of alternatives, as un-mixing model performance may be unacceptably poor.     

滇西南发现石英面状变形构造

采自云南省西南部澜沧江中游临景大桥以东约2km、勐戛河下游北岸的岩石样品的薄片中发现了非常清晰的石英面状变形构造(PDFs)。根据伦敦大学矿物岩石与冰物理实验室费氏台(universalstage)测量分析结果、样品所在地地层时代特征和航卫遥感图像特征的综合分析,认为该PDFs属陨击成因,其陨击事件大约发生在白垩/第三纪边界(距今65Ma),所引起的冲击变质作用已接近最高级阶段的高压二氧化硅相,样品位置接近陨击坑的中心。     

Late Holocene to Recent aragonite-cemented transgressive lag deposits in the Abu Dhabi lagoon and intertidal sabkha

Modern cemented intervals (beachrock, firmgrounds to hardgrounds and concretionary layers) form in the lagoon and intertidal sabkha of Abu Dhabi. Seafloor lithification actively occurs in open, current-swept channels in low-lying areas between ooid shoals, in the intertidal zone of the middle lagoon, some centimetres beneath the inner lagoonal seafloor (i.e. within the sediment column) and at the sediment surface the intertidal sabkha. The concept of ‘concretionary sub-hardgrounds’, i.e. laminar cementation of sediments formed within the sediment column beneath the shallow redox boundary, is introduced and discussed. Based on calibrated radiocarbon ages, seafloor lithification commenced during the Middle to Late Holocene (ca 9000 cal yr bp ), and proceeds to the present-day. Lithification occurs in the context of the actualistic relative sea-level rise shifting the coastline landward across the extremely low-angle carbonate ramp. The cemented intervals are interpreted as parasequence boundaries in the sense of ‘marine flooding surfaces’, but in most cases the sedimentary cover overlying the transgressive surface has not yet been deposited. Aragonite, (micritic) calcite and, less commonly, gypsum cements lithify the firmground/hardground intervals. Cements are described and placed into context with their depositional and marine diagenetic environments and characterized by means of scanning electron microscope petrography, cathodoluminescence microscopy and Raman spectroscopy. The morphology of aragonitic cements changes from needle-shaped forms in lithified decapod burrows of the outer lagoon ooidal shoals to complex columnar, lath and platy crystals in the inner lagoon. Precipitation experiments provide first tentative evidence for the parameters that induce changes in aragonite cement morphology. Data shown here shed light on ancient, formerly aragonite-cemented seafloors, now altered to diagenetic calcites, but also document the complexity of highly dynamic near coastal depositional environments.     

酸洗法测定海洋沉积物有机碳和无机碳含量的致命缺陷

Organic and inorganic carbon contents of marine sediments are important to reconstruct marine productivity,global carbon cycle, and climate change. A proper method to separate and determine organic and inorganic carbons is thus of great necessity. Although the best method is still disputable, the acid leaching method is widely used in many laboratories because of its ease-of-use and high accuracy. The results of the elemental analysis of sediment trap samples reveal that organic and inorganic carbon contents cannot be obtained using the acid leaching method, causing an infinitely amplified error when the carbon content of the decarbonated sample is 12%±1% according to a mathematical derivation. Acid fumigation and gasometric methods are used for comparison, which indicates that other methods can avoid this problem in organic carbon analysis. For the first time, this study uncovers the pitfalls of the acid leaching method, which limits the implication in practical laboratory measurement, and recommends alternative solutions of organic/inorganic carbon determination in marine sediments.