Subduction Influence on Oxygen Fugacity and Trace and Volatile Elements in Basalts Across the Cascade Volcanic Arc

Fluids or melts derived from a subducting plate are often citedas a mechanism for the oxidation of arc magmas. What remainsunclear is the link between the fluid, oxygen fugacity, andother major and trace components, as well as the spatial distributionof the impact of those fluids. To test the potential effectsof addition of a subduction-derived fluid or melt to the sub-arcmantle, olivine-hosted melt inclusions from primitive basalticlavas sampled from across the central Oregon Cascades (43°–45°N)have been analyzed for major, trace and volatile elements andfO₂. Oxygen fugacity was determined in melt inclusions fromsulfur speciation determined by electron microprobe and fromolivine–chromite oxygen geobarometry. The overall rangein fO₂ based on sulfur speciation measurements is from <–0·25log units to + 1·9 log units (FMQ, where FMQ is fayalite–magnetite–quartzbuffer). Oxygen fugacity is positively correlated with fluid-mobiletrace element and light rare earth element contents in basaltsgenerated by relatively low-degree partial melting. Establishinga further correlation between fO₂ and fluid-mobile trace elementabundances with position along the arc requires the basaltsto be subdivided into shoshonitic, calc-alkaline, low-K tholeiiteand enriched intraplate basalt groups. Melt inclusions fromenriched intraplate and shoshonitic lavas show increasing fO₂and trace element abundances closer to the trench, whereas calc-alkalinemelt inclusions exhibit no significant across-arc variations.Low-K tholeiitic melt inclusions record an increase in incompatibletrace elements closer to the trench; however, there is no correlatedincrease in fO₂. The correlation observed in enriched intraplateand shoshonitic melt inclusions is interpreted to reflect aprogressively greater proportion of a fluid-rich, oxidized subductioncomponent in magmas generated nearer the subduction zone. Significantly,calc-alkaline melt inclusions with high ratios of large ionlithophile elements to high field strength elements, characteristicof ‘typical’ arc magmas, have oxidation states indistinguishablefrom low-K tholeiite and enriched intraplate basalt melt inclusions.The lack of across-arc geochemical variation in calc-alkalinemelt inclusions may suggest that these basalts are not necessarilythe most appropriate magmas for examining recent addition ofa subduction component to the sub-arc mantle. Flux and batchmelt model results produce a wide range of predicted amountsof melting and subduction component added to the mantle source;however, general trends characterized by increased melting andproportion of the subduction component from enriched intraplate,to low-K tholeiite, to calc-alkaline are robust. The model resultsdo not require enriched intraplate, low-K tholeiite and calc-alkalinemagmas to be produced from the same more fertile mantle source.However, enriched intraplate magmas, in contrast to calc-alkalineand low-K tholeiite magmas, cannot be generated from a depletedmantle source. Flux or batch melting of either the more fertileor depleted mantle sources used to generate the low-K tholeiite,calc-alkaline, and enriched intraplate magmas cannot reproduceshoshonitic compositions, which require a significantly depletedmantle source strongly metasomatized by a subduction component.The potential mantle source for shoshonitic basalts has a predictedfO₂ (after oxidation) from + 0·3 to + 2·4 logunits (FMQ) whereas the mantle source for low-K tholeiite, calc-alkaline,and enriched intraplate magmas may range from –1·1to + 0·7 log units (FMQ). KEY WORDS: basalt; Cascades; melt inclusions; oxidation state; volatiles     

Exact physical Maxwell-Einstein Tolman-VII solution and its use in stellar models

We derive an exact Maxwell-Einstein metric for a spherically symmetric static perfect fluid with mass and charge (Q), that electrifies the Tolman-VII metric and meets applicable physical boundary conditions. We show that there is more than one way to electrify any Q=0 metric, depending on whether metric component g _tt , g _rr , or neither, is independent of Q. We illustrate an approach not yet in the literature in which g _rr is independent of Q. When applied to a baryonic stellar model, this metric is versatile, capable of producing a range of values for radius, mass, Q, and far-field mass due to the presence of charge.     

Ejecta from impacts at 0.2-2.3 m/s in low gravity

Collisions between planetary ring particles and in some protoplanetary disk environments occur at speeds below 10 m/s. The particles involved in these low-velocity collisions have negligible gravity and may be made of or coated with smaller dust grains and aggregates. We undertook microgravity impact experiments to better understand the dissipation of energy and production of ejecta in these collisions. Here we report the results of impact experiments of solid projectiles into beds of granular material at impact velocities from 0.2 to 2.3 m/s performed under near-weightless conditions on the NASA KC-135 Weightless Wonder V. Impactors of various densities and radii of 1 and 2 cm were launched into targets of quartz sand, JSC-1 lunar regolith simulant, and JSC-Mars-1 martian regolith simulant. Most impacts were at normal or near-normal incidence angles, though some impacts were at oblique angles. Oblique impacts led to much higher ejection velocities and ejecta masses than normal impacts. For normal incidence impacts, characteristic ejecta velocities increase with impactor kinetic energy, KE, as approximately KE^0.5. Ejecta masses could not be measured accurately due to the nature of the experiment, but qualitatively also increased with impactor kinetic energy. Some experiments were near the threshold velocity of 0.2 m/s identified in previous microgravity impact experiments as the minimum velocity needed to produce ejecta [Colwell, J.E., 2003. Icarus 164, 188-196], and the experimental scatter is large at these low speeds in the airplane experiment. A more precise exploration of the transition from low-ejecta-mass impacts to high-ejecta-mass impacts requires a longer and smoother period of reduced gravity. Coefficient of restitution measurements are not possible due to the varying acceleration of the airplane throughout the experiment.     

Use of incipient motion data for backward erosion piping models

Backward erosion piping involves the gradual removal of granular material under the action of water flow from the foundation of a dam or levee, whereby shallow pipes are formed that grow in the direction opposite to the flow. This pipe-forming process can ultimately lead to failure of a water-retaining structure and is considered one of the most important failure mechanisms for dikes and levees in the Netherlands and the United States. Modeling of this mechanism requires the assessment of hydraulic conditions in the pipe, which are controlled by the particle equilibrium at the pipe wall. Since the pipe's dimensions are controlled by the inflow to the pipe from the porous medium, the flow through the pipe is thought to be laminar for fine- to medium-grained sands. The literature provides data for incipient motion in laminar flow, which is reviewed here and complemented with data from backward erosion experiments. The experiments illustrate the applicability of the laminar incipient motion data to determine the erosion pipe dimensions and corresponding pipe hydraulics for fine- to medium-grained sands, for the purpose of backward erosion piping modeling.     

A Century of Spinosaurs - A Review and Revision of the Spinosauridae with Comments on Their Ecology

The spinosaurids represent an enigmatic and highly unusual form of large tetanuran theropods that were first identified in 1915. A recent flurry of discoveries and taxonomic revisions of this important and interesting clade has added greatly to our knowledge. Spinosaur body fossils are however generally rare and most species are known from only limited skeletal remains. Their unusual anatomical adaptations to the skull, limbs and axial column all differ from other large theropods and point to an unusual ecological niche and a lifestyle intimately linked to water.     

Automated landslide mapping using spectral analysis and high-resolution topographic data: Puget Sound lowlands, Washington, and Portland Hills, Oregon

Landslide inventory maps are necessary for assessing landslide hazards and addressing the role slope stability plays in landscape evolution over geologic timescales. However, landslide inventory maps produced with traditional methods — aerial photograph interpretation, topographic map analysis, and field inspection — are often subjective and incomplete. The increasing availability of high-resolution topographic data acquired via airborne Light Detection and Ranging (LiDAR) over broad swaths of terrain invites new, automated landslide mapping procedures. We present two methods of spectral analysis that utilize LiDAR-derived digital elevation models of the Puget Sound lowlands, Washington, and the Tualatin Mountains, Oregon, to quantify and automatically map the topographic signatures of deep-seated landslides. Power spectra produced using the two-dimensional discrete Fourier transform and the two-dimensional continuous wavelet transform identify the characteristic spatial frequencies of deep-seated landslide morphologic features such as hummocky topography, scarps, and displaced blocks of material. Spatial patterns in the amount of spectral power concentrated in these characteristic frequency bands highlight past slope instabilities and allow the delineation of landslide terrain. When calibrated by comparison with detailed, independently compiled landslide inventory maps, our algorithms correctly classify an average of 82% of the terrain in our five study areas. Spectral analysis also allows the creation of dominant wavelength maps, which prove useful in analyzing meter-scale topographic expressions of landslide mechanics, past landslide activity, and landslide-modifying geomorphic processes. These results suggest that our automated landslide mapping methods can create accurate landslide maps and serve as effective, objective, and efficient tools for digital terrain analysis.     

Aragonite and calcite preservation in sediments from Lake Iznik related to bottom lake oxygenation and water column depth

This study examines the forcing mechanisms driving long‐term carbonate accumulation and preservation in lacustrine sediments in Lake Iznik (north‐western Turkey) since the last glacial. Currently, carbonates precipitate during summer from the alkaline water column, and the sediments preserve aragonite and calcite. Based on X‐ray diffraction data, carbonate accumulation has changed significantly and striking reversals in the abundance of the two carbonate polymorphs have occurred on a decadal time scale, during the last 31 ka cal bp . Different lines of evidence, such as grain size, organic matter and redox sensitive elements, indicate that reversals in carbonate polymorph abundance arise due to physical changes in the lacustrine setting, for example, water column depth and lake mixing. The aragonite concentrations are remarkably sensitive to climate, and exhibit millennial‐scale oscillations. Extending observations from modern lakes, the Iznik record shows that the aerobic decomposition of organic matter and sulphate reduction are also substantial factors in carbonate preservation over long time periods. Lower lake levels favour aragonite precipitation from supersaturated waters. Prolonged periods of stratification and, consequently, enhanced sulphate reduction favour aragonite preservation. In contrast, prolonged or repeated exposure of the sediment–water interface to oxygen results in in situ aerobic organic matter decomposition, eventually leading to carbonate dissolution. Notably, the Iznik sediment profile raises the hypothesis that different states of lacustrine mixing lead to selective preservation of different carbonate polymorphs. Thus, a change in the entire lake water chemistry is not strictly necessary to favour the preservation of one polymorph over another. Therefore, this investigation is a novel contribution to the carbon cycle in lacustrine systems.     

A rain on snow climatology and temporal analysis for the eastern United States

ABSTRACT

Rain-on-snow (ROS) has the potential to produce devastating floods by enhancing runoff from snowmelt. Although a common phenomenon across the eastern United States, little research has focused on ROS in this region. This study used a gridded observational snow dataset from 1960–2009 to establish a comprehensive seasonal climatology of ROS for this region. Additionally, different rain and snow thresholds were compared while considering temporal trends in ROS occurrence at four grid cells representing individual locations. Results show most ROS events occur in MAM (March-April-May). ROS events identified with rainfall >1 cm are more frequent near the east coast and events identified with >1 cm snow loss are more common in higher latitudes and/or elevations. Decreasing trends in DJF (December-January-February) ROS events were identified near the coastal areas, with increasing trends in the northern portion of the domain. Significant decreasing trends in MAM ROS are likewise present on a regional scale. Factors playing a role in snowpack depth and rainfall, such as movement of storm tracks in this region, should be considered with future work to discern mechanisms causing the changes in ROS frequency.     

Analysis of cyclical sedimentation in the lower Permian Mchuchuma coalfield (South-West-Tanzania)

A statistical approach by a modified Markov process model was used to prove that the lower Permian coal measures of the Tanzanian Mchuchuma basin developed distinct cyclicities during deposition. From results the transition path of lithologic states typical for this coal sequence is as follows: (A) coarse sandstone, (B) medium sandstone, (C) fine-very fine sandstone, (D) shale, (E) mudstone, (F) coal or (E+F) and again (A) coarse sandstone. The majority of cycles is are asymmetric (ABCDEF-ABC.)but symmetrical cycles are present as well (ABCDEFED). The statistical results concur with observed sedimentological evidence of depositional environment. Fining upward cycles correspond to the development of basal channel bars, changing into levées, then into back swamps which are topped by coal swamps. Frequent interbedding of coal and mudstone in the upper part of the coal measures calls for periodic flooding and flushing of fine clastics into coal-forming swamps causing interruption of peat formation. Cyclical deposition is explained by wandering channels in response to varying discharge and rate of deposition, their lateral frequent shifting caused the formation of asymmetrical cycles in this fluviodeltaic depositional model.

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Zusammenfassung Das kohleführende untere Perm des Mchuchuma Beckens (SW-Tanzania) wurde statistisch mit Hilfe der Markov Analyse auf Zyklizität innerhalb der Abfolge untersucht. Die statistischen Daten zeigen, daß die bevorzugte und für dieses Kohlebecken typische Sequenz folgende lithologische Abfolge umfaßt: (A) grober Sandstein, (B) mittlerer Sandstein, (C) feiner Sandstein, (D) Siltstein, (E) Tonstein, (F) bzw. (E+F) Kohle und erneut (A) grober Sandstein. Es existieren meist asymmetrische Zyklen (ABCDEF-ABCD...) aber symmetrische Zyklen (ABCDEFED) treten ebenfalls auf. Die Markov Analyse ergänzt sehr gut die Beobachtungen bezüglich des Ablagerungsmilieus in den Aufschlüssen. »Fining up« Zyklen beginnen mit basalen Gerinnesanden, überlagert von levée Ablagerungen, welche ihrerseits übergehen in »back swamps« und Kohlesümpfe. Der obere Teil der Kohleabfolge ist durch häufige Wechsellagerungen von Kohle mit Tonstein charakterisiert, die auf periodische Überflutungen und Verfrachtungen von Feinklastika in die Kohlesümpfe zurückzuführen sind. Wandernde Flußgerinne, ausgelöst durch rasch wechselnde Sedimentfracht und Ablagerungsrate, führten zu zyklischen Ablagerungen. Häufig auftretende laterale Gerinneverlagerungen erklären die asymmetrischen Zyklen in diesem fluvio-deltaischen Ablagerungsmodell.

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Résumé Des analyses statistiques ont été effectuées par la méthode de Markov sur le Permien inférieur charbonnier du bassin de Mchuchuma (Tanzanie du sud-ouest) dans le but de montrer l'existence de cycles sédimentaires. Les résultats font apparaître une séquence, typique de ce bassin, qui s'ordonne ainsi de bas en haut: (A) grès grossier, (B) grès moyen, (C) grès fin à très fin, (F) siltite, (E) pélite, (F) charbon ou (E+F) et de nouveau (A) grès grossier. Les cycles sont pour la plupart assymétriques (ABCDEF-ABC...) mais il en existe aussi de symétriques (ABCDEFED).Les résultats obtenus par la méthode de Markov concordent avec les observations sédimentologiques relatives au milieu de dépôt. Les cycles granoclassés débutent par des sables fluviatiles surmontés par des dépôts de levées suivis à leur tour de »back swamps«, et se terminent par des dépôts de marais tourbeux. La partie supérieure de la série est caractérisée par une stratification alternée de charbon et de pélite due à des inondations périodiques amenant dans les marais des produits clastiques fins qui interrompaient la formation de la tourbe. La sédimentation cyclique s'explique par la migration de chenaux, provoquée par les variations de l'apport sédimentaire et de la vitesse de dépôt. Les fréquents déplacements latéraux des chenaux expliquent l'asymétrie des cycles, dans ce modèle fluvio-deltaïque.

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- Mchuchuma (-). , : (A) ; (B) ; (C) - ; (D) ; (E) ; (F) , (E + F) (A) . (ABCDEF-ABCD), (ABCDEFED). . « » , , , . (). , , , . / .

     

Late Pleistocene to Holocene sedimentation and hydrocarbon seeps on the continental shelf of a steep,tectonically active margin,southern California,USA

Small, steep, uplifting coastal watersheds are prolific sediment producers that contribute significantly to the global marine sediment budget. This study illustrates how sedimentation evolves in one such system where the continental shelf is largely sediment-starved, with most terrestrial sediment bypassing the shelf in favor of deposition in deeper basins. The Santa Barbara–Ventura coast of southern California, USA, is considered a classic area for the study of active tectonics and of Tertiary and Quaternary climatic evolution, interpretations of which depend upon an understanding of sedimentation patterns. High-resolution seismic-reflection data over >570 km² of this shelf show that sediment production is concentrated in a few drainage basins, with the Ventura and Santa Clara River deltas containing most of the upper Pleistocene to Holocene sediment on the shelf. Away from those deltas, the major factor controlling shelf sedimentation is the interaction of wave energy with coastline geometry. Depocenters containing sediment 5–20 m thick exist opposite broad coastal embayments, whereas relict material (bedrock below a regional unconformity) is exposed at the sea floor in areas of the shelf opposite coastal headlands. Locally, natural hydrocarbon seeps interact with sediment deposition either to produce elevated tar-and-sediment mounds or as gas plumes that hinder sediment settling. As much as 80% of fluvial sediment delivered by the Ventura and Santa Clara Rivers is transported off the shelf (some into the Santa Barbara Basin and some into the Santa Monica Basin via Hueneme Canyon), leaving a shelf with relatively little recent sediment accumulation. Understanding factors that control large-scale sediment dispersal along a rapidly uplifting coast that produces substantial quantities of sediment has implications for interpreting the ancient stratigraphic record of active and transform continental margins, and for inferring the distribution of hydrocarbon resources in relict shelf deposits.