Young asteroid mixing revealed in ordinary chondrites: The case of NWA 5764, a polymict LL breccia with L clasts

Polymict chondritic breccias—rocks composed of fragments originating from different chondritic parent bodies—are of particular interest because they give insights into the mixing of asteroids in the main asteroid belt (occurrence, encounter velocity, transfer time). We describe Northwest Africa (NWA) 5764, a brecciated LL6 chondrite that contains a >16 cm³ L4 clast. The L clast was incorporated in the breccia through a nondestructive, low‐velocity impact. Identical cosmic‐ray exposure ages of the L clast and the LL host (36.6 ± 5.8 Myr), suggest a short transfer time of the L meteoroid to the LL parent body of 0.1 ± 8.1 Myr, if that meteoroid was no larger than a few meters. NWA 5764 (together with St. Mesmin, Dimmitt, and Glanerbrug) shows that effective mixing is possible between ordinary chondrite parent bodies. In NWA 5764 this mixing occurred after the peak of thermal metamorphism on the LL parent body, i.e., at least several tens of Myr after the formation of the solar system. The U,Th‐He ages of the L clast and LL host, identical at about 2.9 Ga, might date the final assembly of the breccia, indicating relatively young mixing in the main asteroid belt as previously evidenced in St. Mesmin.     

An investigation into the effects of silver nanoparticles on antibiotic resistance of naturally occurring bacteria in an estuarine sediment

The aim of this study was to test whether silver nanoparticles (Ag-NPs) released into estuarine environments result in increased antibiotic resistance amongst the natural bacterial population in estuarine sediments. A 50-day microcosm exposure experiment was carried out to investigate the effects of Ag-NPs (50 nm average diameter) on the antibiotic resistance of bacteria in sediments from an estuary in southwest England. Experimental microcosms were constructed using 3.5 kg sediment cores with 20 l of overlaying seawater treated with (final) Ag-NPs concentrations of 0, 50 or 2000 μg l⁻¹ (n = 3). Sediment samples were screened at the end of the exposure period for the presence of bacteria resistant to eight different antibiotics. Multivariate statistical analyses showed that there was no increase in antibiotic resistance amongst the bacterial population in the sediment due to the dosing of the microcosms with Ag-NPs. This study indicates that, under the tested conditions, Ag-NPs released into the coastal marine environment do not increase antibiotic resistance among naturally occurring bacteria in estuarine sediments. These results contrast previous findings where antimicrobial effects of Ag-NPs on key bacterial species in laboratory experiments have been demonstrated, and reasons for this are discussed. The negligible effects demonstrated on bacterial populations under the selected estuarine conditions, provide important information on no observed effect concentrations (NOECs) for environmental regulation.     

Geochemical diversity in submarine HIMU basalts from Austral Islands, French Polynesia

We present the first report of geochemical data for submarine basalts collected by a manned submersible from Rurutu, Tubuai, and Raivavae in the Austral Islands in the South Pacific, where subaerial basalts exhibit HIMU isotopic signatures with highly radiogenic Pb isotopic compositions. With the exception of one sample from Tubuai, the ⁴⁰Ar/³⁹Ar ages of the submarine basalts show no significant age gaps between the submarine and subaerial basalts, and the major element compositions are indistinguishable at each island. However, the variations in Pb, Sr, Nd, and Hf isotopic compositions in the submarine basalts are much larger than those previously reported in subaerial basalts. The submarine basalts with less-radiogenic Pb and radiogenic Nd and Hf isotopic compositions show systematically lower concentrations in highly incompatible elements than the typical HIMU basalts. These geochemical variations are best explained by a two-component mixing process in which the depleted asthenospheric mantle was entrained by the mantle plume from the HIMU reservoir during its upwelling, and the melts from the HIMU reservoir and depleted asthenospheric mantle were then mixed in various proportions. The present and compiled data demonstrate that the HIMU reservoir has a uniquely low ¹⁷⁶Hf/¹⁷⁷Hf decoupled from ¹⁴³Nd/¹⁴⁴Nd, suggesting that it was derived from an ancient subducted slab. Moreover, the Nd/Hf ratios of the HIMU basalts and curvilinear Nd–Hf isotopic mixing trend require higher Nd/Hf ratios for the melt from the HIMU reservoir than that from the depleted mantle component. Such elevated Nd/Hf ratios could reflect source enrichment by a subducted slab during reservoir formation.     

Formaldehyde in Various Forms of Atmospheric Precipitation and Deposition from Highly Urbanized Regions

Formaldehyde levels were determined in various forms of atmospheric precipitation (rain, snow, road and roof runoff, throughfall) and deposition (rime, hoarfrost, dew) collected over twelve months at various locations in two large urban agglomerations and along two highways. HCHO was found in 303 of 500 samples analyzed, with concentrations ranging from 0.05 to 10.7 mg/dm³. The results confirmed the significant effect of vehicular traffic on formaldehyde levels in various forms of wet deposition. Correlations of formaldehyde levels with other parameters commonly monitored in precipitation and/or deposition were also examined. No correlation was found between HCHO levels and rain volume. On the other hand, positive correlations were found for hydrogen peroxide, non-sea-salt sulphate, nitrate, ammonia, and total organic carbon (TOC). In addition, the effect of selected meteorological parameters (temperature, wind speed, wind direction, rainfall) on the concentration of formaldehyde in various forms of precipitation and runoff (road runoff, roof runoff, throughfall) was studied. The only correlation found was that between HCHO concentration and daily rainfall.     

Air–Sea/Land Interaction in the Coastal Zone

Atmospheric turbulence measurements made at the U.S. Army Corps of Engineers Field Research Facility (FRF) located on the Atlantic coast near the town of Duck, North Carolina during the CASPER-East Program (October–November 2015) are used to study air–sea/land coupling in the FRF coastal zone. Turbulence and mean meteorological data were collected at multiple levels (up to four) on three towers deployed at different landward distances from the shoreline, with a fourth tower located at the end of a 560-m-long FRF pier. The data enable comparison of turbulent fluxes and other statistics, as well as investigations of surface-layer scaling for different footprints, including relatively smooth sea-surface conditions and aerodynamically rough dry inland areas. Both stable and unstable stratifications were observed. The drag coefficient and diurnal variation of the sensible heat flux are found to be indicators for disparate surface footprints. The drag coefficient over the land footprint is significantly greater, by as much as an order of magnitude, compared with that over the smooth sea-surface footprint. For onshore flow, the internal boundary layer in the coastal zone was either stable or (mostly) unstable, and varied dramatically at the land-surface discontinuity. The offshore flow of generally warm air over the cooler sea surface produced a stable internal boundary layer over the ocean surface downstream from the coast. While the coastal inhomogeneities violate the assumptions underlying Monin–Obukhov similarity theory (MOST), any deviations from MOST are less profound for the scaled standard deviations and the dissipation rate over both water and land, as well as for stable and unstable conditions. Observations, however, show a poor correspondence with MOST for the flux-profile relationships. Suitably-averaged, non-dimensional profiles of wind speed and temperature vary significantly among the different flux towers and observation levels, with high data scatter. Overall, the statistical dependence of the vertical gradients of scaled wind speed and temperature on the Monin–Obukhov stability parameter in the coastal area is weak, if not non-existent.     

Mineralogical and geochemical constraints on environmental impacts from waste rock at Taojiang Mn-ore deposit,central Hunan,China

The mineralogy and geochemistry of the waste rocks distributed at Taojiang Mn-ore deposit, central Hunan province, China, were studied using X-ray powder diffraction (XRD), electron microprobe analysis (EMPA) fitted with energy dispersive spectrometer (EDS) and inductively coupled plasma mass spectrum (atomic emission spectra) ICP-MS (AES), with the aim of predicting the environmental impacts of weathering of the waste rocks. The mineralogical results from microscope observation and XRD and EMPA studies show that the waste rock is composed of black shale and minor Mn carbonates. The oxidation of sulfide minerals such as galena, pyrite and chalcopyrite is accompanied by decomposition of Mn carbonates and K-feldspar during exposure to atmospheric O₂. The geochemical characteristics of major, rare earth elements (REE) and trace elements of the waste rocks also show that the waste rock can be divided into black shale and Mn carbonate, and both of them are currently under chemical weathering. The major alkalies and alkaline elements (Ca, Mg, Na, K, Rb, Sr and Cs) and major elements (Fe, S and P) and heavy metals (Sc, V, Cr, Th, U, Sn, Co, Ni, Cu, Zn, Pb, Mo, Cd, Sb, an Tl) are being released during weathering. The mobility of alkalis and alkaline elements Ca, Mg, Na, K, Rb, Sr and Cs is controlled by decomposition of Mn carbonates. The dispersion of Cr, Sc and Th (U) might be related to weathering of K-feldspar, and the release of the heavy metals Co, Ni, Cu, Zn, Pb, Mo, Cd Sb and Tl is dominated by the breaking of sulfide minerals. The REE of the waste rocks and surrounding soils and the spidery distribution patterns of heavy metals in the waste rocks, the surrounding soils and the surface waters show that weathering of the waste rocks and bedrock might be the sources of heavy metal contamination for the surrounding soils and surface water system for the mining area. This is predicted by the mass-balance calculation by using Zr as an immobile element. Therefore, it is urgently necessary take measures to treat the waste rocks distributed throughout the area for the local environmental protection.     

Sodium and strontium in mollusc shells: preservation,palaeosalinity and palaeotemperature of the Middle Pleistocene of eastern England

This paper revisits the utility of sodium (Na) content in aragonite and calcite mollusc shells as an indicator of palaeosalinity. The data come mainly from a related suite of Middle Pleistocene marine and freshwater fossils that have been subject to broadly similar diagenetic histories. Environmental salinity is re-affirmed as the primary factor in determining the sodium content of modern and ancient mollusc shells: values <2000 ppm Na are generally indicative of non-marine environments while values >2000 Na ppm are typically from marine shells. There is a positive relationship between Na (salinity) and Sr which is a helpful discriminator of palaeosalinity in the fossil data set. The Na and Sr data give confidence that the fossil shells have not suffered pervasive diagenetic alteration and that the marine fossils lived in fully marine conditions. Oxygen isotope values in the best-preserved, fully marine fossil shells, suggest Middle Pleistocene ‘eastern England’ seawater temperatures were broadly similar to those of the modern North Sea.     

Physicochemical structural characterization of ambers from deposits in Poland

The physical and chemical properties of 8 samples of amber from different localities in Poland (Baltic Coast, Bełchatów Tertiary brown coal, and Jaroszów clay mine) were investigated by N₂ sorption at 77 K, positron annihilation spectroscopy for chemical analysis (PASCA) and by organic geochemical methods (FT-IR,¹H and¹³C NMR, GC, and GC-MS). The porosity of the ambers as determined by PASCA consists of narrow micropores with diameters ranging from 0.8 to 0.9 nm and a volume 0.025 cm³ g⁻¹. In the external eroded part of the amber samples (rind) the concentration of pores where positronium atoms can form is lower and consists of approximately12 the concentration as in their interior. Values of pore parameters determined from sorption of N₂ are comparable with those found by the PASCA method. The average diameter of pores ranges from 2 to 12 nm, while their volume varies from 0.018 to 0.048 cm³ g⁻¹.. The chemical character of the ambers is similar based on FT-IR spectroscopy. However, noticeable differences in concentrations of ester and hydroxyl groups are observed in both exterior and interior regions, where the abundances of the ester groups are lower in the exterior rind. The proportion of organic material extractable with chloroform-methanol (1:1, v/v) ranges from 15 to 50% and correlates inversely to the average reflectances (R_r) of polished amber surfaces which range from 1.7 to 0.1 %. These variations are attributed to differing concentrations of oxygenated groups in the respective amber samples. The FT-IR spectra of the non-polar fractions (NP) from the extracts resemble the spectra of the source ambers. However, the intensities of the absorbance for the hdroxyl group are much lower, while absorbances for exomethylene groups are not present. The¹H and¹³C NMR data of NP fractions showed a complex diversity of components in mixtures with different relative concentrations but predominantly aliphatic in character for the respective samples.GC and GC-MS analyses of these fractions revealed that they are comprised of a mixture of compounds typical for Baltic amber but with variable relative concentrations. Two groups of compounds are found to be common to all NP fractions. The first is a minor concentration of homologousn-alkanes with a characteristic Gaussian distribution in the range from C₂₂ to C₃₂ and maximizing at C₂₆–C₂₇. In addition C₂₂ is characteristically slightly higher in concentration compared to C₂₃. The second group of compounds is comprised of succinates with methyl, fenchyl, bomyl and isobornyl alcohols. The composition of these diesters revealed the same equilibrium ratio between compounds with fenchyl, bornyl and isobornyl alcohols in all NP fractions. We suggest an early enzymatically controlled (bacterial) process in the formation of succinates during resin diagenesis from the biotic precursors, yielding the same characteristic ratio of the respective succinates in these ambers. These results show that all the ambers analyzed here fall into a common class of fossil resin, succinite (class Ia) independent of the sample location in Poland.     

Dynamic stratigraphy of composite peripheral unconformity in a foredeep basin

This study employs facies analysis and basic principles of sequence stratigraphy to correlate isolated outcrop sections and reveal the depositional history of the Chmielnik Formation – a prominent mid‐Serravalian clastic wedge formed on the basinward forebulge flank of the Polish Carpathian Foredeep. The coarse‐grained clastic wedge, up to 30 m thick and spanning ca 1·1 Ma within biozone NN6, consists of fluvio‐deltaic, foreshore and shoreface deposits with a range of large littoral sand bars, all enveloped in muddy offshore‐transition deposits. Its dynamic stratigraphy indicates rapid shoreline shifts and environmental changes due to the interplay of forebulge tectonism, sediment supply and third‐order eustatic cycles. A similar interplay of tectonism and eustasy is recognizable in the whole middle Miocene sedimentary succession deposited on the forebulge flank, demonstrating an extreme case of an accommodation‐controlled shelf and indicating tectonic cycles of the forebulge uplift and subsidence spanning ca 800 to 900 ka. The episodes of forebulge uplift correlate with the main pulses of orogen thrusting. The resulting composite peripheral unconformity differs markedly from the idealized model of a ‘steady‐state’ stepwise onlap driven by forebulge continuous retreat. It is concluded that the foredeep peripheral unconformities, instead of being simplified in accordance with this idealized model, should rather be studied in detail because they bear a valuable high‐resolution record of regional events and give unique insights into the local role of tectonics, eustasy and sediment supply.     

Thermal treatment of waste from the meat industry in high scale rotary kiln

Recently there has been an increase in consumption of meat, especially poultry. This results in an increase in the quantity of waste, including waste feathers. Waste from the meat industry are hazardous, which must be disposed of in accordance with the law. Wastes from the meat industry normally consist of valuable elements such as phosphorus, calcium, potassium, magnesium (macronutrients), and iron, copper, zinc, manganese (micronutrients), which after suitable processing can be used for the purposes of fertilization. The paper presents the results of thermal treatment of feathers with meat and bone meal and feathers with poultry litter in a high scale rotary kiln. Mixtures of wastes were incinerated in temperature range from 600 to 900 °C for about 20–25 min. The resulting ashes were characterized by a high content of phosphorus (4–17%), calcium (17–30%) and potassium (0.6–3.6%). The study revealed that the selection of process parameters allows for obtaining ash with controlled and desired composition of macro and micronutrients, moreover, it is safe in terms of sanitary.