Cerium and Ytrium in apatite as records of magmatic processes: Insight into fractional crystallization,magma mingling and fluid saturation

Apatite is a versatile mineral crystallizing at different stages of silicic magma evolution. Its composition may record that of magma, but could also be affected by interaction with fluids. The focus of this study is the well-recognized magma mingling process that was previously detected using plagioclase composition and in this study complementary record is sought in apatite. The apatite was analysed in two dioritic enclaves (primitive and hybrid) and host quartz monzonite, which is an igneous rock emplaced at ca. 340 Ma in mylonitized Góry Sowie gneisses (NE Bohemian Massif). The apatite was analysed in-situ by microprobe that allowed for chemical characterization of different apatite populations in quartz monzonite and analyses of thin acicular apatite in the enclaves. Apatite population in the quartz monzonite was chemically distinct from that in both enclave types and characterized by higher Y and lower Ce contents, such values are usually typical for peraluminous magmas. As such, the apatite transfer from felsic to mafic magma should be well recorded in apatite composition, which was not the case. Monzonite apatite composition was not commonly observed in the hybrid enclave despite massive plagioclase transfer and only rare resorbed cores with low Ce and Y contents were present. However, such low Ce and Y cores crystalized at the latest stage of apatite crystallization in the quartz monzonite, whereas the plagioclase transfer was an early episode. Therefore, we conclude that apatite transfer was limited during mingling and the apatite composition in the quartz monzonite is best explained by an early Cl-Ce-rich fluid removal and then fractional crystallization, while apatite in the primitive enclave is affected only by fractional crystallization. Altogether, Ce and Y composition of apatite is a valuable tool to record diverse magmatic processes such as fluid removal and precipitation from fluid in addition to fractionation of different REE phases and should be further explored.     

Sustained Ability of a Natural Microbial Community to Remove Nitrate from Groundwater

Microbial-mediated nitrate removal from groundwater is widely recognized as the predominant mechanism for nitrate attenuation in contaminated aquifers and is largely dependent on the presence of a carbon-bearing electron donor. The repeated exposure of a natural microbial community to an electron donor can result in the sustained ability of the community to remove nitrate; this phenomenon has been clearly demonstrated at the laboratory scale. However, in situ demonstrations of this ability are lacking. For this study, ethanol (electron donor) was repeatedly injected into a groundwater well (treatment) for six consecutive weeks to establish the sustained ability of a microbial community to remove nitrate. A second well (control) located upgradient was not injected with ethanol during this time. The treatment well demonstrated strong evidence of sustained ability as evident by ethanol, nitrate, and subsequent sulfate removal up to 21, 64, and 68%, respectively, as compared to the conservative tracer (bromide) upon consecutive exposures. Both wells were then monitored for six additional weeks under natural (no injection) conditions. During the final week, ethanol was injected into both treatment and control wells. The treatment well demonstrated sustained ability as evident by ethanol and nitrate removal up to 20 and 21%, respectively, as compared to bromide, whereas the control did not show strong evidence of nitrate removal (5% removal). Surprisingly, the treatment well did not indicate a sustained and selective enrichment of a microbial community. These results suggested that the predominant mechanism(s) of sustained ability likely exist at the enzymatic- and/or genetic-levels. The results of this study demonstrated the in situ ability of a microbial community to remove nitrate can be sustained in the prolonged absence of an electron donor.     

Shaking table tests of a full-scale flat-bottom manufactured steel silo filled with wheat: Main results on the fixed-base configuration

This paper reports on a series of shaking table tests on a full-scale flat-bottom steel silo filled with soft wheat, characterized by aspect ratio of around 0.9. The specimen was a 3.64-m diameter and 5.50-m high corrugated-wall cylindrical silo. Multiple sensors were used to monitor the static and dynamic response of the filled silo system, including accelerometers and pressure cells. Numerous unidirectional dynamic tests were performed consisting of random signals, sinusoidal inputs, and both artificial and real earthquake records. The objectives of this paper are (i) to provide a general overview of the whole experimental campaign and (ii) to present selected results obtained for the fixed-base configuration. The measured data were processed to assess the static pressures, the dynamic overpressures (related to the effective mass) and the accelerations of monitored points on the silo wall, and to identify the basic dynamic properties (fundamental frequency of vibration, damping ratio, dynamic amplification factors) of the filled silo. The main findings are discussed and compared with the predictions given by available theoretical models and code provisions. It is found that the fundamental frequency slightly decreases with increasing acceleration, while it slightly increases with increasing compaction of the granular material. For close-to-resonance input, the dynamic amplification (in terms of peak values of accelerations) increases along the height of the silo wall up to values of around 1.4 at the top surface of the solid content. The dynamic overpressures appear to increase with depth (differently from the EN1998-4 expectations), and to be proportional to the acceleration.     

Patterns of cornulitid encrustation on the Late Devonian brachiopod shells from Russia

Upper Devonian brachiopods from the Central Devonian Field, Russia have been investigated with respect to encrustation patterns of cornulitids. These Palaeozoic encrusters were very characteristic component of shelly substrates during the Devonian and may serve as valuable objects for palaeoecological studies, especially those concerning the encrusters-host relationships. On the basis of rich material, it has been shown that cornulitid abundance significantly increased in the lower Famennian. Their disparity also increased from one morphotype (robust) present in the upper Frasnian to two distinct morphotypes (robust and slender, presumably representing two different species) in the lower Famennian. The analysis of the spatial occurrence of cornulitids on two dominant lower Famennian brachiopod species (Cyrtospirifer zadonicus and Ripidiorhynchus huotinus) showed, that these encrusters preferred the marginal parts of the shells. This, together with a dominant directional growth of cornulitids toward the commissure, indicates that cornulitids benefited from food brought by feeding currents produced by the brachiopod’s lophophore. The unequivocal evidence for syn vivo association of the cornulitids and their brachiopod hosts is the presence of distinct shell malformations caused by cornulitid growth affecting the host’s shell-secreting epithelium, preserved on some lower Famennian specimens. Interestingly, these malformations were caused by a slender cornulitid morphotype only. Thus, it is evident that during food gathering from the inhalant currents, this cornulitid species exerted a distinct, negative effect on the brachiopod – a deviation of its shell growth. In this case, we may consider this particular cornulitid species as ectoparasite rather than commensal with respect to its host.     

Prairie or planted? Using time-series NDVI to determine grassland characteristics in Montana

Temperate grasslands are a highly threatened global biome. Complicating management and conservation strategy development, modern grasslands can be difficult to characterize across landscapes since they range from native and semi-native to completely non-native species compositions such as those found in heavily managed pastures. Similar to methods used to differentiate C3 and C4 grasses, we investigate the ability of using temporal variations in growth characteristics as an alternative pathway to predicting native versus introduced species composition across grassland landscapes. To do this, we conducted an exploratory analysis using a time-series of Normalized Difference Vegetation Index values as a measure of vegetation greenness with Landsat 5 TM imagery across a growing season and performed an unsupervised classification. Results from the classification were compared with field observation to determine if we can differentiate between native and introduced grassland types in the Northwest Glaciated Plains subecoregion of northeastern Montana. Our results indicated that we predicted grassland cover with 81% accuracy within our 200 km² study area and 71% accuracy in our 5000 km² secondary study area. Further extrapolation of our methodology, combined with the refinement of vegetation indices of time-series imagery, classification algorithms and the availability of data from planned Landsat and Sentinel missions, may provide the spatial detail necessary to improve grassland monitoring and rangeland management over large areas.     

Gully erosion as a natural hazard: the educational role of geotourism

Gully erosion is one of the greatest natural hazards in the loess areas of E. (Eastern) Poland. At the same time, permanent gullies are a major tourist attraction and can provide a basis for the development of geotourism. The study objective was to assess the possibilities of using the loess gullies for educational purposes. Detailed studies were conducted within the municipality of Kazimierz Dolny, an area with an extremely high concentration of permanent gullies. The questionnaire survey of students and tourists (nearly 300 surveys were completed) showed that the respondents’ knowledge of geomorphology was limited, despite their familiarity with gullies. In most cases, they were unable to accurately identify the determinants of gully erosion, its negative effects and methods for preventing it. An assessment of the tourism and geotourism potential of the municipality made it possible to identify the sites (gullies) that can perform an educational function, with regard to gully erosion. The establishment of the Ma?opolska Vistula Gap Geopark, whose highlights will include numerous loess gullies, can pave the way for the development of geotourism.     

Crystallization and Degassing in the Basement Sill, McMurdo Dry Valleys, Antarctica

The Basement Sill is part of the Ferrar Large Igneous Provinceexposed in the McMurdo Dry Valleys, Antarctica. The sill is330 m thick in the Bull Pass area and 450 + m thick in the Daisarea, 12 km to the west, and is characterized by phenocryst-freelower and upper margins and an orthopyroxene-rich central ‘tongue’(opx 1–5 mm in size). Halogen variations in apatite froma suite of samples collected along vertical transects throughthe sill were examined to evaluate the process of crystallization-induceddegassing (i.e. second boiling) and its effects on magma chemistry.Apatite grains from any given sample are generally unzoned withrespect to Cl and F concentrations, but may vary by 20–30mol% in the halogen site between grains. Overall average Cl/Fmass ratios increase with height from the lower margin to thecenter of the sill, and then decrease to near zero towards thetop margin where the rocks are relatively oxide-rich. The Cl/Ftrend parallels those of bulk MgO and grain size. The uppermargin contains abundant mafic pegmatoids and the apatite inthese segregations has lower Cl/F ratios compared with thatin the host-rocks, although REE show no measurable difference.Numerical modeling illustrates that a cooling and crystallizingsill initially develops two separate vapor-saturated zones atthe lower and upper margins owing to the irreversible heat lossto the cooler country rock. Vapor separating from the lowerzone migrates upward into hotter silicate liquid, where it isresorbed, thus increasing the Cl/F mass ratio of the liquid.This process leads to saturation and precipitation of apatitefrom the liquid with a higher Cl/F ratio than would otherwiseoccur. Volatile enrichment can also aid compaction and graingrowth in the central part of the sill. In contrast, the relativelyFe-rich, Cl-poor nature of the upper zone rocks suggests thatthese rocks may have crystallized from more evolved, degassedsilicate liquid, possibly compacted out of the underlying crystalmush. In addition, as vapor sourced from the lower and centralparts of the sill ascends into the cooler upper zone of thesill, the vapor may be localized (along with late interstitialsilicate liquid) to form pegmatoids at temperatures at whichCl is less favored in apatite and can be leached from existingapatite by the ascending vapor, the latter causing the observeddecrease in the Cl/F mass ratio of apatite in the (evolved)pegmatoids. KEY WORDS: Ferrar Igneous Province; halogens; fluid; apatite     

Dynamics of elastic–plastic shear frames with secondary structures: shake table and numerical studies

Results from experimental and numerical studies of earthquake‐excited small‐scale primary–secondary structures are presented. The primary structure considered is a plane three‐storey shear frame with a fundamental frequency of 5.5 Hz. The columns of the first floor are built with soft aluminium and they are stressed beyond its linear range of behaviour. After each test the elastic–plastic columns are replaced by a new set of undeformed virgin aluminium bars. The elastic–plastic shear frame is tested with and without an attached secondary structure. The secondary structure is modelled as an elastic SDOF oscillator, and its natural frequency is tuned to the fundamental frequency of the shear frame. Alternatively, the oscillator is mounted on the horizontal beam of the second and third floor. The base excitation of the structural model is characterized by a broad band random process with constant spectral density in a frequency range between 3 and 30 Hz. In the numerical study, the digital recorded acceleration of the base excites the mechanical model of the investigated structures. Numerical outcomes assuming fictitious unlimited elastic material behaviour of the shear frame are set in contrast to results from experiments and computational simulations where the measured non‐linear force displacement relation of the elastic–plastic floor is approximated by a piecewise linear curve. The effect of elastic–plastic materials on the dynamic interaction between primary and secondary structure is shown and the difference to unlimited elastic material behaviour is worked out in detail. Copyright © 2001 John Wiley & Sons, Ltd.