A facies geological test of stable isotope interpretation of the Upper Permian depositional environment in West Spitsbergen

Lithofacies analysis of two transgressive sequences within the Kapp Starostin Formation (Upper Permian, West Spitsbergen), indicates considerable differences in seawater chemistry between their depositional environments. The onshore part of the sequence represented in the Vøringen and Svenskeegga Members is largely calcareous, with allochthonous and corroded siliceous materials. In contrast, in the equivalent sequence within the Hovtinden Member, silica is ubiquitous whereas carbonate materials include mainly corroded bioclasts. These differences are consistent with predictions of the oceanographic model of ‘overfed’ and ‘hungry’ oceans proposed previously on the basis of carbon and oxygen stable isotope analysis.     

Impact Break-Up of Cometary Nuclei – Conclusions from Impact Experiments

Experiments of impact-generated break-up of icy and icy/mineral targets were performed. Formulae for the velocity of ejecta and for energy of disruption were fitted to the experimental data. An assumption that these formulae can be extrapolated for kilometer-size bodies enabled us to discuss the consequences of impacts on cometary nuclei and on planetesimals. It was found that the porosity of the targets as well as their composition (mineral to total mass ratio), are the crucial parameters.     

Measurements and interpretation of normal mode attenuation

summary . Measurements of Q for modes of free oscillation provide the most accurate information about the anelastic properties of the whole Earth in the period range from 100 to 3000 s. We have obtained more than 230 Q measurements, by using two different techniques. Individual LaCoste—Romberg gravimeter recordings of three large earthquakes were used to observe the time rate of decay of spectral peaks corresponding to different modes. This method provided measurements of Q for 37 different modes. By stacking 211 WWSSN recordings of two deep earthquakes, we were able to measure Q for 197 modes, including many overtones which cannot be analysed using the spectra of individual recordings.     

The partitioning behavior of As and Au in S-free and S-bearing magmatic assemblages

The partitioning of As and Au between rhyolite melt and low-salinity vapor (2 wt% NaCl eq.) in a melt-vapor-Au metal ± magnetite ± pyrrhotite assemblage has been quantified at 800 °C, 120 MPa and f_O2=NNO. The S-bearing runs have calculated values for the fugacities of H₂S, SO₂ and S₂ of logf_H2S=1.1, logf_SO2=-1.5, and logf_S2=-3.0. The ratio of H₂S to SO₂ is on the order of 400. The experiments constrain the effect of S on the partitioning behavior of As and Au at magmatic conditions. Calculated average Nernst-type partition coefficients (±1σ) for As between vapor and melt, , are 1.0 ± 0.1 and 2.5 ± 0.3 in the S-free and S-bearing assemblages, respectively. These results suggest that sulfur has a small, but statistically meaningful, effect on the mass transfer of As between silicate melt and low-salinity vapor at the experimental conditions. Efficiencies of removal, calculated following Candela and Holland (1986), suggest that the S-free and S-bearing low-salinity vapor can scavenge approximately 41% and 63% As from water-saturated rhyolite melt, respectively, during devolatilization assuming that As is partitioned into magnetite and pyrrhotite during second boiling. The S-free data are consistent with the presence of arsenous acid, As(OH)₃ in the vapor phase. However, the S-bearing data suggest the presence of both arsenous acid and a As-S complex in S-bearing magmatic vapor. Apparent equilibrium constants, , describing the partitioning of As between melt and vapor are −1.3 (0.1) and −1.1 (0.1) for the S-free and S-bearing runs, respectively. The increase in the value of with the addition of S suggests a role for S in complexing and scavenging As from the melt during degassing.The calculated vapor/melt partition coefficients (±1σ) for Au between vapor and melt, , in S-free and S-bearing assemblages are 15 ± 2.5 and 12 ± 0.3, respectively. Efficiencies of removal (Candela and Holland, 1986) for the S-free melt, calculated assuming that magnetite is the dominant Au-sequestering solid phase during crystallization (Simon et al., 2003), suggest that magmatic vapor may scavenge on the order of 72% Au from a water-saturated melt. Efficiencies of removal calculated for the S-bearing assemblage, assuming pyrrhotite and magnetite are the dominant Au-sequestering solid phases, indicate that vapor may scavenge on the order of 60% Au from the melt. These model calculations suggest that the loss of pyrrhotite and magnetite from a melt, owing to punctuated differentiation during ascent and emplacement, does not prohibit the ability of a rhyolite melt to generate a large-tonnage Au deposit. Apparent equilibrium constants describing the partitioning of Au between melt and vapor were calculated using the mean values for the S-free and S-bearing assemblages; only S-bearing data from runs longer than 400 h were used as shorter runs may not have reached equilibrium with respect only to vapor/melt partitioning of Au. The values for are −4.4 (0.1) and −4.2 (0.2) for the S-free and S-bearing runs, respectively. These data suggest that the presence of S does not affect the mass transfer of Au from degassing silicate melt to an exsolved, low-salinity vapor in a low-f_S2 assemblage (i.e., pyrrhotite-magnetite at NNO) at the experimental conditions reported here. Efficiencies of removal are calculated and used to model the mass transfer of Au from a crystallizing silicate melt to an exsolved, low-salinity vapor phase. The calculations suggest that the model, absolute tonnage of Au scavenged and transported by S-free and S-bearing vapors, from a crystallizing melt, would be comparable and that the time-integrated flux of low-salinity vapor could be responsible for a significant quantity of the Au in magmatic-hydrothermal ore deposits.     

Analysis of development and depth of backward erosion pipes in the presence of a coarse sand barrier

Backward erosion piping (BEP) is a failure mechanism that can affect the safety of water-retaining structures. It can occur when a local anomaly on the downstream side of an embankment causes a concentration of seepage flow at that location. Shallow pipes may then form, progressing in the upstream direction and leading to a collapse of the water-retaining structure. A novel and economically appealing measure against BEP is the coarse sand barrier (CSB), which is now being developed in a multiscale experimental programme in the Netherlands. The method involves placing a trench filled with coarse sand below the blanket layer on the downstream side of the embankment. The CSB prevents the upstream progression of the pipe and significantly enhances resistance to BEP. This paper presents medium-scale laboratory tests involving a range of sands, barrier depths and relative densities. The piping process and the observations of pipe progression in the presence of a CSB are presented, followed by a conceptual model. The presence of a CSB changed the erosion pattern. It resulted in pipe formation perpendicular to the flow direction over the entire width of the barrier before the barrier was damaged. The findings also demonstrate the effect of material properties on pipe initiation, progression and pipe depth. Measurements of the pipe depth are presented and analysed, revealing the significance of pipe depth for understanding the piping process. This analysis shows considerable erosion in the downstream background sand and demonstrates that erosion profiles and measured pipe depths are significantly larger than in BEP tests without a CSB.

     

ChemiX: a Bragg crystal spectrometer for the <Emphasis Type="Italic">Interhelioprobe</Emphasis> interplanetary mission

Interhelioprobe (IHP), an analogue to the ESA Solar Orbiter, is the prospective Russian space solar observatory intended for in-situ and remote sensing investigations of the Sun and the inner heliosphere from a heliocentric orbit with the perihelion of about 60 solar radii. One of several instruments on board will be the Bragg crystal spectrometer ChemiX which will measure X-ray spectra from solar corona structures. Analysis of the spectra will allow the determination of the elemental composition of plasma in hot coronal sources like flares and active regions. ChemiX is under development at the Wroc?aw Solar Physics Division of the Polish Academy of Sciences Space Research Centre in collaboration with an international team (see the co-author list). This paper gives an overview of the ChemiX scientific goals and design preparatory to phase B of the instrument development.     

Appropriate aspirations for effective post-mining restoration and rehabilitation: a response to Kaźmierczak et al.

Confusion surrounding the definition and application of terminology in post-mining ecological repair has resulted in uncertainty for industry, the scientific community and regulators. This lack of clarity may underrepresent high aspirations or could be misused to disguise low aspirations and so is problematic for setting objectives, establishing goals and assessing recovery trajectories. We respond to a recently published analysis of the ecosystem repair literature, where we highlight inconsistencies stemming from inadequate reference to a large proportion of the restoration and rehabilitation literature. We outline increasingly well-accepted and internationally applied definitions concerning the restoration and recovery process and invite both the mining industry and policy-makers to re-examine their terminology in the interests of attaining an internationally agreed nomenclature. Clarity in the use and understanding of terminology will align post-mining targets with community expectation, enhance the capacity of the mining industry to understand and meet these targets, and foster better analysis and more industry-relevant discussion of recovery methodologies by the scientific community and practitioners.