Treatability of Dye Solutions Containing Disperse Dyes by Fenton and Fenton‐Solar Light Oxidation Processes

This study attempts to explore the possibility of treating dye solutions containing Disperse Yellow 119 and Disperse Red 167 by Fenton and Fenton under solar‐light oxidation processes. Experiments were conducted to examine the effects of various operating conditions on the performance of the treatment systems. The Fenton results showed that 98.6% spectral absorption coefficient (SAC) and 90.8% chemical oxygen demand (COD) removals were proved at pH 3, 50 mg/L Fe²⁺, and 75 mg/L H₂O₂, 15 min oxidation time for Disperse Yellow 119. After 40 min solar irradiation time during Fenton process the SAC removal was 99.1%. COD reduction of about 98.3% was observed at the same time. It was also obtained as 97.8% SAC and 97.7% COD removal with pH 3, 75 mg/L Fe²⁺, 100 mg/L H₂O₂, and 25 min oxidation time for Disperse Red 167 at this optimum conditions. For Disperse Red 167 during Fenton under solar light process, after 40 min of solar irradiation time the SAC and COD reduction were obtained 99.3 and 98.4%, respectively.     

Physical parameters of some close binaries: ET Boo,V1123 Tau,V1191 Cyg,V1073 Cyg and V357 Peg

With the aim of providing new and up-to-date absolute parameters of some close binary systems, new BVR CCD photometry was carried out at the Ankara University Observatory (AUG) for five eclipsing binaries, ET Boo, V1123 Tau, V1191 Cyg, V1073 Cyg and V357 Peg between April, 2007 and October, 2008. In this paper, we present the orbital solutions for these systems obtained by simultaneous light and radial velocity curve analyses. Extensive orbital solution and absolute parameters for ET Boo system were given for the first time through this study. According to the analyses, ET Boo is a detached binary while the parameters of four remaining systems are consistent with the nature of contact binaries. The evolutionary status of the components of these systems are also discussed by referring to their absolute parameters found in this study.     

Structural evolution of the Gediz Graben,SW Turkey: temporal and spatial variation of the graben basin

The structural evolution of the Miocene to Recent Gediz Graben is intimately related to the evolution of its southern margin. This margin is shaped by a time‐transgressive, composite structure that possesses flat‐ramp geometry with three separate dip domains: a low‐angle shallow segment; a steeper middle segment; and a low‐angle deeper segment. This geometry was probably produced by one of two mechanisms, which operated perpendicular to the general trend of the graben, resulting in gradual back‐rotation followed by abandonment of the shallow segment as it was dissected by the high‐angle normal fault(s). The geometry of the southern margin structure is not simple along‐strike. It includes broad undulations and discrete fault segments, developed by large‐scale fault growth processes through segment linkage. The along‐strike growth of the southern margin‐bounding structure is responsible for the composite character of the Gediz Graben and controls the observed stratigraphic variability. Two sub‐basins aligned with the major segments of the southern graben margin structure have been investigated. The Salihli and Ala?ehir sub‐basins comprising 3000 m sedimentary thickness are separated by an intervening basement high, that is covered by a thin veneer of post‐Miocene sediments. The two sub‐basins, which evolved as isolated basins during most of the graben history, amalgamated during post‐Miocene time to form the composite configuration of the graben. There is a general east to west trend of growth for the Gediz Graben.     

210Po and 210Pb variations in fish species from the Aegean Sea and the contribution of 210Po to the radiation dose

In recent years, there has been increasing interest in the significance of natural radionuclides, particularly (210)Po, in the marine environment. (210)Po, a naturally occurring alpha emitter, accumulates in marine organisms and reflects differences in their diets. In the literature, there is no data for (210)Po and (210)Pb activity concentrations for fish species on the Turkish coast of Aegean Sea. Therefore, in this study, multiple fish species were collected from six stations seasonally on the Turkish coast of Aegean Sea and were analyzed for their (210)Po and (210)Pb content. The (210)Po and (210)Pb concentrations in the fish samples were found to vary from undetectable levels to 499 ± 44 Bq kg(-1) dry weight (dw) and from 1.0 ± 0.3 Bq kg(-1) to 35 ± 4.0 Bq kg(-1) (dw), respectively. There were no significant differences in the activity concentrations of (210)Po and (210)Pb in fish samples between seasons (ANOVA, P>0.05). The highest dose contribution of (210)Po to humans was calculated to be 10,530 μSv year(-1).     

Photometry of three chromospherically active stars: V340 Gem,SAO 62042 and FI Cnc

We present a photometric study of three chromospherically active stars with long periods (V340 Gem, SAO 62042 and FI Cnc). The observations were made at the ÇOMU Observatory in 2006 and 2007. We have made initial photometric analyses of V340 Gem and SAO 62042, which are newly discovered RS CVn–type SB1 binaries, and established the photometric variations of FI Cnc, which is a single G8III active star. Photometric rotation periods of these stars were obtained by analyzing their light variations. The light variations, observed over three or more consecutive orbital cycles, were investigated by using spot models with the program SPOT. We also discussed the surface differential rotation coefficient for the primary component of the SB1 binary star SAO 62042 in this study, using our own photometric period together with an orbital period taken from the literature.     

Tectonic geomorphology of the Kemalpaşa Basin and surrounding horsts,southwestern part of the Gediz Graben,Western Anatolia

The Kemalpa?a Basin is one of the Quaternary basins in Western Anatolia and represents the south-western branch of the Gediz Graben system in this extensional province. This basin has been formed under the NNE–SSW trending extensional tectonic regime. It is bounded by a major fault, the Kemalpa?a Fault, in the south and it is bounded by a number of downstepping faults, called as Spilda?? Fault Zone, in the north. Both margin-bounding faults of the Kemalpa?a Basin are oblique-slip normal faults. In order to better understand the activities of these faults, we investigated the tectonic geomorphology of the Kemalpa?a Basin and interpreted the effect of tectonic activity on the geomorphological evolution using geomorphic markers such as drainage basin patterns, facet geometries and morphometric indices such as hypsometric curves and integral (HI), basin shape index (B_s), valley floor width-to-height ratio (V_f) and mountain front sinuosity (S_mf). The morphometric analysis of 30 drainage basins in total and mountain fronts bounding the basin from both sides suggests a relatively high degree of tectonic activity. The mountain front sinuosity (S_mf) generally varies from 1.1 to 1.3 in both sides of the basin suggesting the active fronts and facet slopes (12°–32°) suggest a relatively high degree of activity along the both sides of the Kemalpa?a Basin. Similarly, the valley floor width-to-height ratios (V_f) obtained from the both sides indicate low values varying from 0.043 to 0.92, which are typical values (<1) for tectonically active mountain fronts. The all values obtained are lower for the southern side. Therefore, we suggest that the tectonic activity of the Kemalpa?a Fault higher than the Spilda?? Fault Zone. This difference that can be arised from the different uplift rates also reveals the typical asymmetric characteristics of the Kemalpa?a Basin. Additionally, the trapezoidal facets which have been observed on the southern side of the basin indicate that the Kemalpa?a Fault is evolutionally more active as compared to the Spilda?? Fault Zone. The geomorphic indices indicate that the Quaternary landscape evolution of the Kemalpa?a Basin was governed by tectonic and erosional processes, and also the all results of morphometric analysis suggest a relatively high degree of tectonic activity along the faults bounding the Kemalpa?a Basin. Moreover, considering that active large normal faults with an average 15 km long can cause major earthquake, the earthquake hazard in the Kemalpa?a Basin should be investigated in detailed paleoseismological studies.     

Continuous resistivity profiling survey in Mersin Harbour, Northeastern Mediterranean Sea

No detailed information has previously been available on the geological and geophysical characteristics of the sea floor and the underlying strata of Mersin Harbour, Northeastern Mediterranean Sea (Turkey). Continuous resistivity profiling (CRP) and borehole data from Mersin Harbour were used to interpret geoelectric stratigraphy of Neogene-Quaternary sediments in the area. This represents one of few such detailed case studies that have applied these valuable CRP techniques for the purpose of marine stratigraphic imaging. It was found that the Neogene-Quaternary sedimentary succession in the area consists of three geoelectric units (GU1, GU2, and GU3 from base to top). The lowest unit, GU1, has a resistivity value of greater than 20.0 ohm-m and consists of Miocene aged limestone and marl. The middle unit, GU2, is characterized by resistivity values ranging from 3.0 to 20.0 ohm-m. Its thickness is greater than 90 m, with the upper section being composed of stiff clay sequences which are Plio-Pleistocene in age. The uppermost unit, GU3, has resistivity values varying from 1.0 to 3.0 ohm-m. This unit displays a maximum thickness of 15 m, and is composed of Holocene muds together with gravel, sand, silt and clay (sometimes incorporating shells) materials of the Plio-Pleistocene age and their various mixtures, silty/clay limestone, and conglomerate sandstone. Comparisons of the geoelectric units with the depositional sequences interpreted from the available seismic data outwith, but close to, Mersin Harbour reveal that the geoelectric unit GU3 corresponds to the depositional sequences C (mainly Holocene) and B (mainly Plio-Pleistocene). The geoelectric unit GU2 partly correlates with the depositional sequence B which appears to be Plio-Pleistocene in age. The geoelectric unit GU1, which has not been encountered in previous seismic surveys, is a new discovery within Mersin Harbour. Limited correlation between the seismic and resistivity structures in the study area is attributed to differences in the acoustic impedance and resistivity contrasts of sub-bottom layers, as well as the penetration versus resolution performance of the systems.     

Modeling of ECBM recovery from Amasra coalbed in Zonguldak Basin,Turkey

Zonguldak coal basin is the only productive hard coal basin of Turkey. The eastern part of the basin is called as Bartin–Amasra District, which has deeper coal seams. The depth and difficulty of mining these coal seams make this district an important candidate for coalbed methane (CBM) recovery. However, there is not enough reservoir data for modeling purposes. In this study, the lithologic information collected for coal mining industry was used to determine the correlations and the continuity of the coal seams. The lithologic information was examined and the depths of the coal seams and the locations of the exploration boreholes were used to perform a reliable correlation using a new method. As a result of the correlation study, 63 continuous coal layers were found. A statistical reserve estimation of each coal layer for methane was made by using Monte Carlo simulation method. The initial methane in place found in the coal layers both in free and adsorbed states were estimated using probabilistic simulations resulted in possible reserve (P10) of 2.07 billion m³, probable reserve (P50) of 1.35 billion m³ and proven reserves (P90) of 0.86 billion m³.Among the determined continuous coal layers, coal layer #26 was selected for a preliminary investigation of the applicability of enhanced coalbed methane (ECBM) recovery and CO₂ storage. The scarcity of coal seam reservoir data required a sensitivity study for the effects of reservoir parameters on operational performance indicators. The effects of adsorption, coal density, permeability, cleat porosity and permeability anisotropy parameters were examined using the Computer Modeling Group's (CMG) GEM module.     

Cyclicity in the Middle Eocene Yamak turbidite complex of the Haymana basin,Central Anatolia,Turkey

The Haymana basin in central Anatolia (Turkey) formed on a Late Cretaceous to Middle Eocene fore-arc accretionary wedge. A sequential model is proposed for the 1-km-thick Lutetian Yamak turbidite complex (YTC) which is the youngest paleotectonic unit of the basin. The YTC represents a prograding submarine fan subdivided into three depositional sequences (DS), each several hundred meters thick. Each depositional sequence consists of a turbidite system (TS), with sandstone and conglomeratic sandstone beds alternating with mudstones, overlain by basin plain mudstones. In each turbidite system, the sandstone and mudstone sequential organization allows the distinction of smaller subdivisions, namely, basic sequences (BS) and basic units (BU), with each basic sequence being composed of several basic units. This subdivision, associated with a two-dimensional geometric reconstruction of the YTC, leads to a better understanding of the evolution in time and space of the submarine fan system. Lower to middle fan depositional lobes, and upper fan and slope channels, are represented. As a whole, the YTC progressed from a sand-poor to a sand-rich system. Depositional sequences (DS) of the YTC may correspond to third-order sea-level cycles of tectonic origin. Accordingly, fourth- and fifth-order cycles might be proposed for the BS and BU, respectively. However, partly because of the limited extent of exposures, the allocyclic origin of these finer subdivisions remains problematic.