Toxic Effects of Copper‐Based and Synthetic Organic Pesticides on Activated Sludge

Toxic effects of five commonly used pesticides on the biomass of a municipal activated sludge system were determined on the basis of the reduction in the oxygen uptake rate (OUR) and specific oxygen uptake rate (SOUR). Toxicity levels of the selected pesticides were determined by employing a modified OECD 209 (Organisation for Economic Cooperation and Development) method which was performed as batch experiments using a respirometer. Copper sulphate (CuSO₄ · 5 H₂O), copper oxychloride (Cu₂Cl(OH)₃), copper calcium oxychloride (CaCu₃Cl₂(OH)₆) as copper‐based pesticides and chlorsulphuron (C₁₂H₁₂ClN₅O₄S), 2,4‐dichlorophenoxyacetic acid (2,4‐D) (C₈H₆Cl₂O₃) as synthetic organic pesticides were selected for the experiments. The EC₅₀ values were determined to be 78, 249 and 281 mg/L for CuSO₄ · 5 H₂O, Cu₂Cl(OH)₃ and CaCu₃Cl₂(OH)₆, respectively. Corresponding values for C₁₂H₁₂ClN₅O₄S and 2,4‐D were 860 and 3664 mg/L, respectively. Results indicated that toxicity effects of copper‐based pesticides were higher than that of synthetic organic pesticides. CuSO₄ · 5 H₂O was found to exert the highest toxicity among the copper‐based pesticides, whereas, C₁₂H₁₂ClN₅O₄S was determined to be the most toxic among the organic pesticides on activated sludge biomass.     

Geological evolution of the Gulf of Saros,NE Aegean Sea

 The Gulf of Saros is an Upper Miocene transtensional basin in NW Anatolia, formed by the interaction between the North Anatolian Fault and the N-S extensional tectonic régime of the Aegean. The present configuration of the basin evolved mainly during the Plio-Quaternary under the increased activity of the North Anatolian Fault. During the late Miocene-late Quaternary, no sedimentation took place on the shelves. After this long hiatus, an important change in tectonic style about 0.2 Ma BP allowed sedimentation to resume in the gulf. Received: 14 February 1997 / Revision received: 12 November 1997     

Modelling Last Glacial Maximum ice cap with the Parallel Ice Sheet Model to infer palaeoclimate in south-west Turkey

Modelling palaeoglaciers in mountainous terrain is challenging due to the need for detailed ice flow computations in relatively narrow and steep valleys, high-resolution climate estimations, knowledge of pre-ice topography, and proxy-based palaeoclimate forcing. The Parallel Ice Sheet Model (PISM), a numerical model that approximates glacier sliding and deformation to simulate large ice sheets such as Greenland and Antarctica, was recently adapted to alpine environments. In an attempt to reconstruct the climate conditions during the Last Glacial Maximum (LGM) on Mount Dedegöl in SW Turkey, we used PISM and explored palaeoglacier dynamics at high spatial resolution (100 m) in a relatively small domain (225 km²). Palaeoice-flow fields were modelled as a function of present temperature and precipitation. Nine different palaeoclimate simulations were run to reach the steady-state glacier extents and the modelled glacial areas were compared with the field-based and chronologically well-established ice extents. Although our results provide a non-unique solution, best-fit scenarios indicate that the LGM climate on Mount Dedegöl was between 9.2 and 10.6 °C colder than today, while precipitation levels were the same as today. More humid (20% wetter) or arid (20% drier) conditions than today bring the palaeotemperature estimates to 7.7–8.8 or 11.5–13.2 °C lower than present, respectively.     

A new method for aquifer system identification and parameter estimation

The standard practice for assessing aquifer parameters is to match groundwater drawdown data obtained during pumping tests against theoretical well function curves specific to the aquifer system being tested. The shape of the curve derived from the logarithmic time derivative of the drawdown data is also very frequently used as a diagnostic tool to identify the aquifer system in which the pumping test is being conducted. The present study investigates the incremental area method (IAM) to serve as an alternative diagnostic tool for the aquifer system identification as well as a supplement to the aquifer parameter estimation procedure. The IAM based diagnostic curves for ideal confined, leaky, bounded and unconfined aquifers have been derived as part of this study, and individual features of the plots have been identified. These features were noted to be unique to each aquifer setting, which could be used for rapid evaluation of the aquifer system. The effectiveness of the IAM methodology was investigated by analyzing field data for various aquifer settings including leaky, unconfined, bounded and heterogeneous conditions. The results showed that the proposed approach is a viable method for use as a diagnostic tool to identify the aquifer system characteristics as well as to support the estimation of the hydraulic parameters obtained from standard curve matching procedures. Copyright © 2012 John Wiley & Sons, Ltd.     

Seismic performance of a high-rise building by using linear and nonlinear methods

Natural Hazards - In this paper, the seismic behavior of the existing reinforced concrete tall building is investigated by using the linear and nonlinear dynamic methods. The selected existing...     

Aquifer parameter estimation using an incremental area method

Theoretical well functions have been derived over the years to predict ground water level behaviour in aquifer systems under stress owing to groundwater extraction. The drawdown data collected during pump tests are typically analysed using graphical curve‐matching procedures to estimate aquifer parameters based on these well functions. Difficulty in aquifer characteristic identification and parameter estimation may arise when the field data do not perfectly match the drawdown curves obtained from the well functions. The present study provides a new method for the interpretation of aquifer pump tests which supplements the existing curve‐matching procedures in case ideal conditions do not exist; the proposed method provides a greater degree of flexibility in the data analysis for diagnostic tool purposes. The method, referred to as the Incremental Area Method (IAM) is based on integrating the logarithmic‐based drawdown curves within a discrete time and matching the results with a corresponding time integral of the Theis ( 1935 ) Well Function which governs ideal confined aquifers. The application of the proposed method to synthetically generated data and field data showed that IAM represents a viable method which yields information on potential non‐idealness of the aquifer and provides aquifer parameter estimates thus potentially overcoming drawdown data curve‐matching difficulties. Copyright © 2011 John Wiley & Sons, Ltd.     

Spatial Variation of the Precipitation Chemistry in the Thrace Region of Turkey

Pollutants affect not only the environment in which they originate since they are also transported by air currents to other locations. For this reason, air pollution is a global problem for all countries and the air and water quality need to be monitored carefully. More information on precipitation chemistry is required to determine the source of pollution as well as its effects on the ecosystems. In this study, precipitation chemistry has been analyzed for the first time by using simple bulk collectors located at four different sites in Northwest Turkey for a period of two years. About 650 sequential rainwater samples were collected and analyzed for pH, electrical conductivity, anions such as , , Cl^?, and cations such as Na⁺, K⁺, Mg²⁺, Ca²⁺, and . The selected sites were under the effect of different environmental factors. Our results showed that the highest and concentrations were measured in the Northwest of the research area. Additionally, it has been found that Ca²⁺ ions are abundant within all rainwater samples.     

Paleogeographic evidence on the Jurassic tectonic history of the Pontides: new paleomagnetic data from the Sakarya continent and Eastern Pontides

The Jurassic paleogeographic position of the Pontides is not well studied because of insufficient paleomagnetic data. For this reason, a paleomagnetic study was carried out in order to constrain the paleolatitudinal drift of the Turkish blocks during the Jurassic period. A total of 32 sites were sampled from volcanic and volcanoclastic rocks of the Lower/Middle Jurassic Kelkit formation (Eastern Pontides), Mudurnu formation (Sakarya continent) and Upper Jurassic–Lower Cretaceous Ferhatkaya formation exposed around Amasya region (Eastern Pontides). Rock magnetic experiments demonstrate that the main ferromagnetic mineral is pseudo-single-domain titanomagnetite in these rocks. Paleomagnetic analysis revealed two main components of the natural remanent magnetization during stepwise thermal and alternating field demagnetization. The first component is a low-coercivity (unblocking temperature) component with a direction sometimes similar to that of the earth’s present field or a viscous component. The second component, which is interpreted as the characteristic remanent magnetization (ChRM) direction, has low to high coercivity properties between 20 and 100 mT or unblocking temperatures between 300 and 580°C. A positive fold test at the 95% level of confidence proved that the ChRM of the sites is primary. Paleomagnetic directions calculated for the Kelkit formation in the Eastern Pontides have a mean direction of D = 334.8°, I = 49.7°, α ₉₅ = 7.1° after tilt-correction. A mean direction of D = 332.2°, I = 48.5°, α ₉₅ = 14.6° was obtained from the volcanoclastic rocks of the Mudurnu formation, and D = 324.3°, I = 43.3°, α ₉₅ = 9.5° was calculated for the Upper Jurassic–Lower Cretaceous limestones/Ferhatkaya formation of the Amasya region. The Jurassic rocks in the Eastern Pontides and Mudurnu region are considered to represent products of the rifted Neo-Tethys ocean, while the Upper Jurassic–Lower Cretaceous sediments in Amasya are related to basin-filling materials. The data suggest that the Kelkit formation was formed at 30.5°N paleolatitude and the equivalent Mudurnu formation at 29.5°N paleolatitude. The paleolatitude of the Eastern Pontides indicates that this rifting block was separated from Eurasia by a marginal basin instead of being a part of Eurasia. The lower paleolatitude of the Amasya region at 24.8°N in the Upper Jurassic to Lower Cretaceous clearly indicates southward drift of the Turkish blocks during the Jurassic to Lower Cretaceous period together with the motion of Eurasia.     

October 23, 2011 Turkey/Van–Ercis earthquake: structural damages in the residential buildings

On October 23, 2011, a magnitude of Mw 7.2 earthquake struck the Van province in eastern Turkey which caused approximately 600 life loss and 4,000 injured people. Although the recorded peak ground accelerations were relatively low (0.15–0.2 g) compared with that of other recent destructive Turkish earthquakes and the code-based design response spectrum, a large number of reinforced concrete buildings with 4–6 stories and non-engineered masonry buildings were either heavily damaged or collapsed in the region. Based on the post-earthquake technical inspections, the goal of this paper is to introduce major reasons for structural damages in the disaster area and to discuss these failures along with the approaches given in the design code which is renewed after August 17, 1999 Marmara Earthquake. Some remarkable lessons learned from earthquake-induced failures and damages specific to building construction techniques are presented in this paper.