Microtectonic and geochemical characterization of thrusting in a foreland basin: Example of the South-Pyrenean orogenic wedge (Spain)

In orogenic systems, thrust faults play a major role in stacking different tectonic units and may act as conduits for the expulsion of large amounts of fluid of different origins (metamorphic, diagenetic, meteoric). This study focuses on the Monte Perdido thrust unit emplaced in the Paleogene Jaca thrust-sheet-top basin, in the SW-central Pyrenees. We aim to decipher the mechanisms and P-T conditions of deformation in fault zones and characterize the related fluid involvement, through combined microstructural, geochemical and microthermometry analyses. Two thrust faults cutting platform limestones, marls and siliciclastic turbidites of the lower part of the basin-fill (Paleocene–lower Eocene) have been studied. The fault zones are characterized by metre-thick shear zones with highly deformed, foliated clay-rich sediments. Foliation is underlined by preferentially oriented phyllosilicates. Several generations of shear and extension calcite, quartz and chlorite-bearing veins attest to fluid-rock interactions during a multi-stage deformation. Microstructural observations and stable isotope analyses on calcite from veins and host sediments suggest that deformation was aseismic and dominated by diffusive mass transfer from pressure solution sites along cleavage and stylolites to the precipitation sites in veins, with mineralizing fluids in equilibrium with the host sediments. Our results suggest an essentially closed hydrologic system, and imply the absence of significant fluid flow along the studied fault zones. Microthermometric study on fluid inclusions present in calcite and quartz veins, and calcite-quartz oxygen isotopic fractionation determined for the first generation shear veins, allow a geothermal gradient of 34 °C/km to be estimated. Analytical results demonstrate an evolution of the fault zones in three stages. The first stage was related to the emplacement of the Monte Perdido thrust unit during the middle Eocene at a temperature of ～208 °C and a burial depth of ～5.7 km. The second stage corresponds to a fault reactivation at a temperature of ～240 °C and a burial depth of ～6.5 km. The latter deformation may have been related to folding of the Monte Perdido thrust unit during the emplacement of the underlying Gavarnie thrust unit during the late Eocene–early Oligocene, with deeper burial resulting from aggradation of the thrust-sheet-top basin-fill. The last event corresponds to the formation of a dilatant vein system likely related to the exhumation of the massif.     

P–T–t estimation of deformation in low‐grade quartz‐feldspar‐bearing rocks using thermodynamic modelling and 40Ar/39Ar dating techniques: example of the Plan‐de‐Phasy shear zone unit (Briançonnais Zone,Western Alps)

Pressure–Temperature–time (P–T–t) estimates of the syn‐kinematic strain at the peak‐pressure conditions reached during shallow underthrusting of the Briançonnais Zone in the Alpine subduction zone was made by thermodynamic modelling and ⁴⁰Ar/³⁹Ar dating in the Plan‐de‐Phasy unit (SE of the Pelvoux Massif, Western Alps). The dated phengite minerals crystallized syn‐kinematically in a shear zone indicating top‐to‐the‐N motion. By combining X‐ray mapping with multi‐equilibrium calculations, we estimate the phengite crystallization conditions at 270 ± 50 °C and 8.1 ± 2 kbar at an age of 45.9 ± 1.1 Ma. Combining this P–T–t estimate with data from the literature allows us to constrain the timing and geometry of Alpine continental subduction. We propose that the Briançonnais units were scalped on top of the slab during ongoing continental subduction and exhumed continuously until collision.     

Study of a rockfall in a limy conglomerate canyon (Covarrubias, Burgos, N. Spain)

In this paper, a rockfall of some tenths of cubic metres of rock, occurred in a conglomerate canyon in the northern Castilian plateau (N-Central Spain), is described in detail. This includes the basic data (geology, mapping, meteorological data and rock involved), the mechanical mechanism of the instability, the propagation and reach of the fallen rock boulders and the final location of the pieces. The study is based on detailed geological, aerial photography and geotechnical studies and advance topographical measurements. Geological engineering techniques are used to analyze the instability initiation and rockfall propagation. This study contributes to a better understanding of the geological processes leading to the occurrence of calcareous canyons and cliffs in the drainage network of the upper Castilian plateau. It is also helpful to improve our knowledge on natural rockfall phenomena for risk engineering purposes aiming to quantify, control and mitigate associated hazards.     

Geochemical processes in a Mediterranean Lake: a high-resolution study of the last 4,000 years in Zoñar Lake,southern Spain

High-resolution geochemical analysis of a 6-m-long sediment core from Zoñar Lake, southern Spain, provides a detailed characterization of major changes in lake and watershed processes during the last 4,000 years. Geochemical variables were used as paleolimnological indicators and complement Zoñar Lakes’s paleoenvironmental reconstruction based on sedimentological and biological proxies, which define periods of increasing allochthonous input to the lake and periods of dominant autochthonous sedimentation. Chemical ratios identify periods of endogenic carbonate formation (higher Ca/Al, Sr/Al and Ba/Al ratios), evaporite precipitation (higher S/Al, Sr/Al ratios), and anoxic conditions (higher Mo/Al, U/Th ratios and Eu anomaly). Higher productivity is marked by elevated organic carbon content and carbonate precipitation (Mg/Ca). Hydrological reconstruction for Zoñar Lake was based on sedimentological, mineralogical and biological proxies, and shows that lower lake levels are characterized by Sr-rich sediments (a brackish lake with aragonite) and S-rich sediments (a saline lake with gypsum), while higher lake levels are characterized by sediments enriched in elements associated with alumino-silicates (Al, K, Ti, Fe, trace and rare earth elements), reflecting fresher conditions. Geochemical indicators also mark periods of higher detrital input to the lake related to human activity in the watershed: (1) during the Iberian Roman Humid Period (650 BC–AD 300), around the onset of the Little Ice Age (AD 1400), during the relatively drier Post-Roman and Middle Ages (AD 800–1400), and over the last 50 years, due to mechanized farming practices. Heavy metal enrichment in the sediments (Cu and Ni) suggests intensification of human activities during the Iberian Roman Period, and the use of fertilizers during the last 50 years.     

It starts at home? Climate policies targeting household consumption and behavioral decisions are key to low-carbon futures

Through their consumption behavior, households are responsible for 72% of global greenhouse gas emissions. Thus, they are key actors in reaching the 1.5 °C goal under the Paris Agreement. However, the possible contribution and position of households in climate policies is neither well understood, nor do households receive sufficiently high priority in current climate policy strategies. This paper investigates how behavioral change can achieve a substantial reduction in greenhouse gas emissions in European high-income countries. It uses theoretical thinking and some core results from the HOPE research project, which investigated household preferences for reducing emissions in four European cities in France, Germany, Norway and Sweden. The paper makes five major points: First, car and plane mobility, meat and dairy consumption, as well as heating are the most dominant components of household footprints. Second, household living situations (demographics, size of home) greatly influence the household potential to reduce their footprint, even more than country or city location. Third, household decisions can be sequential and temporally dynamic, shifting through different phases such as childhood, adulthood, and illness. Fourth, short term voluntary efforts will not be sufficient by themselves to reach the drastic reductions needed to achieve the 1.5 °C goal; instead, households need a regulatory framework supporting their behavioral changes. Fifth, there is a mismatch between the roles and responsibilities conveyed by current climate policies and household perceptions of responsibility. We then conclude with further recommendations for research and policy.     

Single GPS receiver time-relative positioning with loop misclosure corrections

Time-relative positioning makes use of observations taken at two different epochs and stations with a single global positioning system (GPS) receiver to determine the position of the unknown station with respect to the known station. The limitation of this method is the degradation over time of the positioning accuracy due to the temporal variation of GPS errors (ionospheric delay, satellite clock corrections, satellite ephemerides, and tropospheric delay). The impact of these errors is significantly reduced by adding to the one-way move from the known to the unknown station, a back move to the known station. A loop misclosure is computed from the coordinates obtained at the known station at the beginning and at the end of the loop, and is used to correct the coordinates of the unknown station. The field tests, presented in this paper, show that using the loop misclosure corrections, time-relative positioning accuracy can be improved by about 60% when using single frequency data, and by about 40% with dual frequency data. For a 4-min processing interval (an 8-min loop) and a 95% probability level, errors remain under 20 cm for the horizontal components and 36 cm for the vertical component with single frequency data; and under 11 cm for the horizontal components and 29 cm for the vertical component with dual frequency data.     

Combining European Earth Observation products with Dynamic Global Vegetation Models for estimating Essential Biodiversity Variables

ABSTRACT

Global, fast and accessible monitoring of biodiversity is one of the main pillars of the efforts undertaken in order to revert it loss. The Group on Earth Observations Biodiversity Observation Network (GEO-BON) provided an expert-based definition of the biological properties that should be monitored, the Essential Biodiversity Variables (EBVs). Initiatives to provide indicators for EBVs rely on global, freely available remote sensing (RS) products in combination with empirical models and field data, and are invaluable for decision making. In this study, we provide alternatives for the expansion and improvement of the EBV indicators, by suggesting current and future data from the European Space Agencýs COPERNICUS and explore the potential of RS-integrated Dynamic Global Vegetation Models (DGVMs) for the estimation of EBVs. Our review found that mainly due to the inclusion of the Sentinel constellation, Copernicus products have similar or superior potential for EBV indicator estimation in relation to their NASA counterparts. DGVMs simulate the ecosystem level EBVs (ecosystem function and structure), and when integrated with remote sensing data have great potential to not only offer improved estimation of current states but to provide projection of ecosystem impacts. We suggest that focus on producing EBV relevant outputs should be a priority within the research community, to support biodiversity preservation efforts.     

Occurrence and fate of polycyclic aromatic hydrocarbons in the coastal surface microlayer

Polycyclic aromatic hydrocarbons (PAHs) were measured in the coastal sea surface microlayer (SML), the sub-surface waters (SSW) and the overlying atmosphere in order to investigate the influence of the SML on contaminant enrichment and air-sea exchange. Samples were collected at two contrasting locations of the NW Mediterranean, one urban influenced (off Barcelona, Spain) and another comparatively clean (off Banyuls-sur-Mer, France). Statistical data analysis confirmed the accumulation of PAHs in the SML with respect to the SSW (20.3+/-9.1 vs. 13.1+/-10.0 ng L(-1) in the dissolved phase; 709+/-207 vs. 158+/-111 ng g(-1) in the particulate phase). This accumulation was higher at the contaminated location (Barcelona station) compared with the more pristine one, with PAH enrichments 1.5 and 4.5 times higher for the dissolved and particulate phases, respectively, indicating that the enrichment of PAHs in the SML is dominated by particle transport processes.     

Integrative taxonomic description of Plakina kanaky,a new polychromatic sponge species from New Caledonia (Porifera: Homoscleromorpha)

Four similar sponges of different colors, all unknown to science, were collected in submarine caves of New Caledonia. We aimed at determining whether the four chromotypes represented different species or phenotypic variations of a unique new species. We used an integrative taxonomic approach combining morphologic, molecular and metabolomic analyses. The main traits that define these specimens are a skeleton made of monolophose, trilophose and tetralophose calthrops only, high chemical diversity and a high abundance and diversity of prokaryotic symbionts. The symbiotic community includes two unique prokaryote morphotypes, which are described for the first time in Homoscleromorpha, and appeared to be vertically transmitted. Although several features slightly differ among chromotypes, the most parsimonious conclusion was to propose a single new species Plakina kanaky sp. nov. Our phylogenetic analysis indicated the paraphyly of the Plakina genus, with P. kanaky sp. nov. belonging to a clade that includes Plakina jani and Plakina trilopha. The present work demonstrates that integrative taxonomy should be used in order to revise the entire Plakinidae family and especially the non‐monophyletic genus Plakina.     

The age as a diagnostic of the dynamics of marine ecosystem models

The constituent-oriented age theory (CAT) worked out by Delhez et al. (1999) is a flexible tool that can be applied to diagnose complex models. It is shown here how this can be used to quantify the pace at which an ecosystem model works. At the cost of the introduction of one additional evolution equation for each compartment of the ecosystem model, the mean age of the biological material forming these compartments can be computed. The information obtained in this way complements the information provided by the concentration data; while the latter measures the standing stocks, the former provides an integrated assessment of the interaction rates and matter fluxes. The benefits of the method are demonstrated with a simple Lotka–Volterra system and a one-dimensional vertical model of the nitrogen cycle in the Ligurian Sea. The theory can be used to study the biological compartments individually or the ecosystem as a whole. In particular, the age is a valuable tool to quantify the overall cycling rate of nitrogen in the food web.Responsible Editor: Phil Dyke