Bioerosion by the sea urchin Diadema mexicanum along Eastern Tropical Pacific coral reefs

Bioerosion is a natural process in coral reefs. It is fundamental to the health of these ecosystems. In the Eastern Tropical Pacific (ETP) coral reefs, the most important bioeroders are sponges, bivalves, sea urchins and the fish Arothron meleagris. In the 1980s, El Niño caused high coral mortality and an increase in macroalgal growth. As a result, greater sea urchin bioerosion occurred. This weakened the reef framework. Considering the high vulnerability of the ETP coral reefs, the goal of this study was to determine the current bioerosion impact of the sea urchin Diadema mexicanum along the western coasts of Mexico, El Salvador, Costa Rica and Panamá. The balance between coral bioaccretion and sea urchin bioerosion was also calculated. Between 2009 and 2010, in 12 coral reefs localities, D. mexicanum density, bottom cover and rugosity were quantified along band transects. The daily bioerosion rate was obtained from the amount of carbonates evacuated by sea urchins per unit time. The rate of coral accretion was calculated by multiplying the coral growth rate of the dominant genus by the density of their skeleton and by their specific coral cover. The localities were dissimilar (R = 0.765, P < 0.001) in terms of live coral cover, crustose calcareous algae, turf cover, rugosity index, and density and size of D. mexicanum. At all sites, with the exception of Bahía Culebra (Costa Rica), coral bioerosion was less than coral bioaccretion. Diadema mexicanum plays a dominant role in the balance of carbonates in the ETP, but this depends on reef condition (protection, overfishing, eutrophication) and so the impacts can be either positive or negative.     

Nannofossils: the smoking gun for the Canarian hotspot

The origin of volcanism in the Canary Islands has been a matter of controversy for several decades. Discussions have hinged on whether the Canaries owe their origin to seafloor fractures associated with the Atlas Mountain range or to an underlying plume or hotspot of superheated mantle material. However, the debate has recently come to a conclusion following the discovery of nannofossils preserved in the products of the 2011–2012 submarine eruption at El Hierro, which tell us about the age and growth history of the western‐most island of the archipelago. Light coloured, pumice‐like ‘floating rocks’ were found on the sea surface during the first days of the eruption and have been shown to contain fragments of pre‐island sedimentary strata. These sedimentary rock fragments were picked up by ascending magma and transported to the surface during the eruption, and remarkably retained specimens of pre‐island Upper Cretaceous to Pliocene calcareous nannofossils (e.g. coccolithophores). These marine microorganisms are well known biostratigraphical markers and now provide crucial evidence that the westernmost and youngest island in the Canaries is underlain by the youngest sediment relative to the other islands in the archipelago. This finding supports an age progression for the onset of volcanism at the individual islands of the archipeligo. Importantly, as fracture‐related volcanism is known to produce non‐systematic age‐distributions within volcanic alignments, the now‐confirmed age progression corroberates to the relative motion of the African plate over an underlying mantle plume or hotspot as the cause for the present‐day Canary volcanism.     

Geology, ore deposits and hydrothermal venting in Bahía Concepción, Baja California Sur, Mexico

Abstract Bahía Concepción is located in the eastern coast of the Baja California peninsula and it is shaped by northwestern–southeastern normal faults. These are associated with a 12–6 Ma rifting episode, although some have been reactivated since the Pliocene. The most abundant rocks correspond to the arc related Comondú Group, Oligocene to Miocene, which forms a mainly calc‐alkaline volcanic and volcaniclastic sequence. There are less extensive outcrops of sedimentary rocks, lava flows, domes and pyroclastic rocks of Pliocene to Quaternary ages. The Neogene volcanism in the area indicates a shift from a subduction regime to an intraplate volcanism related to continental extension and the opening of an oceanic basin. The Bahía Concepción area contains numerous Mn ore deposits, being the biggest at El Gavilán and Guadalupe. The Mn deposits occur as veins, breccias and stockworks, and are composed by Mn oxides (pyrolusite, coronadite, romanechite), dolomite, quartz and barite. The deposits are hosted in volcanic rocks of the Comondú Group and, locally, in Pliocene sedimentary rocks. Thus, the Mn deposits formed between the Middle Miocene and the Pliocene. The mineralized structures are associated with Miocene northwestern–southeastern fault systems, which are analogous to those associated with the Cu‐Co‐Zn‐Mn deposits of El Boleo. The Bahía Concepción area also bears subaerial and submarine hot springs, which are associated with the same fault systems and host rocks. The submarine and subaerial geothermal manifestations south of the bay are possibly related with recent volcanism. The geothermal manifestations within the bay are intertidal hot springs and shallow submarine diffuse venting areas. Around the submarine vents (5–15 m deep, 87°C), Fe‐oxyhydroxide crusts with pyrite and cinnabar precipitate. In the intertidal vents (62°C), aggregates of opal, calcite, barite and Ba‐rich Mn oxides occur covered by silica‐carbonate stromatolitic sinters. Some 10–30 cm thick crustiform veins formed by chalcedony, calcite and barite are also found close to the vents. The hydrothermal fluids exhibit mixed isotopic compositions between δ¹⁸O‐enriched meteoric and local marine water. The precipitation of Ba‐rich Mn oxides around the vent sites could be an active analog for the processes that produced Miocene to Pliocene hydrothermal Mn‐deposits.     

Changes in scavenging of particles by droplets due to weak electrification in clouds

Electrical charges on aerosol particles and droplets modify the droplet–particle collision efficiencies involved in scavenging, and the droplet–droplet and particle–particle collision efficiencies involved in coalescence of droplets and particles, even in only weakly electrified clouds and aerosol layers. This work places electrically enhanced scavenging, and the electrical inhibition of scavenging in the context of the microphysics of weakly electrified clouds.Collision efficiencies are calculated by numerical integration to obtain particle trajectories, that are determined by the complex interplay of electrical, gravitational and phoretic forces together with inertia. These modify the trajectory of a particle as it is carried by flow around the falling droplet. Conversely, the flow around the particle also modifies the trajectory of the droplet. The flows are specified analytically, using a hybrid of the Proudman–Pearson stream function for that region close to the droplet or particle, where it is accurate, merging into the exact Oseen stream function for larger distances, where that becomes accurate. The effect of the flow around the particle on the motion of the droplet was simulated using Langmuir's superposition technique on the hybrid stream functions. The treatment of inertia in the present calculations allows an extension of the scope of our previous work by a factor of 10 larger in particle size (10³ in mass). The coverage is extended to a wide range of atmospheric conditions and particle densities.The pressures and temperatures used in the models ranged from a representation of the lower troposphere at  1 km altitude (900 hPa, 10 °C) to that of the middle stratosphere at  30 km altitude (12 hPa, − 47 °C). The particles considered range from 0.1 μm to 10 μm radius; the droplet radii range from 4 μm to 50 μm; particle densities range from 300 kg m^− 3 to 2500 kg m^− 3; particle charges range from 2e to 100e with droplet charges of like sign of 100e; and relative humidities range from 10% to 100%.For the larger particles (radii greater than about 3 μm) interacting with the larger droplets (radii greater than about 15 μm) the effects of inertia increase with particle density and dominate at the larger densities. For particles with radii in the range 1–3 μm the ‘Greenfield Gap’ of very low collision efficiencies was found, and was determined to be due to the effects of the gravitational force causing a reduction of collisions of particles with the front of the droplet, and the effect of inertia overcoming the tendency for the weight to produce a collision in the slow velocity region in the rear. When the electrical or phoretic forces are sufficiently large the Greenfield Gap is closed.When the particles have radii < 3 μm inertial effects no longer dominate the collisions, although inertia modifies the weight effects for particles with radii down to about 0.5 μm. For charged aerosol particles with radii smaller than about 0.1 μm interacting with droplets or background aerosol particles smaller than a radius of about 15 μm, the long range electrical repulsive force is effective in opposing the phoretic forces and keeping the particle out of range of the short range attractive image force. Thus ‘electroscavenging’ gives way to ‘electroprotection’ against the scavenging or coagulation processes otherwise caused by Browninan diffusion or phoretic forces.In an atmosphere of temperature 10 °C and pressure 900 hPa the net phoretic force reduces to zero and becomes repulsive for particles with radii above about 2 μm (depending on particle conductivity). This enhances the development of the Greenfield Gap. However, the value of this radius (at which the net phoretic force is zero) increases strongly with decreasing temperature and pressure (increasing altitude) as expected from theory, and is about 5 μm in the middle troposphere and more than 10 μm in the stratosphere. Thus a net attractive phoretic force on particles extends into the 1–3 μm radius range in the upper troposphere; however, the weight and inertial effects can ensure the presence of the Greenfield Gap in that range for 2000 kg m^− 3 particles up to the middle stratosphere.     

The influence of mantle melting on the evolution of Mars

We present a parameterized convection model of Mars by incorporating a new heat-flow scaling law for stagnant-lid convection, to better understand how the evolution of Mars may be affected by mantle melting. Melting in the mantle during convection leads to the formation of a compositionally buoyant lithosphere, which may also be intrinsically more viscous by dehydration. The consequences of these melting effects on the evolution of terrestrial planets have not been explored before. The temporal evolution of crust and lithospheric mantle is modeled in a self-consistent manner considering mantle melting, convective instability, and the rewetting of dehydrated lithosphere from below by hydrogen diffusion. Though the effect of compositional buoyancy turns out to be minimal, the introduction of viscosity contrast between wet and dry mantle can considerably slow mantle cooling and sometimes lead to non-monotonic core cooling. Furthermore, with or without dehydration stiffening, our model predicts that the martian mantle must have been degassed more extensively (>80%) than previously suggested (<10%); the loss of such a large amount of water from the mantle to surface has significant implications about the role of water in the early surface and climate evolution of Mars.     

Geochemical Stratigraphy of Submarine Lavas (3-5 Ma) from the Flamengos Valley, Santiago, Southern Cape Verde Islands

New high-precision Pb–Sr–Nd isotope, major and traceelement and mineral chemistry data are presented for the submarinestage of ocean island volcanism on Santiago, one of the southernislands of the Cape Verde archipelago. Pillow basalts and hyaloclastitesin the Flamengos Valley are divided into three petrographicand compositional groups; the Flamengos Formation lavas (4·6Ma) dominate the sequence, with the younger Low Si and Coastalgroups (2·8 Ma) found near the shoreline. Olivine andclinopyroxene compositions and isotopic data for minerals andtheir host melts indicate disequilibrium between some crystalsand the melt. Intra-sample disequilibrium suggests homogenisationof liquids but eruption before complete equilibration betweencrystals and melt preserves the heterogeneity. Pressures ofcrystallization for clinopyroxene (0·4–1·1GPa) indicate stalling and crystallization of the magmas overa range of depths in the lithosphere. Major element compositionsindicate melting of a carbonated eclogite source. Sr–Nd–Pbisotope data suggest the involvement of FOZO-like and EM1-likecomponents in the mantle source, which are simultaneously availableat all depths in the melting column. The Flamengos Valley lavasdisplay large compositional variations, often between stratigraphicallyadjacent flows; these frequent abrupt changes of magma compositionsuggest stalling and crystallization of discrete magma batcheson transport through the lithosphere. KEY WORDS: Cape Verde; crystal–melt disequilibrium; submarine volcanism; source heterogeneity; Pb–Sr–Nd isotopes     

Ambient vertical flow in long-screen wells: a case study in the Fontainebleau Sands Aquifer (France)

A tritium (³H) profile was constructed in a long-screened well (LSW) of the Fontainebleau Sands Aquifer (France), and the data were combined with temperature logs to gain insight into the potential effects of the ambient vertical flow (AVF) of water through the well on the natural aquifer stratification. AVF is commonly taken into account in wells located in fracture aquifers or intercepting two different aquifers with distinct hydraulic heads. However, due to the vertical hydraulic gradient of the flow lines intercepted by wells, AVF of groundwater is a common process within any type of aquifer. The detection of ³H in the deeper parts of the studied well (approximate depth 50 m), where ³H-free groundwater is expected, indicates that shallow young water is being transported downwards through the well itself. The temperature logs show a nearly zero gradient with depth, far below the mean geothermal gradient in sedimentary basins. The results show that the age distribution of groundwater samples might be biased in relation to the age distribution in the surroundings of the well. The use of environmental tracers to investigate aquifer properties, particularly in LSWs, is then limited by the effects of the AVF of water that naturally occurs through the well.     

Deformation in the Guerrero seismic gap, Mexico, from leveling observations

 The Pacific coast of Guerrero state in Mexico is recognized as the `Guerrero seismic gap', with a high probability of producing a large subduction earthquake (M > 8). A study of the vertical surface deformation was undertaken to understand the interseismic process of elastic strain accumulation. Four leveling lines were installed in the states of Guerrero and Michoacán. Starting in 1995, several high-accuracy leveling surveys have been carried out on those profiles once every year. The vertical uplift rate across the Guerrero coastal region, as determined through the changes in repeated leveling surveys, suggests the accumulation of elastic strain at both ends of the gap. In contrast, the sense of tilting in the middle of the gap is opposite to that observed at the ends and suggests significant changes in the geometry of the locked zone and perhaps even slow strain release. Received: 24 February 2000 / Accepted: 23 August 2000     

Middle Miocene to present plate tectonic history of the southern Central American Volcanic Arc

New mid Miocene to present plate tectonic reconstructions of the southern Central American Volcanic Arc (CAVA) reveal that the inception of Cocos Ridge subduction began no earlier than 3 Ma, and possibly as late as 2 Ma. The Cocos Ridge has been displaced from the Malpelo Ridge to the southeast since 9 Ma along the Panama Fracture Zone (PFZ) system. Ambiguous PFZ and Coiba Fracture Zone (CFZ) interaction since 9 Ma precludes conclusively establishing the age of initial Cocos Ridge subduction. Detailed reconstructions based on magnetic anomalies offshore reveal several other variations in subduction parameters beneath southern Central America that preceded subduction of the Cocos Ridge, including southeastward migration of the Nazca–Cocos–Caribbean triple junction along the Middle America Trench (MAT) from 12 Ma to present, and subduction of ≤2 km high scarps both parallel and perpendicular to the trench from 6 to 1 Ma.The timing of changes in subduction processes has commonly been determined by (and correlated with) geologic changes in the upper plate. However, reliable ⁴⁰Ar/³⁹Ar dating of these events has become available only recently [Abstr. Programs-Geol. Soc. Am. (2002)]. These new dates better constrain the magmatic and structural history of southern Costa Rica. Observations from this data set include: a gap in the volcanic record from 11 to 6 Ma, which coincides temporally with emplacement of most plutons in southern Costa Rica, normal arc volcanism ceased after 3.5 Ma in southern Costa Rica, and Pliocene (mostly 1.5 Ma) adakite volcanism was widely distributed from central Panama to southern Costa Rica (though volumetrically insignificant).This new data reveals that many geologic phenomena, commonly attributed to subduction and underplating of the buoyant Cocos Ridge, in fact precede inception of Cocos Ridge subduction and seem to correlate more favorably in time with earlier tectonic events. Adakite volcanic activity corresponds in space and time with the subduction of a large scarp associated with a tectonic boundary off southern Panama. Regional unconformities and an 11–6 Ma gap in arc volcanism match temporally with oblique subduction of the Nazca plate beneath central and southern Costa Rica. Cessation of volcanic activity, low-temperature cooling of plutons in the Cordillera de Talamanca (CT), and rapid increases in sedimentation in the fore-arc and back-arc basins coincide with passage of the Nazca–Cocos–Caribbean triple junction and initiation of subduction of “rough” crust associated with Cocos–Nazca rifting 3.5 Ma, closely followed by initial subduction of the Cocos Ridge 2–3 Ma. None of the aforementioned geologic events occurred at a time that would allow for underplating by the Cocos Ridge. Rather they are probably related to complex interactions with subduction of complicated plates offshore. All of the aforementioned events indicate that the southern Central American subduction system has been in flux since at least 12 Ma.     

The magma plumbing system for the 1971 Teneguía eruption on La Palma,Canary Islands

The 1971 Teneguía eruption is the most recent volcanic event of the Cumbre Vieja rift zone on La Palma. The eruption produced basanite lavas that host xenoliths, which we investigate to provide insight into the processes of differentiation, assimilation and magma storage beneath La Palma. We compare our results to the older volcano magmatic systems of the island with the aim to reconstruct the temporal development of the magma plumbing system beneath La Palma. The 1971 lavas are clinopyroxene-olivine-phyric basanites that contain augite, sodic-augite and aluminium augite. Kaersutite cumulate xenoliths host olivine, clinopyroxene including sodic-diopside, and calcic-amphibole, whereas an analysed leucogabbro xenolith hosts plagioclase, sodic-augite-diopside, calcic-amphibole and hauyne. Mineral thermobarometry and mineral-melt thermobarometry indicate that clinopyroxene and plagioclase in the 1971 Teneguía lavas crystallised at 20–45 km depth, coinciding with clinopyroxene and calcic-amphibole crystallisation in the kaersutite cumulate xenoliths at 25–45 km and clinopyroxene, calcic-amphibole and plagioclase crystallisation in the leucogabbro xenolith at 30–50 km. Combined mineral chemistry and thermobarometry suggest that the magmas had already crystallised, differentiated and formed multiple crystal populations in the oceanic lithospheric mantle. Notably, the magmas that supplied the 1949 and 1971 events appear to have crystallised deeper than the earlier Cumbre Vieja magmas, which suggests progressive underplating beneath the Cumbre Vieja rift zone. In addition, the lavas and xenoliths of the 1971 event crystallised at a common depth, indicating a reused plumbing system and progressive recycling of Ocean Island plutonic complexes during subsequent magmatic activity.