Stoichiometry among bioactive trace metals in seawater on the Bering Sea shelf

The distribution of Al, Mn, Fe, Co, Ni, Cu, Zn, Cd, and Pb in seawater was investigated on the Bering Sea shelf (56–64°N, 165–169°W) in September 2000. The unfiltered and filtered seawater samples were used for determination of total dissolvable (TD) and dissolved (D) metals (M), respectively. The TD-M concentrations were generally higher than in the Pacific Ocean. TD-Cd was highest in deep water of the outer shelf domain and dominated by dissolved species. The other TD-M were highest at stations close to the Yukon River delta and had higher fractions of labile particulate (LP) species that were obtained as the difference between TD-M and D-M. Dissolved Al, Ni, and Cu were characterized by input from the Yukon River. Dissolved Mn and Co showed maximums on the bottom of the coastal domain, suggesting influence of sedimentary Mn reduction. The correlations of D-Zn, D-Cd, and macronutrients indicated their distributions were largely controlled through uptake by microorganisms and remineralization from settling particles. All these three processes (river input, sedimentary reduction, and biogeochemical cycle) had an influence on the distribution of D-Fe. D-Pb was fairly uniformly distributed in the study area. The stoichiometry of D-M in the Bering Sea shelf showed enrichment of Co and Pb and depletion of Ni, Cu, Zn, and Cd compared with that in the North Pacific. The LP-M/LP-Al ratio revealed significant enrichment of the other eight metals relative to their crustal abundance, suggesting importance of formation of Fe–Mn oxides and adsorption of trace metals on the oxides.     

The missing half of the subduction factory: shipboard results from the Izu rear arc,IODP Expedition 350

IODP Expedition 350 was the first to be drilled in the rear part of the Izu-Bonin, although several sites had been drilled in the arc axis to fore-arc region; the scientific objective was to understand the evolution of the Izu rear arc, by drilling a deep-water volcaniclastic section with a long temporal record (Site U1437). The Izu rear arc is dominated by a series of basaltic to dacitic seamount chains up to ~100-km long roughly perpendicular to the arc front. Dredge samples from these are geochemically distinct from arc front rocks, and drilling was undertaken to understand this arc asymmetry. Site U1437 lies in an ~20-km-wide basin between two rear arc seamount chains, ~90-km west of the arc front, and was drilled to 1804 m below the sea floor (mbsf) with excellent recovery. We expected to drill a volcaniclastic apron, but the section is much more mud-rich than expected (~60%), and the remaining fraction of the section is much finer-grained than predicted from its position within the Izu arc, composed half of ashes/tuffs, and half of lapilli tuffs of fine grain size (clasts <3 cm). Volcanic blocks (>6.4 cm) are only sparsely scattered through the lowermost 25% of the section, and only one igneous unit was encountered, a rhyolite peperite intrusion at ~1390 mbsf. The lowest biostratigaphic datum is at 867 mbsf (~6.5 Ma), the lowest palaeomagnetic datum is at ~1300 mbsf (~9 Ma), and the rhyolite peperite at ~1390 mbsf has yielded a U–Pb zircon concordia intercept age of (13.6 + 1.6/?1.7) Ma. Both arc front and rear arc sources contributed to the fine-grained (distal) tephras of the upper 1320 m, but the coarse-grained (proximal) volcaniclastics in the lowest 25% of the section are geochemically similar to the arc front, suggesting arc asymmetry is not recorded in rocks older than ~13 Ma.     

Cellular automata to describe seismicity: A review

Cellular Automata have been used in the literature to describe seismicity. We first historically introduce Cellular Automata and provide some important definitions. Then we proceed to review the most important models, most of them being variations of the spring-block model proposed by Burridge and Knopoff, and describe the most important results obtained from them. We discuss the relation with criticality and also describe some models that try to reproduce real data.     

Evidence for climatic and hillslope‐aspect controls on vadose zone hydrology and implications for saprolite weathering

Through the delivery of water in snowmelt, climate should govern the rate and extent of saprolite formation in snow‐dominated mountain watersheds, yet the mechanisms by which water flows deeply into regolith are largely unexplored. In this study we link rainfall, snow depth, and water content data from both soil and shallow saprolite to document vadose zone dynamics in two montane catchments over 2 years. Measurements of snow pack thickness and soil moisture reveal strong contrasts between north‐ and south‐facing slopes in both the timing of meltwater delivery and the duration of significant soil wetting in the shallow vadose zone. Despite similar magnitudes of snowmelt recharge, north‐facing slopes have higher sustained soil moisture compared to south‐facing slopes. To help interpret these observations, we use a 2D numerical model of vadose zone dynamics to calculate the expected space–time moisture patterns on an idealized hillslope under two wetting scenarios: a single sustained recharge pulse versus a set of short pulses. The model predicts that the duration of the recharge event exerts a stronger control on the depth and residence time of water in the upper unsaturated zone than the magnitude of the recharge event. Model calculations also imply that water should move more slowly through the subsurface and downward water flux should be substantially reduced when water is applied in several pulses rather than in one sustained event. The results suggest that thicker soil and more deeply weathered rock on north‐facing slopes may reflect greater water supply to the deep subsurface. Copyright © 2015 John Wiley & Sons, Ltd.     

Pliocene trace fossils from oyster substrates in the Nijar Basin,Betic Cordillera,southern Spain

The Almería-Níjar Basin is a Neogene, intermontane depression marginal to the Mediterranean in southern Spain in the vicinity of El Argamasón, Andalucia. The Pliocene Cuevas Formation rests unconformably on the Upper Messinian rock succession in the Carboneras Fault Zone. The Cuevas Formation is a coarse-grained, bioclastic-rich, calcarenite to calcirudite shoreface deposit. Oysters, namely Saccostrea cucullata (Born), are locally common and preserve a moderate diversity of borings: Caulostrepsis taeniola Clarke; Entobia isp.; Gastrochaenolites isp. aff. G. lapidicus Kelly and Bromley; Maeandropolydora isp. cf. M. sulcans Voigt; Oichnus paraboloides Bromley; and Talpina isp. aff. T. hirsuta Voigt. All represent domiciles except for the predatory O. paraboloides trace. This suite of ichnotaxa is assigned to the Entobia ichnofacies sensu Bromley and Asgaard; they are comparable, particularly, with the Boulder Assemblage of the Pliocene of Rhodes, Greece. Physical disturbance is an important parameter in favouring this pattern of infestation, whether the bored clasts are boulders or oyster valves.     

Binding of thorium(IV) to carboxylate, phosphate and sulfate functional groups from marine exopolymeric substances (EPS)

Th(IV) isotopes are important proxies in oceanographic investigations, and are used as tracers of particle dynamics and particulate organic matter (POC) fluxes out of the euphotic zone through the use of ²³⁴Th/POC ratios. These approaches rely on empirically determined and variable POC to ²³⁴Th ratios, which might be controlled, in parts, by the abundance of exopolymeric substances (EPS). EPS contain acidic polysaccharides (APS) and are excreted by both phytoplankton and bacteria. To this end, radiotracer experiments with EPS from microbial cultures were conducted to determine the binding environment of ²³⁴Th(IV)-binding ligands in colloids and suspended particles in marine systems. In these experiments, the ²³⁴Th distribution during isoelectric focusing (IEF) and polyacrylamide gel electrophoresis (PAGE) was related to the functional group composition of EPS and of colloidal organic matter (COM) isolated from the Gulf of Mexico (GOM) using cross-flow ultrafiltration. EPS was extracted from phytoplankton (Emiliania huxleyi and Synechococcus elongatus) and bacteria (Sagittula stellata and Roseobacter gallaeciensis) cultures by repeated alcohol precipitation. Phosphate and sulfate concentrations were determined using ion chromatography (IC). IEF profiles indicated that 49% to 65% of the ²³⁴Th-labeled EPS from plankton and bacteria as well as COM samples from the GOM was found concentrated below pH of 4, near an isoelectric point, pH_IEP, of about 2. The carboxylic acid maxima for extracted EPS and COM samples appeared close to the pH_IEF of ²³⁴Th(IV). The phosphate maximum appeared at the same pH_IEF as ²³⁴Th(IV) for EPS from R. gallaeciensis and S. elongatus. The sulfate maximum was found at the same pH_IEF as ²³⁴Th(IV) for EPS from S. elongatus and COM. The molecular weight (MW) of the strongly Th(IV)-binding ligand varied from 1 to 14 kDa, depending on the species, but was about 10 kDa in COM. Thus, depending on the species of plankton or bacteria, the MW and specific functional group composition of the strongly ²³⁴Th(IV)-binding amphiphilic biomolecule can vary. Therefore, different acidic functional groups can, at times, contribute to the binding of Th(IV) to the EPS chelating ligand, which can also have different MWs. This implies that the binding environment for Th(IV), which is present at total concentrations at least a million times lower than the acid functional groups, consists of strong polydentate chelate complexes in clustered structures of carboxylate, sulfates and/or phosphates. The combination of strongly chelating groups and amphiphilicity gives this biomolecule the unique properties of a “sticky” ligand.     

Methodological Advances in the Spatial Analysis of Land Fragmentation

This article evaluates the effect of moving window (MW) size on observed fragmentation spatial patterns and proposes a method to identify an effective MW size using Simpson's diversity index. To test the robustness of the proposed method, we demonstrate its use in six cities in the Phoenix metropolitan area that have substantial variation in land composition and configuration. Next we explore the effects of gradient observation scale and the role of scale in removing noise. We compare and discuss two popular approaches to measuring urban-to-rural fragmentation gradients—concentric ring- and transect-based approaches—highlighting the usefulness of each approach in an extensive and rapidly urbanizing region. This study provides a new method for selecting window size, offers insights on scale effects, and provides guidance on gradient scale selection to achieve the best representation of land fragmentation patterns for urban analysis.     

Geometry and brittle deformation of the subducting Nazca Plate, Central Chile and Argentina

We use data from the Chile Argentina Geophysical Experiment (CHARGE) broad-band seismic deployment to refine past observations of the geometry and deformation within the subducting slab in the South American subduction zone between 30°S and 36°S. This region contains a zone of flat slab subduction where the subducting Nazca Plate flattens at a depth of ∼100 km and extends ∼300 km eastward before continuing its descent into the mantle. We use a grid-search multiple-event earthquake relocation technique to relocate 1098 events within the subducting slab and generate contours of the Wadati-Benioff zone. These contours reflect slab geometries from previous studies of intermediate-depth seismicity in this region with some small but important deviations. Our hypocentres indicate that the shallowest portion of the flat slab is associated with the inferred location of the subducting Juan Fernández Ridge at 31°S and that the slab deepens both to the south and the north of this region. We have also determined first motion focal mechanisms for ∼180 of the slab earthquakes. The subhorizontal T -axis solutions for these events are almost entirely consistent with a slab pull interpretation, especially when compared to our newly inferred slab geometry. Deviations of T -axes from the direction of slab dip may be explained with a gap within the subducting slab below 150 km in the vicinity of the transition from flat to normal subducting geometry around 33°S.     

Volcanic particles in agriculture and gardening

Volcanic pyroclasts of small size, such as lapilli and small pumice stones, are widely used in agriculture, gardening, and for pot plants as natural inorganic mulch. The technique of using pyroclasts to enhance topsoil stems from the eighteenth century, and specifically from the ad 1730–1736 eruption on Lanzarote. Critical observations on plant development during and after the eruption showed that the vegetation died when buried under a thick layer of lapilli, but grew vigorously when covered thinly. While the agriculture of Lanzarote was restricted to cereals before the eruption, it diversified to many kinds of fruit and vegetables afterwards, including the production of the famous Malvasía wines in the Canaries. The population of Lanzarote doubled in the years after the eruption, from about 5000 in 1730 to near 10 000 in 1768, predominantly as a result of the higher agricultural productivity. This outcome led to widespread use of lapilli and pumice fragments throughout the islands and eventually the rest of the globe. Lapilli and pumice provide vesicle space for moisture to be retained longer within the planting soil, which can create an environment for micro‐bacteria to thrive in. Through this route, nutrients from volcanic matter are transported into the surrounding soil where they become available to plant life. The detailed processes that operate within the pyroclasts are less well understood, such as the breakdown of nutrients from the rock matrix and transport into the soil by biological action. Further studies promise significant potential to optimize future agricultural efforts, particularly in otherwise arid areas of the globe.