Diffuse Emission of Hydrogen from Poás Volcano,Costa Rica,America Central

We report the results of four soil H₂ surveys carried out in 2000–2003 at Poás volcano, Costa Rica, to investigate the soil H₂ distribution and evaluate the diffuse H₂ emission as a potential surveillance tool for Poás volcano. Soil gas H₂ contents showed a wide range of concentration from 0.2 to 7,059 ppmV during the four surveys. Maps of soil gas H₂ based on Sequential Gaussian Simulation showed low H₂ concentration values in the soil atmosphere (<0.7 ppmV) for most of the study area, whereas high soil gas H₂ values were observed inside the active crater of Poás. A significant increase in soil gas H₂ concentration was observed inside the active crater during 2001 and 2002 with respect to year 2000, followed by a decrease in 2003. The observed spatial and temporal variations of soil H₂ concentration have been well correlated with seismicity, microgravimetry and fumarolic chemistry changes which occurred during this study. These observations evidence changes in the shallow magmatic-hydrothermal system of Poás, and it might be related to a potential magmatic intrusion during the period 1998–2004. Therefore, monitoring diffuse H₂ emission of Poás has become an important geochemical tool for the monitoring of its volcanic activity.     

Low‐frequency modulation and trend of the relationship between ENSO and precipitation along the northern to centre Peruvian Pacific coast

The relationship between El Niño Southern Oscillation (ENSO) and precipitation along the Peruvian Pacific coast is investigated over 1964–2011 on the basis of a variety of indices accounting for the different types of El Niño events and atmospheric and oceanographic manifestations of the interannual variability in the tropical Pacific. We show the existence of fluctuations in the ENSO/precipitation relationship at decadal timescales that are associated with the ENSO property changes over the recent decades. Several indices are considered in order to discriminate the influence of the two types of El Niño, namely, the eastern Pacific El Niño and the central Pacific El Niño, as well as the influence of large‐scale atmospheric variability associated to the Madden and Julian Oscillation, and of regional oceanic conditions. Three main periods are identified that correspond to the interleave periods between the main climatic transitions over 1964–2011, i.e. the shifts of the 1970s and the 2000s, over which ENSO experiences significant changes in its characteristics. We show that the relationship between ENSO and precipitation along the western coast of Peru has experienced significant decadal change. Whereas El Niño events before 2000 lead to increased precipitation, in the 2000s, ENSO is associated to drier conditions. This is due to the change in the main ENSO pattern after 2000 that is associated to cooler oceanic conditions off Peru during warm events (i.e. central Pacific El Niño). Our analysis also indicates that the two extreme El Niño events of 1982/1983 and 1997/1998 have overshadowed actual trends in the relationship between interannual variability in the tropical Pacific and precipitation along the coast of Peru. Overall, our study stresses on the complexity of the hydrological cycle on the western side of the Andes with regard to its relationship with the interannual to decadal variability in the tropical Pacific. Copyright © 2014 John Wiley & Sons, Ltd.     

Stoichiometry among bioactive trace metals in seawater on the Bering Sea shelf

The distribution of Al, Mn, Fe, Co, Ni, Cu, Zn, Cd, and Pb in seawater was investigated on the Bering Sea shelf (56–64°N, 165–169°W) in September 2000. The unfiltered and filtered seawater samples were used for determination of total dissolvable (TD) and dissolved (D) metals (M), respectively. The TD-M concentrations were generally higher than in the Pacific Ocean. TD-Cd was highest in deep water of the outer shelf domain and dominated by dissolved species. The other TD-M were highest at stations close to the Yukon River delta and had higher fractions of labile particulate (LP) species that were obtained as the difference between TD-M and D-M. Dissolved Al, Ni, and Cu were characterized by input from the Yukon River. Dissolved Mn and Co showed maximums on the bottom of the coastal domain, suggesting influence of sedimentary Mn reduction. The correlations of D-Zn, D-Cd, and macronutrients indicated their distributions were largely controlled through uptake by microorganisms and remineralization from settling particles. All these three processes (river input, sedimentary reduction, and biogeochemical cycle) had an influence on the distribution of D-Fe. D-Pb was fairly uniformly distributed in the study area. The stoichiometry of D-M in the Bering Sea shelf showed enrichment of Co and Pb and depletion of Ni, Cu, Zn, and Cd compared with that in the North Pacific. The LP-M/LP-Al ratio revealed significant enrichment of the other eight metals relative to their crustal abundance, suggesting importance of formation of Fe–Mn oxides and adsorption of trace metals on the oxides.     

Neotectonics and seismicity in southern Patagonia

Research for evaluation of geologic hazards involving earthquakes and volcanic eruptions in southern Argentina seems to have historically received little attention. Nevertheless, the relatively small work done indicates a Neogene tectonic architecture in the area with capability of generating potential hazardous earthquakes in a growing population region. Seismicity and some morphotectonic evidences of Quaternary activity of the Magallanes–Fagnano left‐lateral fault system in the transform boundary between South America and Scotia plates, are analysed in this paper. This fault system is considered to be an important seismogenic source, responsible for large earthquakes that have occurred in southern Argentina. Some examples from the South and Austral Andean Volcanic Zones are also examined in order to show recent volcanic activity which also generated crustal seismicity. Preliminary hazard estimation clearly shows the presence of both potentially active volcanic centres in southern Patagonia that may also trigger seismicity and the high probability for large crustal earthquake generation. Copyright © 2015 John Wiley & Sons, Ltd.     

Cellular automata to describe seismicity: A review

Cellular Automata have been used in the literature to describe seismicity. We first historically introduce Cellular Automata and provide some important definitions. Then we proceed to review the most important models, most of them being variations of the spring-block model proposed by Burridge and Knopoff, and describe the most important results obtained from them. We discuss the relation with criticality and also describe some models that try to reproduce real data.     

Assessing farmland dynamics and land degradation on Sahelian landscapes using remotely sensed and socioeconomic data

Through the integration of SPOT HRV, biophysical and socioeconomic information, the study identified population carrying capacities and their vulnerability to land degradation. Land use intensification on the landscapes was quantified into expansion, early and late phases based on the Ruthenberg index calculated using a biennial series of SPOT images for the period 1986-96. Subsequently, farmland dynamic on different landscapes was calculated while observed patterns were linked with agricultural intensification and population carrying capacity. Results show a pattern of agricultural land degradation due to increasing pressure of population and agricultural intensification within a system characterised by little or no use of inputs. Fifty-six percent of the study area supports a population density higher than the carrying capacity (≤ 15 pers/km^-2). Sixty-three percent of the study area is under early to late phases of agricultural intensification. Between 1986-96, cultivation declined 2-3% annually on landscapes with Low risk of degradation but increased by 1-2% on those with Average/Extreme risks. This emphasises the process of land abandonment as farmers move on to cultivating marginal lands despite above normal seasonal rainfalls observed during most of the period. By 1996, cultivation tended to include fields much farther away from the vicinity of villages, compared with 10 years earlier. Furthermore, by 1996, farmlands in the zones of late intensification declined from 12 to 4% and increased from 6 to 11% in the zone under the expansion phase. Indicating that by 1996 substantial amount of the land area required increasing lengths of fallowing. The spatial GIS modelling approach allowed not only identification of zones but synthesis of the observed pattern of landscape degradation. The paper highlights the need for combining remote sensing, biophysical and socio-economic data in environmental degradation studies in developing countries with their poor data availability. The role of developing countries scientists is stressed in taking the forefront to tackle environmental problems, which affect their region. The paper calls for increased co-operation between these scientists and regional and international data providers to overcome data availability problems and pave the way for better local and regional studies on environmental degradation.     

Methodological Advances in the Spatial Analysis of Land Fragmentation

This article evaluates the effect of moving window (MW) size on observed fragmentation spatial patterns and proposes a method to identify an effective MW size using Simpson's diversity index. To test the robustness of the proposed method, we demonstrate its use in six cities in the Phoenix metropolitan area that have substantial variation in land composition and configuration. Next we explore the effects of gradient observation scale and the role of scale in removing noise. We compare and discuss two popular approaches to measuring urban-to-rural fragmentation gradients—concentric ring- and transect-based approaches—highlighting the usefulness of each approach in an extensive and rapidly urbanizing region. This study provides a new method for selecting window size, offers insights on scale effects, and provides guidance on gradient scale selection to achieve the best representation of land fragmentation patterns for urban analysis.     

The missing half of the subduction factory: shipboard results from the Izu rear arc,IODP Expedition 350

IODP Expedition 350 was the first to be drilled in the rear part of the Izu-Bonin, although several sites had been drilled in the arc axis to fore-arc region; the scientific objective was to understand the evolution of the Izu rear arc, by drilling a deep-water volcaniclastic section with a long temporal record (Site U1437). The Izu rear arc is dominated by a series of basaltic to dacitic seamount chains up to ~100-km long roughly perpendicular to the arc front. Dredge samples from these are geochemically distinct from arc front rocks, and drilling was undertaken to understand this arc asymmetry. Site U1437 lies in an ~20-km-wide basin between two rear arc seamount chains, ~90-km west of the arc front, and was drilled to 1804 m below the sea floor (mbsf) with excellent recovery. We expected to drill a volcaniclastic apron, but the section is much more mud-rich than expected (~60%), and the remaining fraction of the section is much finer-grained than predicted from its position within the Izu arc, composed half of ashes/tuffs, and half of lapilli tuffs of fine grain size (clasts <3 cm). Volcanic blocks (>6.4 cm) are only sparsely scattered through the lowermost 25% of the section, and only one igneous unit was encountered, a rhyolite peperite intrusion at ~1390 mbsf. The lowest biostratigaphic datum is at 867 mbsf (~6.5 Ma), the lowest palaeomagnetic datum is at ~1300 mbsf (~9 Ma), and the rhyolite peperite at ~1390 mbsf has yielded a U–Pb zircon concordia intercept age of (13.6 + 1.6/?1.7) Ma. Both arc front and rear arc sources contributed to the fine-grained (distal) tephras of the upper 1320 m, but the coarse-grained (proximal) volcaniclastics in the lowest 25% of the section are geochemically similar to the arc front, suggesting arc asymmetry is not recorded in rocks older than ~13 Ma.     

Evidence for climatic and hillslope‐aspect controls on vadose zone hydrology and implications for saprolite weathering

Through the delivery of water in snowmelt, climate should govern the rate and extent of saprolite formation in snow‐dominated mountain watersheds, yet the mechanisms by which water flows deeply into regolith are largely unexplored. In this study we link rainfall, snow depth, and water content data from both soil and shallow saprolite to document vadose zone dynamics in two montane catchments over 2 years. Measurements of snow pack thickness and soil moisture reveal strong contrasts between north‐ and south‐facing slopes in both the timing of meltwater delivery and the duration of significant soil wetting in the shallow vadose zone. Despite similar magnitudes of snowmelt recharge, north‐facing slopes have higher sustained soil moisture compared to south‐facing slopes. To help interpret these observations, we use a 2D numerical model of vadose zone dynamics to calculate the expected space–time moisture patterns on an idealized hillslope under two wetting scenarios: a single sustained recharge pulse versus a set of short pulses. The model predicts that the duration of the recharge event exerts a stronger control on the depth and residence time of water in the upper unsaturated zone than the magnitude of the recharge event. Model calculations also imply that water should move more slowly through the subsurface and downward water flux should be substantially reduced when water is applied in several pulses rather than in one sustained event. The results suggest that thicker soil and more deeply weathered rock on north‐facing slopes may reflect greater water supply to the deep subsurface. Copyright © 2015 John Wiley & Sons, Ltd.