Assessing cadmium risk in wheat grain using soil threshold values

At present, the prior-established threshold values are widely used to classify contaminated agricultural soils with heavy metals under the cultivation of a variety of crops, without considering the different sensitivity of plants to heavy metals. Evaluation of the characteristics of cadmium transfer from a polluted calcareous soil to cultivated wheat crop and assessment of the efficiency of using the threshold values to reflect the soil pollution risk by cadmium in Zanjan Zinc Town area at the northwest of Iran were the goals of this study. Totally, 65 topsoil (0–20 cm) and corresponding wheat samples of an agricultural region in the proximity of a metallurgical factory were collected and analyzed for cadmium concentration. The results revealed that industrial activities strongly control cadmium distribution in the studied soils. Relatively high bioavailable cadmium contents (mean 0.77 mg kg^?1) were found in the soils, notwithstanding their alkalinity. It was observed that just 22.5% of the studied area around the Zinc Town is covered by polluted soils with the cadmium concentration exceeding the maximum permissible concentration of 5 mg kg^?1, whereas cadmium concentration in wheat grains of 19 sampled plants is higher than the threshold value of 0.2 mg kg^?1. Among these polluted plants, a total of eight samples were grown in areas classified as unpolluted soils with cadmium, based on the soil threshold value. It seems that this misclassification of polluted soils is mainly related to the crop sensitivity to heavy metals uptake from the soil which should be considered.     

Determining the Gravitational Gradient Tensor Using Satellite-Altimetry Observations over the Persian Gulf

With the advent of satellite altimetry in 1973, new scientific applications became available in oceanography, climatology, and marine geosciences. Moreover, satellite altimetry provides a significant source of information facilitated in the geoid determination with a high accuracy and spatial resolution. The information from this approach is a sufficient alternate for marine gravity data in the high-frequency modeling of the marine gravity field quantities. The gravity gradient tensor, consisting of the second-order partial derivatives of the gravity potential, provides more localized information than gravity measurements. Marine gravity observations always carry a high noise level due to environmental effects. Moreover, it is not possible to model the high frequencies of the Earth's gravity field in a global scale using these observations. In this article, we introduce a novel approach for a determination of the gravity gradient tensor at sea level using satellite altimetry. Two numerical techniques are applied and compared for this purpose. In particular, we facilitate the radial basis functions (RBFs) and the harmonic splines. As a case study, the gravitational gradient tensor is determined and results presented in the Persian Gulf. Validation of results reveals that the solution of the harmonic spline approach has a better agreement with a theoretical zero-value of the trace of the Marussi gravitational gradient tensor. However, the data-adaptive technique in the RBF approach allows more efficient selection of the parameters and 3-D configuration of RBFs compared to a fixed parameterization by the harmonic splines.     

Clear-water scour around semi-elliptical abutments with armored beds

Experimental study has been carried out under a clear-water scour condition to explore the local scour around semi-elliptical model bridge abutments with armor-layer bed, compared with the local scour process around semi-circular abutment. Two types of model bridge abutments, namely semi-elliptical and semi-circular abutments have been used in this experimental study. The model abutments had a ratio of streamwise length of abutment to the length of abutment transverse to the flow of 2 for semi-circular abutments and 3 for semi-elliptical abutments. In total, 50 Experiments have been designed and conducted under different flow conditions such as bed shear velocities, flow depth, and dimensions of bridge abutment model, as well as grain size of the bed material. Based on these experiments, the scour process around bridge abutments has been assessed. The dependence of the equilibrium scour depth of the scour hole on hydraulic variables has been studied. Empirical equation describing the equilibrium scour depth of the scour hole around bridge abutments has been developed.     

Multigene genetic programming for sediment transport modeling in sewers for conditions of non-deposition with a bed deposit

It is known that construction of large sewers based on consideration of flow with non-deposition without a bed deposit is not economical. Sewer design based on consideration of flow with non-deposition with a bed deposit reduces channel bed slope and construction cost in which the presence of a small depth of sediment deposition on the bed increases the sediment transport capacity of the flow. This paper suggests a new Pareto-optimal model developed by the multigene genetic programming (MGGP) technique to estimate particle Froude number (Fr_p) in large sewers with conditions of sediment deposition on the bed. To this end, four data sets including wide ranges of sediment size and concentration, deposit thickness, and pipe size are used. On the basis of different statistical performance indices, the efficiency of the proposed Pareto-optimal MGGP model is compared to those of the best MGGP model developed in the current study as well as the conventional regression models available in the literature. The results indicate the higher efficiency of the MGGP-based models for Fr_p estimation in the case of no additional deposition onto a bed with a sediment deposit. Inasmuch as the Pareto-optimal MGGP model utilizes a lower number of input parameters to yield comparatively higher performance than the conventional regression models, it can be used as a parsimonious model for self-cleansing design of large sewers in practice.     

Synergic Impacts of Two Non-ionic Natural Surfactants and Low Salinity Water on Interfacial Tension Reduction,Wettability Alteration and Oil Recovery: Experimental Study on Oil Wet Carbonate Core Samples

Natural Resources Research - Low salinity water (LSW) flooding alters rock surface wettability toward more water wetness, and consequently, oil recovery will be increased from a carbonate oil...     

The Maastrichtian-Danian in the SW Zagros Fold-Thrust Belt (S. Iran): An Integration of Planktonic Foraminiferal Biostratigraphy and Gamma-Ray Spectrometry

In this study, the Maastrichtian-Danian boundary was measured and sampled in two stratigraphic sections, the north and south flanks of the Dehnow anticline in Coastal Fars, Southern Iran. This boundary was also investigated in the drilled exploratory well-1 in the same region. The lithology of the Maastrichtian-Danian deposits consists of glauconitic, phosphatic argillaceous limestones and marlstones. 30 genera and 77 species of planktonic foraminifera have been determined. The recognized biozon...     

Chelate-assisted phytoextraction of cadmium from a mine soil by negatively charged sunflower

The effects of some chelating agents and electricity on cadmium phytoextraction from a mine soil were examined in pot culture of sunflower to achieve more remediation efficiency. At the beginning of the flowering stage, ethylene-diamine-tetra-acetic acid (EDTA) as a chemical chelator, cow manure extract (CME) and poultry manure extract (PME) as organic chelators were applied (2 g kg^?1 soil) during irrigation. Seven days later, Helianthus annuus was negatively charged by inserting a stainless steel needle in the lowest part of the stem with 10 and 30 V direct current electricity for 1 h each day for 14 days. Afterward, concentration of cadmium in roots and shoots, cadmium translocation factor (TF), cadmium uptake index (UI) and soil available (diethylene-triamine-penta-acetic acid extractable) cadmium were measured. Results indicated that EDTA reduced roots dry weight while none of the roots and shoots was affected by other chelating agents and by electrical treatment as well. Highest concentration of cadmium in shoots was measured in 10 V-control with no significant differences with 30 V-PME and 30 V-EDTA. Utilization of chelating agents did not increase the cadmium TF and cadmium UI while highest values for cadmium TF and cadmium UI were observed in 10 and 30 V treatments, respectively. Available cadmium in the soil near root system treated with 10 and 30 V was relatively lower compared with the soil far from root system. Results of this experiment indicated that charging the plant with direct current electricity ameliorated the efficiency of cadmium phytoremediation.     

Wind energy potential assessment using Weibull distribution with various numerical estimation methods: a case study in Mersing and Port Dickson,Malaysia

Theoretical and Applied Climatology - In this study, the Weibull distribution with various numerical estimation methods is utilized for the assessment of wind energy potential in Mersing and Port...