Simultaneous Determination of 11 Sulfonamides by HPLC–UV and Application for Fast Screening of Their Aerobic Elimination and Biodegradation in a Simple Test

Sulfonamides (SAs) are one of the most frequently used antibiotics. SAs have been found in various environmental compartments. If SAs are not degraded in the environment, they can affect bacteria by their antibiotic properties and contribute to bacterial antibiotic resistance. Therefore, the biodegradability of 11 SAs (sulfanilamide, sulfaguanidine monohydrate, sulfadiazine, sulfathiazole, sulfapyridine, sulfamerazine, sulfamethoxypyridazine, sulfachloropyridazine, sulfamethazine, sulfamethoxazole, and sulfadimethoxine) was studied. For this purpose, the Closed Bottle Test (CBT, OECD 301D) was performed, which includes a toxicity control. In order to monitor the environmental fate of the parent compound and to check for transformation products, a simple, efficient, and reliable HPLC–UV method for the simultaneous determination of these SAs has been developed. Acetonitrile and water (with 0.1% formic acid) were used as mobile phase solvents for gradient elution. The method was validated in terms of precision, detection and quantitation limits, selectivity, and analytical solution stability. In the CBT, none of these SAs was readily biodegradable. The HPLC–UV analysis confirmed that no degradation of any SA took place. In the toxicity control, these SAs showed no toxic effect in the used concentration of environmental bacteria applied in the test.     

Stratigraphy of the Cenomanian–Turonian Oceanic Anoxic Event OAE2 in shallow shelf sequences of NE Egypt

Two shallow water late Cenomanian to early Turonian sequences of NE Egypt have been investigated to evaluate the response to OAE2. Age control based on calcareous nannoplankton, planktic foraminifera and ammonite biostratigraphies integrated with δ¹³C stratigraphy is relatively good despite low diversity and sporadic occurrences. Planktic and benthic foraminiferal faunas are characterized by dysoxic, brackish and mesotrophic conditions, as indicated by low species diversity, low oxygen and low salinity tolerant planktic and benthic species, along with oyster-rich limestone layers. In these subtidal to inner neritic environments the OAE2 δ¹³C excursion appears comparable and coeval to that of open marine environments. However, in contrast to open marine environments where anoxic conditions begin after the first δ¹³C peak and end at or near the Cenomanian–Turonian boundary, in shallow coastal environments anoxic conditions do not appear until the early Turonian. This delay in anoxia appears to be related to the sea-level transgression that reached its maximum in the early Turonian, as observed in shallow water sections from Egypt to Morocco.     

New ophiolite occurrences in Sudan and constraint on the western boundary of the Nubian Shield: Petrographical and geochemical evidence

Important mafic–ultramafic masses have been located for the first time in the intersection area between the Keraf Shear Zone and the Nakasib Suture Zone of the Nubian Shield. The masses, comprising most of the members of the ophiolite suite, are Sotrebab and Qurun complexes east of the Nile, and Fadllab complex west of the Nile. The new mafic–ultramafic masses are located on the same trend of the ophiolitic masses decorating the Nakasib Suture. A typical complete ophiolite sequence has not been observed in these complexes, nevertheless, the mafic–ultramafic rocks comprise basal unit of serpentinite and talc chlorite schists overlain by a thick cumulate facies of peridotites, pyroxenites and layered gabbros overlain by basaltic pillow lavas with dolerite dykes and screens of massive gabbros. Associated with pillow lavas are thin layers of carbonates and chert. The best section of cumulate mafic–ultramafic units has been observed in Jebel Qurun and El Fadlab complexes, comprising peridotites, pyroxenites and layered gabbros. Dolerite dykes and screens of massive gabbros have been observed with basaltic pillow lava sections in Wadi Dar Tawaiy. The basal ultramafic units of the complexes have been fully or partly retrograded to chlorite magnetite schist and talc to talc-carbonate rocks (listowenites), especially in the Jebel Qurun and Sotrebab complexes. Petrographically, the gabbros (layered and massive) and the basaltic pillow lavas show mineral assemblages of epidote amphibolite facies. The mafic members from the three complexes show a clear tholeiitic trend and oceanic floor affinity. The pillow lavas plot in the field of oceanic floor basalt, namely in the back arc field. Primitive mantle normalized spider diagram of the pillow lavas reveals a closer correspondence to Enrich-Mid-Oceanic Ridge Basalt (E-MORB) type, which is confirmed by the flat chondrite normalized Rare Earth Elements (REE) pattern. Field, petrographical and geochemical evidence supports ophiolitic origin of the three complexes. The newly discovered ophiolitic complexes mark the western continuation of the Nakasib Suture Zone.     

Hydrogeophysical investigation of groundwater potential in the El Bawiti, Northern Bahariya Oasis, Western Desert, Egypt

The future development of agriculture, industry, and civil activity planned to be in the Western Desert. This strategy need to the groundwater resource. Vertical electrical soundings (VES) and electromagnetic (TEM) measurements conducted in the El Bawiti, northern Bahariya Oasis. The measurements give detailed information about the geometry of the different hydrogeological layers in the aquifer system and depth to them. A total of 22 VES and TEM were carried out within El Bawiti area. Thirty-one sub soil samples were collected from eight sites to determine the chemical characteristics and address the effects of lithogenic source and anthropogenic activity on them. The geoelectrical measurements and borehole information indicate the presence of five geoelectrical units, from top to base; the surface cover, sand and shale, upper aquifer (Nubian sandstone), sand and shale, and lower aquifer (Nubian sandstone). Surface cover was equally distributed in thickness and composed of dry sand, gravel, and clay deposits. The regional resistivity of the upper aquifer increased in the southwestern part and decline in the northern, eastern, southern, and western parts. The decline in the resistivity reflects the high water yields and potentiality, as well as low salinity. The resistivity of the lower aquifer increased due the northwestern part and the southwestern part. The information collected during this research provides valuable data for estimating the fresh- to brackish-water resources and for development of a groundwater management plan. The integrated analyses carried out represent a significant and cost-effective method for delineating the main aquifer in this area. In turn, future well locations can be placed with more confidence than before, in accordance with the evaluation of the potentiality of the groundwater aquifers in the area. The electrical conductivity of the soil ranges from 302 to 8,490 μS/cm, increases in the western and central-northern parts. It is attributed to the location from the salt-affected soils (playa), the relatively lower elevation units (depressions) and the position in landscape in the Oasis. Sodium adsorption ratio ranges from 0.44 to 11 and the exchangeable sodium ratio ranges from 0.11 to 5. The estimated magnesium hazard fluctuated below 50%. The statistical analyses were accomplished in soil chemistry and discussed.     

Delivery and deposition of organic matter in surface sediments of Lagoa do Caçó (Brazil)

Elemental and isotopic compositions of organic matter in surficial sediments from five transects across Lagoa do Caçó (Brazil) were analyzed to identify the depth-related processes that affect the production and deposition of sedimentary organic matter in this shallow tropical lake. Each of four transverse transects began at a margin dominated by aquatic macrophytes (Eleocharis), crossed the central deep part of the lake, and terminated in the opposite, macrophyte-dominated margin. In each transect, TOC concentrations, C/N ratios, and δ¹³C values decreased between 0 and 4 m, whereas δ¹⁵N values increased. The variables remained stable in sediment from 4 m water depth to the center of the lake at 10 m. The depth-related patterns reflect differences in both the delivery and the deposition of organic matter in the lake. Organic matter is produced in abundance in the marginal area by emersed and submerged macrophyte vegetation that diminishes with depth and disappears at 4 meters. After the disappearance of macrophytes, organic matter is produced at low rates principally by open-lake phytoplankton. Drawdown of dissolved oxygen is high in the lake margins, but it is low in the oligotrophic open waters of the lake. Preservation of organic matter is consequently better in sediments of the lake margins than in deep waters. The depth-related pattern of organic matter delivery and deposition in the sediments of Lagoa do Caçó, in which water levels are sensitive to groundwater fluctuations, shows that the elemental and isotopic compositions of sediment organic matter can provide a record of changes in the paleohydrology of this and other similar shallow lake systems.     

Removal of heavy metal ions from aqueous solutions with multi-walled carbon nanotubes: Kinetic and thermodynamic studies

Multi-walled carbon nanotubes were used successfully for the removal of Copper(II), Lead(II), Cadmium(II), and Zinc(II) from aqueous solution. The results showed that the % adsorption increased by raising the solution temperature due to the endothermic nature of the adsorption process. The kinetics of Cadmium(II), Lead(II), Copper(II), and Zinc(II) adsorption on Multi-walled carbon nanotubes were analyzed using the fraction power function model, Lagergren pseudo-first-order, pseudo-second-order, and Elovich models, and the results showed that the adsorption of heavy metal ions was a pseudo-second-order process, and the adsorption capacity increased with increasing solution temperature. The binding of the metal ions by the carbon nanotubes was evaluated from the adsorption capacities and was found to follow the following order: Copper(II) > Lead(II) > Zinc(II) > Cadmium(II). The thermodynamics parameters were calculated, and the results showed that the values of the free energies were negative for all metals ions, which indicated the spontaneity of the adsorption process, and this spontaneity increased by raising the solution temperature. The change in entropy values were positives, indicating the increase in randomness due to the physical adsorption of heavy metal ions from the aqueous solution to the carbon nanotubes’ surface. Although the enthalpy values were positive for all metal ions, the free energies were negative, and the adsorption was spontaneous, which indicates that the heavy metal adsorption of Multi-walled carbon nanotubes was an entropy-driving process.     

Factors controlling mechanisms of groundwater salinization and hydrogeochemical processes in the Quaternary aquifer of the Eastern Nile Delta, Egypt

In this study, combining interpretations of conservative dissolved ions and environmental isotopes in water were used to investigate the main factors and mechanisms controlling groundwater salinization and hydrogeochemical processes in the Eastern Nile Delta, Egypt. Hydrogeochemical and isotopic study has been carried out for 61 water samples from the study area. Total dissolved solid (TDS) contents of groundwater are highly variable rising along flowpath from the south (410 mg/L) to the north (14,784 mg/L), implying significant deterioration and salinization of groundwater. Based on TDS and ionic ratios, groundwater samples were classified into three groups. In low-saline groups, water chemistry is greatly influenced by cation exchange, mineral dissolution/precipitation, anthropogenic pollutants and mixing with surface water. Whilst, in high-saline groups, water chemistry is affected by salt-water intrusion, reverse cation exchange and evaporation. The chemical constituents originating from saline water sources, reverse ion exchange and mineral dissolution are successfully differentiated using ionic delta and saturation index approaches. The δ¹⁸O–δ²H relationship plots on a typical evaporation line, suggesting potential evaporation of the recharging water prior to infiltration. Isotope evidence concludes that the groundwater have been considerably formed by mixing between depleted meteoric water recharged under different climatic conditions and recently infiltrating enriched surface water and excess of irrigation water. The δ¹⁸O data in conjunction with chloride concentrations provide firm evidence for impact of dissolution of marine-origin evaporite deposits, during past geologic periods, on groundwater salinity in the northern region. Moreover, the relation between ¹⁴C activities and Cl^? concentration confirms this hypothesis.     

Complex impact assessment of coastal development in the United Arab Emirates using GIS: a case study of Wurayah Biosphere Reserve

Wadi Wurayah area is one of the major wadis originating and running on the Oman Mountains and drains into the Oman Gulf. These wadis in general and Wadi Wurayah in particular are characterized with a rich diversity of rare and mountainous and freshwater habitats and species. These wadis contain unequal, representative, and sensitive areas of the dry lands ecosystem with natural, outstanding landscapes and cultural heritage, while the socioeconomic situation indicates that it has enough socioeconomic infrastructures to develop new alternatives ecologically and economically sustainable. As most of the United Arab Emirates and the region, the study area is undergoing dramatic changes linked to economic diversification and promotion of tourism. Established under the UNESCO’s Man and the Biosphere Program, Wurayah Biosphere Reserve represents protected areas intended to demonstrate well-balanced relationship between conservation of biodiversity and an appropriate local development. The main objectives of this study are to develop an environmental information system to understand the dynamics of human activities associated to land use in the study area, highlight the threats to the environment, educate people about the basic environmental issues and positive traditional practices, and promote tourism. Based on the gained results, the concept of biosphere reserve as a model is to implement ideas of sustainable land use in practice.     

Use of satellite data and GIS for assessing the agricultural potentiality of the soils South Farafra Oasis, Western Desert, Egypt

Overpopulation and food security are the main global problems alert decision makers. In developing countries, such problem put extra pressure for horizontal expansion for agricultural development. The rapid sprawl of urbanized areas on the alluvial land of the River Nile and delta to accommodate the population growth has encouraged governmental and private sector for agricultural expansion in the desert. Unless there are reliable information and accurate studies for land and soil suitability, there will be a collapse of such investment. To evaluate the potential suitability of soil for agriculture development in areas of the western desert, satellite images, geographic information, and field survey including soil profiles and artesian water samples with laboratory analysis were integrated to classify the soils according their suitability for specific crop. The main land qualities of the different mapping units and the crop requirement were rated and matched to obtain the current and potential land suitability using Automated Land Evaluation System “ALES”. The study found that the main physiographic units are plateaus, hilland, mountain, and depression floor. But there are three limiting parameters for land suitability which are the lack of nutrient elements, wind erosion vulnerability, and soil texture. The study concluded that the best crops adapted with the soil conditions and could be feasible for economic use are: (1) native vegetation such as agol, sand trees, sammar, halfaa, bawaal, qordaob, bardi, and qortom; (2) filed crops such as onion, garlic, watermelon and wheat; and (3) fruits such as olive and date palms.