Thermodynamic controls on element partitioning between titanomagnetite and andesitic–dacitic silicate melts

Titanomagnetite–melt partitioning of Mg, Mn, Al, Ti, Sc, V, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Hf and Ta was investigated experimentally as a function of oxygen fugacity (fO₂) and temperature (T) in an andesitic–dacitic bulk-chemical compositional range. In these bulk systems, at constant T, there are strong increases in the titanomagnetite–melt partitioning of the divalent cations (Mg²⁺, Mn²⁺, Co²⁺, Ni²⁺, Zn²⁺) and Cu²⁺/Cu⁺ with increasing fO₂ between 0.2 and 3.7 log units above the fayalite–magnetite–quartz buffer. This is attributed to a coupling between magnetite crystallisation and melt composition. Although melt structure has been invoked to explain the patterns of mineral–melt partitioning of divalent cations, a more rigorous justification of magnetite–melt partitioning can be derived from thermodynamic principles, which accounts for much of the supposed influence ascribed to melt structure. The presence of magnetite-rich spinel in equilibrium with melt over a range of fO₂ implies a reciprocal relationship between a(Fe²⁺O) and a(Fe³⁺O_1.5) in the melt. We show that this relationship accounts for the observed dependence of titanomagnetite–melt partitioning of divalent cations with fO₂ in magnetite-rich spinel. As a result of this, titanomagnetite–melt partitioning of divalent cations is indirectly sensitive to changes in fO₂ in silicic, but less so in mafic bulk systems.     

Mechanisms of tropical precipitation biases in climate models

Climate Dynamics - We investigate the possible causes for inter-model spread in tropical zonal-mean precipitation pattern, which is divided into hemispherically symmetric and anti-symmetric modes...     

Political orientation moderates Americans’ beliefs and concern about climate change

I offer some theoretical insights to help us better understand the moderator effect of political orientation that Larry Hamilton and others have found in recent years. Reflexive modernization theory highlights an emerging tension between those who direct attention to the negative consequences of industrial capitalism such as climate change (e.g., the scientific community and environmental organizations) and those who defend the economic system against such critiques (e.g., the conservative movement). Political divisions in the American public increasingly map onto these societal divisions between critics and defenders of the industrial capitalist order—especially for the issue of climate change. This alignment is facilitated by increased polarization among political elites and balkanization of the news media. Strong evidence of the moderator effect is consistent with the expectations of information processing theory and elite cues hypothesis from political science. Recent empirical findings in political psychology and neuroscience also seem pertinent for explaining this moderator effect. I end by outlining a few implications for climate change research and communication.     

The origin of high δ<Superscript>18</Superscript>O zircons: marbles,megacrysts, and metamorphism

The oxygen isotope ratios (δ¹⁸O) of most igneous zircons range from 5 to 8‰, with 99% of published values from 1345 rocks below 10‰. Metamorphic zircons from quartzite, metapelite, metabasite, and eclogite record δ¹⁸O values from 5 to 17‰, with 99% below 15‰. However, zircons with anomalously high δ¹⁸O, up to 23‰, have been reported in detrital suites; source rocks for these unusual zircons have not been identified. We report data for zircons from Sri Lanka and Myanmar that constrain a metamorphic petrogenesis for anomalously high δ¹⁸O in zircon. A suite of 28 large detrital zircon megacrysts from Mogok (Myanmar) analyzed by laser fluorination yields δ¹⁸O from 9.4 to 25.5‰. The U–Pb standard, CZ3, a large detrital zircon megacryst from Sri Lanka, yields δ¹⁸O = 15.4 ± 0.1‰ (2 SE) by ion microprobe. A euhedral unzoned zircon in a thin section of Sri Lanka granulite facies calcite marble yields δ¹⁸O = 19.4‰ by ion microprobe and confirms a metamorphic petrogenesis of zircon in marble. Small oxygen isotope fractionations between zircon and most minerals require a high δ¹⁸O source for the high δ¹⁸O zircons. Predicted equilibrium values of Δ¹⁸O(calcite-zircon) = 2–3‰ from 800 to 600°C show that metamorphic zircon crystallizing in a high δ¹⁸O marble will have high δ¹⁸O. The high δ¹⁸O zircons (>15‰) from both Sri Lanka and Mogok overlap the values of primary marine carbonates, and marbles are known detrital gemstone sources in both localities. The high δ¹⁸O zircons are thus metamorphic; the 15–25‰ zircon values are consistent with a marble origin in a rock-dominated system (i.e., low fluid_(external)/rock); the lower δ¹⁸O zircon values (9–15‰) are consistent with an origin in an external fluid-dominated system, such as skarn derived from marble, although many non-metasomatized marbles also fall in this range of δ¹⁸O. High δ¹⁸O (>15‰) and the absence of zoning can thus be used as a tracer to identify a marble source for high δ¹⁸O detrital zircons; this recognition can aid provenance studies in complex metamorphic terranes where age determinations alone may not allow discrimination of coeval source rocks. Metamorphic zircon megacrysts have not been reported previously and appear to be associated with high-grade marble. Identification of high δ¹⁸O zircons can also aid geochronology studies that seek to date high-grade metamorphic events due to the ability to distinguish metamorphic from detrital zircons in marble.     

Gold solubility in oxidized and reduced, water-saturated mafic melt

We have performed experiments to evaluate Au solubility in natural, water-saturated basaltic melts as a function of oxygen fugacity. Experiments were carried out at 1000 °C and 200 MPa, and oxygen fugacity was controlled at the fayalite-magnetite-quartz (FMQ) oxygen fugacity buffer and FMQ + 4. All experiments were saturated with a metal-chloride aqueous solution loaded initially as a 10 wt% NaCl eq. fluid. The stable phase assemblage at FMQ consists of basalt melt, olivine, clinopyroxene, a single-phase aqueous fluid, and metallic Au. The stable phase assemblage at FMQ + 4 consists of basalt melt, clinopyroxene, magnetite-spinel solid solution, a single-phase aqueous fluid, and metallic Au. Silicate glasses (i.e., quenched melt) and their contained crystalline material were analyzed by using both electron probe microanalysis (EPMA) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Measured Au concentrations in the quenched melt range from 4.8 μg g⁻¹ to 0.64 μg g⁻¹ at FMQ + 4, and 0.54 μg g⁻¹ to 0.1 μg g⁻¹ at FMQ. The measured solubility of Au in olivine and clinopyroxene was consistently below the LA-ICP-MS limit of detection (i.e., 0.1 μg g⁻¹). These melt solubility data place important limitations on the dissolved Au content of water-saturated, Cl- and S-bearing basaltic liquids at geologically relevant fO₂ values. The new data are compared to published, experimentally-determined values for Au solubility in dry and hydrous silicate liquids spanning the compositional range from basalt to rhyolite, and the effects of melt composition, oxygen fugacity, pressure and temperature are discussed.     

A search for amino acids and nucleobases in the Martian meteorite Roberts Massif 04262 using liquid chromatography‐mass spectrometry

The investigation into whether Mars contains signatures of past or present life is of great interest to science and society. Amino acids and nucleobases are compounds that are essential for all known life on Earth and are excellent target molecules in the search for potential Martian biomarkers or prebiotic chemistry. Martian meteorites represent the only samples from Mars that can be studied directly in the laboratory on Earth. Here, we analyzed the amino acid and nucleobase content of the shergottite Roberts Massif (RBT) 04262 using liquid chromatography‐mass spectrometry. We did not detect any nucleobases above our detection limit in formic acid extracts; however, we did measure a suite of protein and nonprotein amino acids in hot‐water extracts with high relative abundances of β‐alanine and γ‐amino‐n‐butyric acid. The presence of only low (to absent) levels of several proteinogenic amino acids and a lack of nucleobases suggest that this meteorite fragment is fairly uncontaminated with respect to these common biological compounds. The distribution of straight‐chained amine‐terminal n‐ω‐amino acids in RBT 04262 resembled those previously measured in thermally altered carbonaceous meteorites (Burton et al. 2012; Chan et al. 2012). A carbon isotope ratio of ?24‰ ± 6‰ for β‐alanine in RBT 04262 is in the range of reduced organic carbon previously measured in Martian meteorites (Steele et al. 2012). The presence of n‐ω‐amino acids may be due to a high temperature Fischer‐Tropsch‐type synthesis during igneous processing on Mars or impact ejection of the meteorites from Mars, but more experimental data are needed to support these hypotheses.     

Harvest patterns and effort dynamics of indigenous and non-indigenous commercial sectors of the eastern Torres Strait reef line fishery

The reef line fishery (RLF) in eastern Torres Strait (ETS) is unique in that it has both a commercial indigenous sector and a commercial non-indigenous sector. Recently, concerns have been expressed by all stakeholders about the long-term sustainability of the fishery. These concerns have been exacerbated by the lack of detailed catch and effort information from both sectors, which has precluded any formal assessment of the fishery. In this paper, we characterise the harvest patterns and effort dynamics of the indigenous and non-indigenous commercial sectors of the ETS RLF using a range of data sources including commercial logbooks, community freezer records, voluntary logbooks and observer surveys. We demonstrate that bycatch is a significant component of the catch for both sectors and identify substantial differences in harvest patterns and effort dynamics between the sectors. Differences between sectors were observed in species composition and spatial and temporal patterns in catch, effort and catch per unit effort. These results highlight the inherent variation in catch and effort dynamics between the two commercial sectors of the ETS RLF and provide valuable information for the development of future assessments and appropriate management strategies for the fishery. The more reliable estimates of harvest patterns and effort dynamics for both sectors obtained from observer surveys will also assist in resolving issues relating to allocation of reef fish resources in Torres Strait.     

Late Tertiary paleoclimatic interpretation from lacustrine rhythmites in the Gray Fossil Site,northeastern Tennessee,USA

The Gray Fossil Site (GFS) includes a small (<2 ha) paleosinkhole lake fill with an exceptionally well-preserved record of sedimentation and fossils from the latest Miocene to earliest Pliocene. The uppermost lacustrine stratigraphy is characterized by rhythmites that regularly alternate between coarse-grained and organic-rich (A) laminae and fine-grained, silty clay (B) laminae. Both the A and B components are almost exclusively comprised of exogenic sediment (including organic matter). Periodicities of 24 and 4.4 are recorded within a continuous 96 interpreted year sequence of rhythmite sediment. In a small lake with a poorly oxygenated bottom, the presence of laterally continuous laminated sediment that includes well-known periodicities in rhythmite thickness is interpreted as representing annually generated varves that correspond to seasonal variations in sedimentation. The distinctly larger fraction of medium sand-size quartz grains present within the A laminae, as well as the abrupt transitions between A and B components suggest that the rhythmites represent deposition during alternating high-energy and lower-energy seasons, which is consistent with a monsoonal precipitation pattern. The seasonal climate may relate to changes in the ocean circulation pattern prior to 4.6 Ma that resulted in an increased temperature and atmospheric pressure gradient between the east coast of North America and the Atlantic Ocean, but this climate phase seems to be only a temporary condition, as underlying and overlying sediment are both consistent with drier conditions. The periodicity at 24 interpreted years is consistent with the well-known Hale solar cycle. The 4.4 interpreted-year periodicity occurs within the ENSO frequency band, and if this documentation of ENSO-like interannual climate change is correct, then it suggests that ENSO operated at times during the warm Earth conditions characterizing the late Tertiary.     

The formation of headland/island sandbanks

There are four extensive sandbanks in the vicinity of the Isle of Portland, a headland in the English Channel. The formation and maintenance of the two most prominent of these sandbanks (one on either side of the headland) can largely be explained by net bedload convergence, driven by instantaneous headland eddies generated by tidal flow past the headland. However, there are also two less prominent sandbanks (again, one on either side of the headland), which are not located in zones of bedload convergence. It is suggested here that these latter two sandbanks were formed when the Isle of Portland was isolated from the mainland by a tidal strait. Relative sea-level data and radiocarbon dates indicate that this would have occurred ca. 9–7 ka BP, prior to the closure of the strait by sedimentation. Tidal flow through this strait generated eddy systems in addition to the headland eddies, leading to the formation of associated headland/island sandbanks. At 7 ka BP, sedimentation resulted in closure of the strait, leading to the present-day headland configuration, and subsequent reworking of these now moribund sandbanks formed by the strait. A series of idealised morphological model experiments, parameterised using bedrock depths and glacial isostatic adjustment model output of relative sea level, are here used to simulate this hypothesised sequence of sandbank evolution over the Holocene. The results of the model experiments are corroborated by in situ observations of bedforms and sediment characteristics, and by acoustic Doppler current profiler (ADCP) data applied to predictions of bedload transport over the sandbanks. In addition to demonstrating the mechanism which leads to the formation of sandbanks by tidal flow through a strait, the model results show that upon subsequent closure of such a strait, these sandbanks will no longer be actively maintained, in contrast to sandbanks which are continuously maintained by headland eddies.