Radium mass-balance in Jamaica Bay, NY: Evidence for a substantial flux of submarine groundwater

A mass balance for the naturally-occurring radium isotopes (²²⁴Ra, ²²³Ra, ²²⁸Ra, and ²²⁶Ra) in Jamaica Bay, NY, was conducted by directly estimating the individual Ra contributions of wastewater discharge, diffusion from fine-grained subtidal sediments, water percolation through marshes, desorption from resuspended particles, and water exchange at the inlet. The mass balance revealed a major unknown source term accounting for 19–71% of the total Ra input, which could only be resolved by invoking a source from submarine groundwater. Shallow (< 2 m depth) groundwater from permeable sediments in Jamaica Bay was brackish and enriched in Ra relative to surface bay waters by over two orders of magnitude. To balance Ra fluxes, a submarine groundwater input of 0.8 × 10⁹–9.0 × 10⁹ L d^− 1 was required. This flux was similar for all four isotopes, with individual estimates varying by less than a factor of 2. Our calculated groundwater flux was 6- to 70-fold higher than the fresh groundwater discharge to the bay estimated by hydrological methods, but closely matched direct flow rates measured with seepage meters. This suggests that a substantial portion of the discharge consisted of recirculated seawater. The magnitude of submarine groundwater discharge varied seasonally, in the order: summer > autumn > spring. Chemical analyses suggest that the recirculated seawater component of submarine groundwater delivers as much dissolved nitrogen to the bay as the fresh groundwater flux.     

Socioeconomic dynamics of the Ghanaian tuna industry: a value-chain approach to understanding aspects of global fisheries

This study investigated how an industrial tuna fishery functions in terms of procedures, practices, governance and finance in the context of Ghana, West Africa. Tuna is Ghana’s biggest seafood export, contributing significantly to the domestic fisheries sector. A case-study approach was used to analyse relevant social and economic factors at the local scale to better understand how the global seafood industry operates in a low-income country. A value-chain framework was adopted to assess market structures, sales pathways and revenue distribution. We also investigated the role of actors engaged in the industry using secondary data, interviews, questionnaires and participant observations. The results revealed a changing organisational structure in tuna production, moving from bait-boat fishing with smaller companies to large-scale purse-seine fishing backed by consolidated Asian seafood companies. Production was found to depend significantly on local female intermediaries for access to funds through prefinancing arrangements. Considerable illegalities were identified within the value chain, highlighting the need for improved partnership and licensing negotiations, and for low-cost marine control and surveillance tools. As vertical integration increases within the industry, the influence of corporations as keystone actors becomes evident for the future social and ecological sustainability of the industry.     

Dynamical lifetime survey of geostationary transfer orbits

In this paper, we study the long-term dynamical evolution of highly elliptical orbits in the medium-Earth orbit region around the Earth. The real population consists primarily of Geosynchronous Transfer Orbits (GTOs), launched at specific inclinations, Molniya-type satellites and related debris. We performed a suite of long-term numerical integrations (up to 200 years) within a realistic dynamical model, aimed primarily at recording the dynamical lifetime of such orbits (defined as the time needed for atmospheric reentry) and understanding its dependence on initial conditions and other parameters, such as the area-to-mass ratio (A / m). Our results are presented in the form of 2-D lifetime maps, for different values of inclination, A / m, and drag coefficient. We find that the majority of small debris (\(>70\%\), depending on the inclination) can naturally reenter within 25–90 years, but these numbers are significantly less optimistic for large debris (e.g., upper stages), with the notable exception of those launched from high latitude (Baikonur). We estimate the reentry probability and mean dynamical lifetime for different classes of GTOs and we find that both quantities depend primarily and strongly on initial perigee altitude. Atmospheric drag and higher A / m values extend the reentry zones, especially at low inclinations. For high inclinations, this dependence is weakened, as the primary mechanisms leading to reentry are overlapping lunisolar resonances. This study forms part of the EC-funded (H2020) “ReDSHIFT” project.     

Evaluation of Hydraulic Conductivity Estimates from Various Approaches with Groundwater Flow Models

Significant efforts have been expended for improved characterization of hydraulic conductivity (K) and specific storage (S_s) to better understand groundwater flow and contaminant transport processes. Conventional methods including grain size analyses (GSA), permeameter, slug, and pumping tests have been utilized extensively, while Direct Push-based Hydraulic Profiling Tool (HPT) surveys have been developed to obtain high-resolution K estimates. Moreover, inverse modeling approaches based on geology-based zonations, and highly parameterized Hydraulic Tomography (HT) have also been advanced to map spatial variations of K and S_s between and beyond boreholes. While different methods are available, it is unclear which one yields K estimates that are most useful for high resolution predictions of groundwater flow. Therefore, the main objective of this study is to evaluate various K estimates at a highly heterogeneous field site obtained with three categories of characterization techniques including: (1) conventional methods (GSA, permeameter, and slug tests); (2) HPT surveys; and (3) inverse modeling based on geology-based zonations and highly parameterized approaches. The performance of each approach is first qualitatively analyzed by comparing K estimates to site geology. Then, steady-state and transient groundwater flow models are employed to quantitatively assess various K estimates by simulating pumping tests not used for parameter estimation. Results reveal that inverse modeling approaches yield the best drawdown predictions under both steady and transient conditions. In contrast, conventional methods and HPT surveys yield biased predictions. Based on our research, it appears that inverse modeling and data fusion are necessary steps in predicting accurate groundwater flow behavior.     

Concurrent Treatment of 1,4‐Dioxane and Chlorinated Aliphatics in a Groundwater Recirculation System Via Aerobic Cometabolism

This research demonstrates that groundwater contaminated by a relatively dilute but persistent concentration of 1,4‐dioxane (1,4‐D), approximately 60 μg/L, and chlorinated aliphatic co‐contaminants (1.4 to 10 μg/L) can be efficiently and reliably treated by in situ aerobic cometabolic biodegradation (ACB). A field trial lasting 265 days was conducted at Operable Unit D at the former McClellan Air Force Base and involved establishing an in situ ACB reactor through amending recirculated groundwater with propane and oxygen. The stimulated indigenous microbial population was able to consistently degrade 1,4‐D to below 3 μg/L while the co‐contaminants trichloroethene (TCE) and 1,2‐dichloroethane (1,2‐DCA) were decreased to below 1 μg/L and 0.18 μg/L, respectively. A stable treatment efficiency of more than 95% removal for 1,4‐D and 1,2‐DCA and of more than 90% removal for TCE was achieved. High treatment efficiencies for 1,4‐D and all co‐contaminants were sustained even without propane and oxygen addition for a 2‐week period.     

Performance Assessment of Pump‐and‐Treat Systems

Pump‐and‐treat (P&T) is a widely applied remedy for groundwater remediation at many types of sites for multiple types of contaminants. Decisions regarding major changes in the remediation approach are an important element of environmental remediation management for a site using P&T. While existing guidance documents provide information on design, operation, and optimization for P&T systems, these documents do not provide specific technical guidance to support remedy decisions regarding when to transition to a new remedy or to initiate closure of the P&T remedy. A structured approach for P&T performance assessment was developed and is described herein, using analysis of three example P&T systems. These examples highlight key aspects of the performance assessment decision logic and represent assessment outcomes associated with optimizing the P&T system, transitioning from P&T to natural attenuation, and supplementing P&T with another technology to hasten transition to natural attenuation.     

Fine particle transport dynamics in response to wood additions in a small agricultural stream

Wood additions to streams can slow water velocities and provide depositional areas for bacteria and fine particles (e.g., particulate organic carbon and nutrients sorbed to fine sediment), therefore increasing solute and particle residence times. Thus, wood additions are thought to create biogeochemical hotspots in streams. Added wood is expected to enhance in-stream heterogeneity, result in more complex flow paths, increase natural retention of fine particles and alter the geomorphic characteristics of the stream reach. Our aim was to directly measure the impact of wood additions on fine particle transport and retention processes. We conducted conservative solute and fluorescent fine particle tracer injection studies in a small agricultural stream in the Whatawhata catchment, North Island of New Zealand in two reaches—a control reach and a reach restored 1-year earlier by means of wood additions. Fine particles were quantified in surface water to assess reach-scale (channel thalweg) and habitat-scale (near wood) transport and retention. Following the injection, habitat-scale measurements were taken in biofilms on cobbles and by stirring streambed sediment to measure fine particles available for resuspension. Tracer injection results showed that fine particle retention was greater in the restored compared to the control reach, with increased habitat-scale particle counts and reach-scale particle retention. Particle deposition was positively correlated with cobble biofilm biomass. We also found that the addition of wood enhanced hydraulic complexity and increased the retention of solute and fine particles near the wood, especially near a channel spanning log. Furthermore, particles were more easily remobilized from the control reach. The mean particle size remobilized after stirring the sediments was ~5 μm, a similar size to both fine particulate organic matter and many microorganisms. These results demonstrate that particles in this size range are dynamic and more likely to remobilize and transport further downstream during bed mobilization events.     

Seismic markers of the Messinian salinity crisis in the deep Ionian Basin

We conduct the seismic signal analysis on vintage and recently collected multichannel seismic reflection profiles from the Ionian Basin to characterize the deep basin Messinian evaporites. These evaporites were deposited in deep and marginal Mediterranean sedimentary basins as a consequence of the “salinity crisis” between 5.97 and 5.33 Ma, a basin-wide oceanographic and ecological crisis whose origin remains poorly understood. The seismic markers of the Messinian evaporites in the deep Mediterranean basins can be divided in two end-members, one of which is the typical “trilogy” of gypsum and clastics (Lower Unit – LU), halite (Mobile Unit – MU) and upper anhydrite and marl layers (Upper Unit – UU) traced in the Western Mediterranean Basins. The other end-member is a single MU unit subdivided in seven sub-units by clastic interlayers located in the Levant Basin. The causes of these different seismic expressions of the Messinian salinity crisis (MSC) appear to be related to a morphological separation between the two basins by the structural regional sill of the Sicily Channel. With the aid of velocity analyses and seismic imaging via prestack migration in time and depth domains, we define for the first time the seismic signature of the Messinian evaporites in the deep Ionian Basin, which differs from the known end-members. In addition, we identify different evaporitic depositional settings suggesting a laterally discontinuous deposition. With the information gathered we quantify the volume of evaporitic deposits in the deep Ionian Basin as 500,000 km³ ± 10%. This figure allows us to speculate that the total volume of salts in the Mediterranean basin is larger than commonly assumed. Different depositional units in the Ionian Basin suggest that during the MSC it was separated from the Western Mediterranean by physical thresholds, from the Po Plain/Northern Adriatic Basin, and the Levant Basin, likely reflecting different hydrological and climatic conditions. Finally, the evidence of erosional surfaces and V-shaped valleys at the top of the MSC unit, together with sharp evaporites pinch out on evaporite-free pre-Messinian structural highs, suggest an extreme Messinian Stage 3 base level draw down in the Ionian Basin. Such evidence should be carefully evaluated in the light of Messinian and post-Messinian vertical crustal movements in the area. The results of this study demonstrates the importance of extracting from seismic data the Messinian paleotopography, the paleomorphology and the detailed stratal architecture in the in order to advance in the understanding of the deep basins Messinian depositional environments.     

Vertical physicochemical parameter distributions and health risk assessment for trace metals in water columns in eastern Lake Tanganyika,Tanzania

The vertical distributions of trace metals and physicochemical parameters in water columns in Kigoma Bay and Kungwe Bay in eastern Lake Tanganyika, Tanzania, were studied. The Al, Ba, Ca, Co,K, Mg, Mn, Mo, Na, Sn, Sr, and V concentrations were low and varied very little with depth. The toxic heavy metal(As, Cr, Cu, Ni, Pb, and Zn) concentrations were relatively high in the surface water, and the Cu, Ni, Pb, and Zn concentrations decreased with depth. Principal component and cluster analyses indicated that the metals in the lake had three main sources. Al, Ba, Ca, Co, Cu, Cr, Mn, Sr, Sn, and V were found to be geogenic; As, Cr, Cu, Mo, Ni, Pb, Sn and Zn anthropogenic; and As, Ca, Co, Mg, and Na biogenic.Human health risk assessments were performed, and it was found that trace metals in the water at most of the sampling sites would cause no potential adverse ef fects or non-carcinogenic health risks through dermal contact or ingestion. However, trace metals in surface water in Kungwe Bay could have certain adverse ef fects on human health through the ingestion pathway(the total hazard quotient for ingestion(ΣHQi ng)was 1.75(a value 1 was de?ned as possibly indicating adverse ef fects). The Pb HQi ng for surface water in Kungwe Bay was 1.50 and contributed 80% of the ΣHQ_(ing_, implying that Pb pollution is a water quality and safety problem that needs to be carefully monitored and the potential sources identi?ed.     

Particulate organic matter and ballast fluxes measured using time-series and settling velocity sediment traps in the northwestern Mediterranean Sea

Prompted by recent data analyses suggesting that the flux of particulate organic carbon sinking into deep waters is determined by fluxes of mineral ballasts, we undertook a study of the relationships among organic matter (OM), calcium carbonate, opal, lithogenic material, and excess aluminum fluxes as part of the MedFlux project. We measured fluxes of particulate components during Spring and Summer of 2003, and Spring of 2005, using a swimmer-excluding sediment trap design capable of measuring fluxes both in a time-series (TS) mode and in a configuration for obtaining particle settling velocity (SV) profiles. On the basis of these studies, we suggest that distinct OM–ballast associations observed in particles sinking at a depth of 200 m imply that the mechanistic basis of the organic matter–ballast association is set in the upper water column above the Twilight Zone, and that the importance of different ballast types follows the seasonal succession of phytoplankton. As in other studies, carbonate appears to enhance the flux of organic matter over opal. Particles must be at least half organic matter before their settling velocity is affected by ballast concentration. This lack of change in ballast composition with SV in particles with <40% OM content suggests that particle SV reaches a maximum because of the increasing importance of inertial drag. Relative amounts of OM and opal decrease with depth due to decomposition and dissolution; carbonates and lithogenic material contribute about the same amount to total mass, or increase slightly, throughout the water column. The high proportion of excess Al cannot be explained by its incorporation into diatom opal or reverse weathering, so Al is most likely adsorbed to particulate oxides. On shorter time scales, dust appears to increase particle flux through its role in aggregation rather than by nutrient inputs enhancing productivity. We suggest that the role of dust as a catalyst in particle formation may be a central mechanism in flux formation in this region, particularly when zooplankton fecal pellet production is low.