首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   368篇
  免费   24篇
  国内免费   4篇
测绘学   5篇
大气科学   46篇
地球物理   94篇
地质学   130篇
海洋学   30篇
天文学   60篇
综合类   3篇
自然地理   28篇
  2024年   2篇
  2023年   1篇
  2022年   3篇
  2021年   12篇
  2020年   14篇
  2019年   15篇
  2018年   18篇
  2017年   17篇
  2016年   20篇
  2015年   13篇
  2014年   22篇
  2013年   23篇
  2012年   18篇
  2011年   20篇
  2010年   22篇
  2009年   36篇
  2008年   26篇
  2007年   22篇
  2006年   12篇
  2005年   11篇
  2004年   12篇
  2003年   11篇
  2002年   6篇
  2001年   7篇
  2000年   6篇
  1999年   3篇
  1998年   3篇
  1997年   2篇
  1996年   3篇
  1995年   1篇
  1994年   2篇
  1992年   2篇
  1989年   2篇
  1988年   1篇
  1987年   1篇
  1984年   2篇
  1983年   2篇
  1981年   1篇
  1980年   1篇
  1976年   1篇
排序方式: 共有396条查询结果,搜索用时 31 毫秒
151.
Abstract

A long history of overt discrimination left an enduring racialized imprint upon the geography of the East Bay. While the benefits of a metropolitan decentralization of jobs, housing, and public investment fell to Whites, discrimination in employment and housing trapped African Americans in urban neighborhoods burdened by infrastructure encroachment and divestment. By circa 1970, overt discrimination succumbed to new, racially neutral, legal, and administrative forms, including regional planning processes. Using an environmental racism framework, we show that these new forms reproduced the existing racialized geography by means of new inequalities in representation and transportation service provision. These new regional transportation policies, like those challenged by a 2005 civil rights lawsuit, favored the mobility needs of more affluent suburbanites over those of African American East Bay bus riders. These policies, layered onto an existing racialized geography, reinforced existing inequalities by failing to address racial barriers to opportunity in the built environment. [Key words: transportation, race, segregation, Oakland]  相似文献   
152.

Background

Although uniquely capable of measuring multiple redox constituents nearly simultaneously with no or minimal sample pretreatment, voltammetry is currently underutilized in characterizing redox conditions in aquatic and terrestrial systems. Investigation of undisturbed media such as pore water requires a solid-state electrode, and such electrodes can be difficult to fabricate reproducibly. An approach to determine the concentrations of electroactive constituents using indirectly calibrated electrodes has been developed, but the protocol for and accuracy of this approach??the pilot ion method??has not been documented in detail.

Results

A detailed procedure for testing electrode quality is provided, and the application and limitations of the pilot ion method have been documented. To quantify Fe(II) and Mn(II), subtraction of non-linear baseline functions from voltammetric signals produced better calibration curves than did linear baselines, enabled lower detection limits and reliable deconvolution of overlapping signals, and was successfully applied to sediment pore water signals. We observed that electrode sensitivities often vary by tens of percent, and that the sensitivity declines over time. The ratio of calibration slopes of Mn(II) to Fe(II) varied by no more than 11% from one Hg/Au electrode to another and Fe(II) concentrations predicted by the Mn(II) pilot ion were, on average, 13% different from their actual values. However, concentration predictions by the pilot ion method were worse for less than 15???M Fe(II) (46% different on average). The ratio of calibration slopes of Mn(II) to S(?II) varied by almost 20% from one Hg/Au electrode to another, and S(?II) predicted concentrations were as much as 58% different from their actual values. These predictions of Fe(II) and S(?II) concentrations indicate that the accuracy of the pilot ion method depends on how independent calibration slope ratios are from the electrode used. At medium-to-high concentration for the ocean, naturally derived dissolved organic carbon did not significantly affect the baseline-corrected electrode response of Mn(II) and Fe(II), but did significantly affect the response of S(?II).

Conclusions

Despite their intrinsic variability, Hg/Au electrodes fabricated by hand can be used to quantify O2, S(?II), Fe(II), and Mn(II) without calibrating every electrode for every constituent of interest. The pilot ion method can achieve accuracies to within 20% or less, provided that the underlying principle??the independence of slope ratios??is demonstrated for all voltammetric techniques used, and effects of the physicochemical properties of the system on voltammetric signals are addressed through baseline subtraction.  相似文献   
153.
The scale-location specific control on vegetation distribution was investigated through continuous wavelet transforms approaches in subtropical mountain-hill region, Fujian, China. The Normalized Difference Vegetation Index (NDVI) was calculated as an indicator of vegetation greenness using Chinese Environmental Disaster Reduction Satellite images along latitudinal and longitudinal transects. Four scales of variations were identified from the local wavelet spectrum of NDVI, with much stronger wavelet variances observed at larger scales. The characteristic scale of vegetation distribution within mountainous and hilly regions in Southeast China was around 20 km. Significantly strong wavelet coherency was generally examined in regions with very diverse topography, typically characterized as small mountains and hills fractured by rivers and residents. The continuous wavelet based approaches provided valuable insight on the hierarchical structure and its corresponding characteristic scales of ecosystems, which might be applied in defining proper levels in multilevel models and optimal bandwidths in Geographically Weighted Regression.  相似文献   
154.

An array of three seafloor transponders was acoustically surveyed to centimeter precision with a deeply-towed interrogator. Measurements of two-way acoustic travel time and hydrostatic pressure made as the interrogator was towed above the array were combined in a least-squares adjustment to estimate the interrogator and transponder positions in two surveys spanning two years. No transponder displacements were expected at this site in the interior of the Juan de Fuca Plate (48?11′ N, 127?12′ W) due to the lack of active faults. This was confirmed to a precision of ±2 cm by least-squares adjustment. Marginally detectable blunders in the observations were shown to affect the transponder position estimates by no more than 3 mm, demonstrating the geometric strength of the data set. The accumulation of many hundreds of observations resulted in a significant computational burden on the least-squares inversion procedure. The sparseness of the normal matrix was exploited to reduce by a factor of 1000 the number of calculations. The acoustic survey results suggested that the near-bottom sound speed fields during the two surveys were in better agreement than inferred from yearly single-profile conductivity, temperature, and pressure (CTD) measurements.  相似文献   
155.
S K-edge XANES and Mn-, W- and Ni-XANES and EXAFS spectra of silicate glasses synthesised at 1400 °C and 1 bar with compositions in the CaO-MgO-Al2O3-SiO2-S plus MnO, NiO, or WO3 systems were used to investigate sulphur speciation in silicate glasses.S K-edge spectra comprised a composite peak with an edge between 2470 and 2471.4 eV, which was attributed to S2−, and a peak of variable height with an edge at 2480.2-2480.8 eV, which is consistent with the presence of S6+. The latter peak was attributed to sample oxidation during sample storage. W-rich samples produced an additional lower energy peak at 2469.8 eV that is tentatively attributed to the existence of S 3p orbitals hybridised with the W 5d states.Deconvolution of the composite peak reveals that the composite peak for Mn-bearing samples fits well to a model that combines three Lorentzians at 2473.1, 2474.9 and 2476.2 eV with an arctan edge step. The composite peak for W-bearing samples fits well to the same combination plus an additional Lorentzian at 2469.8 eV. The ratio of the proportions of the signal accounted for by peaks at 2473.1 and 2476.2 eV correlates with Mn:Ca molar ratios, but not with W:Ca ratios. Spectra from Ni-bearing samples were qualitatively similar but S levels were too low to allow robust quantification of peak components. Some part of the signal accounted for by the 2473.1 eV peak was therefore taken to record the formation of Mn-S melt species, while the 2469.8 peak is interpreted to record the formation of W-S melt species. The 2474.9 and 2476.2 eV peaks were taken to be dominated by Ca-S and Mg-S interactions. However, a 1:1 relationship between peak components and specific energy transitions is not proposed. This interpretation is consistent with known features of the lower parts of the conduction band in monosulphide minerals and indicates a similarity between sulphur species in the melts and the monosulphides. S-XANES spectra cannot be reproduced by a combination of the spectra of the component element monosulphides.Mn-, W- and Ni-XANES and EXAFS for synthetic glasses without sulphide exsolution did not show any sensitivity to the presence of sulphur, which is unsurprising as S:O ratios were sufficiently low that metals would be mostly co-ordinated by O. Mn EXAFS spectra were consistent with divalent Mn in 5 co-ordinated Mn-O melt species. W spectra were consistent with tetrahedrally co-ordinated hexavalent W, most likely in scheelite-like melt species, and Ni spectra were consistent with [4] co-ordinated divalent Ni. These results indicate lower co-ordinations for both W and Ni than those inferred by some previous workers. Cation co-ordination may reflect the proportion of non-bridging oxygens, which is lower in the Ca-rich and Al-poor samples investigated here than for previous studies.  相似文献   
156.
A single stem section (pluricolumnal) belonging to a post-Palaeozoic crinoid (sea lily) is reported from a small outcrop of Lower Jurassic Lias Group strata exposed in low cliff near Dunrobin Castle. This is the first Jurassic crinoid recorded from Eastern Scotland and the small fragment has enough diagnostic characters to be assigned to the species Isocrinus cf. robustus; a crinoid found commonly in the Lower Jurassic of England. The Scottish form collected has unusual morphology that is atypical of the genus.  相似文献   
157.
Zircon (ZrSiO4) is used to study impact structures because it responds to shock loading and unloading in unique, crystallographically controlled manners. One such phenomenon is the transformation of zircon to the high-pressure polymorph, reidite. This study quantifies the geometric and crystallographic orientation relationships between these two phases using naturally shocked zircon grains. Reidite has been characterized in 32 shocked zircon grains (shocked to stages II and III) using a combination of electron backscatter diffraction (EBSD) and focused ion beam cross-sectional imaging techniques. The zircon-bearing clasts were obtained from within suevite breccia from the Nördlingen 1973 borehole, close to the center of the 14.4 Ma Ries impact crater, in Bavaria, Germany. We have determined that multiple sets (up to 4) of reidite lamellae can form in a variety of non-rational habit planes within the parent zircon. However, EBSD mapping demonstrates that all occurrences of lamellar reidite have a consistent interphase misorientation relationship with the host zircon that is characterized by an approximate alignment of a {100}zircon with a {112}reidite and alignment of a {112}zircon with a conjugate {112}reidite. Given the tetragonal symmetry of zircon and reidite, we predict that there are eight possible variants of this interphase relationship for reidite transformation within a single zircon grain. Furthermore, laser Raman mapping of one reidite-bearing grain shows that moderate metamictization can inhibit reidite formation, thereby highlighting that the transformation is controlled by zircon crystallinity. In addition to lamellar reidite, submicrometer-scale granules of reidite were observed in one zircon. The majority of reidite granules have a topotaxial alignment that is similar to the lamellar reidite, with some additional orientation dispersion. We confirm that lamellar reidite likely forms via a deviatoric transformation mechanism in highly crystalline zircon, whereas granular reidite forms via a reconstructive transformation from low-crystallinity ZrSiO4 within the reidite stability field. The results of this study further refine the formation mechanisms and conditions of reidite transformation in naturally shocked zircon.  相似文献   
158.
Hazard research has made significant strides over the last several decades, answering critical questions surrounding vulnerability and recovery. Recently, resilience has come to the forefront of scholarly debates and practitioner strategies, yet there remain challenges implementing resilience in practice, the result of a complex web of research that spread across numerous fields of study. As a result, there is a need to analyze and reflect on the current state of resilience literature. We reviewed 241 journal articles from the Web of Science and Engineering Village databases from 1990 to 2015 to analyze research trends in geographic location of studies, methods employed, units of analysis, and resilience dimensions studied, as well as correlations between each of these categories. The majority of the studies analyzed were conducted in North America, used quantitative methods, focused on infrastructure and community units of analysis, and studied governance, infrastructure, and economic dimensions of resilience. This analysis points to the need to: (1) conduct studies in developing country contexts, where resilience is particularly important; (2) employ mixed-methods for additional depth to quantitative studies; (3) connect units of analysis, such as infrastructure and community; and (4) expand on the measurement and study of environmental and social dimensions of resilience.  相似文献   
159.
Catchment sediment budget models are used to predict the location and rates of bank erosion in tropical catchments draining to the Great Barrier Reef lagoon, yet the reliability of these predictions has not been tested due to a lack of measured bank erosion data. This paper presents the results of a 3 year field study examining bank erosion and channel change on the Daintree River, Australia. Three different methods were employed: (1) erosion pins were used to assess the influence of riparian vegetation on bank erosion, (2) bench‐marked cross‐sections were used to evaluate annual changes in channel width and (3) historical aerial photos were used to place the short term data into a longer temporal perspective of channel change (1972–2000). The erosion pin data suggest that the mean erosion rate of banks with riparian vegetation is 6·5 times (or 85%) lower than that of banks without riparian vegetation. The changes measured from cross‐section surveys suggest that channel width has increased by an average of 0·74 (±0·47) m a?1 over the study period (or ~0·8% yr?1). The aerial photo results suggest that over the last 30 years the Daintree River has undergone channel contraction of the order of 0·25 m a?1. The cross‐section data were compared against modelled SedNet bank erosion rates, and it was found that the model underestimated bank erosion and was unable to represent the variable erosion and accretion processes that were observed in the field data. The reach averaged bank erosion rates were improved by the inclusion of locally derived bed slope and discharge estimates; however, the results suggest that it will be difficult for catchment scale sediment budget models to ever accurately predict the location and rate of bank erosion due to the variation in bank erosion rates in both space and time. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
160.
Coral trout (Plectropomus spp.) are the main target species for commercial fishers in the eastern Torres Strait Reef Line Fishery (ETS RLF). The four species of coral trout known to occur in Torres Strait: Plectropomus leopardus, Plectropomus maculatus, Plectropomus areolatus and Plectropomus laevis are currently managed as a single species in Torres Strait, as there is no species-specific biological information available for the region which could be used to assess whether species differ in their response to fishing pressure. The aim of our study was to determine whether it is appropriate (biologically) to manage coral trout in the ETS RLF as a single species group or whether different management arrangements are required for some species. We used catch data and biological data from samples collected by commercial fishers to examine the distribution within Torres Strait and estimate a range of biological parameters for P. leopardus, P. maculatus and P. areolatus. Insufficient P. laevis samples were collected to reliably examine this species. Results indicated that the population biology, particularly the reproductive biology, of P. areolatus was substantially different to both P. leopardus and P. maculatus. Although it is difficult to predict the response to fishing, P. areolatus may be more vulnerable to fishing than P. leopardus and P. maculatus, due to the larger size at sex change observed for this species and the very low proportion of males protected by the current minimum size limit. Therefore, while the common management arrangements for P. leopardus and P. maculatus appear to be adequate for these species, separate management arrangements are needed for the sustainable harvest of P. areolatus populations in the ETS. Specifically, we recommend the introduction of a maximum size limit for P. areolatus, in addition to the current minimum size limit, which may allow a proportion of males some protection from fishing.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号