Fluid inclusion and cathodoluminescence studies on fluorite from the Kerio valley, Kenya

The Kerio valley lies between the Elgeyo escarpment and the Tugen hills which mark the western margin of the Kenya rift valley. The main fluorite deposits are located in the southern part of the valley at Kimwarer, Choff and Kamnaon.Three types of inclusion fillings were identified: Liquid+Vapour, Liquid+Daughter Minerals and Liquid. The L+V type is dominant. Inclusions occur as clusters, trails along the crystal growth zones and as isolated ones. Low salinities, apparently lower than the 5% wt. NaCl equivalent, were established. Homogenization temperatures suggest that fluorite mineralization took place at different stages and at temperatures between 120 and 180 °C. Isolated readings above 180°C may be referring to the original inclusions in limestone. These measurements and the absence of CO₂ in the inclusions, as well as the occurrence of vugs and crustifications with fluorite, suggest that mineralization took place at relatively shallow depths.Emission spectrum lines representing Eu²⁺, Dy³⁺, Tb³⁺ and Sm³⁺ in fluorite were identified. Sm³⁺ was detected only in the pinkish luminescence of veined fluorite, whereas the pinkish zone in banded fluorite contains Tb³⁺. Eu²⁺ which gives the strongest emission lines in the blue part of the visible spectrum, apparently is responsible for the strong blue cathodoluminescence (CL) in fluorite. The dominance of Eu²⁺ peaks further points to the fact that fluorite mineralization in the Kerio valley took place in an environment that was enriched in Lanthanide Rare Earth Elements (LREE). The presence of rare earths and radioactive elements in fluorite points towards their enrichment in the environment of fluorite mineralization. A juvenile origin of mineral forming solutions is proposed.Two generations of fluorite were established: allotriomorphic fluorite, forming the matrix, and the idiomorphic variety, occurring either in barite or in druzes in early fluorite. Barite in turn forms idiomorphic crystals in allotriomorphic fluorite. Relics of calcite occur in both K-feldspars and in early fluorite. Oxides and hydroxides of Fe, Mn, Ti and Al commonly occur in open spaces in fluorite. Of significance is the presence of gold in fluorite. Fluorite mineralization is of hydrothermal origin in the post-Miocene era and was formed as a result of metasomatic replacement of marble and open space fillings.     

Nuclear Waste Disposal Simulations: Couplex Test Cases

We give some results obtained for the Couplex test cases proposed by the ANDRA. In this paper our aim is twofold. Firstly, to compute the release of nuclides out of the repository by concentrating on the 3D near field (Couplex 2). The simulation of the transport phenomena takes into account the dissolution of the glass containers and congruent emissions of the radio-nuclides including filiation chains and some simplified chemistry. Secondly, it is to use the near field computations in order to simulate the nuclide migrations in a 2D far field (Couplex 3). Coupling in between the two simulations takes into consideration the periodicity of the disposal modules and the geometry of the repository described in Couplex 1. The mixed finite element and discontinuous Galerkin methods are used to solve the convection–diffusion equations. In order to handle the nonlinear precipitation/dissolution term, we developed a new iterative technique that combines Picard and Newton–Raphson methods.     

A statistical approach to evaluating distance metrics and analog assignments for pollen records

The modern analog technique typically uses a distance metric to determine the dissimilarity between fossil and modern biological assemblages. Despite this quantitative approach, interpretation of distance metrics is usually qualitative and rules for selection of analogs tend to be ad hoc. We present a statistical tool, the receiver operating characteristic (ROC) curve, which provides a framework for identifying analogs from distance metrics. If modern assemblages are placed into groups (e.g., biomes), this method can (1) evaluate the ability of different distance metrics to distinguish among groups, (2) objectively identify thresholds of the distance metric for determining analogs, and (3) compute a likelihood ratio and a Bayesian probability that a modern group is an analog for an unknown (fossil) assemblage. Applied to a set of 1689 modern pollen assemblages from eastern North America classified into eight biomes, ROC analysis confirmed that the squared-chord distance (SCD) outperforms most other distance metrics. The optimal threshold increased when more dissimilar biomes were compared. The probability of an analog vs no-analog result (a likelihood ratio) increased sharply when SCD decreased below the optimal threshold, indicating a nonlinear relationship between SCD and the probability of analog. Probabilities of analog computed for a postglacial pollen record at Tannersville Bog (Pennsylvania, USA) identified transitions between biomes and periods of no analog.     

On determining the noon polar cap boundary from SuperDARN HF radar backscatter characteristics

Previous work has shown that ionospheric HF radar backscatter in the noon sector can be used to locate the footprint of the magnetospheric cusp particle precipitation. This has enabled the radar data to be used as a proxy for the location of the polar cap boundary, and hence measure the flow of plasma across it to derive the reconnection electric field in the ionosphere. This work used only single radar data sets with a field of view limited to 2 h of local time. In this case study using four of the SuperDARN radars, we examine the boundary determined over 6 h of magnetic local time around the noon sector and its relationship to the convection pattern. The variation with longitude of the latitude of the radar scatter with cusp characteristics shows a bay-like feature. It is shown that this feature is shaped by the variation with longitude of the poleward flow component of the ionospheric plasma and may be understood in terms of cusp ion time-of-flight effects. Using this interpretation, we derive the time-of-flight of the cusp ions and find that it is consistent with approximately 1 keV ions injected from a subsolar reconnection site. A method for deriving a more accurate estimate of the location of the open-closed field line boundary from HF radar data is described.     

Persistent organic pollutants and histological lesions in Mayan catfish Ariopsis assimilis from the Bay of Chetumal, Mexico

Livers of catfish (Ariopsis assimilis) from the Bay of Chetumal were analyzed for organochlorine compounds and hydrocarbons as part of a study to diagnose the environmental health of the Bay after a catfish mass mortality that occurred in 1996. The presence of histological lesions in several organs of the fish as result of chemical exposure was also evaluated. The concentrations of organic pollutants found in the Bay may be considered high if compared to the levels reported for sites affected by chemical pollution. High prevalences of cellular alteration histopathologies were found in liver, including hepatic tumors. The presence of some lesions may be related statistically to environmental pollution in the Bay, specially with chlorinated compounds.     

Petrology of the Easter microplate region in the South Pacific

Submersible investigations along the East Rift segments, the Pito Deep and the Terevaka transform fault of the Easter microplate eastern boundary, and on a thrust-fault area of the Nazca Plate collected a variety of basalts and dolerites. The volcanics consist essentially of depleted (N-MORB), transitional (T-MORB) and enriched (E-MORB) basalts with low (0.01−0.1, < 0.7), intermediate (0.12–0.25, 0.7–1.2) and high (> 0.25, > 1.2–2) K/Ti and(La/Sm)_N ratios, respectively. The Fe-Ti-rich ferrobasalt encountered among the N-MORBs are found on the Pito Deep Central volcano, on the Terevaka intra-transform ridge, on the ancient (< 2.5 Ma) Easter microplate (called EMP, comprising the East Rift Inner pseudofaults and Pito Deep west walls) and on thrust-fault crusts. The most enriched (T- and E-MORB) volcanics occur along the East Rift at 25 °50′–27 °S (called 26 °S East Rift) and on the Pito seamount located near the tip of the East Rift at 23 °00′–23 °40′S (called 23 °S East Rift). The diversity in incompatible element ratios of the basalts in relation to their structural setting suggests that the volcanics are derived from a similar heterogenous mantle which underwent variable degrees of partial melting and magma mixing. In addition the Pito seamount volcanics have undergone less crystal fractionation (< 20%) than the lavas from the other Easter microplate structures (up to 35–45%). The tectonic segmentation of the East Rift observed between 23 and 27 °S corresponds to petrological discontinuities related to Mg# variations and mantle melting conditions. The highest Mg# (> 61) are found on topographic highs (2000–2300 m) and lower values (Mg# < 56) at the extremities of the East Rift segments (2500–5600 m depths). The deepest area (5600 m) along the East Rift is located at 23 °S and coincides with a Central volcano constructed on the floor of the Pito Deep. Three major compositional variabilities of the volcanics are observed along the East Rift segments studied: (1) the 26 °S East Rift segment where the volcanics have intermediate Na₈ (2.5–2.8%) and Fe₈ (8.5–11%) contents; (2) the 23 °S East Rift segment (comprising Pito seamount and Pito Deep Central volcano) which shows the highest (2.9–3.4%) values of Na₈ and a low (8–9%) Fe₈ content; and (3) the 25 °S (at 24 °50′–26 °10′S) and the 24 °S (at 24 °10′–25 °S) East Rift segments where most of the volcanics have low to intermediate Na₈ (2.6–2.0%) and a high range of Fe₈ (9–13%) contents. When modeling mantle melting conditions, we observed a relative increase in the extent of partial melting and decreasing melting pressure. These localized trends are in agreement with a 3-D type diapiric upwelling in the sense postulated by Niu and Batiza (1993). Diapiric mantle upwelling and melting localized underneath the 26, 25 and 23 °S (Pito seamount and Central volcano) East Rift segments are responsable for the differences observed in the volcanics. The extent of partial melting varies from 14 to 19% in the lithosphere between 18 and 40 km deep as inferred from the calculated initial (P_o=16kbar) and final melting (P_f=7kbar) pressures along the various East Rift segments. The lowest range of partial melting (14–16%) is confined to the volcanics from 23 °S East Rift segment including the Pito seamount and the Central volcano. The Thrust-fault area, and the Terevaka intra-transform show comparable mantle melting regimes to the 25 and 26 °S East Rift segments. The older lithosphere of the EMP interior is believed to have been the site of high partial melting (17–20%) confined to the deeper melting area (29–50 km). This increase in melting with increasing pressure is similar to the conditions encountered underneath the South East Pacific Rise (13–20 °S).     

Interaction of particles with ion cyclotron waves and magnetosonic waves. Observations from GEOS 1 and GEOS 2

Coordinated observations involving ion composition, thermal plasma, energetic particle, and ULF magnetic field data from GEOS 1 and 2 often reveal the presence of electromagnetic ion cyclotron and magnetosonic waves, which are distinguished by their respective polarization characteristics and frequency spectra. The ion cyclotron waves are identified by a magnetic field perturbation that lies in a plane perpendicular to the Earth's magnetic field B₀ and propagate along B₀. They are associated with the abundance of cold He⁺ in the presence of anisotropic pitch angle distributions of ions having energies E > 20 keV, and were observed at frequencies near the He⁺ gyrofrequency. The magnetosonic waves are characterized by a magnetic field perturbation parallel to B₀ and thus seem to be propagating perpendicular to the Earth's magnetic field. They often occur at harmonics (not always including the fundamental) at the proton gyrofrequency and are associated with phase-space-density distributions that peak at energies E ～ 5–30 keV and at a pitch angle of 90°. Such a ring-like distribution is shown to excite instability in the magnetosonic mode near harmonics of the proton gyrofrequency. Magnetosonic waves are associated in other cases with sharp spatial gradients in energetic ion intensity. Such gradients are encountered in the early afternoon sector (as a consequence of the drift shell distortion caused by the convection electric field) and could likewise constitute a source of free energy for plasma instabilities.