Palaeo-carbonate seep structures above an oil reservoir, Gryphon Field, Tertiary, North Sea

Petrographic and geochemical analyses performed on a North Sea core from the Gryphon Field reveal the presence of palaeo-degassing features surrounded by injected sandstones in the Eocene interval. The injected sandstones are oil-stained and poorly cemented by carbonate and quartz. ¹⁸O isotope analyses indicate that carbonate cementation occurred during shallow burial (likely less than about 300 m). Depleted ¹³C (around –30 V-PDB) carbonate cement suggests that bicarbonate was derived from the microbial oxidation of oil and gas. Late quartz overgrowths enclose oil present in the injected units. The tubular degassing conduits are composed of zoned cements and have ¹⁸O and ¹³C isotope values similar to the injected sandstones, indicating that oil and gas seepage induced the precipitation of authigenic carbonate in the shallow subsurface. Oil inclusions in inter- and intra-crystal cement sites in both injected sandstones and degassing conduits indicate that oil seepage was an ongoing feature at shallow burial. A proposed model involves oil and gas seepage and the formation of the degassing conduits, followed by a sand injection phase. It seems likely that oil and gas continued to leak towards the seabed by exploiting the network of permeable injected sandstones and the horizons of porous degassing features.     

Hydrodynamic Tidal Model of the Persian Gulf Based on Spatially Variable Bed Friction Coefficient

The aim of this study is to develop a two-dimensional hydrodynamic tidal model for the Persian Gulf (PG2017) using 2D-MIKE21 software. The advantages of present study is accounting for the spatial variation of bed friction coefficient besides a precise bathymetry together with a 23-year of combined records of satellite altimetry data. We found that the bed friction coefficient has a significant effect on sea level changes in the region under our modeling consideration. Since the tidal behavior in the northern part of the Qeshm Island is significantly different from the other parts of the Persian Gulf, to present a more accurate hydrodynamic tidal model, the Gulf is divided into two regions where the bed friction coefficient is modeled separately for each region. The root mean square value of the differences between the amplitude of dominant constituents; M2, S2, K1, and O1 derived from the PG2017 model and that of 98 altimetry and coastal tide gauge stations are respectively equal to 1.6, 1.9, 2.8, and 1.3?cm. Moreover, comparing the PG2017 model efficiency with the FES2014, OSU12, EOT11a, DTU10, and Admiralty models shows that the PG2017 model has an improvement of 22.1%, 47.2%, 43.2%, 44.2%, and 57.6% in terms of relative error, respectively.     

Devitrite (Na2Ca3Si6O16)—structural, spectroscopic and computational investigations on a crystalline impurity phase in industrial soda-lime glasses

Single crystals of devitrite (Na₂Ca₃Si₆O₁₆) were synthesized as pale-yellow transparent needle shaped crystals using a Na₂MoO₄-flux. Experiments aiming to prepare the K-equivalent of devitrite from the corresponding K₂MoO₄-flux were unsuccessful. The crystal structure of devitrite was determined from single-crystal X-ray diffraction data (Mo-K_α radiation, 2θ_max.?=?25.34°, R_int?=?2.66%) and refined in space group P $ \bar{1} $ (no. 2) to R(|F|)?=?3.08% using 2,513 observed reflections with I?>?2σ(I). Unit-cell parameters are: a?=?7.2291(8), b?=?10.1728(12), c?=?10.6727(12) Å, α?=?95.669(9), β?=?109.792(10), γ?=?99.156(9)°, V?=?719.19(14) ų, Z?=?2. The structure belongs to the group of multiple chain silicates consisting of dreier quadruple chains, i.e. the crystallochemical formula can be written as $ {\hbox{N}}{{\hbox{a}}_2}{\hbox{C}}{{\hbox{a}}_3}\left\{ {{\mathbf{uB}}{,4}_\infty^1} \right\}\left[ {^3{\hbox{S}}{{\hbox{i}}_6}} \right.\left. {{{\hbox{O}}_{16}}} \right\} $ . Linkage between the bands running along [100] is provided by double chains of edge sharing CaO₆-octahedra as well as additional more irregularly coordinated Na- and Ca-cations located in the tunnel-like cavities of the mixed tetrahedral-octahedral framework. Structural investigations were completed by Raman and infrared spectroscopical studies. The allocation of the bands to certain vibrational species was aided by density functional theory (DFT) calculations.     

NAO–ocean circulation interactions in a coupled general circulation model

The interplay between the North Atlantic Oscillation (NAO) and the large scale ocean circulation is inspected in a twentieth century simulation conducted with a state-of-the-art coupled general circulation model. Significant lead–lag covariance between oceanic and tropospheric variables suggests that the system supports a damped oscillatory mode involving an active ocean–atmosphere coupling, with a typical NAO-like space structure and a 5 years timescale, qualitatively consistent with a mid-latitude delayed oscillator paradigm. The two essential processes governing the oscillation are (1) a negative feedback between ocean gyre circulation and the high latitude SST meridional gradient and (2) a positive feedback between SST and the NAO. The atmospheric NAO pattern appears to have a weaker projection on the ocean meridional overturning, compared to the gyre circulation, which leads to a secondary role for the thermohaline circulation in driving the meridional heat transport, and thus the oscillatory mode.     

Using idealized snow forcing to test teleconnections with the Indian summer monsoon in the Hadley Centre GCM

Anomalous heavy snow during winter or spring has long been regarded as a possible precursor of deficient Indian monsoon rainfall during the subsequent summer. However previous work in this field is inconclusive, in terms of the mechanism that communicates snow anomalies to the monsoon summer, and even the region from which snow has the most impact. In this study we explore these issues in coupled and atmosphere-only versions of the Hadley Centre model. A 1050-year control integration of the HadCM3 coupled model, which well represents the seasonal cycle of snow cover over the Eurasian continent, is analysed and shows evidence for weakened monsoons being preceded by strong snow forcing (in the absence of ENSO) over either the Himalaya/Tibetan Plateau or north/west Eurasia regions. However, empirical orthogonal function (EOF) analysis of springtime interannual variability in snow depth shows the leading mode to have opposite signs between these two regions, suggesting that competing mechanisms may be possible. To determine the dominant region, ensemble integrations are carried out using HadAM3, the atmospheric component of HadCM3, and a variety of anomalous snow forcing initial conditions obtained from the control integration of the coupled model. Forcings are applied during spring in separate experiments over the Himalaya/Tibetan Plateau and north/west Eurasia regions, in conjunction with climatological SSTs in order to avoid the direct effects of ENSO. With the aid of idealized forcing conditions in sensitivity tests, we demonstrate that forcing from the Himalaya region is dominant in this model via a Blanford-type mechanism involving reduced surface sensible heat and longwave fluxes, reduced heating of the troposphere over the Tibetan Plateau and consequently a reduced meridional tropospheric temperature gradient which weakens the monsoon during early summer. Snow albedo is shown to be key to the mechanism, explaining around 50% of the perturbation in sensible heating over the Tibetan Plateau, and accounting for the majority of cooling through the troposphere.     

Kriging of water levels in the Souss aquifer,Morocco

Universal kriging is applied to water table data from the Souss aquifer in central Morocco. The procedure accounts for the spatial variability of the phenomenon to be mapped. With the use of measured elevations of the water table, an experimental variogram is constructed that characterizes the spatial variability of the measured water levels. Spherical and Gaussian variogram models are alternatively used to fit the experimental variogram. The models are used to develop contour maps of water table elevations and corresponding estimation variances. The estimation variances express the reliability of the kriged water table elevation maps. Universal kriging also provides a contour map of the expected elevation of the water table (drift). The differences between the expected and measured water table elevations are called residuals from the drift. Residuals from the drift are compared with residuals obtained by more traditional least-squares analysis.     

Simulation Of Salt-Water Encroachment In A Multi-Layer Groundwater System,Bangkok, Thailand

Salt-water encroachment in the multi-layer groundwater system underlying the Bangkok metropolitan area was simulated with a quasi-three-dimensional flow and solute-transport model. The quasi-three-dimensional model used in this study is based on the model SUTRA. Accurate conceptualization of the initial state of the system with regard to the distribution of salt-water concentration is very important for modeling, especially in areas where localized zones of high salt concentration exist in the groundwater. Data adequacy and model results were evaluated by a geostatistical analysis. The model is capable of simulating the regional trend of potentiometric levels and salt concentration. However, lack of monitoring data in areas where localized zones of high salt concentration exist resulted in large model residuals. RÉSUMÉ: L'empiétement des eaux salées dans le système hydrologique multi-couche sous-jacent la zone métropolitaine de Bangkok a été simulé à l'aide d'un modèle quasi-tridimensionnel représentant l'écoulement des eaux et le transport d'éléments en solution. Le modèle quasi-tridimensionnel utilisé dans cette étude est basé sur le modèle SUTRA. Une conceptualisation exacte de l'état initial du système en ce qui concerne la répartition de la concentration des eaux salines est très important, particulièrement dans les endroits localisés où l'eau souterraine presente une forte concentration en sel. La qualité des donnés et des résultats a été estimée à l'aide d'une analyse géostatistique. Le modèle est capable de simuler la tendance régionale des niveaux potentiométriques et de la concentration en sel. Cependant, le manque de données de contrôle dans les endroits à forte concentration a donné lieu à des résiduels importants. RESUMEN: La intrusión de agua salina en el sistema multicapa bajo el área metropolitana de Bangkok se simuló mediante un modelo de flujo y transporte de solutos casi-tridimensional, basado en el modelo SUTRA. La conceptualizacián precisa de la distribución inicial de concentraciones de agua salina es muy importante para el modelo, especialmente en áreas donde existen zonas locales de alta concentración salina en el agua subterránea. La exactitud de los datos y del modelo se evaluaron mediante un análisis geoestadístico. El modelo permite simular la tendencia regional de los niveles piezométricos y la concentración de sales. Sin embargo, la falta de datos de muestreo en las zonas locales de alta salinidad resultaron en valores altos de los residuos calculados por el modelo.     

OPTIMUM DIGITAL FILTERING AND INVERSE FILTERING IN THE FREQUENCY DOMAIN*

Two distinct filters are developed in the frequency domain which represent an attempt to increase the resolution of fine structure contained in the signal whilst keeping the expected filtered noise energy within reasonable bounds. A parameter termed the White Noise Amplification is defined and used together with a measure of the deconvolved pulse width in order to provide a more complete characterisation of the filters. Each of the two main types of frequency domain filters discussed varies in properties with respect to a single adjustable parameter. This may be contrasted with a time domain Wiener filter which in general has three variables: length, delay and an adjustable noise parameter or weight. The direct frequency domain analogue of the Wiener filter is termed a gamma-Fourier filter, and is shown to have properties which span the range from those of a spiking filter with zero least square error at one extreme, to those of a matched filter at the other extreme of its variable parameter's range. The second type of filter considered—termed the modulated Gaussian filter—is similarly shown to be a perfect spiking filter at one extreme of its parameter range, but adopts the properties of an output energy filter at the other extreme.     

Influence of the spatial resolution of satellite-derived vegetation parameters on the biogenic Volatile Organic Compounds (VOC) emission modeling

Vegetation is a natural source of Volatile Organic Compounds (VOC) that plays an important role in atmospheric chemistry. The main objective of the current study is to implement a model to quantify process-based VOC emissions from plants that focuses on the relationship between the sensitivity of VOC emission estimates to spatial resolution data, based on scientific knowledge and vegetation dynamics derived from satellite observations. The Normalized Difference Vegetation Index (NDVI) and Leaf Area Index (LAI) were elected to examine this issue using different resolutions of satellite-derived products: 22m from the DEIMOS-1 satellite, and 250m and 1000m provided by MODIS. The study is focused on an area of 80×80km² in Portugal for 2011. Detailed land cover and meteorological data are also included in the emission quantification algorithm. The primary outcomes were determined using a multi-scale analysis showing spatial and temporal variations in the vegetation parameters and modeling results. The results confirm that the emissions model is highly sensitive to the spatial resolution of the satellite-derived data, resulting in about a 30% difference in total isoprene emissions for the study area.