Application of a square wave potentiometry technique for electroreductive sulfur removal from a thiophenic model fuel

Thiophene-containing solutions were electroreductively desulfurized by a dynamic method. Initially, cyclic voltammetry was utilized to study thiophene electroadsorption from aqueous solution onto a platinum electrode surface and also to investigate the thiophene electroreductive behavior. Then, the solution was desulfurized via a square wave potentiometry method. The objective of this study was to find the optimal conditions. In this regard, the best adsorption potential, electroreduction potential, and square wave frequency were found to be ?0.54 V, ?0.95 V, and 1 Hz, respectively. Finally, a model fuel (containing 294 part per millions thiophene) was desulfurized by the square wave potentiometry method. Gas chromatography and Fourier transform infrared spectroscopy were used to examine the feed and product solutions. Gas chromatographic measurements revealed that sulfur content decreased to 55 part per millions. Based on the acquired results, electroreductive desulfurization could be designated as an efficient superseded for the commercial hydrodesulfurization process. However, more studies must perform to overcome technical limitations of electroreductive desulfurization technique and to guarantee its reliability.     

Melanterite and szomolnokite as weathering products of pyrite from the Bazhenovo Formation

Weathering of pyrite in the core recovered from black shales of the Bazhenovo Formation (Upper Jurassic-Lower Cretaceous) in the West Siberian marine basin promoted the successive formation of melanterite (FeSO₄ · 7H₂O) and szomolnokite (FeSO₄ · H₂O). Szomolnokite was detected in West Siberia for the first time.     

Comparative phylogeography of African rain forest trees: A review of genetic signatures of vegetation history in the Guineo-Congolian region

The biogeographic history of the African rain forests has been contentious. Phylogeography, the study of the geographic distribution of genetic lineages within species, can highlight the signatures of historical events affecting the demography and distribution of species (i.e. population fragmentation or size changes, range expansion/contraction) and, thereby, the ecosystems they belong to. The accumulation of recent data for African rain forests now enables a first biogeographic synthesis for the region. In this review, we explain which phylogeographic patterns are expected under different scenarios of past demographic change, and we give an overview of the patterns detected in African rain forest trees to discuss whether they support alternative hypotheses regarding the history of the African rain forest cover. The major genetic discontinuities in the region support the role of refugia during climatic oscillations, though not necessarily following the classically proposed scenarios. We identify in particular a genetic split between the North and the South of the Lower Guinean region. Finally we provide some perspectives for future study.     

3d transition metal L-edge X-ray absorption studies of the dichalcogenides of Fe, Co and Ni

The X-ray absorption spectra of the transition metal L_3,2-edges of the dichalcogenides FeS₂ (pyrite), FeSe₂, FeTe₂, CoS₂, CoSe₂, CoTe₂, NiS₂, NiSe₂ and NiTe₂ have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe.     

Enter the working forest: Discourse analysis in the Northern Forest

In 1988, four states in the northeastern USA commissioned a study to address land use changes in the Northern Forest, 26 million acres of temperate and boreal forest extending from Maine to eastern New York State. Against a backdrop of economic destabilization and concerns regarding social and ecological implications of a real estate boom, the sustained deliberative dialogue catalyzed by this study has come to rely heavily on the ambiguous concept of “working forest.” To clarify political and environmental dynamics in the region, we analyzed how people respond to and seek to capitalize on the interpretive flexibility of the term working forest. We combine an analysis of socio-political discourses of working forest based on a structured literature review with an assessment of local peoples’ definitions of working forest based on a survey conducted in a pair of contrasting New York State communities. The first study site represents an amenity-oriented community (i.e. a place where the forest supports a service economy including recreation and tourism) and the other study site represents a timber-dependent community. By linking data from community-level analysis to data derived from a general analysis of forest politics, we seek to develop a more robust perspective. By comparing discourses across differently structured communities, we investigate how local forest politics are mediated by local economic development processes. Our study empirically illustrates contested and geographically uneven processes of social construction of environment and rural development in a region confronting pressures of globalization. Results indicate that timber harvesting is a heavily privileged management objective, as a logic of ‘the forest that pays is the forest that stays’ dominates. Environmental politics in the region, and perhaps more generally, increasingly conforms to a form of pragmatism in which economic opportunities structure conservation planning and investment.     

Thermomechanical properties of deep argillaceous formations

A difficulty in the interpretation of mechanical and thermo-mechanical tests on specimens drawn from large argillaceous formations is the strong inhomogeneity of void ratio, clay minerals and carbonates content.

In this paper a relationship is developed to link strength and the maximum preconsolidation stress to the initial void ratio and carbonate content. Compressibility is also correlated to carbonates.

Thermal strains in drained and undrained conditions for a Spanish, a belgian and an Italian natural clay are compared. In the elastic state strains are comparable, while in the plastic range thermal strains are highest for the Belgian clay, lower in the Spanish cemented clay and lowest in the Italian clay, very stiff and cemented.     

Dependence of the types of coasts and coastal eolian relief on the variations of the sea level using the example of the Caspian Sea

In this work, the history of the development of the Turali area (the Dagestan coast of the Caspian Sea) in the Late Holocene is under consideration. The analysis of the geological structure of the bay bar that separates the Bolshoy Turali lagoon from the sea, the granulometric analysis of the coastal deposits, and the data of geo-radar profiles make it possible to assert that the large eolian relief forms were formed during the New Caspian (Novokaspiyskoe) transgression of the Caspian Sea.