Hafnium isotopic variations in East Atlantic intraplate volcanism

The broad belt of intraplate volcanism in the East Atlantic between 25° and 37° N is proposed to have formed by two adjacent hotspot tracks (the Madeira and Canary tracks) that possess systematically different isotopic signatures reflecting different mantle source compositions. To test this model, Hf isotope ratios from volcanic rocks from all individual islands and all major seamounts are presented in this study. In comparison with published Nd isotope variations (6 εNd units), ¹⁷⁶Hf/¹⁷⁷Hf ratios span a much larger range (14 εHf units). Samples from the proposed Madeira hotspot track have the most radiogenic Hf isotopic compositions (¹⁷⁶Hf/¹⁷⁷Hf_m up to 0.283335), extending across the entire field for central Atlantic MORB. They form a relatively narrow, elongated trend on the Nd vs. Hf isotope diagram (stretching over > 10 εHf units) between a depleted N-MORB-like endmember and a moderately enriched composition located on, or slightly below, the Nd–Hf mantle array, which overlaps the proposed “C” mantle component of Hanan and Graham (1996). In contrast, all samples from the Canary hotspot track plot below the mantle array (¹⁷⁶Hf/¹⁷⁷Hf_m = 0.282943–0.283067) and form a much denser cluster with less compositional variation (~4 εHf units). The cluster falls between (1) a low Hf isotope HIMU-like endmember, (2) a more depleted composition, and (3) the moderately enriched end of the Madeira trend. The new Hf isotope data confirm the general geochemical distinction of the Canary and Madeira domains in the East Atlantic. Both domains, however, seem to share a common, moderately enriched endmember that has “C”-like isotope compositions and is believed to represent subducted, <1-Ga-old oceanic lithosphere (oceanic crust and possibly minor sediment addition). The lower ¹⁷⁶Hf/¹⁷⁷Hf ratio of the enriched, HIMU-like Canary domain endmember indicates the contribution of oceanic lithosphere with somewhat older recycling ages of ≥1 Ga.     

Energetic electron signatures of Saturn's smaller moons: Evidence of an arc of material at Methone

We present several energetic charged particle microsignatures of two Lagrange moons, Telesto and Helene, measured by the MIMI/LEMMS instrument. These small moons absorb charged particles but their effects are usually obscured by Tethys and Dione, the two larger saturnian satellites that occupy the same orbits. The scales and structures of these microsignatures are consistent with standard models for electron absorption from asteroid-sized moons in Saturn's radiation belts. In the context of these observations, we also examine the possibility that the 3 km Satellite Methone is responsible for two electron microsignatures detected by Cassini close to this moon's orbit. We infer that a previously undetected arc of material exists at Methone's orbit (R/2006 S5), we speculate how such a structure could form and what its physical characteristics and location could be. The origin of this arc could be linked to a possible presence of a faint ring produced by micrometeoroid impacts on Methone's surface, to E-ring dust clump formation at that distance or to temporary dust clouds produced by enceladian activity that spiral inwards under the effect of non-gravitational forces.     

Spectroscopy of candidate metal-deficient galaxies with the 6-m telescope

We present the first results of our program of search for the most metal-deficient blue compact galaxies (BCGs) carried out with the 6-m Special Astrophysical Observatory telescope. The results of spectrophotometry are presented and discussed for ten galaxies from the Case and Hamburg/SAO surveys. The selection of candidates, observations, and data reduction are described in detail. For all the galaxies studied, we measured the intensity of the [O III] λ4363 Å emission line, which allows us to properly determine the temperatures of H II regions and to deduce elemental abundances. We measured the intensities of all the detected emission lines in H II regions of the galaxies under study and determined the abundances of oxygen and neon in them and in some of these galaxies, of other elements (N, S, He, Ar, and Fe). The oxygen abundance log (O/H)+12 in six galaxies was derived with an error ≤0.1 dex. Six of the ten galaxies studied turned out to be metal-poor with an oxygen abundance ≤1/10 of its solar value [i.e., 12+log(O/H)≤7.92]. HS 0837+4717 with 12+log(O/H) ≤7.7 is one of the most metal-poor galaxies in this sample and one of the candidates for young galaxies. Low-contrast, broad emission components of the nebular [O III]λ4959 and 5007 Å lines were detected in its spectrum, suggesting high velocities of gas motions in this galaxy.     

Formation rates of Subantarctic mode water and Antarctic intermediate water within the South Pacific

The formation of Subantarctic Mode Water (SAMW) and Antarctic Intermediate Water (AAIW) significantly contributes to the total uptake and storage of anthropogenic gases, such as CO₂ and chlorofluorocarbons (CFCs), within the world's oceans. SAMW and AAIW formation rates in the South Pacific are quantified based on CFC-12 inventories using hydrographic data from WOCE, CLIVAR, and data collected in the austral winter of 2005. This study documents the first wintertime observations of CFC-11 and CFC-12 saturations with respect to the 2005 atmosphere in the formation region of the southeast Pacific for SAMW and AAIW. SAMW is 94% and 95% saturated for CFC-11 and CFC-12, respectively, and AAIW is 60% saturated for both CFC-11 and CFC-12. SAMW is defined from the Subantarctic Front to the equator between potential densities 26.80-27.06 kg m⁻³, and AAIW is defined from the Polar Front to 20°N between potential densities 27.06-27.40 kg m⁻³. CFC-12 inventories are 16.0×10⁶ moles for SAMW and 8.7×10⁶ moles for AAIW, corresponding to formation rates of 7.3±2.1 Sv for SAMW and 5.8±1.7 Sv for AAIW circulating within the South Pacific. Inter-ocean transports of SAMW from the South Pacific to the South Atlantic are estimated to be 4.4±0.6 Sv. Thus, the total formation of SAMW in the South Pacific is approximately 11.7±2.2 Sv. These formation rates represent the average formation rates over the major period of CFC input, from 1970 to 2005. The CFC-12 inventory maps provide direct evidence for two areas of formation of SAMW, one in the southeast Pacific and one in the central Pacific. Furthermore, eddies in the central Pacific containing high CFC concentrations may contribute to SAMW and to a lesser extent AAIW formation. These CFC-derived rates provide a baseline with which to compare past and future formation rates of SAMW and AAIW.     

The Characteristic Patterns of Macrofaunal Fouling Assemblages in Nearshore Waters of the South China Sea

The spatio-temporal patterns of macrofaunal fouling assemblages were quantitatively investigated in the nearshore waters of the South China Sea. The work was undertaken by deploying seasonal panels at two sites (H-site, L-site) for one year, and the fouling communities on the panels were examined and analyzed. The results indicated that species composition of assemblages was obviously different between the two sites. At both sites the assemblages were characteristic with solitary dominant species throughout the year, with Amphibalanus reticulates dominating at H-site and Hydroides elegans at L-site. Shannon index and biomass of the assemblages varied with depth and season at both sites. At H-site the total biomass in summer and autumn were significantly higher than those in spring and winter, while at L-site the assemblage biomass also differed significantly among the four seasons, and the greatest biomass occurred at the depth of 2.0 m in winter. The abundance of all seasonal samples in non-metric multidimensional scaling was clustered as one group at L-site and three groups at H-site. The environmental factors were more likely to be related to the variation of fouling assemblages. Furthermore, it also suggests that in tropical seas the integrated adaptability would qualify a species for dominating a fouling assemblage despite its short life cycle, rather than the usually assumed only species with long life span. This study reveals the complexity and characteristic dynamics of macrofaunal fouling assemblages in the tropical habitats, and the results would provide valuable knowledge for biodiversity and antifouling research.     

Influence of Headland Breakwaters on Morphological Processes at Longfengtou Beach in Haitan Bay,Facing the Taiwan Strait

Breakwaters can be used as artificial headlands in beach nourishment to mitigate coastal erosion. Longfengtou Beach, located on the southwest coast of Haitan Bay facing the Taiwan Strait on the northeast, suffers severe erosion, where the monsoon causes significant season hydrodynamic variations. Headland breakwaters are intended to be employed to mitigate coastal erosion. A 2D sediment transport model is established using MIKE21 based on current-wave coupling and calibrated by measured data. Summer and winter wave conditions are chosen as characteristic weak and strong waves respectively. The numerical results of suspended sediment concentration and seasonal morphological evolution are compared under the conditions with and without the headland breakwaters. Sediment transport in summer can be regarded as mainly determined by current field, while in winter wave effect is strong enough to change current field. The northern breakwater, nearly perpendicular to the ebb current direction, obstructs the currents and decreases velocity of the ebb currents, and confines the water carrying sediments within the protection area during the flood period. The southern breakwater also breaks the waves in advance and significantly reduces the hydrodynamic effects during the flood period and maintains high suspended sediment concentration in the protection area. In general, two headland breakwaters decrease the erosion near the beach and enlarge the deposition area, which play a significant role in prevention of sediment loss in nearshore area and mitigate coastal erosion.     

Chemical composition of Russian Arctic precipitation in 2007-2015

The results of observations of the chemical composition of precipitation in the Russian Arctic in 2007-2015 are summarized including the data from NP-35 drifting ice station obtained in 2007-2008 in the framework of the joint program of Arctic and Antarctic Research Institute and Voeikov Main Geophysical Observatory. The qualitative and quantitative difference in the chemical composition of precipitation in the Atlantic, Siberian, and Pacific sectors of the Russian Arctic is revealed. It is found that the concentration of microelements (heavy metals) in precipitation at NP-35 ice station did not exceed 12% of total ions at the lowest mineralization. The comparative analysis is presented of the concentration of sulfate ions in precipitation in Norilsk and at NP-35 ice stations.     

The role of the thermal convection of fluids in the formation of unconformity-type uranium deposits: the Athabasca Basin,Canada

In the global production of uranium, ~18% belong to the unconformity-type Canadian deposits localized in the Athabasca Basin. These deposits, which are unique in terms of their ore quality, were primarily studied by Canadian and French scientists. They have elaborated the diagenetic–hydrothermal hypothesis of ore formation, which suggests that (1) the deposits were formed within a sedimentary basin near an unconformity surface dividing the folded Archean–Proterozoic metamorphic basement and a gently dipping sedimentary cover, which is not affected by metamorphism; (2) the spatial accommodation of the deposits is controlled by the rejuvenated faults in the basement at their exit into the overlying sedimentary sequence; the ore bodies are localized above and below the unconformity surface; (3) the occurrence of graphite-bearing rocks is an important factor in controlling the local structural mineralization; (4) the ore bodies are the products of uranium precipitation on a reducing barrier. The mechanism that drives the circulation of ore-forming hydrothermal solutions has remained one of the main unclear questions in the general genetic concept. The ore was deposited above the surface of the unconformity due to the upflow discharge of the solution from the fault zones into the overlying conglomerate and sandstone. The ore formation below this surface is a result of the downflow migration of the solutions along the fault zones from sandstone into the basement rocks. A thermal convective system with the conjugated convection cells in the basement and sedimentary fill of the basin may be a possible explanation of why the hydrotherms circulate in the opposite directions. The results of our computations in the model setting of the free thermal convection of fluids are consistent with the conceptual reasoning about the conditions of the formation of unique uranium deposits in the Athabasca Basin. The calculated rates of the focused solution circulation through the fault zones in the upflow and downflow branches of a convection cell allow us to evaluate the time of ore formation up to the first hundreds of thousands years.     

Petrological considerations for the demineralization of Rajmahal coals with <Emphasis Type="Italic">Pseudomonas mendocina</Emphasis> B6-1

The present study entails the results of the petrological coniderations for demineralization of Rajmahal Gondwana coals with Psudomonas mendocina B6-1. Inertinite group macerals are the dominant constituents of these coals, followed by vitrinite group, while liptinite occurs in low concentration. The amount of Mineral matter is moderately high. The concentration of major, minor and trace elements is high when compared with Clarke values. After the treatment of these coals with Pseudomonas mendocina strain B6-1, a significant reduction in the elemental content of oxygen, hydrogen and sulphur was observed. A gradual reduction of pyrite phase due to bioleaching was identified and its signatures were reflected in the XRD spectra and FTIR absorption bands. Over 5 % reduction in the ash content and decrease of major, minor and trace element to variable degrees were also noticed. Fe, As, and Ca positively correlate with the ash removal percentage indicating that the samples with high concentration of these elements were prone to demineralization with Pseudomonas mendocina strain B6-1 whereas Ni, Zn, Cr and Cu, negatively correlate with the ash removal percentage and shows that their enrichment impeded the process of demineralization. With increasing concentration of vitrinite the removal of major/minor/trace elements also increased which is attributed to the possible association of these elements with the mineral matter occurring as superficial mounting and superficial blanketing over the vitrinite macerals. This could facilitate the bacterial access to the elements to act upon and remove it to the variable extent. Some minerals occur intergrown with inertinites causing restricted bacterial action owing to the nonexposure of the mineral particles and less surface area available to the bacteria for bioleaching. Sulfur removal strongly relates with increase in inertinite content and decrease in liptinite content. This appears that sulfur associated with liptinites have shown difficult removal condition. The maximum removal of the trace elements like Cd, Cu, Co, Zn and Pb was observed from the ‘banded dull coal’ samples of the Rajmahal basin while maximum removal of major/minor elements like Fe, Ca and Mg was noticed from the ‘banded bright coal’ samples. However, maximum removal of Mn and As was also observed in the samples of ‘banded coal’.     

Monitoring and prediction of land use/land cover changes using CA-Markov model: a case study of Ravansar County in Iran

Human‐induced land use/land cover (LULC) changes are among the most important processes that shape the dynamics of the earth’s surface. This phenomenon, which is occurring at an astonishing rate, and its consequential environmental impacts have become an important area of research for scientists.Therefore, a wide range of methods and models have been developed to detect and predict these alterations, among which cellular automata (CA) models such as the CA‐Markov model, due to their affinity to geographic information system (GIS) and remote sensing (RS), are appropriate for detailed resolution modelling and simulating dynamic spatial processes. In Iran, the district of Ravansar has undergone severe LULC changes recently, thus to take the necessary precautions, decision‐makers need to predict and determine the extent of these changes. In this study, using spatial analysis methods the LULC changes in Ravansar were investigated from 1992 to 2015. Subsequently, the CA‐Markov model was applied to simulate the spatial pattern changes of LULC until 2030. Our results indicated that from 1992 to 2015, this region has witnessed a noticeable increase in the areas of the built‐up and agricultural lands (both aquatic and non‐aquatic), resulting in the decrease of the gardens, range, and bare lands. The simulated LULC map showed that this trend will continue due to more urbanization and development of agricultural areas.