Schorlomite: a discussion of the crystal chemistry, formula, and inter-species boundaries

Examination of schorlomite from ijolite at Magnet Cove (USA) and silicocarbonatite at Afrikanda (Russia), using electron-microprobe and hydrogen analyses, X-ray diffraction and Mössbauer spectroscopy, shows the complexity of substitution mechanisms operating in Ti-rich garnets. These substitutions involve incorporation of Na in the eightfold-coordinated X site, Fe²⁺ and Mg in the octahedrally coordinated Y site, and Fe³⁺, Al and Fe²⁺ in the tetrahedrally coordinated Z site. Substitutions Ti⁴⁺Fe³⁺Fe³⁺_–1Si_–1 and Ti⁴⁺Al³⁺Fe³⁺_–1Si_–1 are of major significance to the crystal chemistry of schorlomite, whereas Fe²⁺ enters the Z site in relatively minor quantities (<3% Fe). There is no evidence (either structural or indirect, such as discrepancies between the measured and calculated Fe²⁺ contents) for the presence of ^[6]Ti³⁺ or ^[4]Ti⁴⁺ in schorlomite. The simplified general formula of schorlomite can be written as Ca₃Ti⁴⁺₂[Si_3-x(Fe³⁺,Al,Fe²⁺)_xO₁₂], keeping in mind that the notion of end-member composition is inapplicable to this mineral. In the published analyses of schorlomite with low to moderate Zr contents, x ranges from 0.6 to 1.0, i.e. Ti⁴⁺ in the Y site is <2 and accompanied by appreciable amounts of lower-charged cations (in particular, Fe³⁺, Fe²⁺ and Mg). For classification purposes, the mole percentage of schorlomite can be determined as the amount of ^[6]Ti⁴⁺, balanced by substitutions in the Z site, relative to the total occupancy in the Y site: (^[6]Ti⁴⁺–^[6]Fe²⁺–^[6]Mg²⁺– ^[8]Na⁺)/2. In addition to the predominant schorlomite component, the crystals examined in this work contain significant (>15 mol.%) proportions of andradite (Ca₃Fe³⁺₂Si₃O₁₂), morimotoite (Ca₃Fe²⁺TiSi₃O₁₂), and Ca₃MgTiSi₃O₁₂. The importance of accurate quantitative determination and assignment of Fe, Ti and other cations to the crystallographic sites for petrogenetic studies is discussed.

Free convection effects on the oscillatory flow in the Stokes's problem past an infinite porous vertical limiting surface with constant suction — I

An analysis of Rayleigh's problem (also Stokes's problem) for the flow of a viscous fluid (e.g. of a stellar atmosphere) past an impulsively started infinite, vertical porous limiting surface (e.g. of a star) with constant suction, when the free stream velocity oscillates in time about a constant mean, has been carried out. On solving the coupled non-linear equations in approximate way, expressions for the mean velocity, the mean temperature, the mean skin-friction and the mean rate of heat transfer, expressed in terms of Nusselt number, are obtained. The effects of Grashof numberG, Eckert numberE and Prandtl numberP, on these quantities, is discussed for the cases of an externally heating and cooling of the limiting surface, by the free convection currents, and the variations of them are shown graphically.     

Mantle(?) xenoliths in the carbonatites of northern Transbaikalia

The composition and nature of high-Cr minerals in lithic clasts from the carbonatites of the Veseloe occurrence, northern Transbaikalia, were considered. In order to determine their source, the Cr-bearing phases were compared with chromite, magnetite, and rutile from ultrabasic rocks, mantle xenoliths, and eclogites. It was suggested that the xenoclasts studied were formed at great depths, whereas the carbonatites were directly derived from the mantle rather than formed by the crustal differentiation of a silicate-carbonate melt.     

Rock warming and drying under simulated intertidal conditions,part II: weathering and biological influences on evaporative cooling and near‐surface micro‐climatic conditions as an example of biogeomorphic ecosystem engineering

The way in which rocks and engineering materials heat‐up and dry‐out in the intertidal zone is of relevance to both weathering and ecology. These behaviours can be measured in the laboratory under controlled conditions designed to replicate those occurring in the field. Previous studies have demonstrated differences in thermal behaviours between rock types and through time as a result of soiling in terrestrial environments, but the influence of weathering and colonization on rock behaviours in the intertidal zone has not been previously assessed. We measured the warming and drying of blocks of rock (limestone and granite) and marine concrete during ‘low‐tide’ events simulated in the laboratory, before and after a period of exposure (eight months) on rock platforms in Cornwall, UK. As well as differences between the material types, temperatures of control (unexposed) and field‐exposed blocks differed in the order of 1 to 2 °C. Drying behaviours were also different after field exposure. Differences during the first few hours of exposure to air and heat were attributed to discolouration and albedo effects. Over longer periods of time, changes in the availability of near‐surface pore water as a result of micro‐scale bioerosion of limestone and the development of bio‐chemical crusts on marine concrete [observed using scanning electron microscopy (SEM)] are suggested as mechanisms enhancing and reducing, respectively, the efficiency of evaporative cooling. The retention of moisture by epilithic biofilms may also influence thermal and drying behaviours of granite. These observations represent one of the first examples of cross‐scalar biogeomorphic linkages in the intertidal zone. The significance of the results for the subsequent efficiency of weathering, and near‐surface micro‐climatic conditions experienced by colonizing organisms is discussed. The involvement of microorganisms in the creation of more (or less) ecologically stressful conditions through the alteration of substratum geomorphic properties and behaviours is suggested as an example of ‘biogeomorphic ecosystem engineering’. Copyright © 2011 John Wiley & Sons, Ltd.     

Stratigraphie und Fazies des Erzgebirgischen Kristallins im Rahmen des Mitteleuropäischen Varistikums

Zusammenfassung Es läßt sich zeigen, daß im erzgebirgischen Raum die jungalgonkische Serie des varistischen Sockels von der Petrofazies diskordant geschnitten wird. Im Bereich des erzgebirgischen Kristallins steigt die Amphibolitfazies beulenförmig bis an die Basis des varistischen Sedimenttroges auf. Mit diesem Aufstieg wird eine Granitbildung regionalen und lokalen Charakters als möglich in Verbindung gebracht.

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It can be demonstrated that the Upper Algonkian rocks of the Hercynian basement are disconformably cut by the petrofacies of the Erzgebirge. In the environment of crystallin rocks amphibolitic facies ascend to the bottom of the hercynian sedimentary trough. With this rise a granitisation of regional and locally restricted character might seem to be possible.

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Résumé On peut montrer que dans la région de l'Erzgebirge les couches de l'Algonkien supérieur du socle hercynien sont recoupées en discordance par le petrofacies. Dans le domaine du cristallin de l'Erzgebirge, le facies amphibolite a la forme d'un dûme atteignant la base de la fosse sédimentaire varisque. On croit pouvoir établir une relation entre la formation de granite à l'échelle régionale et locale et cette montée métamorphique.

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Herrn Prof. Dr. Dr. h. c.Erich Bederke zum 70. Geburtstag gewidmet.     

Linear mechanism of generation and intencification of internal gravity waves in the ionosphere at their interaction with a nonuniform zonal wind: 1. Model of the medium and initial dynamic equations

The specific features of the generation and intensification of internal gravity wave structures in different atmospheric-ionospheric regions, caused by zonal local nonuniform winds (shear flows), are studied. The model of the medium has been explained and an initial closed system of equations has been obtained in order to study the linear and nonlinear dynamics of internal gravity waves (IGWs) when they interact with the geomagnetic field in a dissipative ionosphere (for the D, E, and F regions).