Mudbank regime off the Kerala coast during monsoon and non-monsoon seasons

Field experiments conducted in the nearshore ocean to understand the dynamics of mudbank off Kerala, south-west coast of India, are highlighted. Real time monitoring of the nearshore ocean off Purakkad, Kerala was accomplished using pressure transducers for nearshore surface wave measurements, and current sensors for nearshore velocity measurements. Comprehensive information on the spatial structure of mudbank was obtained from aerial surveys. Extensive data collected on surface waves and currents in the nearshore ocean, indicate that the infra-gravity (IG) waves (leaky modes and trapped edge wave modes), and far infra-gravity (FIG) waves coupled with strong shoreline reflections and undertow play an important role in the dynamics associated with the mudbanks off Kerala during the monsoon season. During the non-monsoon season evidence for progressive edge waves in the infragravity frequency band, an energetic gravity wave band and a strong undertow with weak reflections was observed.     

A study on the interpretation of spontaneous potential and resistivity logs in layered aquifer sequence of Pondicherry Region,South India

Geophysical logs provide a strong mechanism for interpretation and determination of the depositional environments, facies and also help in interpretations of hydrogeologic units. Spontaneous potential (SP) and resistivity logs can be used as an indicator of textural parameters. Pondicherry region has a complicated geology and with formation of different ages. The boreholes (BH) of this region are examined for litholog, SP and resistivity from four different BH locations, viz, Ariyankuppam, Chinnaverampattinam, Thavalakuppam and Nallavadu. These locations were studied and interpreted by using the shapes of the curves to identify the depositional environments, and this was later compared with the vertical litholog profile. Comparing the variation of these logs, the lateral variation of sedimentary facies was also attempted. The average resistivity values of Ariyankuppam, Chinnaverampattinam, Thavalakuppam and Nallavadu are 42.4, 30.4, 50.4 and 28.3?Ωm, respectively. Majority of the resistivity values corresponds from fine- to medium-grained sand, clayey pebbles, fine to very coarse sand and clayey sand with lignite. Frequency of resistivity values in each BH were identified for determining the dominant representative grain size. The study has pointed out the lithological variation of the system laterally and vertically using geophysical well logs.     

Spatial distribution of uranium and vanadium in the upper phosphorite member in Eshidiyya basin, southern Jordan

Geostatistical analysis of geochemical exploration data can provide useful information for evaluating the mineralization potential of geologic bodies. The main objective of this study was to evaluate the spatial distribution of U and V over an area in the upper phosphorite member, the A0 unit, in Eshidiyya basin in southern Jordan. Drill-hole samples were analyzed. The geochemistry of the analyzed elements was assessed. The spatial variability of U and V was also assessed using semivariance analysis. Both U and V were found to exhibit a normal distribution as indicated by the constructed histograms and the calculated skewness and kurtosis coefficients. Exponential models with nugget effects were fitted to the experimental semivariograms. Ordinary kriging was performed to generate geochemical maps. The applied interpolation technique proved to be the best in producing geochemical exploration maps for both U and V in Eshidiyya phosphorites. The constructed geochemical maps helped visualize a WNW–ESE U mineralization trend in the studied phosphorites. This trend should be taken into consideration in any future exploration programs for U in south Jordan.     

Application of a square wave potentiometry technique for electroreductive sulfur removal from a thiophenic model fuel

Thiophene-containing solutions were electroreductively desulfurized by a dynamic method. Initially, cyclic voltammetry was utilized to study thiophene electroadsorption from aqueous solution onto a platinum electrode surface and also to investigate the thiophene electroreductive behavior. Then, the solution was desulfurized via a square wave potentiometry method. The objective of this study was to find the optimal conditions. In this regard, the best adsorption potential, electroreduction potential, and square wave frequency were found to be ?0.54 V, ?0.95 V, and 1 Hz, respectively. Finally, a model fuel (containing 294 part per millions thiophene) was desulfurized by the square wave potentiometry method. Gas chromatography and Fourier transform infrared spectroscopy were used to examine the feed and product solutions. Gas chromatographic measurements revealed that sulfur content decreased to 55 part per millions. Based on the acquired results, electroreductive desulfurization could be designated as an efficient superseded for the commercial hydrodesulfurization process. However, more studies must perform to overcome technical limitations of electroreductive desulfurization technique and to guarantee its reliability.