Equation of state of Fe3+-bearing phase-X

We investigated the high-pressure behaviour of Fe³⁺-bearing hydrous phase-X, (K_1.307Na_0.015)(Mg_1.504Fe _0.373 ³⁺ Al_0.053Ti _0.004 ⁴⁺ )Si₂O₇H_0.36, up to 34?GPa at room temperature by synchrotron X-ray powder diffraction. The lattice parameters behave anisotropically, with the [001] direction stiffer than [100]. In the 10^?4 to 22?GPa pressure range, the axial bulk moduli are K _0a ?=?112(3) GPa and K′?=?4, and K _0c ?=?158(2) GPa and K′?=?4, and the anisotropy of the lattice parameters is β_0c :β_0a ?=?0.71:1. The cell volumes are fitted by a second-order Birch–Murnaghan equation of state giving a bulk modulus of K ₀?=?127(1) GPa and K′?=?4 in the same pressure range. After 22?GPa, a discontinuity in volume and lattice parameters can be recognized. Sample did not become amorphous up to 34?GPa. The coupled substitution K?+?Mg?=?[]?+?Fe³⁺ has only a limited influence on the bulk modulus and structural stability of phase-X.     

Behaviour of brick infill walls strengthened with expanded steel plates

The present study was dedicated to investigate an effective, economical and convenient method for strengthening brick infill walls, i.e. the use of externally-bonded expanded steel plates. A total of 30 plastered wall assemblies were tested under monotonic diagonal loading to investigate the contribution of these plates to the load capacities, ductilities and rigidities of brick walls. The plate thickness, bolt spacing and location of the plates in the wall were the parameters of the test program. The experiments indicated that application of the plates on the outermost fine plaster layer significantly improves the diagonal load–deflection behaviour of infill walls and reducing the bolt spacing provides the strengthened walls with higher load capacity values. An analytical expression was developed for estimating the diagonal load capacities of plated brick walls. The analytical load estimates were found to be in close agreement with the experimental values.     

Cause of scale inconsistencies in DORIS time series

In this paper we analyze the scale of the DORIS (Doppler Orbitography and Radiopositioning Integrated by Satellite) solutions with respect to DORIS extension of the International Terrestrial Reference Frame (ITRF) for Precise Orbit Determination DPOD2014. The main goal is to explain the scale inconsistencies and to find the optimal solution reaching low-biased and consistent scale time series. Our analysis profits from 4 different strategies based only on the Geodetic Observatory Pecný analysis center solution, using DORIS exchange format data 2.2. A difference in the sequence of the solutions directly corresponds to one of the changes in the solution settings: data elevation dependent weighting, application of data validity indicators and application of phase center - reference point correction. We process multi-satellite and single-satellite solutions for the time period 2011.0–2017.0. Our analysis examines scale inconsistency issues in 2011/2012 and in 2015. The scale increment in 2011/2012 is explained as a result of the concurrence of changes in satellite constellation and change in the provider data validity standards for Cryosat-2 and Jason-2 satellites. The scale increment in 2015 is explained as the effect of change in the standards for phase center - reference center corrections for Saral, Jason-2 and Cryosat-2 satellites. Moreover, comparing the solutions with and without elevation dependent data downweighting using the same elevation cutoff (10°), we found a significant reduction of scale bias and scale variation applying the data downweighting. The data downweighting improved also the station positioning repeatability. We demonstrate that the solution, which is completely free from the additional data associated with observations in DORIS exchange format 2.2 and includes the data downweighting law, eventuates in a consistent scale time series with the lowest offset with respect to DPOD2014 (version 1.0) (12.7 ± 2.3 mm for 2011.0–2017.0). The only remaining scale issue is the part of 2011/2012 increment of around 5 mm, explained by a change in the DORIS satellite constellation.     

Authigenic carbonates in methane seeps from the Norwegian sea: Mineralogy, geochemistry, and genesis

Authigenic carbonates in the caldera of an Arctic (72°N) submarine mud volcano with active CH₄bearing fluid discharge are formed at the bottom surface during anaerobic microbial methane oxidation. The microbial community consists of specific methane-producing bacteria, which act as methanetrophic ones in conditions of excess methane, and sulfate reducers developing on hydrogen, which is an intermediate product of microbial CH₄ oxidation. Isotopically light carbon (δ¹³C_av =−28.9%0) of carbon dioxide produced during CH₄ oxidation is the main carbonate carbon source. Heavy oxygen isotope ratio (δ¹⁸O_av = 5%0) in carbonates is inherited from seawater sulfate. A rapid sulfate reduction (up to 12 mg S dm⁻³ day⁻¹) results in total exhausting of sulfate ion in the upper sediment layer (10 cm). Because of this, carbonates can only be formed in surface sediments near the water-bottom interface. Authigenic carbonates occurring within sediments occur do notin situ. Salinity, as well as CO ₃ ²⁻ /Ca and Mg/Ca ratios, correspond to the field of nonmagnesian calcium carbonate precipitation. Calcite is the dominant carbonate mineral in the methane seep caldera, where it occurs in the paragenetic association with barite. The radiocarbon age of carbonates is about 10000 yr.     

Evaluation and treatment of seepage problems at Chapar-Abad Dam, Iran

Engineering geological properties of the ground at the Chapar-Abad Dam were investigated in order to evaluate seepage problems and to select a proper method of water-proofing prior to construction. The dam is located to the northwest of Iran and is undergoing construction phase. The geology of the site consists of a series of Early Cambrian limestones and shales that crop out on the abutments and a valley that is filled by 60 m of alluvium deposits. The presence of thick alluvium deposits with various coefficients of permeability along the foundation demonstrates a possible seepage problem after water impoundment in the reservoir. The potential of water seepage was evaluated by the study of joint systems of the rock units, the use of numerical analysis to simulate water flow in the ground, and by conducting in-situ tests to estimate the permeability's values. Based on the obtained results and by reviewing many types of water-proofing methods regarding cost, feasibility and safety factors, the installation of a grout curtain is suggested.     

一次强冰雹过程的物理机制分析

从冰雹形成所需具备的三个条件入手,详细分析了2002年7月19日出现在郑州地区的强冰雹过程。结果表明：水汽条件、不稳定层结、外部抬升力等条件同时满足,易导致强对流性天气的产生;适宜的0℃层和-20℃层高度及大的环境风垂直切变有利于雹粒的增长;低空水平螺旋度和差动位温平流与此次强雹落区有较好的对应关系。     

Estimation of drought-related yield loss using the dynamic statistical model of crop productivity forecasting

The methodological approach is proposed to the estimation of drought-related crop yield loss based on the dynamic statistical model of crop productivity forecasting. The obtained results agree well with the total actual crop yield loss. The approach under consideration is the first stage of creation of operational assessment of expected loss.